CN105794813B - A kind of Pesticidal combination and its method for controlling agricultural pests - Google Patents
A kind of Pesticidal combination and its method for controlling agricultural pests Download PDFInfo
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- CN105794813B CN105794813B CN201410835507.9A CN201410835507A CN105794813B CN 105794813 B CN105794813 B CN 105794813B CN 201410835507 A CN201410835507 A CN 201410835507A CN 105794813 B CN105794813 B CN 105794813B
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- ichlorbenzuron
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Abstract
The present invention relates to a kind of Pesticidal combination, including fluorine worm pyrrole quinoline and d ichlorbenzuron；The Pesticidal combination is used to prevent or control the animal pest encountered in agricultural, animal health, forest, garden and Relexing device, the protection of Stored Product and health field.A kind of Pesticidal combination, including fluorine worm pyrrole quinoline and d ichlorbenzuron, the weight ratio of the fluorine worm pyrrole quinoline and d ichlorbenzuron is 1:100 to 100:1.A kind of method prevented or control agricultural pests, by the Pesticidal combination for target useful plant, target agricultural pests or its environment, the propagating materials of target useful plant.A kind of method that plant is protected to be invaded to prevent agricultural pests, carries out including being infected in plant, plant propagation material, environment by agricultural pests the Pesticidal combination before and/or after.The Pesticidal combination prevention or the purposes of control sanitary insect pest.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, including fluorine worm pyrrole quinoline and d ichlorbenzuron；More particularly to a kind of control agricultural evil
The method of worm.
Background technology
Chemical prevention is agriculturally to prevent and control an important means for pest.However, it is current, due to the kind of pest etc.
The reasons such as effect caused by class, living nature, living environment etc. is poor, repellence is strong can not be prevented and kill off effectively sometimes.Especially
It is harmful life to Lepidoptera, coleoptera, Diptera, Homoptera, Semiptera, Hymenoptera, Thysanoptera, Arachnoidea and Nematoda etc.
For object, carry out prevention and control using conventional dose and just becoming increasingly difficult.Therefore, in order to effectively prevent and kill off can not possibly prevent and kill off or
It prevents and kill off difficult harmful organism and needs to seek a kind of new means and method.
The snout moth's larva of rice, rice leaf roller, tea geometrid, beet armyworm, prodenia litura, diamondback moth, planthopper, aphid, tetranychid,
Thrips, Bemisia tabaci, Trialeurodes vaporariorum Westwood are pest common on the plants such as rice, wheat, corn, cotton, vegetables, fruit tree, tealeaves.
If corresponding measure is not carried out to pest, then the growth of agriculture plant must be influenced.
Fluorine worm pyrrole quinoline（Pyrifluquinazon）, chemical name is：（1- acetyl group -1,2,3,4- tetrahydrochysenes -3- [(3- pyrroles
Piperidinyl methyl) amino] -6- [1,2,2,2,-four fluoro- 1-（Trifluoromethyl）Ethyl] quinazoline -2- ketone；Fluorine worm pyrrole quinoline is known
, and it is described in such as EP1097932；Its molecular structural formula is（Formulas I）：
Formula（I）
Fluorine worm pyrrole quinoline is developed by Japanese pesticide company, belongs to a kind of new quinazoline（Metadiazine）Insecticides.Fluorine
Worm pyrrole quinoline is generally with water dispersible granules application, and the mechanism of action is that pest is made to stop feeding and then is died of hunger, so as to prevent plant group
It knits and is more damaged, while control the propagation of some important diseases.At present, it is mainly used for preventing vegetables, fruit tree and tealeaves
On aleyrodid, aphid and scale insect.
D ichlorbenzuron（Chlorbenzuron）, 1- neighbour's chlorobenzene formacyl -3- (4- chlorphenyls) urea, molecular formula：
C14H10N2O2Cl2, structural formula is：
Formula（II）
D ichlorbenzuron category benzoyl area kind Chitin synthesis inhibitor is insect hormone.By inhibiting insect
The activity of epidermis chitin synthetase and urine nucleosides coenzyme inhibits insect chitin synthesis that cannot normally cast off a skin so as to cause insect
It is and dead.It is applied in larval phase, the new epidermis formation of pest is made to be obstructed, delayed development or shortage hardness, it is impossible to normally cast off a skin and lead
It is lethal to die or form lopsided pupa death.Good insecticidal activity is shown as to abnormal insect, particularly lepidopterous larvae.
The activity of fluorine worm pyrrole quinoline or d ichlorbenzuron single compound is good；However, it is low or during for special pest in rate of application,
Sometimes they can not meet the high request that insecticide must reach.
Field of pest control occur a typical purpose be need reduce prevent active constituent dosage rate and
Unfavorable environment or toxicological effects are reduced or avoided, while still allows for the insecticide of effect.
Field of pest control also needs to combine the pest control agent of snap action and dauer effect, that is, combines and knock down work
Property with the insecticide of long-acting prevention.
And the repetition of single agricultural chemical compound and single administration can lead to the fast selective of pest in many cases, evil
Worm has had the active constituent drug resistance that is natural or adapting to.Therefore, field of pest control also need to contribute to prevention or
Overcome the insecticide of drug resistance.
Invention content
The invention aims to solve above-mentioned technical problem, provide a kind of Pesticidal combination, the composition pass through by
Fluorine worm pyrrole quinoline and d ichlorbenzuron are combined so that obtained composition has gain effect in control effect, and expands
Insecticidal spectrum improves snap action and long-acting to control of insect, has delayed the generation of drug resistance.
It has been found that the combination of fluorine worm pyrrole quinoline and d ichlorbenzuron has synergistic effect, and particularly suitable for preventing agricultural pests.
The technical solution adopted by the present invention to solve the technical problems is：
A kind of Pesticidal combination, including fluorine worm pyrrole quinoline and d ichlorbenzuron, the fluorine worm pyrrole quinoline and d ichlorbenzuron are by weight ratio
1:100-100:1。
As a further improvement on the present invention, the fluorine worm pyrrole quinoline and d ichlorbenzuron are 1 by weight ratio:50-50:1.
As a further improvement on the present invention, the fluorine worm pyrrole quinoline and d ichlorbenzuron are 1 by weight ratio:25-25:1.
As a further improvement on the present invention, the fluorine worm pyrrole quinoline and d ichlorbenzuron are 1 by weight ratio:10-10:1.
A kind of Pesticidal combination, including fluorine worm pyrrole quinoline and d ichlorbenzuron, the weight of the fluorine worm pyrrole quinoline and d ichlorbenzuron accounts in total
The 1%-90% of the composition by weight.
A kind of Pesticidal combination, including fluorine worm pyrrole quinoline and d ichlorbenzuron, the fluorine worm pyrrole quinoline and d ichlorbenzuron account for the combination altogether
The 10%-80% of object by weight.
A kind of Pesticidal combination, including fluorine worm pyrrole quinoline and d ichlorbenzuron, the fluorine worm pyrrole quinoline and d ichlorbenzuron account for described group in total
Close the 20%-60% of object by weight.
Pesticidal combination according to the present invention, also comprising surfactant and/or extender.
Pesticidal combination according to the present invention, the Pesticidal combination can be configured to the arbitrary dosage form agriculturally allowed.
Pesticidal combination according to the present invention, the dosage form of the Pesticidal combination is missible oil, suspending agent, seed coat agent, moisture
Shot agent, suspension emulsion, squeezes out granule, is coated granule, smoke agent, aqueous emulsion, microcapsule suspending agent, ultralow wettable powder
Volume liquids, bait grain.
On the other hand, the present invention also provides a kind of Pesticidal combinations by the present invention for preventing or controlling agricultural pests
Purposes.
