MXPA99006252A - Wrappable sleeve - Google Patents

Abstract

A split sleeve (11) for insulation of heat generating components, such as an exhaust gas recirculation device, comprises an outer layer of knitted woven or braided glass fibre yarn (12). A first metal wire (14) skeleton or frame in the form of a continuous wire support for the outer layer (12) is bent in a first step with a series of reverse bends to form a comb-like structure and in a second step to a C-shaped cross-sectional configuration in which the wire defines a cavity and the wire bends define an opening (22) extending lengthwise of the cavity. A layer of heat insulating mineral paper (16) is spaced from the cover layer (12) by the metal wire (14) skeleton. The heat insulating mineral paper (16) is provided with a metal foil layer (18) on the side away from the metal wire (14) skeleton. A second metal wire layer (20) configured like the first extends lengthwise of the sleeve (11) and spaces the reflective surface (19) of the foil (18) from the heat generating component. The various layers of the sleeve are secured together to form an axially extending opening which fits over the component requiring insulation.

Description

COMPOSITION OF TENIDO FOR QUERATXNIC FIBERS WITH DIRECT CATIONIC ON COLORING AND THICK POLYMER ON FIELD OF THE INVENTION The invention relates to a dyeing composition for keratin fibers, in particular for human keratin fibers such as hair, comprising, in a medium suitable for dyeing, at least one direct cationic dye of the given formula and at least one particular thickener polymer. DESCRIPTION OF THE INVENTION The invention also has as its object the dyeing methods and devices that perform said composition. In the capillary field, two types of coloration can be distinguished. The first is the semi-permanent or temporary coloration, or direct coloring, which uses dyes that are able to contribute to the natural coloration of the hair, a more or less pronounced color modification resistant eventually to several shampoos. These dyes are called direct dyes; they can be made with or without oxidizing agent. In the presence of Ref .: '30699 oxidant, the purpose is to obtain a lightening coloration. The lightening coloration is carried out by applying to the hair the extemporaneous mixture of a direct dye and an oxidant and makes it possible, in particular, to obtain by clearing the melanin of the hair, an advantageous effect such as a uniform color in the case of gray hair or highlighting the color in the case of naturally pigmented hair. -The second is permanent coloring or oxidation coloring. This is carried out with dyes called "oxidation" which comprise oxidation dye precursors and copulators. Oxidation staining precursors, commonly called "oxidation bases", are initially colorless or sparsely colored compounds that develop their dyeing power in the hair in the presence of added oxidizing agents at the time of use, leading to the formation of compounds colored and dyes. The formation of these colored compounds and dyes results either from an oxidative condensation of the "oxidation bases" on themselves, or from an oxidative condensation of the "oxidation bases" on coloring modifying compounds commonly called "couplers" and generally present in the dyeing compositions used in oxidation dyeing. To vary the shades obtained with the indicated oxidation dyes, or enrich them with reflections, it happens that direct dyes are added. Among the cationic direct dyes available in the field of dyeing of particularly human keratin fibers, the compounds are already known, whose structure is developed in the following text; however, these dyes lead to colorations that have still insufficient characteristics, while at the same time in the plane of color homogeneity distributed along the fiber, it is said then that the coloration is too selective, as in the plane of the tenacity, in terms of resistance to the various aggressions that the hair can experience (light, bad weather, shampooing). However, after important research carried out on the subject, the applicant firm has now discovered that it is possible to obtain new compositions for the dyeing of keratin fibers capable of carrying out less selective colorations and that better resist the various aggressions that can experience the hair, associating at least one particular thickener polymer with at least one cationic direct dye known from the prior art and with the formulas respectively defined below. This discovery forms the basis of the present invention. The present invention therefore has as its first object a composition for dyeing keratin fibers and in particular human keratin fibers such as hair, which include in a medium suitable for dyeing, (i) at least one direct cationic dye whose structure corresponds to the formulas (I) to (IV) defined below, characterized in that it also contains (ii) at least a particular thickener polymer. (i) The cationic direct dye usable according to the present invention is a compound selected from those of formula (I), (II), (III), (III '), (IV) below: a) compounds of formula (X) ) following: wherein: D represents a nitrogen atom or the group -CH, Ri and R2, identical or different, represent a hydrogen atom; an alkyl radical of C? -C which can be substituted by a radical -CN, -OH -NH2 or form with a carbon atom of the benzene ring an optionally oxygenated or nitrogenated heterocycle, which can be substituted by one or more alkyl radicals of C? -C4; a