CN105297059B - A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration - Google Patents
A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration Download PDFInfo
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- CN105297059B CN105297059B CN201510762848.2A CN201510762848A CN105297059B CN 105297059 B CN105297059 B CN 105297059B CN 201510762848 A CN201510762848 A CN 201510762848A CN 105297059 B CN105297059 B CN 105297059B
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- metal surface
- discoloration
- carbon hydrogen
- hydrocarbon solvent
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Abstract
The invention belongs to industry cleaning link domain technology field, and in particular to a kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration；It is made up of hydrocarbon solvent and inhibition agent composition, wherein concentration of the corrosion inhibiter in hydrocarbon solvent is 2ppm~50ppm, and corrosion inhibiter includes the BTA calculated in parts by weight：0.05 part~0.1 part, 1827：0.05 part~0.1 part, the alcohol of 3 methyl, 1 pentyne 3：0.05 part~0.2 part, naphthenic soap：0.05 part~0.1 part, 6501：0 part~0.05 part, sorbester p17：0 part~0.05 part；Metal surface after being cleaned with the present invention is not oxidized and color keep is constant, realizes anti-oxidation, Anti- tarnishing function during agent for carbon hydrogen detergent cleaning hardware workpiece, good protective action is especially played to non ferrous metal and their alloy.
Description
Technical field
The invention belongs to industry cleaning link domain technology field, and in particular to a kind of anti-metal surface oxidation and discoloration it is hydrocarbon
Cleaning agent.
Background technology
In hardware process, the surface for having some workpiece is vulnerable to the erosion production of the trace oxygen dissolved in cleaning agent
Raw oxidation.For workpiece after cleaning, drying, oxygen invasion and attack of the surface easily in by air produce oxidation.Both of these case can make workpiece
Surface produces spot corrosion, and serious meeting causes the corrosion of large area, and even outward appearance integrally changes colour.Especially fresh processed five metal working
Part its machined surface ripple very living, its surface and it is subject to the attack of oxygen after cleaning removes Surface Machining oil and gets rusty, that is, cause
Spot corrosion, large area corrosion or overall discoloration.The workpiece quality so cleaned is severely impacted, so that causing workpiece to discard.Cause
This, it is ensured that hardware workpiece is in cleaning work, and (i.e. the antirust of inter process) non-corrosive in a few days after cleaning, is that cleaning agent must
The performance that must possess.
The content of the invention
In order to solve the above problems, it is an object of the invention to provide the hydrocarbon clear of a kind of anti-metal surface oxidation and discoloration
Lotion.
The present invention is achieved through the following technical solutions：
A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration, are made up of hydrocarbon solvent and inhibition agent composition, its
Concentration of the middle corrosion inhibiter in hydrocarbon solvent is 2ppm~50ppm, and corrosion inhibiter includes what is calculated in parts by weight：
It is preferred that the boiling range of the hydrocarbon solvent is 120 DEG C~223 DEG C.
It is preferred that the boiling range of the hydrocarbon solvent is 130 DEG C~210 DEG C.
It is preferred that the boiling range of the hydrocarbon solvent is 166 DEG C~192 DEG C.
It is preferred that CH1140, CH1145, CH1150 or CH1130 system of the new ball cleaning Science and Technology Co., Ltd. production in Guangdong
Row.
Wherein, BTA, 1827,6501, Arlacel-80, di (isooctyl) phosphate, naphthenic soap, 3- methyl-1-pentenes alkynes-
The amount for being added to hydrocarbon solvent of 3- alcohol is that 2ppm~0.5% part effect is best.
Wherein, BTA can select oiliness, in terms of environmental angle, be preferably selected water-soluble BTA；BTA (benzos
Triazole) and copper atom formation covalent bond and coordinate bond, it is mutually to replace into chain polymer more, in copper plus the protection of surface composition multilayer
Film, the surface of copper is not played redox reaction, hydrogen does not occur, plays corrosion protection.