The present invention provides a kind of Pesticidal combinations by the present invention for preventing or controlling invasion plant or plant propagation
The purposes of the agricultural pests of material.
The plant propagation material is seedling, rhizome, garden seedling, cutting or seed.
The agricultural pests are scale insect, the snout moth's larva of rice, rice leaf roller, tea geometrid, beet armyworm, prodenia litura, small
Diamond-back moth, planthopper, aphid, thrips, Bemisia tabaci, Trialeurodes vaporariorum Westwood, tea lesser leafhopper, red spider, cabbage caterpillar, bollworm.
On the other hand, the present invention also provides a kind of method prevented or control agricultural pests, by the desinsection group of the present invention
It closes object and acts on target agricultural pests and/or its environment.
A kind of method that plant is protected to be invaded to prevent agricultural pests, the Insecticidal combinations including making fluorine-containing worm pyrrole quinoline and d ichlorbenzuron
Object is contacted with target useful plant, target agricultural pests and/or its environment, the propagating materials of target useful plant.
It is a kind of to protect method invade to prevent agricultural pests of plant, including separating, sequentially or simultaneously using fluorine worm pyrrole quinoline and
D ichlorbenzuron.
A kind of method prevented or control agricultural pests, wherein fluorine worm pyrrole quinoline and d ichlorbenzuron is individually formulated composition
Form.
It is a kind of to protect method invade to prevent agricultural pests of plant, including by the Pesticidal combination of the present invention in plant, plant
Object propagating materials such as seed, environment insect infestation carry out before and/or after.
It is a kind of protect vegetable seeds method, include make seed prior to seeding and/or vernalization later with a effective amount of
The Pesticidal combination contact of invention.
The Pesticidal combination of the present invention is used to handle the purposes of seed.
On the other hand, the present invention also provides a kind of Pesticidal combination, for preventing or controlling sanitary insect pest
Purposes.The sanitary insect pest is red fire ant, termite, mosquito, fly.
The present invention also provides a kind of method prevented or control sanitary insect pest, including the Pesticidal combination of the present invention is applied
With to target sanitary insect pest and/or its environment.
The present invention has the following by the benefit that the two compounds：
A, it is apparent to pest synergistic effect, the dosage of two compositions can be reduced；
B, the two is mixed, solves the problems, such as, to pest lasting period and quick-acting, so as to reduce times for spraying, to reduce people
Work cost；
C, the generation of resistance has been delayed：The two mechanism of action and the mode of action are entirely different, combination after have tag, stomach
The effects that malicious, so as to which pest be made to be more easy to be killed, so as to delay the generation of resistance；
Specific embodiment
Present invention discover that：The additive property of insecticidal spectrum can not only be brought to improve fluorine worm pyrrole quinoline and d ichlorbenzuron combination, but also
Realize amazing synergistic effect.
Term " synergistic effect " used herein refers to inventive compound combination insecticidal effect and is more than each active constituent
The sum of effect, in other words, effect is superadditivity.
The present invention provides a kind of Pesticidal combinations comprising fluorine worm pyrrole quinoline and d ichlorbenzuron.
The present invention provides a kind of Pesticidal combinations, and wherein fluorine worm pyrrole quinoline and d ichlorbenzuron weight proportion is 1:100-100:1,
It is preferred that 1:50-50:1, further preferably 1:25-25:1, more preferable 1:10-10:1.
The total amount of active constituent can be selected according to material elements in the present composition, to realize desired work
With.The factor is for example, dosage form, object to be administered, method of administration etc..Fluorine worm pyrrole quinoline and d ichlorbenzuron account in total the composition with
1% to the 90% of weight meter, preferably 10% to 80%, more preferable 20% to 60%.
The composition of the present invention is optionally including agronomically acceptable surfactant or extender.
According to the present invention, term " filler ", which refers to, can be combined with reactive compound or combines to make it easier for being administered to
Object（Such as plant, crop or careless class）Natural or synthetic organic or inorganic compound.Therefore, the carrier is preferably lazy
Property, it at least should be agronomically acceptable.The filler can be solid or liquid.
The liquid filler for preparing the present invention is suitble to include water, alcohols（Such as methanol, ethyl alcohol）, ketone（Such as acetone, first
Base ethyl ketone）, it is aromatic hydrocarbon（Such as benzene,toluene,xylene, ethylbenzene, methyl naphthalene）, aliphatic hydrocarbon（Such as n-hexane, ring
Hexane, kerosene）, esters（Such as ethyl acetate, butyl acetate）, nitrile（Such as acetonitrile, isobutyronitrile）, ethers（For example, Er Evil
Alkane, diisopropyl ether）, sour amides（Such as N, N- dimethylformamide, dimethylacetylamide>And halogenated hydrocarbons（Such as two
Chloroethanes, trichloro ethylene, carbon tetrachloride）Deng.
The solid-filling agent for being suitble to the present invention can be diatomite, aluminum magnesium silicate, atlapulgite, kaolin, clay, stone
Cream, bentonite, white carbon, precipitated calcium carbonate, lime stone, sawdust, cornstarch, soluble starch etc..
To make the emulsification of active ingredient compound, dispersion, solubilized and/or wetting that can use surfactant example
Fatty alcohol polyoxyethylene ether, polyoxyethylene alkylaryl ether, polyoxyethylene higher fatty acid esters, polyoxyethylene alcohol can such as be enumerated
Or the branch shape copolymerization of the phosphate of phenol, the aliphatic ester of polyalcohol, naphthalene sulfonic acid polymer, lignosulfonates, macromolecule comb shape
Object, butyl naphthalene sulfonate, alkylaryl sulfonates, sodium alkylsulfosuccinates, grease, fatty alcohol and ethylene oxide condensate,
Polyacrylate, the protein hydrolysate of alkyltaurate.Suitable oligosaccharide object or polymer, such as based on individual second
Alkene monomer, acrylic acid, polyoxyethylene and/or polyoxypropylene or its with for example（It is polynary）Alcohol or（It is polynary）The combination of amine.
To make the dispersion of active ingredient compound, stabilizing, attachment, such as xanthans, aluminium-magnesium silicate, gelatin, shallow lake can be used
Powder, methyl cellulose, polyvinyl alcohol, polyvinyl acetate and natural phospholipid（Such as cephalin and lecithin）And synthetic phospholipid,
The adjuvants such as bentonite, sodium lignin sulfonate.
The optional spent glycol of antifreezing agent, propylene glycol, glycerine, sorbierite.
Deflocculant as suspension product can use the auxiliary such as naphthalene sulfonic acid polymer, polymeric phosphate
Agent.Organic silicon defoamer can be used as antifoaming agent.
To improve the mobility of solid product, the adjuvant such as paraffin, stearate, alkylphosphonate can be used.
The colorant that can be used, such as inorganic pigment, such as iron oxide, titanium oxide and Prussian blue；And organic pigment/
Dyestuff：Alizarin dyes, azo dyes and metallized phthalocyanine dye；And trace element, such as molysite, manganese salt, boron salt, mantoquita, cobalt
Salt, molybdenum salt and zinc salt.
Optionally, also may include other annexing ingredients, for example, protecting colloid, adhesive, thickener, thixotropic agent, bleeding agent,
Stabilizer, screening agent.
The present invention Pesticidal combination dosage form be：Aerosol, suspending agent, microcapsulated granule, granula subtilis, flowable concentrate,
Ready to use solution agent, pulvis, aqueous emulsion, oil emu, fine granule, oil dispersed pulvis, the miscible mobility concentrate of oil, oily miscible fluid
Body, foaming agent, paste, suspending concentrate, suspension emulsion, solubility concentrate, soluble powder, granule, water-soluble granular and/
Or in tablet, water solube powder, wettable powder, the natural or synthetic material impregnated through reactive compound, polymer material
Microcapsules and water-dispersible granule.
