Nothing Special   »   [go: up one dir, main page]

Pranckevicius et al., 2013 - Google Patents

Three-Coordinate, Cyclic Bent Allene Iron Complexes

Pranckevicius et al., 2013

Document ID
11402065098436267428
Author
Pranckevicius C
Stephan D
Publication year
Publication venue
Organometallics

External Links

Snippet

Novel three-coordinate Fe complexes featuring 1, 2-diphenyl-3, 5-bis (2, 6- dimethylphenoxy) pyrazolin-4-ylidine or “cyclic bent allene”(CBA) have been synthesized. Reaction with FeCl2 (PPh3) 2 results in the loss of both phosphines to yield monomeric Fe …
Continue reading at pubs.acs.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic System
    • C07F1/08—Copper compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds

Similar Documents

Publication Publication Date Title
Pranckevicius et al. Three-Coordinate, Cyclic Bent Allene Iron Complexes
Whited et al. Dinitrogen complexes supported by tris (phosphino) silyl ligands
Pranckevicius et al. Cyclic bent allene hydrido-carbonyl complexes of ruthenium: highly active catalysts for hydrogenation of olefins
Huang et al. Stereoelectronic effects characterizing nucleophilic carbene ligands bound to the Cp* RuCl (Cp*= η5-C5Me5) moiety: A structural and thermochemical investigation
Archer et al. Arene coordination in bis (imino) pyridine iron complexes: identification of catalyst deactivation pathways in iron-catalyzed hydrogenation and hydrosilation
Lipschutz et al. Synthesis, characterization, and alkyne trimerization catalysis of a heteroleptic two-coordinate FeI complex
Yu et al. Binding affinity of alkynes and alkenes to low-coordinate iron
Weinberger et al. Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino) carbenes
Murugesan et al. Synthesis, structure, and reactivity of Co (II) and Ni (II) PCP pincer borohydride complexes
Northcutt et al. 11B NMR: A New Tool for the Determination of Hapticity of Tris (pyrazolyl) borate Ligands
Haller et al. Activation of an Alkyl C− H Bond Geminal to an Agostic Interaction: An Unusual Mode of Base-Induced C− H Activation
Liu et al. Do short C–H–M (M= Cu (I), Ag (I)) distances represent agostic interactions in pincer-type complexes? unusual NHC transmetalation from Cu (I) to Ag (I)
Gischig et al. A dinuclear copper (I) complex containing a bridging chiral tridentate carbene ligand
Chai et al. Synthesis and Reaction of [{HC (CMeNAr) 2} Mn] 2 (Ar= 2, 6-i Pr2C6H3): The Complex Containing Three-Coordinate Manganese (I) with a Mn− Mn Bond Exhibiting Unusual Magnetic Properties and Electronic Structure
Xu et al. Activation of sp3 Carbon− Hydrogen Bonds by Cobalt and Iron Complexes and Subsequent C− C Bond Formation
Gierz et al. Rhodium complexes bearing 1, 10-phenanthroline analogue bis-NHC ligands are active catalysts for transfer hydrogenation of ketones
Ouyang et al. Linear and T-shaped iron (I) complexes supported by N-heterocyclic carbene ligands: Synthesis and structure characterization
Timerbulatova et al. Bimetallic complexes for enhancing catalyst efficiency: probing the relationship between activity and intermetallic distance
Wang et al. Monomeric Bis (anilido) iron (II) Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Redox Reactivity toward Aryl Halides
Morris Estimating the wavenumber of terminal metal-hydride stretching vibrations of octahedral d6 transition metal complexes
Stokes et al. Low-coordinate iron complexes stabilized by N-(tert-hydrocarbyl) anilide ligation: Adduct formation, chemical oxidation, and nitric oxide complexation
Zhang et al. Dinuclear Iron–Imido Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Structure, and Redox Reactivity
Walter et al. Reactivity studies on [Cp′ FeI] 2: monomeric amido, phenoxo, and alkyl complexes
Gilbertson et al. Coordination chemistry of H2 and N2 in aqueous solution. Reactivity and mechanistic studies using trans-FeII (P2) 2X2-type complexes (P2= a chelating, water-solubilizing phosphine)
Reid et al. Syntheses and structures of dinuclear double-stranded helicates of divalent manganese, iron, cobalt, and zinc