radical 4'-aminophenyl, R3 and R'3, identical or different, represent a hydrogen or halogen atom selected from chlorine, bromine, iodine and fluorine, a cyano C1-C4 alkyl radical, alkoxy C1-C4 or acetyloxy, X "represents an anion preferably chosen from chloride, methyl sulfate and acetate, A represents a group selected by the following structures Al a Al9: . TO, ?, A 16 '17 x18 wherein R4 represents a C1-C4 alkyl radical which may be substituted by a hydroxyl radical and R5 represents a C4-C4 alkoxy radical, with the proviso that when D represents -CH, A represents A4, or Ai3 and R3 is different from an alkoxy radical, then Ri and R2 do not simultaneously designate a hydrogen atom; b) the compounds of formula (II) below: wherein: R6 represents a hydrogen atom or an alkyl radical of C? -C4, R represents a hydrogen atom, an alkyl radical which can be substituted by a -CN radical, or by an amino group, a radical 4'-Amino-phenyl or form with Re a possibly oxygenated and / or nitrogenated heterocycle which can be substituted by an alkyl radical of C? -C4, Rs and R9, identical or different, represent a hydrogen atom, a halogen atom such as bromine, chlorine, iodine or fluorine, an alkyl radical of C? -C4 or C? -C4 alkoxy, a radical -CN, X? represents an anion preferably chosen from chloride, methyl sulfate and acetate, B represents a group selected by the following structures Bl to B6: in which Rio represents an alkyl radical of C? ~ C, Ru and RX2, identical or different, represent a hydrogen atom or a C? -C4 alkyl radical; c) the following compounds of formulas (XXI) and (XXX '): wherein: R13 represents a hydrogen atom, a C1-C4 alkoxy radical, a halogen atom such as bromine, chlorine, iodine or fluorine or an amino radical, R? 4, represents an atom of hydrogen, an alkyl radical of C? ~ C4, or form with a carbon atom of the benzene ring a heterocycle optionally oxygenated and / or substituted by one or more C? -C alkyl groups, Ri5, represents a hydrogen or halogen atom such as bromine, chlorine, iodine or fluorine, R and R17, identical or different, represent a hydrogen atom or an alkyl radical of C? -C4, Di and D2, identical or different, represent a nitrogen atom or the group -CH , = 0 or 1, it being understood that when R 3 represents an unsubstituted amino group, then Di and D 2 simultaneously represent a group -CH and m = 0, X "represents an anion preferably chosen from chloride, methyl sulfate and acetate, E represents a group selected by structures El a E8 following: E6 E7 E8 wherein R 'represents an alkyl radical of C? -C4; when m = 0 and Di represents a nitrogen atom, then E may also designate a group of structure E9 below: wherein R 'represents an alkyl radical of C? -C4. d) the compounds of formula (IV) below: 6-N = N-J (IV) in which: the symbol G represents a group selected from the following Gx to G3 structures: structures Gi to G3 in which, Ris, designates a C 1 -C 4 alkyl radical, a phenyl radical which can be substituted by a C 1 -C alkyl radical or a halogen atom selected from chlorine, bromine, iodine and fluorine; Ris, designates a C 1 -C 4 alkyl radical or a phenyl radical; R20 and R21, identical or different, represent a C1-C4 alkyl radical, a phenyl radical, or form together in Gi a benzene ring substituted by one or more Cx-C alkyl radicals, C? -C4 alkoxy, or N02 or form together in G2 a benzene ring optionally substituted by one or more C? -C4 alkyl radicals, C? -C4 alkoxy, or N02; R2o, can also designate a hydrogen atom; Z denotes an oxygen atom, a sulfur atom or a -NRi 9 group; M represents a group -CH, -CR (designating R alkyl of C? -C4), or -NR22 (X ") r; K represents a group -CH, -CR (designating R alkyl of C? -C4), or -NR22 (? -) r; P represents a group -CH, -CR (denoting R alkyl of C? -C), or -NR22 (~) r r designates zero or 1; R22 represents a 0"atom, an alkoxy radical of -C? -C4, or an alkyl radical of C? -C4; R23 and R2, identical or different, represent a hydrogen or halogen atom selected from chlorine, bromine , the iodo and fluorine, an alkyl radical of C?-C4, alkoxy of C?-C4, a radical -N02; X "represents an anion preferably chosen from chloride, iodide, methyl sulfate, ethyl sulfate, acetate and perchlorate; with the proviso that, if R22 designates, 0", then r designates zero, if K or P or M designates -N-alkyl C" -C X ", then R23 or R24 is different from a hydrogen atom; if K designates -NR22 (X ~) r, then M = P = -CH, -CR; if M designates -NR22 (X ") r, then K = P = -CH, -CR; if P designates -NR22 (X_) r, then K = M and designate -CH, or -CR; if Z designates a sulfur atom with R2? which designates C 1 -C 4 alkyl, then R 20 is different from a hydrogen atom; if Z designates -NR22 with Ri9 which designates C1-C4 alkyl, then at least one of the radicals Ris, R20 or R2? of G2 is different from a C1-C4 alkyl radical; the symbol J represents; - (a) a group of structure Ji, following: structure Ji in which, R25, represents a hydrogen atom, a halogen atom selected from chlorine, bromine, iodine and fluorine, an alkyl radical of C? -C4, C? -C4 alkoxy, a radical -OH, -N02, -NHR28-NR29R30, -NHCO alkyl of C? ~ C4, or form with R26 a cycle of 5 or 6 links containing or not one or more heteroatoms selected from nitrogen, oxygen or sulfur; R26 represents a hydrogen atom, a halogen atom selected from chlorine, bromine, iodine and fluorine, an alkyl radical of C?-C4, alkoxy of C?