In preferred embodiments, the agricultural insecticide composition for suspending agent, water dispersible granules, wettable powder,
Suspension emulsion, seed coat agent, wettable powder, squeezes out granule, coated granule, smoke agent, aqueous emulsion, microcapsule suspending agent at missible oil.
The reactive compound can be mixed to prepare with conventional additives by the preparation of the present invention by known way.
The conventional additives such as conventional extender and solvent or diluent, emulsifier, dispersant, and/or adhesive or fixative,
Wetting agent, waterproofing agent, if it is desired, drier and colorant, stabilizer, pigment, antifoaming agent, preservative, increasing can also be included
Thick dose, water and other processing aids.
These compositions not only include can be by suitable equipment as sprayed or dusting equipment is immediately suitable for pending
Object, and be additionally included in be applied to before object and need the concentration commercial composition being diluted.
The Pesticidal combination of the present invention can be used with itself or can be according to its respective physically and/or chemically property
It is used with its dosage form or use form prepared therefrom.
The Pesticidal combination of the present invention can also be applied with other active ingredient combinations, and other active constituents for example kill
Epiphyte pharmaceutical, bactericide, attractant, insecticide, acaricide, nematicide, growth regulator, herbicide, safener, fertilizer
Or semiochemical etc..
The present invention also provides a kind of Pesticidal combinations by the present invention for preventing or controlling agricultural pests, sanitary insect pest
Purposes.
The present invention also provides a kind of Pesticidal combinations by the present invention for preventing or controlling invasion plant or plant numerous
Grow the purposes of the agricultural pests of material.
The present invention also provides the purposes that a kind of Pesticidal combination by the present invention is used to prevent or control sanitary insect pest.
The Pesticidal combination of the present invention is suitable for prevention in agricultural, gardening, animal husbandry, forestry, garden and Relexing device, storage
Animal pest, particularly insect, arthropod, parasitic worm, nematode and software are encountered in the protection of Tibetan product and health field
Animal.The Pesticidal combination of the present invention shows to plant good tolerance, to the hypotoxicity of warm blooded species and good simultaneously
Environmental compatibility.It is active to normal sensitive and resistance kind, it is active to all or special stage of development.Above-mentioned evil
Worm includes：
From Isopoda, such as damp worm（Oniscusaselluse）, pillworm（Armadillidiumvulgare）, and
Spot pillworm（Porcellioscaber）.
From Diplopoda, such as Blaniuusguttulatus.
From chilopoda, for example, centipede（Geophiluscarpophagus）With common house centipede dragonfly（Scutigera spp.）.
From Symphyla, such as clean symphilid（Scutigerella immaculate）.
From Thysanoptera, such as silverfiss（Lepismasaccharina）.
From Collembola, such as Onychiurus arcticus（Onychiurusarmatus）.
From Orthoptera, such as house cricket found in a kitchen（Achetadomesticus）, Gryllotalpa spp（Gryllotalpa spp.）, the torrid zone
Migratory locusts（Locustamigratoriamigratorioides）, long volume bears locust category（Melanoplus spp.）, and desert locust
（Schistocercagregaria）.
From Blattaria, such as oriental cockroach（Blattaorientalis）, American cockroach（Periplaneta
Americana）, leucophaea maderae（Leucophaeamaderae）, Groton bug（Blattellagermanica）.
From Dermaptera, such as European earwig（Forficulaauricularia）.
From Isoptera, such as Reticulitermes.
From Anoplura, such as body louse（Pediculushumanuscorporis）, blind pediculus and long volume Pediculus, poultry louse
Belong to, Damalinia.
From Thysanoptera, such as greenhouse Hercinothrips spp（Hercinothripsfemoralis）, cotton thrips
（Thripstabaci）, Thripspalmi and Frankliniellaaccidentalis.
From Heteroptera, such as Eurygasterspp category, middle red cotton bug（Dysdercusintermedius）, beet plan lace bug
（Piesmaquadrata）, the smelly stinkbug in temperate zone（Cimexlectularius）, red abdomen hunts stinkbug（Rhodniusprolixus）And cone
Stinkbug category.
From Homoptera, such as wild cabbage aleyrodid（Aleurodesbrassicae）, Bemisia tabaci（Bemisiatabaci）,
Trialeurodes vaporariorum Westwood（Trialeurodesvaporariorum）, cotten aphid（ Aphis gossypii）, brevicoryne brassicae
（Brevicorynebrassicae）, the hidden knurl volume aphid of tea deer（Cryptomyzusribis）, black bean aphid
（Brevicorynebrassicae）, apple aphid（Aphispomi）, apple aphid（Eriosomalanigerum）, the big tail of peach
Aphid（Hyalopterusarundinis）, grape phylloxera（Phylloxeravastatrix）, Pemphigus, grain aphid
(Macrosiphumavenae), knurl volume Aphis, hops knurl volume aphid (Phorodo), rice green leafhopper
(Nephotettixcincticeps), brown apricot scale (Lecanium
Corni), olive helmet (Saissetiaoleae), rice small brown rice planthopper (Laodelphaxstriatellus) are brown
Rice lice (Nilaparvatalugens), California red scale (Aonidiel1a aurantii), oleander circle a red-spotted lizard
(Aspidiotushederae), mealybug category and Psylla spp.
From Lepidoptera, such as pink bollworm (Pectinophoragossypiella), loose looper
(Bupaluspiniarius), winter geometrid moth (Chemimatobiabrumata), Lithoclletisblancardela, cherry
Peach ermine moth（Hyponomeutapadella）, diamondback moth (Plutellaxylostella), tent caterpillar
(Malacosomaneustria), pornography and drug moth (Euproctischrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid
(Bucculatrixthurberiella), tangerine leaf miner (Phyllocnistiscitrella), Agrotis, cutworm
Belong to, brown Noctua, earias insulana (Eariasinsulana), Noctua, lopper worm (Mamestrabrassicae),
Small noctuid (Panolisflammea), Noctua, cabbage looper (Trichoplusiani), carpocapsa pononella
(Carpocapsapomonella), Pier, snout moth's larva category（Pyraustlla), bag casemaking clothes moth (Tineolabisselliella),
Etting moth (TineaPellionella), brown oecophorid (Hofmannophilapseudospretella), yellow tail leaf roller
(Cacoeciapodana), choristoneura fumigerana (Choristoneurafumiferana), grape stay moth-eaten moth
(Clysiaambiguella), tea yellow leaf curl moth (Homonamagnanima), the green leaf roller of oak (Tortrixviridana)
, roll up snout moth's larva category, Oulema oryzae (Oulemaoryzae).
From coleoptera, such as furniture death watch beetle (Anobiumpunctatum), lesser grain borer (Rhizoperthadominica)
, Bruchidiusobtectus, bean weevil (Acanthoscelidesobtectus), house longhorn beetle
(Hylotrupesbajulus), alder purple flea beetle (Agelasticaalni), colorado potato bug
(Leptinotarsadecemlineata), horseradish ape is chrysomelid (Phaedoncochleariae), chrysomelid category, rape orchid flea beetle
(Psylliodeschrysocephala), mexican bean ladybird (Epi1achna varivestis), hidden wing first category saw chest
Ostomatid (Oryzaephilussurinamensis), weevil category, Sitophilus, vine black ear as
(Otiorrhynchussulcatus), banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil
(Ceuthorrhynchusassimilis), alfalfa weevil (Hyperapostica), khapra beetle category, spot khapra beetle category, circle khapra beetle
Belong to, hair moth category, powder moth category, pollen beetle (Meligethesaeneus), spider
First category, golden yellow ptinid (Niptushololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium,
Cabot's Tragopan (Tenebriomolitor), click beetle category, acupuncture needle Eimeria, angle cockchafer (Melolonthamelolontha), June are golden
Tortoise (Amphimallonsolstitialis), brown New Zealand's rib wing gill cockchafer (Costelytra
) and Lissorhoptrusoryzophilus (Lissorhoptrusoryzophilus) zealandica.
