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BR9911158A - Processos de polimerização de olefinas usando complexos ativados ácido-base de lewis - Google Patents

Processos de polimerização de olefinas usando complexos ativados ácido-base de lewis

Info

Publication number
BR9911158A
BR9911158A BR9911158-6A BR9911158A BR9911158A BR 9911158 A BR9911158 A BR 9911158A BR 9911158 A BR9911158 A BR 9911158A BR 9911158 A BR9911158 A BR 9911158A
Authority
BR
Brazil
Prior art keywords
lewis acid
lewis
olefin polymerization
polymerization processes
compound
Prior art date
Application number
BR9911158-6A
Other languages
English (en)
Inventor
Matthew W Holtcamp
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of BR9911158A publication Critical patent/BR9911158A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Patente de Invenção: <B>"PROCESSOS DE POLIMERIZAçãO DE OLEFINAS USANDO COMPLEXOS ATIVADOS áCIDO-BASE DE LEWIS"<D>. Esta descrição refere-se a um processo para a preparação de poliolefinas a partir de um ou mais monómeros olefínicos, compreendendo a combinação das referidas olefinas em condições de polimerização de olefinas com i) um composto catalisador organometálico de metal de transição, ii) um complexo ácido-base de Lewis onde o grupo ácido de Lewis é um composto de alumínio ou boro, tendo pelo menos um ligando arila halogenado e o grupo base de Lewis é um composto amina ou éter, a referida combinação sendo conduzida na presença de um composto tri-n-alquil alumínio ou gálio.
BR9911158-6A 1998-06-12 1999-06-03 Processos de polimerização de olefinas usando complexos ativados ácido-base de lewis BR9911158A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8902398P 1998-06-12 1998-06-12
PCT/US1999/012491 WO1999064476A1 (en) 1998-06-12 1999-06-03 Olefin polymerization process using activated lewis acid-base complexes

Publications (1)

Publication Number Publication Date
BR9911158A true BR9911158A (pt) 2001-04-03

Family

ID=22215054

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9911158-6A BR9911158A (pt) 1998-06-12 1999-06-03 Processos de polimerização de olefinas usando complexos ativados ácido-base de lewis

Country Status (9)

Country Link
US (1) US6211312B1 (pt)
EP (1) EP1090045B1 (pt)
JP (1) JP2002517571A (pt)
AU (1) AU743376B2 (pt)
BR (1) BR9911158A (pt)
CA (1) CA2330529A1 (pt)
DE (1) DE69916834T2 (pt)
ES (1) ES2216586T3 (pt)
WO (1) WO1999064476A1 (pt)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6451938B1 (en) * 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
US6147173A (en) * 1998-11-13 2000-11-14 Univation Technologies, Llc Nitrogen-containing group 13 anionic complexes for olefin polymerization
JP2002533484A (ja) * 1998-12-18 2002-10-08 ユニベーション・テクノロジーズ・エルエルシー 架橋されたメタロセンポリオレフィン触媒上のハロアリール含有第１３族置換基
CA2370799A1 (en) 2000-02-24 2001-08-30 Basell Technology Company Bv Organometallic compound useful as cocatalyst for polymerizing olefins
US20040072975A1 (en) * 2000-03-17 2004-04-15 Jorg Schottek Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins
KR20030043971A (ko) * 2000-09-26 2003-06-02 비피 케미칼즈 리미티드 지지된 촉매계
US7249170B2 (en) * 2000-12-06 2007-07-24 Intelliden System and method for configuration, management and monitoring of network resources
DE10114345A1 (de) 2001-03-23 2002-09-26 Bayer Ag Katalysator mit einer Donor-Akzeptor-Wechselwirkung
US6960634B2 (en) 2001-10-31 2005-11-01 Univation Technologies, Llc Methods for adjusting melt properties of metallocene catalyzed olefin copolymers
US6703338B2 (en) * 2002-06-28 2004-03-09 Univation Technologies, Llc Polymerization catalyst activators, method of preparing, and their use in polymerization processes
US20030207757A1 (en) * 2002-04-30 2003-11-06 Daelim Industries Co., Ltd. Catalyst composition comprising metallocene compound having bulky cycloalkyl-substituted cyclopentadienyl ligand, and process for olefin polymerization using the same
WO2004005360A2 (en) 2002-07-09 2004-01-15 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
KR101118495B1 (ko) * 2002-12-17 2012-03-12 이네오스 유럽 리미티드 지지된 올레핀 중합 촉매
US7741417B2 (en) 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
US8399056B2 (en) 2006-06-02 2013-03-19 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Method of forming high-k dielectric films based on novel titanium, zirconium, and hafnium precursors and their use for semiconductor manufacturing
US8022005B2 (en) 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
WO2009123609A1 (en) * 2008-03-31 2009-10-08 Advanced Elastomer Systems, L.P. Thermoplastic vulcanizates
KR102022132B1 (ko) 2011-11-08 2019-09-17 유니베이션 테크놀로지즈, 엘엘씨 촉매 시스템의 제조 방법
US9034998B2 (en) 2011-12-16 2015-05-19 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9156924B2 (en) 2013-03-12 2015-10-13 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9631038B2 (en) 2013-10-11 2017-04-25 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9771442B2 (en) 2015-05-13 2017-09-26 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10337104B2 (en) 2016-12-30 2019-07-02 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Zirconium, hafnium, titanium precursors and deposition of group 4 containing films using the same
US10364259B2 (en) 2016-12-30 2019-07-30 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Zirconium, hafnium, titanium precursors and deposition of group 4 containing films using the same
US10465289B2 (en) 2016-12-30 2019-11-05 L'Air Liquide, Société Anonyme pour l'Etude at l'Exploitation des Procédés Georges Claude Zirconium, hafnium, titanium precursors and deposition of group 4 containing films using the same
CN110520471B (zh) 2017-02-28 2022-05-24 埃克森美孚化学专利公司 用油增量的双峰茂金属合成的epdm制备的热塑性硫化橡胶
US10167352B1 (en) 2017-06-28 2019-01-01 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10047174B1 (en) 2017-06-28 2018-08-14 Infineum International Limited Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10174138B1 (en) 2018-01-25 2019-01-08 University Of Massachusetts Method for forming highly reactive olefin functional polymers
US10851187B2 (en) 2018-01-31 2020-12-01 Exxonmobil Chemical Patents Inc. Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
US10865258B2 (en) 2018-01-31 2020-12-15 Exxonmobil Chemical Patents Inc. Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same
WO2019152209A1 (en) * 2018-01-31 2019-08-08 Exxonmobil Chemical Patents Inc. Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
US10829573B1 (en) 2019-05-21 2020-11-10 Infineum International Limited Method for forming highly reactive olefin functional polymers
JP2023532133A (ja) 2020-07-02 2023-07-26 セラニーズ・インターナショナル・コーポレーション メタロセン多峰性コポリマーゴムを含有する熱可塑性加硫物組成物およびその製造方法