-C4, or a form with R2, or R28 a cycle of 5 or 6 links containing or not one or more heteroatoms selected from nitrogen, oxygen or sulfur; R 27 represents a hydrogen atom, a -OH radical, a -NHR 2 β radical, a -NR 29 R 30 radical; Rs represents a hydrogen atom, an alkyl radical of C1-C4, a monohydroxyalkyl radical of C1-C4, polyhydroxyalkyl of C2-C4, a phenyl radical; R29 and R30, identical or different, represent a C1-C4 alkyl radical, a monohydroxyalkyl radical of O.-C4, polyhydroxyalkyl of C? ~ C4; - (b) a 5- or 6-membered nitrogenous heterocyclic group capable of including other heteroatoms and / or carbonylated groups and being able to be substituted by one or more C 1 -C 4 alkyl, amino or phenyl radicals, and particularly a group of structure J 2 below : structure J2 in which, R31 and R32, identical or different, represent a hydrogen atom, an alkyl radical of C? -C4, a phenyl radical; CH3 I Y designates the radical -CO- or the radical - C =; n = or 1, with, when n designates 1, U designates the radical -CO- In the structures (I) to (IV) defined above the alkyl or C 1 -C 4 alkoxy group, preferably designates methyl, ethyl, butyl, methoxy, ethoxy. The cationic direct dyes of formulas (I), (II), (III) and (III ') which can be used in the dyeing compositions according to the invention are known compounds and are described, for example, in patent applications WO 95/01772, WO 95/15144 and EP-A-0714 954. Those of formula (IV) which can be used in the dyeing compositions according to the invention are known compounds and are described, for example, in patent applications FR-2189006, FR-2285851 and FR. -2140205 and its certificates of addition. Among the cationic direct dyes of formula (I) which can be used in the dyeing compositions according to the invention, compounds which respond to structures (II) to (154) below may be mentioned more particularly: CH, / H3C-N X + -CH:: CH- / W N Cl (13) \ CH, í CH, N Among the compounds of structures (II) to (154) described above, compounds which respond to structures (II), (12), (114) and (131) are very particularly preferred. Among the cationic direct dyes of formula (II) which can be used in the dyeing compositions according to the invention, compounds which respond to structures (III) to (119) below may be mentioned more particularly: cr (113) ; and CH, Among the direct cationic dyes of formula (III) which can be used in the dyeing compositions according to the invention, mention may be made more particularly of the compounds which respond to the following structures (lili) to (III18): CH3SO4 (1114) (1117) H3C - N + X-CH CH3SO4 (11113) Among the particular compounds of structures (IIIl) to (III18) described above, compounds which respond to structures (III4), (III5) and (III13) are very particularly preferred. Among the direct cationic dyes of formula (III ') which can be used in the dyeing compositions according to the invention, the compounds which respond to the following structures (III'l) to (III'3) can be more particularly mentioned: Among the cationic direct dyes of formula (IV) which can be used in the dyeing compositions according to the invention, compounds with structures can be mentioned more particularly. { IV) to (IV) 77 following: (, V)? twenty OR I. 10 O I- O 15 CH3SO4- CH3SO4- CH3SO4" CH3SO4" CH3SO4" fifteen CH3SO4" twenty CH3S04"CH3SO4" CH3SO4" C4H9 fifteen twenty fifteen twenty fifteen CH3SO4" fifteen The cationic direct dyes used according to the invention preferably represent from 0.001 to 10% by weight approximately of the total weight of the dyeing composition and even more preferably from 0.005 to 5% by weight approximately of this weight. (ii) The thickening polymer usable according to the present invention is selected from the group consisting of: 1- the crosslinked homopolymers of acrylic acid; 2- the partially neutralized or fully neutralized homopolymers and copolymers of 2-acrylamido-2-methylpropane sulfonic acid; 3- the ammonium acrylate homopolymers and the acrylamide and acrylamide copolymers; 4- cross-linked acid copolymers (meth) acrylic and C 1 -C 6 alkyl acrylate; 5- homopolymers and nonionic copolymers containing ethylenically unsaturated monomers of the ester and / or amide type. Among the crosslinked homopolymers of acrylic acid, there may be mentioned, for example, the products sold under the names CARBOPOLS 980, 981, 954, 2984 and 5984 by the company GOODRICH or the products sold under the names SYNTHALEN M and SYNTHALEN K by the company 3 VSA; Among the homopolymers of 2-acrylamido-2-methylpropane sulfonic acid, mention may be made of those described in the application EP-A-0815828 (which form an integral part of the content of the description). Mention may also be made of the product marketed by the company HENKEL under the name COSMEDIA HSP 1160. Among the copolymers of 2-acrylamido-2-methylpropanesulfonic acid partially or totally neutralized (by a base such as sodium hydroxide, potassium hydroxide or amine), mention may be made in particular of the product described in example 1 of EP-A-503 853 (which forms an integral part of the content of the description), and particularly the product marketed by SEPPIC under the name SEPIGEL 305. Among the ammonium acrylate homopolymers, mention may be made of the product sold under the name MICROSAP PAS 5193 by the Company HOECHST. Among the copolymers of ammonium acrylate and acrylamide, mention may be made of the product sold under the name BOZEPOL C NOUVEAU or the product PAS 5193 sold by the Company HOECHST (described and prepared in documents FR 2 416 723, USP2798053 and USP 2 923 692).