From Hymenoptera, such as Neodiprion spp category, tenthredinidae, field ant category, MonomoriumMayr (Monomoriumpharaonis) and
Vespa.
From Diptera, such as Aedes, spot Anopheles, Culex, drosophila yellow gorilla (Drosophila
Melanogaster), Musca, male servant's fly category, calliphora erythrocephala (Calliphoraerythrocephala), lucilia sericata category,
Carysomyia, cuterbrid category, Gasterophilus, Hippobosca, chela fly category, nose fly category, Hypoderma, Pituophis, march fly category
（Bibiohortulanus）, Sweden's straw rope (Oscinella frit), wheat fly category, beet fly
(Pegomyiahyoscyami), Mediterranean fruitfly (Ceratitiscapitata), dacus oleae (Dacusoleae) and
European daddy-longlegs (Tipulapaludosa), Hylemyia and Hippelates.
From Siphonaptera, such as Xenopsyllacheopis (Xenopsyllacheopis) and angle leaf sage mouse.
From Arachnoidea, such as scorpion (Scorpio maurus), black widow (Latrodectusmactans),
Acarus siro (Acarussiro), hidden category, blunt port belong to, Dermanyssus gallinae (Dermanyssysgallinae), tea deer goitre mite
(Eriophyesribis), citrus rust mite (Phyllocoptrutaoleivora), Boophilus, carrapato category, Amblyomma, glass eye tick
Belong to, Isodesspp, Acarus tritici category, ginger mite category, Sarcoptesspp, the compacted category of line, Bryobia praetiosa (Bryobiapraetiosa) is red spider category, red
The compacted category of leaf, sharp tenthredinidae, short whisker Acarapis
Parasitic plant nematode includes such as Pratylenchus, Radopholus similis Throne (Radopholussimilis), raising
Grass blade nematode (Ditylenchusdipsaci), Tylenchulus Semipenetrans (Tylenchulussemipenetrans), golden nematode
Belong to, ball Heterodera, Meloidogyne, Aphelenchoides, minute hand Turbatrix, Xiphinema and burr Turbatrix, remote spring dragonfly
Belong to.
The Pesticidal combination of the present invention specifically includes following pest especially suitable for preventing " biting " pest, these pests：
From Lepidoptera, such as pink bollworm (Pectinophoragossypiella), loose looper
(Bupaluspiniarius), winter geometrid moth (Cheimatobiabrumata), Lithocolletis blancardel1a,
Cherry ermine moth (Hyponomeutapadella), diamondback moth (Plutellaxylostella), tent caterpillar
(Malacosomaneustria), pornography and drug moth (Euproctischrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid
(Bucculatrixthurberlella), tangerine leaf miner (Phyllocnistiscitrella), Agrotis, cutworm
Belong to, brown Noctua, Egyptian complete just brill (Eariasinsulana), Noctua, lopper worm (Mamestrabrassicae),
Small noctuid (Panolisflammea), Noctua, powder pattern moth (Trichoplusiani), carpocapsa pononella
(Carpocapsapomonella), Pier, snout moth's larva category, Pyraustanubilalis, Anagasta kuehniella
(Ephestiakuehniella), rheum officinale snout moth's larva (Gal1eriamellonella), bag casemaking clothes moth (Tineolabisselliella)
, etting moth (Tineapellionella), brown oecophorid (Hofmannophilapseudospretella), yellow tail leaf roller
(Cacoeciapodana), Capua reticulana, choristoneura fumigerana (Choristoneurafumiferana), grape
Slow-witted moth moth (Clysiaambiguella), tea yellow leaf curl moth (Homonamagnanima), the green leaf roller of oak
(Tortrixviridana), snout moth's larva category, Oulema oryzae (Oulemaoryzae) are rolled up.
From coleoptera, such as furniture death watch beetle (Anobiumpunctatum), lesser grain borer (Rhizoperthadominica)
, Bruchidiusobtectus, bean weevil (Acanthoscelidesobtectus), house longhorn beetle
(Hylotrupesbajulus), alder purple flea beetle (Agelasticaalni), colorado potato bug
(Leptinotarsadecemlineata), horseradish ape is chrysomelid (Phaedoncochleariae), chrysomelid category, rape orchid flea beetle
(Psylliodeschrysocephala), mexican bean ladybird (Epilachnavarivestis), hidden wing first category saw chest paddy
It steals (Oryzaephilussurinamensis), weevil category, Sitophilus, vine black ear beak (Otiorrhynchussulcatus)
When, banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil (Ceuthorrhynchusassimilis)
, alfalfa weevil (Hyperapostica), khapra beetle category, spot khapra beetle category, Anthrenus, hair moth category, powder moth category, rape liquid distilled from honeysuckle flowers or lotus leaves tail
First (Meligethesaeneus), spider
First category, golden yellow ptinid (Niptushololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium,
Cabot's Tragopan (Tenebriomolitor), click beetle category, acupuncture needle Eimeria, angle cockchafer (Melolonthamelolontha), June
Chafer (Amphimallonsolstitialis), brown New Zealand's rib wing gill cockchafer, angle cockchafer
(Costelytrazealandica) and Lissorhoptrusoryzophilus (Lissorhoptrusoryzophilus).
The Pesticidal combination of the present invention is also particularly suitable prevention " sucking " pest, these pests specifically include following evil
Worm：
From Homoptera, such as wild cabbage aleyrodid (Aleurodesbrassicae), Bemisia tabaci (Bemisiatabaci),
Trialeurodes vaporariorum Westwood (Trialeurodesvaporariorum), cotten aphid (Aphis gossypii), brevicoryne brassicae
(Brevicorynebrassicae), the hidden knurl volume aphid (Cryptomyzusribis) of tea deer, black bean aphid (Aphis fabae),
Apple aphid (Aphispomi), apple aphid (Eriosomalanigerum), mealy plum aphid (Hyalopterusarundinis)
, grape phylloxera (Phylloxeravastatrix), goitre cotten aphid category, grain aphid (Macrosiphumavenae), knurl volume
Aphis, hops knurl volume aphid (Phorodonhumuli), grain Rhopalosiphum spp (Rhopalosiphumpadi), leafhopper category
（Cicadellidae）, rice green leafhopper (Nephotettixcincticeps), brown apricot scale (Lecaniumcorni), olive
Helmet (Saissetiaoleae), rice small brown rice planthopper (Laodelphaxstriatellus), brown back rice plant hopper
(Nilaparvatalugens), California red scale (Aonidiellaaurantii), oleander circle a red-spotted lizard
(Aspidiotushederae), mealybug category and Psylla spp.
Preferably, the Pesticidal combination is used to prevent scale insect, the snout moth's larva of rice, rice leaf roller, tea geometrid, beet night
Moth, prodenia litura, diamondback moth, planthopper, aphid, thrips, Bemisia tabaci, Trialeurodes vaporariorum Westwood, tea lesser leafhopper, red spider, dark greyish green
Worm, bollworm.
Preferably, Pesticidal combination of the invention is suitable for the sanitary insect pests such as prevention termite, red fire ant, mosquito, fly.
It on the other hand, will be of the invention the present invention also provides a kind of prevention or control agricultural pests, the method for sanitary insect pest
Pesticidal combination act on target agricultural pests, sanitary insect pest and/or its environment.
In order to fight non-crop pests such as ant, termite, wasp, fly, mosquito, cricket, locust or cockroach, by the present invention's
Pesticidal combination is configured to bait preparation.
