Nothing Special   »   [go: up one dir, main page]

MX2014010831A - Procedimiento continuo para la sintesis de polimeros de injerto basados en polieteres. - Google Patents

Procedimiento continuo para la sintesis de polimeros de injerto basados en polieteres.

Info

Publication number
MX2014010831A
MX2014010831A MX2014010831A MX2014010831A MX2014010831A MX 2014010831 A MX2014010831 A MX 2014010831A MX 2014010831 A MX2014010831 A MX 2014010831A MX 2014010831 A MX2014010831 A MX 2014010831A MX 2014010831 A MX2014010831 A MX 2014010831A
Authority
MX
Mexico
Prior art keywords
continuous process
graft polymers
polyethers
synthesis
polymers based
Prior art date
Application number
MX2014010831A
Other languages
English (en)
Inventor
Rainer Dobrawa
Dieter Boeckh
Aaron Flores-Figueroa
Faissal-Ali El-Toufaili
Michaela Heubler
Christian Schwede
Wolfgang Loth
Gerd Konrad
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2014010831A publication Critical patent/MX2014010831A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/242—Tubular reactors in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2435—Loop-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/249—Plate-type reactors
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/08—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00788—Three-dimensional assemblies, i.e. the reactor comprising a form other than a stack of plates
    • B01J2219/00792—One or more tube-shaped elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00858—Aspects relating to the size of the reactor
    • B01J2219/0086—Dimensions of the flow channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00873—Heat exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00889—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00891—Feeding or evacuation
    • B01J2219/00894—More than two inlets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00905—Separation
    • B01J2219/00916—Separation by chromatography

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Graft Or Block Polymers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

La invención se refiere a un procedimiento continuo para la preparación de polímeros de injerto anfifílicos, en donde un componente de éster de vinilico (B) compuesto de acetato de vinilo y/o propionato de vinilo (B1) y, si se desea, otro monómero etilénicamente insaturado (B2), es polimerizado en presencia de un óxido de polialquileno (A), un iniciador que formar radicales libres (C) y, si se desea, un aditivo (D), a una temperatura media de polimerización a la cual el iniciador (C) tiene un tiempo medio de descomposición de 1 a 500 min, en por lo menos un segmento de reactor tubular con un lado de la alimentación y un lado de salida, a través del cual corre la mezcla de reacción que comprende por lo menos una parte del componente (A) a (C), y si se desea (D). La invención se refiere además a un polímero de injerto anfifílico de la invención y al uso de éste.
MX2014010831A 2012-03-09 2013-03-08 Procedimiento continuo para la sintesis de polimeros de injerto basados en polieteres. MX2014010831A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12158794 2012-03-09
PCT/EP2013/054673 WO2013132042A1 (en) 2012-03-09 2013-03-08 Continuous process for the synthesis of graft polymers based on polyethers

Publications (1)

Publication Number Publication Date
MX2014010831A true MX2014010831A (es) 2016-04-15

Family

ID=47884310

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014010831A MX2014010831A (es) 2012-03-09 2013-03-08 Procedimiento continuo para la sintesis de polimeros de injerto basados en polieteres.

Country Status (11)

