CN105070338B - GFRP (glass fiber reinforced Polymer) reinforcement reinforced sacrificial concrete and preparation method thereof - Google Patents
GFRP (glass fiber reinforced Polymer) reinforcement reinforced sacrificial concrete and preparation method thereof Download PDFInfo
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- CN105070338B CN105070338B CN201510419388.3A CN201510419388A CN105070338B CN 105070338 B CN105070338 B CN 105070338B CN 201510419388 A CN201510419388 A CN 201510419388A CN 105070338 B CN105070338 B CN 105070338B
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- 239000003365 glass fiber Substances 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 229920002430 Fibre-reinforced plastic Polymers 0.000 title abstract 2
- 230000002787 reinforcement Effects 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000002002 slurry Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 17
- 229910052742 iron Inorganic materials 0.000 claims abstract description 17
- 239000010453 quartz Substances 0.000 claims abstract description 17
- 239000004568 cement Substances 0.000 claims abstract description 15
- 239000010881 fly ash Substances 0.000 claims abstract description 14
- 210000002435 tendon Anatomy 0.000 claims description 48
- 230000002708 enhancing effect Effects 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 5
- 239000011440 grout Substances 0.000 claims description 4
- 239000002956 ash Substances 0.000 claims description 3
- 239000003245 coal Substances 0.000 claims description 3
- 102100040287 GTP cyclohydrolase 1 feedback regulatory protein Human genes 0.000 claims 24
- 101710185324 GTP cyclohydrolase 1 feedback regulatory protein Proteins 0.000 claims 24
- 239000000835 fiber Substances 0.000 abstract description 15
- 238000010276 construction Methods 0.000 abstract description 2
- 239000004575 stone Substances 0.000 abstract 2
- 239000011152 fibreglass Substances 0.000 description 68
- 238000012360 testing method Methods 0.000 description 9
- 238000005336 cracking Methods 0.000 description 7
- 238000010998 test method Methods 0.000 description 6
- 239000002689 soil Substances 0.000 description 5
- 229920002748 Basalt fiber Polymers 0.000 description 4
- 230000015271 coagulation Effects 0.000 description 4
- 238000005345 coagulation Methods 0.000 description 4
- 230000007774 longterm Effects 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 210000003205 muscle Anatomy 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention belongs to the technical field of nuclear power construction, and relates to GFRP (glass fiber reinforced Polymer) bar reinforced sacrificial concrete and a preparation method thereof, wherein the GFRP bar reinforced sacrificial concrete is formed by pouring sacrificial concrete slurry into a GFRP bar framework, a GFRP stirrup binds a first GFRP stress bar and a second GFRP stress bar to form the GFRP bar framework with a cuboid structure, the first GFRP stress bar is uniformly distributed at the top end of the GFRP bar framework, and the second GFRP stress bar is uniformly distributed at the bottom end of the GFRP bar framework; the sacrificial concrete slurry consists of P.I cement, water, a water reducing agent, iron ore, quartz stone, fly ash and fibers, wherein the weight percentages of the components are as follows: 9-20% of P.I cement, 35-45% of iron ore, 20-35% of quartz stone, 3-9% of fly ash, 0.9-2.5% of fiber, 4-7% of water, 0.8-1.2% of water reducing agent and 100% of total amount; simple structure, simple preparation method, low cost, strong crack resistance and long service life.
Description
Technical field:
The invention belongs to nuclear power construction technical field, and it is mixed to be related to a kind of GFRP (fiberglass reinforced plastics) muscle enhancing sacrifice
Solidifying soil and preparation method thereof.
Background technology:
Sacrificial concrete component is the important component of third generation EPR nuclear power plant reactor cores.When nuclear power station occurs sternly
During weight accident, reactor core element can melt in the case of cooling not in time, and melt temperature may be up to 3000~
4000 DEG C, fusant causes lower head of pressure vessel to fail, and then flows into reactor cavity and concrete material reaction concrete
Melt decomposition temperature and there was only 1100 DEG C or so, fusant starts down-cutting errosion bottom plate, produces a large amount of non-condensable gas, improves safety
The pressure of shell, once bottom plate is fused, the integrality of containment is lost, and a large amount of emissivity rays will leak, it is possible to cause difficulty
With the consequence of appraisal.In order to improve the security of nuclear power station, sacrificial concrete component must have enough stability to provide
Time needed for fusant aggregation, the temperature of fusant is reduced by chemically reacting, and is fired with reducing the density of oxide and core
The radiation value of material.Therefore, sacrificial concrete component not only needs very high intensity, cracking resistance, and is needed on component
Meet certain requirement (especially Fe2O3And SiO2Component), experimental molten oxide experiment display, existing common building
It can only meet intensity requirement with concrete component, and be difficult to meet sacrificial concrete component in terms of crack resistance, chemical composition
It is required that, it is difficult to reactor core is played a role.