Among the crosslinked copolymers of (meth) acrylic acid and Ci-Ce alkyl acrylate, mention may be made of the product sold under the name VISCOATEX 538C by the company COATEX which is a crosslinked copolymer of methacrylic acid and ethyl acrylate in dispersion Aqueous 38% of Materia Activa or the product sold under the name ACULYN 33 by the company ROHM & HAAS which is a crosslinked copolymer of acrylic acid and ethyl acrylate in 28% aqueous dispersion of Active Material. Among the nonionic homopolymers or copolymers containing ethylenically unsaturated monomers of the ester and / or amide type, mention may be made of the products sold under the names: CYANAMER P250 by the company CYTEC (polyacrylamide); PMMA MBX-8C by the US COSMETICS Company (methyl methacrylate / ethylene glycol dimethacrylate copolymer); ACRYLOID B66 by the RHOM & HAAS (butyl methacrylate / methyl methacrylate copolymer); BPA 500 by the KOBO Company (polymethyl methacrylate). According to the present invention, it is more particularly preferred to use the thickener polymers indicated above in classes 1-; 2-; 3-; 4-, that is, the ones chosen from the group consisting of: 1- the crosslinked homopolymers of acrylic acid; 2- the partially neutralized or fully neutralized 2-acrylamido-2-methylpropanesulfonic acid homopolymers and copolymers; 3-the ammonium acrylate homopolymers and the acrylamide and acrylamide copolymers; 4- the crosslinked copolymers of (meth) acrylic acid and of C? -C6 alkyl acrylate. The thickening polymer (s) (ii), used according to the invention, preferably represent 0.01 and 10% by weight approximately of the total weight of the composition: dyeing, and even more preferably 0.1 to 5% by weight approximately of this weight. The appropriate medium for dyeing (or support) is generally constituted by water or by a mixture of water and by at least one organic solvent to solubilize compounds that are not sufficiently soluble in water. As the organic solvent, there may be mentioned, for example, the lower alkanols of C? -C, such as ethanol and isopropanol; aromatic alcohols such as benzyl alcohol or phenoxyethanol, as well as analogous products and their mixtures. The solvents can be present in proportions preferably comprised between 1 and 40% by weight approximately relative to the total weight of the dyeing composition, and even more preferably between 5 and 30% by weight approximately.