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5155080A (en) 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5763547A (en) 1992-10-02 1998-06-09 The Dow Chemical Company Supported catalyst complexes for olefin in polymerization
US5763549A (en) 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
US5387568A (en) 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
EP0500944B1 (en) 1990-07-24 1998-10-07 Mitsui Chemicals, Inc. Catalyst for alpha-olefin polymerization and production of poly-alpha-olefin therewith
JP2895199B2 (ja) 1990-10-02 1999-05-24 三井化学株式会社 オレフィンの重合触媒
US5369196A (en) 1990-11-30 1994-11-29 Idemitsu Kosan Co., Ltd. Production process of olefin based polymers
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5288677A (en) 1991-06-28 1994-02-22 Exxon Chemical Patents Inc. Immobilized Lewis acid catalysts
WO1993011172A1 (en) 1991-11-25 1993-06-10 Exxon Chemical Patents Inc. Polyonic transition metal catalyst composition
CA2105555C (en) 1992-01-06 2003-12-30 Brian W. S. Kolthammer Improved catalyst composition
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5407882A (en) 1992-08-04 1995-04-18 Tosoh Corporation Olefin polymerization catalyst and olefin polymerization process
KR100311244B1 (ko) 1993-02-22 2001-12-15 가지와라 야스시 에틸렌/α-올레핀공중합체의제조방법
US6313240B1 (en) 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
US5498582A (en) 1993-12-06 1996-03-12 Mobil Oil Corporation Supported metallocene catalysts for the production of polyolefins
JP3369294B2 (ja) 1994-03-11 2003-01-20 出光興産株式会社 遷移金属化合物、それを用いた重合用触媒及び該重合用触媒を用いたスチレン系重合体の製造方法
IT1273701B (it) 1994-07-29 1997-07-09 Enichem Elastomers Derivati metallorganici del grupo iiia e procedimento per la loro preparazione
PL318432A1 (en) * 1994-08-03 1997-06-09 Exxon Chemical Patents Inc Ionic supported catalyst composition
US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
US5554775A (en) 1995-01-17 1996-09-10 Occidental Chemical Corporation Borabenzene based olefin polymerization catalysts
US5939347A (en) 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
JPH11501342A (ja) 1995-03-01 1999-02-02 ミネソタ マイニング アンド マニュファクチャリング カンパニー トリス（ペンタフルオロフェニル）ボレート錯体およびそれらから誘導された触媒
CN1116309C (zh) 1995-03-10 2003-07-30 陶氏环球技术公司 负载型催化剂组分、负载型催化剂及制备方法,聚合方法,配位化合物及其制备方法
US5721183A (en) 1995-03-10 1998-02-24 The Dow Chemical Company Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds
MX9708182A (es) 1995-04-25 1998-02-28 Equistar Chem Lp Complejos metalicos de azaborolinilo como catalizadores de polimerizacion de olefinas.
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
WO1997007141A1 (de) 1995-08-18 1997-02-27 Targor Gmbh Katalysatorkomponente und katalysatorsystem mit hoher polymerisationsaktivität zur herstellung von polymeren
US5756609A (en) 1995-10-19 1998-05-26 Amoco Corporation Homogeneous metallocene-based olefin polymerization system with increased activity
IT1275812B1 (it) 1995-10-27 1997-10-17 Enichem Spa Sistema catalitico attivato per la (co)polimerizzazione delle alfa-olefine
US6017842A (en) 1996-07-23 2000-01-25 The Dow Chemical Company Olefin polymerization catalyst composition comprising group 13 compound
US5854166A (en) 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion

Also Published As

Publication number Publication date
CA2330529A1 (en) 1999-12-16
US6211312B1 (en) 2001-04-03
AU743376B2 (en) 2002-01-24
DE69916834D1 (de) 2004-06-03
AU4333399A (en) 1999-12-30
EP1090045B1 (en) 2004-04-28
WO1999064476A1 (en) 1999-12-16
DE69916834T2 (de) 2004-09-30
JP2002517571A (ja) 2002-06-18
EP1090045A1 (en) 2001-04-11
ES2216586T3 (es) 2004-10-16

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B09B Patent application refused [chapter 9.2 patent gazette]

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