The content of the invention:
It is an object of the invention to overcome shortcoming existing in the prior art, design provides a kind of GFRP tendons enhancing and sacrifices coagulation
Soil and preparation method thereof, makes the reactor core that it is constructed to improve reactor core fusant when major accident occurs for nuclear power station
Characteristic is cooled down with its heat flow density, quickening reactor core fusant is reduced, and alleviates the serious consequence of nuclear accident.
To achieve these goals, GFRP tendons of the present invention enhancing sacrificial concrete by sacrificial concrete slurry pour in
Formed in GFRP tendons skeleton, the first GFRP principal rods and the 2nd GFRP principal rods are bound to form rectangular parallelepiped structure by GFRP stirrups
GFRP tendons skeleton, the first GFRP principal rods are evenly distributed on the top of GFRP tendons skeleton, and the 2nd GFRP principal rods are evenly distributed on
The bottom of GFRP tendons skeleton;Sacrificial concrete is starched by P.I cement, water, water-reducing agent, iron ore, quartz, flyash and fiber group
Into the percentage by weight of each component is:P.I cement 9~20%, iron ore 35~45%, quartz 20~35%, flyash 3
~9%, fiber 0.9~2.5%, water 4~7%, water-reducing agent 0.8~1.2%, total amount 100%.
Fiber of the present invention includes glass fibre, PP fibers and basalt fibre.
The method that the present invention prepares GFRP tendons enhancing sacrificial concrete includes template construct, the binding of GFRP tendons skeleton, sacrifices
Prepared by concrete grout and sacrificial concrete slurry pours four steps, its detailed process is:
(1), template construct:Use template frame of the wooden template construct size for 172mm × 172mm × 900mm:
(2), GFRP tendons skeleton is bound:The position of the first GFRP principal rods and the 2nd GFRP principal rods is fixed, is bound round with GFRP
Muscle binds the first GFRP principal rods and the 2nd GFRP principal rods into the GFRP tendons skeleton that size is 72mm × 72mm × 800mm,
Then GFRP tendons skeleton is positioned over inside template frame:First GFRP principal rods and the 2nd GFRP principal rods are used using a diameter of
The GFRP principal rods of 12mm;
(3), prepared by sacrificial concrete slurry:According to the raw material proportioning of regulation, by P.I cement, iron ore, quartz and fine coal
2min is mixed in ash, adds fiber stirring 1min, is eventually adding water-reducing agent and water stirring 2min, sacrifice coagulation is prepared
Soil paste;
(4), sacrificial concrete slurry pours:Sacrificial concrete slurry is poured into the template frame for placing GFRP tendons skeleton, is shaken
24h is stood after smashing 1min, template frame of then dismantling, that is, be made GFRP tendons enhancing sacrificial concrete.
Compared with prior art, the present invention has the following advantages:First, the main component SiO of GFRP2Formed at high temperature
Glassy matrix, can not only contain has radioactive fission product, prevents it from diffusing in external environment, moreover it is possible to further
The activity that fusant (zirconium) carries out energy response with water is reduced, avoids generation nuclear power generating sets hydrogen caused by zirconium is reacted with water quick-fried
It is fried;Second, the fiber in sacrificial concrete slurry is split with the resistance of stronger cracking resistance and toughening effect, concrete component is significantly improved
Shrinkage cracking cracks with thermal shock, and component is had good ductility and shock resistance, increases substantially nuclear power sacrificial concrete
Performance;Third, organically combined GFRP tendons and the characteristic of sacrificial concrete, can at high temperature with the other meltings of reactor core
Thing interacts, and reduces the temperature of reactor core fusant, the preliminary characteristic for changing molten mixture, and the height for reducing reactor core fusant is put
Penetrating property component, reduces the increase of containment internal pressure, meets the requirements as reactor core construction material;Its structure
Simply, preparation method is easy, and cost is low, and cracking resistance is strong, service life length.
Brief description of the drawings:
Fig. 1 strengthens the agent structure principle schematic of sacrificial concrete, including the first GFRP for GFRP tendons of the present invention
Principal rod 1, sacrificial concrete slurry 2,3 and the 2nd GFRP principal rods 4 of GFRP stirrups.
Embodiment:
The invention will be further described by way of example and in conjunction with the accompanying drawings.