Bait can be liquid, solid or semisolid preparation.There should be enough suctions for the bait in Pesticidal combination
Gravitation eats the Pesticidal combination to stimulate the insect of ant, termite, wasp, fly, mosquito, cockroach etc..The attractant can be with
Selected from feeding stimulants known to this field or puppet and/or sex pheromone.
Typical content for the active constituent of bait composition is 0.0001-15%, it is generally desirable to which 0.001-5% is activated
Close object.Also may include in the Pesticidal combination solvent of other additives such as active material, flavoring agent, preservative, dyestuff or
Bitters.
The composition of the present invention is used via soil application.Soil application for be used to fighting ant, termite, cricket or
The purposes of cockroach is particularly advantageous.
The present invention also provides a kind of method that plant is protected to be invaded to prevent agricultural pests, sanitary insect pest, including making the present invention
Pesticidal combination contacted with target useful plant, target pest and/or its environment, the propagating materials of target useful plant.
The meaning of plant herein is interpreted as all plants and plant population.Plant is can be by conventional breeding and excellent
Choosing method can pass through biotechnology and genetic engineering method or the plant that can be obtained by the combination of these methods.The plant
Including genetically modified plants, also include that (plant breeders'rights) protection can be weighed by plant breeder or be not protected by it
Plant variety.The meaning of plant parts is interpreted as plant part all above and below the ground and organ, as branch,
Leaf, Hua Hegen, the example that can be mentioned that is leaf, needle, leaf, stem, dry, flower, fructification, fruit and seed, Yi Jigen, stem tuber and root
Stem.The plant parts also include harvested material and asexual with generative propagation object, such as transplant, stem tuber, rhizome, sprout and seed.
It can be used for useful plant that is that the present invention protects and applying Pesticidal combination according to the present invention to include：Cereal
Plant such as wheat, oat, barley, triticale and rye and corn, jowar, rice；Beet, such as sugar beet or fodder beet；
Fruit, such as apple class fruit, drupe, tree nut or soft water fruit, such as apple, pears, plum, peach, banana, almond, walnut, are opened
Heart fruit, cherry or berry, such as strawberry or blackberry, blueberry；Legume such as Kidney bean, pea or soybean；Oily plant, such as rape, leaf mustard, olive
Olive, sunflower, castor-oil plant, cocoa chocolate tree or peanut；Cucurbitaceous plant, such as watermelon, pumpkin, cucurbita pepo, cucumber or muskmelon；Fiber is planted
Object, such as cotton, flax, hemp or jute；Citrus fruit, such as orange, lemon, grape fruit or orange；Vegetables such as spinach, lettuce
Lettuce, asparagus, cabbage, carrot, onion, tomato, hot red pepper, potato or bell pepper；Lauraceae, such as avocado, Chinese cassia tree or camphor；With
And tobacco, nut, coffee, eggplant, sugarcane, tealeaves, pepper, grapevine, hops, Plantaginaceae, lactiferous plant, lawn, grass
Level ground, fodder grasses and ornamental plant, such as Petunia, heartsease and balsamine；And shrub, broad leaf tree and aithullium,
Such as coniferous tree.
The processing of plant is directly carried out or with conventional treatment method by acting on it with the Pesticidal combination of the present invention
Environment, habitat or storage areas and carry out, the conventional treatment method is for example impregnated, is poured, being sprayed, atomizing, is broadcasted sowing, is sprayed
Powder, mist formation, broadcast sowing, foam, coating, being coated with, the modes such as trickle irrigation are applied to the blade of plant（Foliage applying）, application can be adjusted
Frequency and dosage, adapt it to the degree encroached on by the agricultural pests.
The Pesticidal combination of the present invention is also suitable for propagating materials such as seed, fruit, stem tuber or the kernel of protection plant
Or plant cutting is not encroached on by harmful organism particularly insect and acarid.It is most of that crop plants are made as caused by pest
Into damage during the storage of seeds, seed be sown into after soil and plant germination during with infected after firm rudiment
When just have occurred.The stage is particularly critical, because the root and bud of the plant being growing are especially sensitive, even the injury of very little
It can result in the death of whole plant.Therefore, it protects seed by using suitable composition and just has in the plant of rudiment
There is crucial importance.
The method of the protection seed of the present invention, without in addition being protected after planting or after plant emergence using crop protection agents
Protect seed and just in the plant of rudiment.Meanwhile the one side of Pesticidal combination of the invention can be to seed and just in rudiment
Plant provides best protection in order to avoid the invasion of pest, while will not injure plant sheet due to used reactive compound again
Body.Seeds self is not only protected with the Pesticidal combination processing seed of the present invention, but also protect growing up to after emergence
Plant is from pest attacks.It can save and crop is handled immediately in the short period so at seeding time or hereafter.
The medicament of the method for seed treatment, such as can there are, diluent liquid or solid-like or without diluting directly general
Seed is immersed in the method that medicament is made to be impregnated with seed in liquid condition solution, is blended in solid chemicals or liquid preparation and seed
Together, the methods of processing of powder clothing makes the method for the surface of the seed attachment medicament, sprayed near seed while plantation is carried out.Into
The seed of the row seed treatment refers to the plant at the cultivation initial stage for plant propagation, such as can there are, except seed,
The plant nourished and generated of napiform root, stem tuber, potato kind, strain bud, bulb or cultivation of transplanting.In order to handle plant propagation material
Particularly seed can also impregnate stem tuber or grain in succession or by using having combined by using the liquid preparation of each active constituent
Wet or dry preparation coating, so as to which active constituent is administered on seed（Coating）.
The Pesticidal combination of the present invention is applied to seed with itself or suitable dosage form.It is preferred that seed is in stable state
It is lower to be handled, so that processing does not cause any damage.To the processing of seed usually can be between harvesting and sowing it is any
Time carries out.It has to be noticed that being applied to the amount of the present composition of seed and/or other additions usually during seed treatment
The amount selected as of agent does not interfere with the germination of seed or will not damage gained plant.
Term " plant propagation material " is interpreted as referring to all plant parts for having fertility, such as seed, Yi Jizhi
Physical property material such as cuttage item or stem tuber（Such as potato）.Therefore, plant part used herein includes plant propagation
Material.It is mentioned that such as seed（In the narrow sense）, root, fruit, stem tuber, bulb, rhizome and plant part.It treats from soil
The germination plant and effective plant inhibited after germination or after emergence is also what is be related to.Young plant can pass through dipping before transplantation
Whole or Local treatment are carried out to be protected.
Plant part and the plant organ then grown are by any of the plant propagation material such as plant of seed generation
Part.Plant part, plant organ and plant can also be benefited to be planted by the way that composition is applied to plant propagation material protection
Object is from plant disease.Certain plants part and certain plant organs then grown can also regard plant propagation material as,
Itself can be applied with composition（Or processing）；So as to the plant generated by processed plant part and processed plant organ
Object, other plant part and other plant organs can also benefit from by by composition be applied to certain plants part and
Certain plants Organoprotective plant is from insect pest of the plant.
The Pesticidal combination of the present invention is for processing plant propagation material, particularly rice, rape, cotton, wheat, big
Wheat, soybean, corn, peanut seed be particularly advantageous.
A kind of method for protecting seed, includes making seed prior to seeding and/or vernalization sheet with cooperative effective quantity later
The Pesticidal combination contact of invention.
The purposes of the Pesticidal combination processing seed of the present invention.
The Pesticidal combination of the present invention can be also applied to environment, habitat or the storage areas of plant growth.Plant growth
Environment, habitat be the supporter for referring to that crops is made to take root, are grown, such as：Soil, water etc., specific raw material can be with
Use such as sand, float stone, vermiculite, diatomite, agar-agar, gelling material, polymer substance, asbestos, sawdust, bark etc..It is preferred that
Soil.