Wherein, 1827 (stearyl dimethyl benzyl ammonium chloride), 50 parts of active matter content for weak yellow liquid, content
95 parts for faint yellow decorating film, produce cationic reactive groups in dissociation in water, there is emulsification, antistatic property.
Wherein, di (isooctyl) phosphate (abbreviation p204), also it is di-(2-ethylhexyl)phosphoric acid ester；Double (2- ethylhexyls) phosphorus
Acid esters；Dioctylphosphoric acid ester.Organic solvent is typically used as, is a kind of acidic extractant, organic synthesis intermediate, it is in the present invention
Acted on other materials, play a part of making wetting agent and surfactant.
Wherein, naphthenic soap is used as preservative, preferably cobalt naphthenate, manganese, lead salt, copper, zinc salt in the present invention.
Wherein, methylpentynol plays glazing agent, viscosity stabiliser, stabilizer, corrosion inhibiter in the present invention
Effect.
Present invention selection adds BTA, 6501,1827, Arlacel-80, di (isooctyl) phosphate, ring in hydrocarbon solvent
One or more combination thing in alkanoic acid soap, methylpentynol is as inhibition antioxidant, and not only price is low
It is honest and clean, and by the synergy between these inhibition antioxidants can be good at protect hardware workpiece oxidation, warp
A couple of days to several moons can be placed by crossing the treated workpiece of the cleaning agent, and appearance color is constant, preferably as the clear of inter process
Anti-oxidation reagent is washed, good protective action is especially played to non ferrous metal and their alloy；Realize agent for carbon hydrogen detergent cleaning five
Anti-oxidation, Anti- tarnishing function during metal working part.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, is managed to help those skilled in the art
The solution present invention.
Embodiment 1
A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration, are made up of hydrocarbon solvent and inhibition agent composition, its
Contain in middle 1000L：BTA 5g, 1827：1g, methylpentynol 10g, naphthenic soap 2g.
Embodiment 2
A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration, are made up of hydrocarbon solvent and inhibition agent composition, its
Contain BTA 10g in middle 1000L.
Embodiment 3
A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration, are made up of hydrocarbon solvent and inhibition agent composition, its
Contain 1827 (10g) in middle 1000L.
Embodiment 4
A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration, are made up of hydrocarbon solvent and inhibition agent composition, its
Contain in middle 1000L：Methylpentynol 20g.
Embodiment 5
A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration, are made up of hydrocarbon solvent and inhibition agent composition, its
Contain naphthenic soap 10g in middle 1000L.
Embodiment 6
A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration, are made up of hydrocarbon solvent and inhibition agent composition, its
Contain in middle 1000L：BTA=10g, 1827=5g, 6501=5g, Arlacel-80=5g.
Embodiment 7
A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration, are made up of hydrocarbon solvent and inhibition agent composition, its
Contain in middle 1000L：1827=3g, naphthenic soap=5g, Arlacel-80=10g.
Embodiment 8
A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration, are made up of hydrocarbon solvent and inhibition agent composition, its
Contain in middle 1000L：BTA=10g, 1827=10g, methylpentynol=5g, naphthenic soap=1g.
Its preparation method is to be well mixed under normal temperature.
Above-described embodiment, simply presently preferred embodiments of the present invention, is not used for limiting the scope of the present invention, therefore all with this
The equivalent change or modification that feature and principle described in invention claim are done, all should be included in scope of the invention as claimed
Within.
The present invention's is specifically used, and workpiece normal temperature is ultrasonic 2 minutes, then rinses, dries up.Wherein, red copper workpiece：72 is small
When it is non-discolouring.Cast zinc alloy workpiece：Cleaned after sandblasting, January is non-discolouring.Easy car ironworker's part：2 months unattacked.