The pH of the dyeing composition. according to the invention, it is generally between approximately 2 and 11, and preferably between approximately 5 and approximately 10. It can be adjusted to the desired value by means of acidifying or alkalizing agents usually used in the dyeing of keratin fibers. Among the acidulating agents, mention may be made, by way of example, of mineral or organic acids such as hydrochloric acid, orthophosphoric acid, sulfuric acid, carboxylic acids such as acetic acid, tartaric acid, citric acid, acid lactic, sulfonic acids. Among the alkalizing agents, mention may be made, by way of example, of ammonia, alkali metal carbonates, alkanolamines such as mono-, di- and triethanolamines as well as their derivatives, sodium or potassium hydroxides and compounds of formula (V) following: wherein W is a propylene residue optionally substituted by a hydroxyl group or an alkyl radical of Ci-Ce R33, R34, R35 and 36, identical or different, represent a hydrogen atom, an alkyl radical of Ci-Cß or hydroxyalkyl of C? -C6. The dyeing composition according to the invention can, in addition to the cationic direct dye (s) defined above, contain one or more additional direct dyes, which can be chosen, for example, from nitrobenzene dyes, anthraquinone dyes, naphthoquinone dyes, triarylmethanic dyes, xanthine dyes, non-cationic azo dyes. When it is intended for dyeing by oxidation, the dyeing composition according to the invention contains, in addition to the cationic direct dye (i) one or more oxidation bases selected from the oxidation bases conventionally used for dyeing by oxidation and between dyes. which may be particularly cited paraphenylenediamines, bis-phenylalkylenediamines, para-aminophenols, ortho-aminophenols and heterocyclic bases. When used, the oxidation base or bases preferably represent from 0.0005 to 12% by weight approximately of the total weight of the dyeing composition, and even more preferably from 0.005 to 6% by weight approximately of this weight .