Country Link
EP (4) EP2865692A1 (es)
JP (1) JP2015512981A (es)
KR (1) KR20140136939A (es)
CN (1) CN104271626B (es)
CA (1) CA2865460A1 (es)
ES (1) ES2587787T3 (es)
MX (1) MX2014010831A (es)
PH (1) PH12014502017B1 (es)
PL (1) PL2822981T3 (es)
RU (1) RU2014140667A (es)
WO (1) WO2013132042A1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160090447A1 (en) * 2013-05-29 2016-03-31 Basf Se Continuous Process For The Preparation Of Polyoxazolines
US9534062B2 (en) * 2014-07-02 2017-01-03 Corning Incorporated Synthesis of an acrylate polymer in flow reactor
CN107849175B (zh) * 2015-07-24 2020-12-04 巴斯夫欧洲公司 在反应器单元系列中制备n-乙烯基羧酰胺
EP3168237A1 (en) * 2015-11-10 2017-05-17 Dow Global Technologies LLC High pressure, free radical polymerizations to produce ethylene-based polymers
WO2017080909A1 (de) * 2015-11-11 2017-05-18 Fluitec Invest Ag Vorrichtung zur durchführung einer chemischen reaktion in einem kontinuierlichen verfahren
EP3205393A1 (en) 2016-02-12 2017-08-16 Basf Se Process for preparation of microcapsules
CN106748943B (zh) * 2016-12-30 2018-03-02 厦门金达威维生素有限公司 一种维生素a中间体双格氏缩合物的连续水解中和的方法及装置
CN108671867A (zh) * 2018-06-06 2018-10-19 博立尔化工（扬州）有限公司 一种制备固体丙烯酸树脂的设备及其方法
CN111087539B (zh) * 2018-10-24 2021-10-19 中国石油化工股份有限公司 用于制备轻烃交替共聚微球的反应装置和方法
JP2023515384A (ja) * 2020-02-14 2023-04-13 ビーエーエスエフ ソシエタス・ヨーロピア 生分解性グラフトポリマー
CN111408319B (zh) * 2020-03-26 2022-01-28 北京理工大学 一种制备对叔丁基甲苯的方法
US20240368316A1 (en) * 2021-09-24 2024-11-07 Sekisui Chemical Co., Ltd. Chlorinated vinyl-chloride-based resin, resin composition for molding, and molded object
WO2023048247A1 (ja) * 2021-09-24 2023-03-30 積水化学工業株式会社 塩素化塩化ビニル系樹脂、成形用樹脂組成物及び成形体
EP4292699A1 (de) 2022-06-17 2023-12-20 Fluitec Invest AG Vorrichtung und verfahren zur durchführung einer nicht-selektiven chemischen reaktion
EP4386025A1 (de) * 2022-12-15 2024-06-19 Aurotec GmbH Verfahren und modularer reaktor zur herstellung eines prepolymers

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1077430B (de) 1958-04-15 1960-03-10 Hoechst Ag Verfahren zur Herstellung von Pfropfpolymerisaten von Polyvinylestern
FR1222944A (fr) 1958-04-15 1960-06-14 Hoechst Ag Polymères greffés et leur procédé de préparation
NL7700412A (nl) * 1977-01-15 1978-07-18 Synres Internationaal Nv Continu bereiding van polymeren in de massa.
DE3536530A1 (de) 1985-10-12 1987-04-23 Basf Ag Verwendung von pfropfcopolymerisaten aus polyalkylenoxiden und vinylacetat als vergrauungsinhibitoren beim waschen und nachbehandeln von synthesefasern enthaltendem textilgut
DE3711319A1 (de) 1987-04-03 1988-10-20 Basf Ag Verwendung von pfropfpolymerisaten auf basis von polyalkylenoxiden als vergrauungsinhibitoren beim waschen und nachbehandeln von synthesefasern enthaltendem textilgut
DE3711298A1 (de) 1987-04-03 1988-10-13 Basf Ag Verwendung von propfpolymerisaten auf basis von polyalkylenoxiden als vergrauungsinhibitoren beim waschen und nachbehandeln von synthesefasern enthaltendem textilgut
DE3711318A1 (de) 1987-04-03 1988-10-20 Basf Ag Verwendung von pfropfpolymerisaten auf basis von polyalkylenoxiden als vergrauungsinhibitoren beim waschen und nachbehandeln von synthesefasern enthaltendem textilgut
FR2768740B1 (fr) * 1997-09-19 2001-07-06 Bp Chem Int Ltd Procede de polymerisation continue d'un monomere vinylique
DE19814739A1 (de) 1998-04-02 1999-10-07 Basf Ag Verwendung von Polyalkylenoxid-haltigen Pfropfpolymerisaten als Solubilisatoren
DE19816886C2 (de) * 1998-04-17 2001-06-07 Axiva Gmbh Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polymerisaten
DE10050958A1 (de) * 2000-10-13 2002-04-18 Basf Ag Verwendung von wasserlöslichen oder wasserdispergierbaren Polyetherblöcken enthaltenden Pfropfpolymerisaten als Beschichtungs- und Verpackungsmittel für Wasch-, Reinigungs- und Wäschebehandlungsmitte
DE10245858A1 (de) 2002-09-30 2004-04-08 Basf Ag Verwendung von Polyetherblöcken enthaltenden Pfropfpolymerisaten zur Oberflächenveredelung von Papier
DE102005053064A1 (de) * 2005-11-04 2007-05-16 Basf Ag Verfahren zur Herstellung von Pfropfpolymerisaten
DE102006055473B4 (de) 2005-12-21 2019-05-16 Basf Se Verfahren zur Herstellung von Pfropfcopolymeren auf Basis von Polyethern
WO2007138053A1 (en) 2006-05-31 2007-12-06 Basf Se Amphiphilic graft polymers based on polyalkylene oxides and vinyl esters
WO2009013202A1 (de) 2007-07-26 2009-01-29 Basf Se Verfahren zur herstellung von durch pfropfpolymerisation in lösung erhaltenen copolymeren auf basis von polyethern in fester form
CN102015775B (zh) * 2008-05-02 2014-07-09 巴斯夫欧洲公司 通过自由基聚合连续生产聚合物的方法及设备
JP5693598B2 (ja) 2009-11-04 2015-04-01 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 水性ポリアクリル酸溶液の製造方法
WO2011061076A1 (de) * 2009-11-17 2011-05-26 Basf Se Verfahren zur herstellung von pfropfcopolymeren auf basis von polyethern