The method of medicament is applied into soil, such as liquid preparation is diluted in water or do not diluted and is directly applied to plant
Granule is disseminated to the side in the root of plant or the rice seedling bed of seedling by the methods of in the root of body or the rice seedling bed of seedling
Method has the method that pulvis, water dispersible granules etc. are sprayed in soil prior to seeding and are integrally mixed with soil, before sowing or plants
It will be sprayed in implantation hole, seed furrow after pulvis, water-dispersible grain dilution agent before kind plant, carrying out method of sowing etc..
The present invention also provides a kind of method that plant is protected to be invaded to prevent agricultural pests, including separating, sequentially or simultaneously applying
With fluorine worm pyrrole quinoline and d ichlorbenzuron.In the case of separate administration, sequence does not usually influence the result of control measure.
It is a kind of to protect method invade to prevent agricultural pests of plant, including by the Pesticidal combination of the present invention in plant, plant
Object propagating materials, environment insect infestation carry out before and/or after.
The Pesticidal combination of the present invention by the reactive compound of insecticidal effective dose handle agricultural pests or it is to be protected to prevent
Plant, the propagulum such as seed, environment of pest attacks and directly or use in the form of compositions.Using can plant,
Plant propagation material, environment insect infestation carry out in the past and later.
The Pesticidal combination of the present invention is common and advantageous usually with the application of following dosage：
For leaf portion processing：0.1-10000 g/ha, preferably 10-1000 g/ha, more preferable 20-300 g/ha；For
For dipping or application of instiling, the dosage can also even reduce, particularly when using inert base such as asbestos or perlite
Shi Shi；
For seed treatment：2-200g/100kg seeds, preferably 3-150g/100kg seeds；
For soil treatment：0.1-10000 g/ha, preferably 1-5000 g/ha.
Above-mentioned dosage is only general exemplary dose, and those skilled in the art can be according to practical feelings when reality is applied
Condition and needs adjust rate of application especially in accordance with the property and insect pest situation of pending plant or plant.
On the other hand, processing of the invention can also generate following super additive effect：Improve plant growth, improve to high temperature
Or low temperature tolerance, improve to arid or to the tolerance of water or soil salt content, improve Flowering quality, make harvesting simpler
Just, accelerate ripe, raising harvesting yield, improve the quality of harvested products and/or improve its nutritive value, improve harvested products
Bin stability and/or its processing performance.
It should be pointed out that the present invention any embodiment or embodiment any technical characteristic can independently with this
Any other embodiment of invention is combined with each other.That is, one or more technologies of any embodiment of the present invention
Feature can all be reconfigured with any other technical characteristic.Thus the technical characteristic that technical characteristic is reconfigured and formed is disclosed in
Herein, as especially being recorded herein it.
Specific embodiment
Below with reference to embodiment, the invention will be further elaborated.
Example of formulations
1 missible oil of embodiment
By said components mix to the liquid of transparent and homogeneous to get to the present invention cream preparation.
2 wettable powder of embodiment
Active constituent, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the wettable powder of the present invention
3 aqueous emulsion of embodiment
Active compound, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase；Water-soluble component and water are mixed to prepare
Water phase；Under high velocity agitation, it is oil phase is mixed with water, the aqueous emulsion of the present invention is made.
4 water dispersible granules of embodiment
Active constituent, dispersant, wetting agent, disintegrant and filler are uniformly mixed in the ratio of formula, by air-flow powder
Wettable powder is broken into, adds a certain amount of water mixing extruder grain.The water-dispersible grain of the present invention is obtained after dry sieve
Agent.
5 water dispersible granules of embodiment
Active constituent, dispersant, wetting agent, disintegrant and filler are uniformly mixed in the ratio of formula, by air-flow powder
Wettable powder is broken into, adds a certain amount of water mixing extruder grain.The water-dispersible grain of the present invention is obtained after dry sieve
Agent.
6 wettable powder of embodiment
Active constituent, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the wettable powder of the present invention.
7 suspension emulsion of embodiment
Fluorine worm pyrrole quinoline is dissolved in SOLVESSO TMIn 100, ethoxylated castor oil is added in, obtains missible oil；By d ichlorbenzuron,
Fatty alcohol polyoxyethylene ether sulfosuccinic acid monoesters disodium, MODIFIED LIGNOSULPHONATE, xanthans, bentonite, glycerine, water etc.
Above-mentioned each component mixes in proportion, and through being sanded, is prepared into the suspending agent containing d ichlorbenzuron.The oil phase of fluorine-containing worm pyrrole quinoline is added
Enter into the suspending agent containing d ichlorbenzuron, obtain suspension emulsion.
8 aqueous emulsion of embodiment
Oil phase：
Water phase：
Fluorine worm pyrrole quinoline and d ichlorbenzuron are dissolved in methyl oleate, polystyrene is added in and obtains oil phase；According in formula
Component is uniformly mixed to obtain water phase；Oil phase addition water phase is obtained into aqueous emulsion under stiring.
9 wettable powder of embodiment
Said combination is mixed, and grind in proportion, crushes, is prepared into wettable powder.
10 coated granule of embodiment
It in a mixer, will be on levigate active constituent even spread to the carrier soaked by polyethylene glycol.By this method
Dust-free coated granules agent can be obtained.
11 wettable powder of embodiment
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
Embodiment 12 squeezes out granule
Active component is mixed and ground with auxiliary agent, mixture is moistened with water.The mixture is squeezed out, then in air stream
Middle drying.
13 suspension emulsion of embodiment
D ichlorbenzuron is dissolved in SOLVESSOTMIn 200, ethoxylated castor oil is added in, obtains missible oil；By fluorine worm pyrrole quinoline,
Fatty alcohol polyoxyethylene ether sulfosuccinic acid monoesters disodium, MODIFIED LIGNOSULPHONATE, xanthans, bentonite, glycerine, water etc.
Above-mentioned each component mixes in proportion, and through being sanded, is prepared into fluorine-containing worm pyrrole quinoline suspending agent.Oil phase containing d ichlorbenzuron is added in
Into the suspending agent of fluorine-containing worm pyrrole quinoline, suspension emulsion is obtained.
14 suspension emulsion of embodiment
D ichlorbenzuron is dissolved in SOLVESSOTMIn 200, ethoxylated castor oil is added in, obtains missible oil containing d ichlorbenzuron；It will
Fluorine worm pyrrole quinoline, fatty alcohol polyoxyethylene ether sulfosuccinic acid monoesters disodium, MODIFIED LIGNOSULPHONATE, xanthans, bentonite, third
The above-mentioned each component such as triol, water mixes in proportion, and through being sanded, is prepared into fluorine worm pyrrole quinoline suspending agent.
Oil phase containing d ichlorbenzuron is added in the suspending agent of fluorine-containing worm pyrrole quinoline, obtains suspended emulsion.
15 missible oil of embodiment
By said components mix to the liquid of transparent and homogeneous to get to the present invention missible oil.
16 microcapsule suspension-suspendinagent agent of embodiment
By poly methylene poly phenyl poly isocyanate（PAPI）, the oil phase addition that d ichlorbenzuron and methyl oleate are formed contains
ATLOXTMIn 4913 aqueous solution, emulsion is formed.Then it heats and keeps the temperature 50oCatalyst reaction is added under C 2 hours.It is cold
But the microcapsules containing d ichlorbenzuron is obtained afterwards.
ATLOX TM4913, dispersant LFH, antifoaming agent, urea, fluorine worm pyrrole quinoline and water mix in proportion, and pass through
It is sanded, is prepared into suspending agent.