When it is intended for oxidation dyeing, the dyeing composition according to the invention can also include, in addition to the direct cationic dye (i) and the thickener polymer (ii) as well as the oxidation bases, one or more couplers for the purpose to modify -or enrich with reflections the tonalities obtained using the direct dye (s) cationic (s) (i) and the oxidation base (s).

The copulators which can be used in the dyeing composition according to the invention can be chosen from the couplers conventionally used in the dye by oxidation and among which, metaphenylenediamines, meta-aminophenols, meta-diphenols and heterocyclic couplers can be particularly mentioned.

When present, the copulators or copulators preferably represent from 0.0001 to 10% by weight approximately of the total weight of the dyeing composition and even more preferably from 0.005 to 5% by weight approximately of this weight.

The dyeing composition according to the invention can also include various adjuvants conventionally used in dyeing compositions for hair, such as antioxidants, penetrating agents, sequestering agents, perfumes, buffers, dispersing agents, surface active agents, smoke-killing agents, ceramides. , preservatives, filtering agents, opacifying agents.

Of course, the person skilled in the art will try to choose this or these possible complementary compounds in such a way that the advantageous properties intrinsically related to the dyeing composition according to the invention are not, or substantially, altered by the addition (s) considered.

The dyeing composition according to the invention can be present in various forms, such as in the form of liquids, shampoos, creams, gels, or in any other form suitable for dyeing the keratin fibers, and in particular human hair. It can be obtained by extemporaneous mixing of a composition, possibly pulverulent, containing the cationic direct dye (s) with a composition containing the particular thickener polymer.

When the combination of the cationic direct dye (i) and the thickener polymer (ii) according to the invention is used in a composition intended for oxidation dyeing (one to several oxidation bases are then used, optionally in the presence of one or more copolymers ) or when used in a composition intended for direct lightening dyeing, then the dyeing composition according to the invention further includes at least one oxidizing agent, selected for example between hydrogen peroxide, urea peroxide, alkali metal bromates , persalts such as perborates and persulfates, and enzymes such as peroxidases, laccases and oxidoreductases of two electrons. The use of hydrogen peroxide or enzymes is particularly preferred.

Another object of the invention is a process for dyeing keratin fibers and in particular human keratin fibers such as hair using the dye composition as defined above.

According to a first variant of this dyeing process according to the invention, at least one dyeing composition as defined above is applied to the fibers for a sufficient time to develop the desired dyeing, after which it is rinsed, it is eventually washed with shampoo, it is rinsed again and dried.

The time necessary for the development of the coloration on the keratin fibers is generally between 3 and 60 minutes and even more precisely between 5 and 40 minutes.

According to a second variant of this dyeing process according to the invention, at least one dyeing composition as defined above is applied to the fibers for a sufficient time to develop the desired dyeing, without final rinsing.

According to a particular embodiment of this dyeing process, and when the dyeing composition according to the invention includes at least one oxidation base and at least one oxidizing agent, the dyeing process includes a preliminary step consisting of storing separately , on the one hand, a composition (Al) comprising, in a medium suitable for dyeing, at least one direct cationic dye (i) as defined above and at least one oxidation base and, on the other hand, a composition (Bl) including, in a suitable medium for the dye, at least one oxidizing agent, then in proceeding to its mixture at the time of use- before applying this mixture on the keratin fibers, containing the composition (Al) or the composition (Bl) the polymer thickener (ii) as defined above.

According to another particular embodiment of this dyeing process, and when the dyeing composition according to the invention includes at least one oxidizing agent, the dyeing process includes a preliminary step consisting of storing separately, on the one hand, a composition (A2) comprising, in a medium suitable for dyeing, at least one direct cationic dye (i) as defined above and, on the other hand, a composition (B2) including, in a medium suitable for dyeing , at least one oxidizing agent, then in mixing it at the time of use before applying this mixture on the keratin fibers, the composition (A2) or the composition (B2) containing the thickening polymer as defined above .

Another object of the invention is a multi-compartment device or dye "kit" or any other multi-compartment conditioning system of which a first compartment includes the composition (Al) or (A2) as defined above and a second , compartment includes the composition (Bl) or (B2) as defined above. These devices can be equipped with a means for providing the desired mixture on the hair, such as the devices described in patent FR-2,586,913 in the name of the applicant. The following examples are intended to illustrate the invention without thereby limiting the scope.