GFRP tendons enhancing sacrificial concrete is poured in shape in GFRP tendons skeleton by sacrificial concrete slurry 2 described in the present embodiment
Into, the first GFRP principal rods 1 and the binding of the 2nd GFRP principal rods 4 are formed the GFRP tendons skeleton of rectangular parallelepiped structure by GFRP stirrups 3,
First GFRP principal rods 1 are evenly distributed on the top of GFRP tendons skeleton, and the 2nd GFRP principal rods 4 are evenly distributed on GFRP tendons skeleton
Bottom;Sacrificial concrete slurry 2 is made of P.I cement, water, water-reducing agent, iron ore, quartz, flyash and fiber, each component
Percentage by weight be:P.I cement 9~20%, iron ore 35~45%, quartz 20~35%, flyash 3~9%, fiber
0.9~2.5%, water 4~7%, water-reducing agent 0.8~1.2%.
Fiber described in the present embodiment includes glass fibre, PP fibers and basalt fibre.
The method that the present embodiment prepares GFRP tendons enhancing sacrificial concrete includes template construct, GFRP tendons skeleton binds, is sacrificial
Prepared by domestic animal concrete grout and sacrificial concrete slurry pours four steps, its detailed process is:
(1), template construct:Use template frame of the wooden template construct size for 172mm × 172mm × 900mm:
(2), GFRP tendons skeleton is bound:The position of the first GFRP principal rods 1 and the 2nd GFRP principal rods 4 is fixed, uses GFRP
First GFRP principal rods 1 and the 2nd GFRP principal rods 4 are bound into the GFRP tendons that size is 72mm × 72mm × 800mm by stirrup 3
GFRP tendons skeleton, is then positioned over inside template frame by skeleton:First GFRP principal rods 1 and the 2nd GFRP principal rods 4 are adopted
With the GFRP principal rods of a diameter of 12mm;
(3), prepared by sacrificial concrete slurry:According to the raw material proportioning of regulation, by P.I cement, iron ore, quartz and fine coal
2min is mixed in ash, adds fiber stirring 1min, is eventually adding water-reducing agent and water stirring 2min, sacrifice coagulation is prepared
Soil paste;
(4), sacrificial concrete slurry pours:Sacrificial concrete slurry is poured into the template frame for placing GFRP tendons skeleton, is shaken
24h is stood after smashing 1min, template frame of then dismantling, that is, be made GFRP tendons enhancing sacrificial concrete.
Embodiment 1:
The present embodiment makes GFRP tendons enhancing sacrificial concrete component according to Fig. 1, and sacrificial concrete slurry 2 is by P.I cement, iron
Ore, quartz, flyash, miberal powder, glass fibre, water-reducing agent, water, which are stirred, to be formed, and the percentage by weight of each component is:
P.I cement 13%, iron ore 41.1%, quartz 33%, flyash 5%, glass fibre 1%, water 6%, water-reducing agent 0.9%,
Template first is made according to GFRP tendons enhancing sacrificial concrete scantling, then binds GFRP tendons skeleton, finally pours sacrifice coagulation
Soil paste, is tested after maintenance, during test, reference《Standard for test methods of mechanical properties of ordinary concrete》(GB/T 50081-
2002) strength test, reference are carried out《Standard for test methods of longterm performance and durability of ordinary concrete standard》(GB/T 50082-
2009) cracking performance test is carried out, result of the test surface, which is IV grades, by 1000 DEG C of height
After temperature processing, there is microcrack and roomy crack, but there is no Decrepitation Phenomena, residual strength is the 31% of initial strength,
The integrality of self structure can be kept completely.
Embodiment 2:
The present embodiment makes GFRP tendons enhancing sacrificial concrete component according to Fig. 1, and the sacrificial concrete slurry is by P.I water
Mud, iron ore, quartz, flyash, PP fibers, water-reducing agent, water are stirred and form, and the percentage by weight of each component is:P.I
Cement 17%, iron ore 37.5%, quartz 33%, flyash 3%, PP fibers 1.5%, water 7%, water-reducing agent 1.0%, first according to
Template is made according to GFRP tendons enhancing sacrificial concrete scantling, then binds GFRP tendons skeleton, finally pours sacrificial concrete slurry,
Tested after maintenance, during test, reference《Standard for test methods of mechanical properties of ordinary concrete》(GB/T 50081-2002) into
Row strength test, reference《Standard for test methods of longterm performance and durability of ordinary concrete standard》(GB/T50082-2009) carry out
Cracking performance is tested.Result of the test surface, which is IV grades, after 1000 DEG C of high-temperature process,
Only occur microcrack on surface, Decrepitation Phenomena does not occur, residual strength is the 27% of initial strength, can be kept completely
The integrality of self structure.