The obtained microcapsules containing d ichlorbenzuron is added in the aqueous suspension agent of fluorine-containing worm pyrrole quinoline, is uniformly mixing to obtain the present invention
Microcapsule suspension-suspendinagent agent.
17 suspension seed-coating agent of embodiment
D ichlorbenzuron is dissolved in cyclohexanone, butanol PO/EO copolymers is added in, obtains the missible oil containing d ichlorbenzuron；By fluorine worm
Pyrrole quinoline, tristyryl phenol（10-20EO）, xanthans, glycerine, polyvinylpyrrolidone, the above-mentioned each component such as water is in proportion
It is uniformly mixed, and through being sanded, is prepared into suspending agent.
Oil phase containing d ichlorbenzuron is added in the suspending agent of fluorine-containing worm pyrrole quinoline, obtains the suspension seed-coating agent of the present invention.
18 smoke agent of embodiment
First by antifreezing agent propylene glycol, diluent SOLVESSOTM100 mixing, are added with stirring fluorine worm pyrrole quinoline and children of going out
Urea；Surfactant is added thereto, is crushed under stiring by a disintegrating apparatus colloid mill, will be by colloid mill after
Suspension, using a micronizer.It moves in circles until grain size≤2um of solids.
19 wettable powder of embodiment
Active constituent, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the wettable powder of the present invention
20 oil-suspending agent of embodiment
Fluorine worm pyrrole quinoline 10%
D ichlorbenzuron 20%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Bentonite 5%
Glycerine 5%
Corn oil complements to 100%
Active component, dispersant, wetting agent each component are uniformly mixed according to the ratio of formula, ground and/or high speed
After shearing, corn oil is added in, obtains oil-suspending agent.
21 wettable powder of embodiment
Active constituent, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the wettable powder of the present invention.
22 missible oil of embodiment
By said components mix to the liquid of transparent and homogeneous to get to the present invention missible oil.
23 suspension concentrates of embodiment
Used additives are mixed with the active constituent of fine grinding, obtain suspension concentrates.
24 seed treatment dry powder doses of embodiment
Active constituent is sufficiently mixed with the auxiliary agent, and mixture is fully ground in suitable flour mill, and obtaining can be straight
Connect the pulvis for seed treatment.
+ 0.01% d ichlorbenzuron bait grain of 25 1% fluorine worm pyrrole quinoline of embodiment
Fluorine worm pyrrole quinoline 1%
D ichlorbenzuron 0.01%
Bait 60%
Cornstarch complements to 100%
It adds a certain amount of water mixing extruding into wettable powder through air-flow crushing after said components are uniformly mixed and makes
Material obtains bait grain.
26 active ingredient compositions of embodiment
| Fluorine worm pyrrole quinoline | 20% |
| D ichlorbenzuron | 80% |
Fluorine worm pyrrole quinoline and d ichlorbenzuron are mixed in proportion.
Proportioning is weight per distribution ratio in above example.
Biological test example
Pesticide is made in the combination of active principles of different pesticides, be current exploitation and develops novel pesticide and prevention agriculturally
A kind of effective and quick way of resistant insect.After the pestsides synthesis of different cultivars, three kinds of type of action are typically exhibited：Phase
Add effect, synergistic effect and antagonism.But it is specially which kind of effect, it is unpredictable, only just it can know that by many experiments.
Compound synergic is formulated well, due to significantly improving practical control effect, the usage amount of pesticide is reduced, so as to greatly prolong
The generation speed of pest resistance to insecticide is delayed, has been the important means of integrated control insect pest.
Inventor by a large amount of screening test, the different ratio of fluorine worm pyrrole quinoline and d ichlorbenzuron has been carried out a large number of experiments with
And effectiveness analysis, it finding in certain ratio range, obtained Pesticidal combination has gain effect, rather than just
The simple addition of two kinds of medicaments, is specifically illustrated with implementation below.
In embodiments of the present invention using Toxicity Determination mode, by Toxicity Determination, clear and definite two kinds of medicaments
Co-toxicity coefficient after compounding by a certain percentage（CTC）, CTC<80 for resist effect short of money, 80≤CTC≤120 be summation action, CTC ＞
120 be synergistic effect.
Test method：It is respectively that the Pesticidal combination reagent dilutions matched in above-described embodiment are dense into five series during experiment
Degree, is respectively placed in spare in beaker.It then, will be not in contact with the of the same size of any medicament using the method that first leaching leaf is followed by worm
Blade takes out after 5s is impregnated in the liquid being configured, naturally dry, is put into insect box, then connects for examination larva, 25
It is raised under the conditions of DEG C, often handles 3 repetitions, it is 20, while set blank control often to repeat test worm number used, is checked in 72h dead
Borer population calculates the death rate and corrected mortality, acquires virulence regression equation and calculate LC50Value.If compareing the death rate is more than 10%,
Then it is considered as invalid experiment.Calculation formula is as follows：
The death rate（%）=（Work borer population after work borer population-medicine before medicine）Live borer population * 100 before/medicine
Corrected mortality（%）=（The processing group death rate-control group death rate）/（The 100- control group death rates）*100
Probit value will be converted into for examination insect corrected mortality（y）, concentration for the treatment of（μg/ml）It is converted into logarithm（x）, with
Least square method obtains virulence regression equation, and thus calculates the value of each medicament.It is calculated altogether according to the abundant equations of Sun Yun
Malicious coefficient CTC.Calculation formula is as follows（Using fluorine worm pyrrole quinoline as standard agent, toxicity index 100）：
Survey toxicity index（ATI）=（Standard agent LC50/ reagent agent LC50）×100
Theoretical toxicity index（TTI）In=A medicaments ATI × mixture in percentage composition+B medicaments ATI × mixture of A B hundred
Divide content
Co-toxicity coefficient（CTC）=（Mixture ATI/ mixtures TTI）×100
Experiment one：To the Toxicity Determination of cotton aphid
Table 1
As known from Table 1, fluorine worm pyrrole quinoline and d ichlorbenzuron are in the proportioning 1 for preventing cotton aphid:100-100:When in 1 range,
Co-toxicity coefficient is all higher than 120, illustrates that mixture of the two in the range of this shows as gain effect.
Experiment two：To the The Toxicity Determination result of Bemisia tabaci
Table 2
As known from Table 2, fluorine worm pyrrole quinoline prevents Bemisia tabaci with d ichlorbenzuron, in proportioning 1:100-100:When in 1 range, altogether
Malicious coefficient is all higher than 120, illustrates that mixture of the two in the range of this shows as gain effect.
Experiment three：To the The Toxicity Determination result of citrus scale insect
Table 3
As known from Table 3, fluorine worm pyrrole quinoline prevents citrus scale insect with d ichlorbenzuron, in proportioning 1:100-100:In 1 range
When, co-toxicity coefficient is all higher than 120, illustrates that mixture of the two in the range of this shows as gain effect.
Experiment four：To the The Toxicity Determination result of bollworm
Table 4
As known from Table 4, fluorine worm pyrrole quinoline prevents bollworm with d ichlorbenzuron, in proportioning 1:100-100:When in 1 range, altogether
Malicious coefficient is all higher than 120, illustrates that mixture of the two in the range of this shows as gain effect.
Experiment five：To the The Toxicity Determination result of citrus red mite
Table 5
As known from Table 5, fluorine worm pyrrole quinoline prevents citrus red mite with d ichlorbenzuron, in proportioning 1:100-100:In 1 range
When, co-toxicity coefficient is all higher than 120, illustrates that mixture of the two in the range of this shows as gain effect.
Experiment six：To the The Toxicity Determination result of tea lesser leafhopper
Table 6
As known from Table 6, fluorine worm pyrrole quinoline prevents tea lesser leafhopper with d ichlorbenzuron, in proportioning 1:100-100:In 1 range
When, co-toxicity coefficient is all higher than 120, illustrates that mixture of the two in the range of this shows as gain effect.