EXAMPLES EXAMPLE 1 to 4 The four direct dye compositions grouped in the following table were prepared: (all contents are expressed in grams) MA * is gna Active Matter The compositions indicated above were each applied for 30 minutes on wicks of natural gray hair at 90% white. The hair strands were then rinsed, washed with a standard shampoo and then dried. The wicks were stained in the following shades: It is noted that in relation to this date, the best method known to the applicant to carry out the aforementioned invention, is that which is clear from the present description of the invention.

Having described the invention as above, property is claimed as contained in the following:

Claims (24)

1. RE IV IND I CAC I ONE S 1. Composition for dyeing keratin fibers and in particular human keratin fibers such as hair, characterized Doraue .. included in a suitable medium for dyeing, (i) at least one compound selected from those of formulas (I), (II), (III), (III '), (IV) below: a) the compounds of formula (I) below: wherein: D represents a nitrogen atom or the group -CH, Ri and 2, identical or different, represent a hydrogen atom; an alkyl radical of C? -C4 which can be substituted by a radical -CN, -OH -NH2 or form with a carbon atom of the benzene ring a possibly oxygenated or nitrogenated heterocycle, which can be substituted by one or more alkyl radicals of C? -C4; a radical 4'-aminophenyl, R3 and R'3, identical or different, represent a hydrogen or halogen atom selected from chlorine, bromine, iodine and fluorine, a cyano C1-C4 alkyl radical, alkoxy C1-C4 or acetyloxy, X ~ represents an anion preferably chosen from chloride, methyl sulfate and acetate, A represents a group selected by the structures Al to Al9 following: ? A. As * A7 10 11 l12 wherein R4 represents a C1-C4 alkyl radical that can be substituted by a hydroxyl radical and R5 represents a C1-C4 alkoxy radical, with the proviso that when D represents -CH, A represents .A4, or A13 and R3 is different from an alkoxy radical, then Ri and R2 do not simultaneously designate a hydrogen atom; b) the compounds of formula (II) below: wherein: R6, represent a hydrogen atom or an alkyl radical of L-C4, R7, represent a hydrogen atom, an alkyl radical which can be substituted by a -CN radical, or by an amino group, a radical '-aminophenyl, or form with R6 an optionally oxygenated and / or nitrogenated heterocycle which OO can be substituted by a C1-C4 alkyl radical, R8 and R9, identical or different, represent a hydrogen atom, a halogen atom such as bromine, chlorine, iodine or fluorine, a C1-C4 alkyl radical or C? -C4 alkoxy, a radical - CN, X represents a preferred anion chosen from chloride, methyl sulfate and acetate, B represents a group selected by the following structures Bl to B6: B4 B5 B6 in which Rio represents an alkyl radical of C? -C, Ra and Ri2, identical or different, represent a hydrogen atom or an alkyl radical of C? -C4; c) the following compounds of formulas (III) and (III '): wherein: R13 represents a hydrogen atom, an alkoxy radical of C1-C4, a halogen atom such as bromine, chlorine, iodine or fluorine or an amino radical, R14, represents a hydrogen atom, an alkyl radical of C1-C4, or form with a carbon atom of the benzene ring a heterocycle optionally oxygenated and / or substituted by one or more C1-C4 alkyl groups, R1S, represents a hydrogen or halogen atom such as bromine, chlorine , the iodine or the fluorine, Ie and Rp, identical or different, represent a hydrogen atom or a C 1 -C 4 alkyl radical Di and D 2, identical or different, represent a nitrogen atom or the group -CH, m = 0 or 1, it being understood that when R 3 represents an unsubstituted amino group, then Di and D 2 simultaneously represent a group -CH and m = 0, X represents an anion preferably chosen from chloride, methyl sulfate and acetate, and represents a group selected by the structures El a E8 following: E7 E8 wherein R 'represents an alkyl radical of C? -C4; when m = 0 and Di represents a nitrogen atom, then E may also designate a group of structure E9 below: wherein R 'represents a C 1 -C 4 alkyl radical d) the compounds of formula (XV) below: G - N = N - J (IV) in which: the symbol G represents a group chosen from the following Gi to G3 structures: G, G, structures Gi to G3 in which, Ris, designates a C 1 -C 4 alkyl radical, a phenyl radical which can be substituted by a C 1 -C 4 alkyl radical or a halogen atom selected from chlorine, bromine, iodine and fluorine; R 19 denotes a C 1 -C 4 alkyl radical or a phenyl radical; R20 and R21, identical or different, represent an alkyl radical of C? -C4, a phenyl radical, or together form in Gi a benzene ring substituted by one or more C? -C4 alkyl radicals, C? -C4 alkoxy, or N02, or form together in G2 a benzene ring optionally substituted by one or more C?-C4 alkyl radicals, C?-C4 alkoxy, or N02; R 20 can also designate a hydrogen atom; Z denotes an oxygen atom, a sulfur atom or a group -NR? 9; M represents a group -CH, -CR (denoting R alkyl of C? ~ C4), or -NR22 (? -) r; K represents a group -CH, -CR (denoting R alkyl of C? ~ C4), or -NR22 (X ") r; P represents a group -CH, -CR (denoting R C 4 C alkyl), or -NR 22 (X ~) r; r designates zero or 1; R22 represents an atom 0 ~, a C1-C4 alkoxy radical, or an alkyl radical of C? -C4 R23 and R24, identical or different, represent a hydrogen or halogen atom selected from chlorine, bromine, iodine and fluorine, a C1-C4 alkyl radical, C1-C4 alkoxy, a -N02 radical; X "represents an anion preferably chosen from chloride, iodide, methyl sulfate, ethyl sulfate, acetate, and perchlorate, with the proviso that, if R22 designates, 0", then r designates zero; if K or P or M designates -N-C1-C4alkyl X ", then R23 or R24 is different from a hydrogen atom, if K designates -NR22 (X") r then M = P = -CH, -CR; if M designates -NR22 (X ~) r then K = P = -CH, -CR; if P designates -NR22 (X ") r then K = M and designate -CH, or -CR; if Z designates a sulfur atom with R2i which designates C1-C4 alkyl, then R2o is different from a hydrogen atom; if Z designates -NR22 with Ri9 which designates C1-C4 alkyl, then at least one of the radicals Rie, R20 or R2 ?, of G2 is different from a C1-C4 alkyl radical; the symbol J represents; - (a) a group of structure I, following: structure Ji in which, R25, represents a hydrogen atom, a halogen atom selected from chlorine, bromine, iodine and fluorine, an alkyl radical of C? -C4, alkoxy of C? -C4 a radical - OH, N02, -NHR28-NR29R3o, -NHCO alkyl of C? -C, or form with R26, a cycle of 5 or 6 links containing or not one or more heteroatoms selected from nitrogen, oxygen or sulfur; R26 represents a hydrogen atom, a halogen atom selected from chlorine, bromine, iodine and fluorine, an alkyl radical of C?-C4, alkoxy of C?-C4, or form with R27, or R28 a cycle of 5 or 6 links containing or not one or more heteroatoms selected from nitrogen, oxygen or sulfur; R 27 represents a hydrogen atom, a -OH radical, a radical -NHR 2 β, a radical -R 29 30; R28 represents a hydrogen atom, a C1-C4 alkyl radical, a C1-C4 monohydroxyalkyl radical, a C2-C4 polyhydroxyalkyl radical, a phenyl radical; R29 and R30, identical or different, represent a C 1 -C 4 alkyl radical, a C 1 -C 4 monohydroxyalkyl radical, C 1 -C 4 polyhydroxyalkyl radical; - (b) a 5- or 6-membered nitrogenous heterocyclic group capable of including other heteroatoms and / or carbonylated groups and being able to be substituted by one or more C?