Embodiment 3:
The present embodiment makes GFRP tendons enhancing sacrificial concrete component according to Fig. 1, and the sacrificial concrete slurry 2 is by P.I water
Mud, iron ore, quartz, flyash, basalt fibre, water-reducing agent, water, which are stirred, to be formed, the percentage by weight of each component
For:P.I cement 14%, iron ore 42.1%, quartz 34%, flyash 2%, basalt fibre 0.9%, water 6%, water-reducing agent
1.0%, template first is made according to GFRP tendons enhancing sacrificial concrete scantling, then GFRP tendons skeleton is bound, finally pour sacrificial
Domestic animal concrete grout, is tested after maintenance, during test, reference《Standard for test methods of mechanical properties of ordinary concrete》(GB/
T50081-2002 strength test, reference) are carried out《Standard for test methods of longterm performance and durability of ordinary concrete standard》(GB/T
50082-2009) carry out cracking performance test.Result of the test surface, which is IV grades, by 1000
DEG C high-temperature process after, there is microcrack, but there is no Decrepitation Phenomena, residual strength is the 18% of initial strength, completely
It can keep the integrality of self structure.
Claims (1)
1. a kind of GFRP tendons strengthen sacrificial concrete, it is characterised in that are poured by sacrificial concrete slurry in shape in GFRP tendons skeleton
Into, the first GFRP principal rods and the 2nd GFRP principal rods are bound the GFRP tendons skeleton to form rectangular parallelepiped structure by GFRP stirrups, the
One GFRP principal rods are evenly distributed on the top of GFRP tendons skeleton, and the 2nd GFRP principal rods are evenly distributed on the bottom of GFRP tendons skeleton
End;Sacrificial concrete slurry is stirred by P.I cement, iron ore, quartz, flyash, glass fibre, water-reducing agent, water to be formed,
The percentage by weight of each component is:P.I cement 13%, iron ore 41.1%, quartz 33%, flyash 5%, glass fibre
1%, water 6%, water-reducing agent 0.9%;Include template construct during preparation, GFRP tendons skeleton is bound, prepared by sacrificial concrete slurry and sacrificial
Four steps of domestic animal concreting, its detailed process are:
(1), template construct:Use template frame of the wooden template construct size for 172mm × 172mm × 900mm:
(2), GFRP tendons skeleton is bound:The position of the first GFRP principal rods and the 2nd GFRP principal rods is fixed, will with GFRP stirrups
The GFRP tendons skeleton of first GFRP principal rods and the binding of the 2nd GFRP principal rods into size for 72mm × 72mm × 800mm, then
GFRP tendons skeleton is positioned over inside template frame:First GFRP principal rods and the 2nd GFRP principal rods use a diameter of 12mm
GFRP principal rods;
(3), prepared by sacrificial concrete slurry:According to the percentage by weight of each component, by P.I cement, iron ore, quartz and fine coal
2min is mixed in ash, adds glass fibre stirring 1min, is eventually adding water-reducing agent and water stirring 2min, sacrifice is prepared
Concrete grout;
(4), sacrificial concrete slurry pours:Sacrificial concrete slurry is poured into the template frame for placing GFRP tendons skeleton, is vibrated
24h is stood after 1min, template frame of then dismantling, that is, be made GFRP tendons enhancing sacrificial concrete.
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CN201510419388.3A CN105070338B (en) | 2015-07-16 | 2015-07-16 | GFRP (glass fiber reinforced Polymer) reinforcement reinforced sacrificial concrete and preparation method thereof |
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CN108751868B (en) * | 2018-07-17 | 2020-12-08 | 南京林业大学 | Siliceous nuclear power sacrificial material and preparation method thereof |
CN108840626B (en) * | 2018-07-17 | 2021-02-02 | 南京林业大学 | Ferrosilicon nuclear electricity sacrificial material and preparation method thereof |
CN112960951A (en) * | 2021-03-01 | 2021-06-15 | 中冶建筑研究总院有限公司 | Precast structure combined by concrete and fiber composite bars and concrete preparation method |
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CN102176331B (en) * | 2011-01-28 | 2013-06-05 | 东南大学 | Nuclear power sacrificial concrete prepared from basalt fibers and preparation method thereof |
CN102176332B (en) * | 2011-01-28 | 2013-05-01 | 东南大学 | Nuclear power sacrificial concrete prepared from medium-grade iron ore and quartz stone and preparation method thereof |
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