Experiment seven：To the The Toxicity Determination result of diamondback moth
Table 7
As known from Table 7, fluorine worm pyrrole quinoline prevents diamondback moth with d ichlorbenzuron, in proportioning 1:100-100:When in 1 range, altogether
Malicious coefficient is all higher than 120, illustrates that mixture of the two in the range of this shows as gain effect.
Experiment eight：To the The Toxicity Determination result of fly
Table 8
As known from Table 8, fluorine worm pyrrole quinoline prevents fly with d ichlorbenzuron, in proportioning 1:100-100:When in 1 range, poison is altogether
Number is all higher than 120, illustrates that mixture of the two in the range of this shows as gain effect.
Experiment nine：To the The Toxicity Determination result of termite
Table 9
As known from Table 9, fluorine worm pyrrole quinoline prevents termite with d ichlorbenzuron, in proportioning 1:100-100:When in 1 range, poison is altogether
Number is all higher than 120, illustrates that mixture of the two in the range of this shows as gain effect.
Further according to the method for above toxicity test, to panonychus ulmi, thrips, rice leaf roller, the snout moth's larva of rice, temperature
Room trialeurodes vaporariorum, tea geometrid, beet armyworm The Toxicity Determination result also indicate that fluorine worm pyrrole quinoline and d ichlorbenzuron prevent the full pawl of apple
Mite, thrips, rice leaf roller, the snout moth's larva of rice, Trialeurodes vaporariorum Westwood, tea geometrid, beet armyworm are in proportioning 1:100-100:1 range
In when, co-toxicity coefficient is all higher than 120, both illustrates that the mixture in the range of this shows as gain effect.
Claims (19)
1. a kind of Pesticidal combination, which is characterized in that include fluorine worm pyrrole quinoline（Formulas I）
Formula（I）
With d ichlorbenzuron (Formula II),
Formula (II)
The weight proportion of the fluorine worm pyrrole quinoline and d ichlorbenzuron is 1:100 to 100:1.
2. Pesticidal combination according to claim 1, it is characterised in that：The weight proportion of the fluorine worm pyrrole quinoline and d ichlorbenzuron
It is 1:50 to 50:1.
3. Pesticidal combination according to claim 1, it is characterised in that：The weight proportion of the fluorine worm pyrrole quinoline and d ichlorbenzuron
It is 1:25 to 25:1.
4. Pesticidal combination according to claim 1, it is characterised in that：The weight proportion of the fluorine worm pyrrole quinoline and d ichlorbenzuron
It is 1:10 to 10:1.
5. Pesticidal combination according to claim 1, it is characterised in that：The fluorine worm pyrrole quinoline and d ichlorbenzuron account for described in total
The 1%-90% of composition by weight.
6. Pesticidal combination according to claim 1, it is characterised in that：The fluorine worm pyrrole quinoline and d ichlorbenzuron account for described in total
The 10%-80% of composition by weight.
7. Pesticidal combination according to claim 1, it is characterised in that：The fluorine worm pyrrole quinoline and d ichlorbenzuron account for described in total
The 20%-60% of composition by weight.
8. Pesticidal combination according to claim 1, it is characterised in that：Also include surfactant and/or extender.
9. Pesticidal combination according to claim 1, it is characterised in that：The Pesticidal combination, dosage form are missible oil, hang
Floating agent, seed coat agent, water dispersible granules, wettable powder, suspension emulsion, squeeze out granule, coated granule, smoke agent, aqueous emulsion,
Microcapsule suspending agent, ultra low volume liquids, bait grain.
10. Pesticidal combination described in claim 1 is used to prevent or control the purposes of agricultural pests.
A kind of 11. method prevented or control agricultural pests, it is characterised in that：Pesticidal combination described in claim 1 is used
In target agricultural pests and/or its environment.
12. a kind of method prevented or control agricultural pests according to claim 11, it is characterised in that：The agricultural evil
Worm be selected from scale insect, the snout moth's larva of rice, rice leaf roller, tea geometrid, beet armyworm, prodenia litura, diamondback moth, planthopper, aphid,
Thrips, Bemisia tabaci, Trialeurodes vaporariorum Westwood, tea lesser leafhopper, red spider.
13. a kind of method prevented or control agricultural pests according to claim 11, it is characterised in that：Including separating,
Sequentially or simultaneously apply fluorine worm pyrrole quinoline, d ichlorbenzuron.
14. a kind of method prevented or control agricultural pests according to claim 11, it is characterised in that：Wherein fluorine worm pyrrole
Quinoline and d ichlorbenzuron are individually the form of formulated composition.
A kind of 15. method that plant is protected to be invaded to prevent agricultural pests, it is characterised in that：By desinsection group described in claim 1
Object is closed to contact with target useful plant, target agricultural pests and/or its environment, the propagating materials of target useful plant.
A kind of 16. method for protecting vegetable seeds, it is characterised in that：Including make seed prior to seeding and/or vernalization after with having
The Pesticidal combination according to claim 1 contact of effect amount.
17. a kind of method that plant is protected to be invaded to prevent agricultural pests, is planting including Pesticidal combination described in claim 1
Object, plant propagation material, environment are infected by agricultural pests to carry out before and/or after.
18. Pesticidal combination prevention described in claim 1 or the purposes of control sanitary insect pest.
19. Pesticidal combination described in claim 1 is applied to target health by a kind of method prevented or control sanitary insect pest
Pest and/or its environment.
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| CN105794813B true CN105794813B (en) | 2018-06-08 |
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| CN107751206A (en) * | 2016-08-16 | 2018-03-06 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination and its method for controlling agricultural pest |
| CN108713531A (en) * | 2018-05-25 | 2018-10-30 | 福建省农业科学院植物保护研究所 | A kind of method that Highly Effective collects natural enemy food mite Staphylinus insect pupa |
| CN111109276A (en) * | 2019-12-17 | 2020-05-08 | 金陵科技学院 | Pesticide composition for bemisia tabaci |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006106798A1 (en) * | 2005-03-30 | 2006-10-12 | Nihon Nohyaku Co., Ltd. | Pest control agent and method of using the same |
| CN102217623A (en) * | 2011-04-27 | 2011-10-19 | 成都科利隆生化有限公司 | Pesticide composition containing chlorbenzuron and flubendiamide |
| CN102613221A (en) * | 2012-03-02 | 2012-08-01 | 内蒙古帅旗生物科技股份有限公司 | Emulsifiable powder containing chlorbenzuron and abamectin and preparation method thereof |
| CN102885065A (en) * | 2012-10-25 | 2013-01-23 | 京博农化科技股份有限公司 | Trichomonacida and acaricidal composition for compounding acarid metaflumizone and chlorbenzuron |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2013032310A (en) * | 2011-08-02 | 2013-02-14 | Sumitomo Chemical Co Ltd | Pest-controlling composition |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006106798A1 (en) * | 2005-03-30 | 2006-10-12 | Nihon Nohyaku Co., Ltd. | Pest control agent and method of using the same |
| CN102217623A (en) * | 2011-04-27 | 2011-10-19 | 成都科利隆生化有限公司 | Pesticide composition containing chlorbenzuron and flubendiamide |
| CN102613221A (en) * | 2012-03-02 | 2012-08-01 | 内蒙古帅旗生物科技股份有限公司 | Emulsifiable powder containing chlorbenzuron and abamectin and preparation method thereof |
| CN102885065A (en) * | 2012-10-25 | 2013-01-23 | 京博农化科技股份有限公司 | Trichomonacida and acaricidal composition for compounding acarid metaflumizone and chlorbenzuron |
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