-C4, amino or phenyl alkyl radicals, and particularly a group of structure J2 following: structure J2 in which, R31 and R32, identical or different, represent a hydrogen atom, an alkyl radical of C? -C4, a phenyl radical; CH3 I Y designates the radical -CO- or the radical - C =; n = 0 or 1, with, when n designates 1, U designates the radical -CO- characterizing said composition by the fact that it also contains (ii) at least one thickening polymer selected from the group comprising: 1- the crosslinked homopolymers of acrylic acid; 2- the partially neutralized or fully neutralized homopolymers and copolymers of 2-acrylamido-2-methylpropane sulfonic acid; 3- the ammonium acrylate homopolymers and the acrylamide and acrylamide copolymers; 4- the crosslinked copolymers of (meth) acrylic acid and of Ci-Cß alkyl acrylate; 5- the nonionic homopolymers and copolymers containing ethylenically unsaturated monomers of the ester and / or amide type. Composition according to Claim 1, characterized in that the cationic direct dyes of formula (I) are chosen from the compounds which correspond to the structures (II) to (154) below: (16) Cl (126) 3. Composition according to claim 2, characterized in that the direct cationic dyes respond to structures (II), (12), (114), and (131). 4. Compositions according to claim 1, characterized in that the direct cationic dyes of formula (II) are chosen from the compounds that respond to structures (III) to (1119) below: CH3SO4 (H5) 5. Composition according to claim 1, characterized in that the direct cationic dyes of formula (III) are chosen from the compounds that respond to the following structures (lili) to (III18): H3C- -N + -CH = N - N- // W CH3SO4"(||| 4) CK H3C- -N? + - CH Cl (11117) 6. Composition according to claim 5, characterized in that the direct cationic dyes of formula (III) are chosen from the compounds that respond to structures (III4), (III5) and (III13). 7. Composition according to claim 1, characterized in that the cationic direct dyes of formula (III ') are chosen from the compounds that respond to the following structures (III' 1) to (III '3): 8. Composition according to claim 1, characterized in that the cationic direct dyes of formula (IV) are chosen from the compounds that respond to the following structures (IVi) to (IV77): I. O CH3S04- CH3S04"CH3SO4- CH3SO4- 10 CH3SO4" fifteen CH3SO4- 20 CH3S04- CH3SO4- CH3SO4" 10 C4HS C 20 50 10 fifteen 10 fifteen twenty fifteen CH3SO4"CH3SO4" 10 fifteen twenty 9. Composition according to any one of the preceding claims, characterized in that the cationic direct dye (s) of formulas (I), (II), (III), (III ') or (IV) represent from 0.001 to 10% in weight of the total weight of the composition. Composition according to Claim 9, characterized in that the cationic direct dye (s) of formulas (I), (II), (III), (III ') or (IV) represent from 0.005 to 5% by weight of the total weight of the composition. Composition according to claim 1, characterized in that the thickener polymer of class (4) is a crosslinked copolymer of methacrylic acid and ethyl acrylate. Composition according to claim 1, characterized in that the thickener polymer of class (4) is a crosslinked copolymer of acrylic acid and ethyl acrylate. Composition according to any one of Claims 1, 11 and 12, characterized in that the thickener polymer (ii) represents from 0.01 to 10% by weight of the total weight of the composition. 14. Composition according to claim 13, characterized in that the thickener polymer (ii) represent from 0.1 to 5% by weight of the total weight of the composition. Composition according to any one of the preceding claims, characterized in that the medium suitable for the dye (or support) is constituted by water or by a mixture of water and at least one organic solvent. Composition according to any one of the preceding claims, characterized in that it has a pH comprised between 2 and 11, and preferably between 5 and 10. 17. Composition according to any one of the preceding claims, characterized by the The fact that it is intended for oxidation dyeing and because it contains one or more oxidation bases selected from para-phenylenediamines, bis-phenylalkylenediamines, para-aminophenols, ortho-aminophenols and heterocyclic bases. 18. Composition according to claim 17, characterized in that the oxidation base (s) represent from 0.0005 to 12% by weight of the total weight of the dyeing composition. 19. Composition according to claim 18, characterized in that the oxidation base (s) represent from 0.005 to 6% by weight of the total weight of the dyeing composition. Composition according to any one of Claims 17 to 19, characterized in that it includes one to several couplers selected from meta-phenylenediamines, meta-aminophenols, meta-diphenols and heterocyclic couplers. The composition according to claim 20, characterized in that the coupler (s) represent from 0.0001 to 10% by weight of the total weight of the dyeing composition. 22. Composition according to claim 21, characterized in that the coupler (s) represent from 0.005 to 5% by weight of the total weight of the dyeing composition. Composition according to any one of the preceding claims, characterized in that it is intended for oxidation dyeing or direct lightening dyeing and includes at least one oxidizing agent. 24. Process for dyeing keratin fibers and in particular human keratin fibers such as hair, characterized in that at least one dyeing composition is applied to the fibers as defined in any one of claims 1 to 23, for a sufficient time to develop the desired coloration, after which it is rinsed, washed eventually with shampoo, rinsed again and dried. 2b. Dyeing process of keratin fibers and in particular of human keratin fibers such as hair, characterized in that at least one dyeing composition as defined in any one of claims 1 to 23 is applied to the fibers, for a sufficient time to develop the desired coloration, without final rinse. 26. Process for dyeing keratin fibers and in particular human keratin fibers, such as hair, characterized in that it comprises a preliminary stage consisting in storing separately, on the one hand, a composition (Al) comprising , in a medium suitable for the dye, at least one cationic direct dye (i) as defined in claims 1 to 10 and at least one oxidation base and, on the other hand, a composition (Bl) that includes, in a suitable medium for the dye, at least one oxidizing agent, then in proceeding to its mixing at the time of use before applying this mixture on the keratin fibers, containing the composition (Al) to the composition (Bl) the thickening polymer (ii) as defined in claims 1 and 11 to 14. 27. Dyeing process of the keratin fibers and in particular of the human keratin fibers such as the hair , characterized in that it comprises a preliminary step consisting in storing separately, on the one hand, a composition (A2) comprising, in a medium suitable for dyeing, at least one direct cationic dye (i) as defined in claims 1 to 10 and, on the other hand, a composition (B2) including, in a means suitable for the dye, at least one oxidizing agent, then in proceeding to its mixing at the time of use before applying this mixture on the keratin fibers, the composition (A2) or the composition (B2) containing the thickening polymer ( ii) as defined in claims 1, and 11 to 14. 28. Multi-compartment staining device or "kit", characterized in that a first compartment includes the composition (Al) or ( A2) as defined in claim 26 or 27 and a second compartment includes composition (Bl) or (B2) as defined in claim 26 or 27.