Also Published As

Publication number Publication date
ES2587787T3 (es) 2016-10-26
PH12014502017A1 (en) 2014-11-24
JP2015512981A (ja) 2015-04-30
EP2862884A1 (en) 2015-04-22
EP2865692A1 (en) 2015-04-29
WO2013132042A1 (en) 2013-09-12
EP2886567A1 (en) 2015-06-24
CN104271626A (zh) 2015-01-07
CA2865460A1 (en) 2013-09-12
PL2822981T3 (pl) 2016-11-30
KR20140136939A (ko) 2014-12-01
PH12014502017B1 (en) 2014-11-24
RU2014140667A (ru) 2016-04-27
CN104271626B (zh) 2017-03-15
EP2822981A1 (en) 2015-01-14
EP2822981B1 (en) 2016-05-25

Similar Documents

Publication Publication Date Title
PH12014502017B1 (en) Continuous process for the synthesis of graft polymers based on polyethers
PH12015500393A1 (en) Process for producing polymers
WO2010091345A3 (en) Novel multifunctional azo initiators for free radical polymerizations: uses thereof
PH12016500854A1 (en) Method for controlling polyolefin properties during polymerisation
WO2013093632A3 (en) Polymer dispersions, their preparation and use
WO2012125788A3 (en) Synthesis of 2,3,3,3-tetrafluoropropene containing fluoropolymers
MY156587A (en) Process for the continuous production of polyesters
NZ736149A (en) Durable anti-fingerprint polymers and coating compositions
MX2017006809A (es) Polimero multifasico como agente de espesamiento y suspension.
MY166046A (en) Process for preparing high-reactivity isobutene homo-or copolymers
MY162438A (en) Process for producing water-absorbent resin
PH12017502077A1 (en) Copolymers of bicyclic (meth)acrylates and alkyl (meth)acrylates and their use as rheology modifiers in fuels
MX2016005089A (es) Fluorocopolimero curable formado a partir de tetrafluoropropeno.
ATE488532T1 (de) Kontinuierliches polymerisationsverfahren
MX2016016709A (es) Proceso para preparar polimeros basados en etileno que usa una distribucion de monoxido de carbono.
MX2013002770A (es) Proceso para producir una resina de cloruro de polivinilo (pvc).
MY173470A (en) Polyalkenyl coupling agent and conjugated diene polymers prepared therefrom
WO2009100956A3 (de) Kontinuierlich betriebenes verfahren zur herstellung von copolymeren
DE502007001870D1 (de) Verfahren zur herstellung von ethylencopolymeren
MX2017004771A (es) Emulsiones y productos de polímero de etilvinilacetato/acrílico y métodos relacionados con estos.
EA201690674A1 (ru) Композиция полиэтилена, подходящая для применений в литье под давлением
MY179907A (en) Method of producing (meth)acrylic resin composition
MY187040A (en) Thermoplastic resin composition, method for producing same, and molded article of same
JP2018518574A5 (es)
MX2015008309A (es) Preparacion de polimeros de baja viscocidad.