Claims (4)
1. a kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration, it is characterised in that mixed by hydrocarbon solvent and corrosion inhibiter
Thing forms, and wherein concentration of the corrosion inhibiter in hydrocarbon solvent is 2ppm~50ppm, and corrosion inhibiter includes what is calculated in parts by weight：
2. anti-metal surface oxidation as claimed in claim 1 and the agent for carbon hydrogen detergent of discoloration, it is characterised in that the hydrocarbon solvent
Boiling range be 120 DEG C~223 DEG C.
3. anti-metal surface oxidation as claimed in claim 2 and the agent for carbon hydrogen detergent of discoloration, it is characterised in that the hydrocarbon solvent
Boiling range be 130 DEG C~210 DEG C.
4. anti-metal surface oxidation as claimed in claim 3 and the agent for carbon hydrogen detergent of discoloration, it is characterised in that the hydrocarbon solvent
Boiling range be 166 DEG C~192 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510762848.2A CN105297059B (en) | 2015-11-09 | 2015-11-09 | A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510762848.2A CN105297059B (en) | 2015-11-09 | 2015-11-09 | A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105297059A CN105297059A (en) | 2016-02-03 |
| CN105297059B true CN105297059B (en) | 2018-01-02 |
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|---|---|---|---|
| CN201510762848.2A Active CN105297059B (en) | 2015-11-09 | 2015-11-09 | A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114214633B (en) * | 2021-12-30 | 2023-11-07 | 广东新球清洗科技股份有限公司 | Rust-proof hydrocarbon cleaning agent, and preparation method and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101768499A (en) * | 2010-01-25 | 2010-07-07 | 蓝星环境工程有限公司 | Lipid type antirust oil with gaseous phase antirust function |
| CN102719302A (en) * | 2012-07-03 | 2012-10-10 | 上海福岛化工科技发展有限公司 | Volatile rust preventive oil |
| CN103468434A (en) * | 2013-09-17 | 2013-12-25 | 华阳新兴科技（天津）集团有限公司 | Environment-friendly safe solvent cleaning agent |
| CN103469236A (en) * | 2013-09-22 | 2013-12-25 | 西北机器有限公司 | Copper base material cleaning agent and preparation method thereof |
| CN103571448A (en) * | 2012-07-26 | 2014-02-12 | 中国石油天然气集团公司 | Acidizing corrosion inhibitor applicable to high temperature of 160 to 180 DEG C, and preparation and application thereof |
| CN104195587A (en) * | 2014-07-31 | 2014-12-10 | 青岛华承天机械制造有限公司 | Deoiling cleaning agent |
| CN104911042A (en) * | 2015-07-03 | 2015-09-16 | 陈泽林 | Washing liquid for display screen for electronic device |
-
2015
- 2015-11-09 CN CN201510762848.2A patent/CN105297059B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101768499A (en) * | 2010-01-25 | 2010-07-07 | 蓝星环境工程有限公司 | Lipid type antirust oil with gaseous phase antirust function |
| CN102719302A (en) * | 2012-07-03 | 2012-10-10 | 上海福岛化工科技发展有限公司 | Volatile rust preventive oil |
| CN103571448A (en) * | 2012-07-26 | 2014-02-12 | 中国石油天然气集团公司 | Acidizing corrosion inhibitor applicable to high temperature of 160 to 180 DEG C, and preparation and application thereof |
| CN103468434A (en) * | 2013-09-17 | 2013-12-25 | 华阳新兴科技（天津）集团有限公司 | Environment-friendly safe solvent cleaning agent |
| CN103469236A (en) * | 2013-09-22 | 2013-12-25 | 西北机器有限公司 | Copper base material cleaning agent and preparation method thereof |
| CN104195587A (en) * | 2014-07-31 | 2014-12-10 | 青岛华承天机械制造有限公司 | Deoiling cleaning agent |
| CN104911042A (en) * | 2015-07-03 | 2015-09-16 | 陈泽林 | Washing liquid for display screen for electronic device |
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| Publication number | Publication date |
|---|---|
| CN105297059A (en) | 2016-02-03 |
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