Nothing Special   »   [go: up one dir, main page]

Xu et al., 2009 - Google Patents

Activation of sp3 Carbon− Hydrogen Bonds by Cobalt and Iron Complexes and Subsequent C− C Bond Formation

Xu et al., 2009

Document ID
12320018221713521334
Author
Xu G
Sun H
Li X
Publication year
Publication venue
Organometallics

External Links

Snippet

The sp3 C− H bond activation induced by CoMe (PMe3) 4 and FeMe2 (PMe3) 4 was investigated. C (sp3)-cyclometalated complexes, based on diphosphinito PCP ligand (Ph2POCH2) 2CH2, Co {(Ph2POCH2) 2CH}(PMe3) 2 (1), and Fe {(Ph2POCH2) …
Continue reading at pubs.acs.org (other versions)

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02Boron compounds
    • C07F5/025Boronic and borinic acid compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • C07F17/02Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds

Similar Documents

Publication Publication Date Title
Xu et al. Activation of sp3 Carbon− Hydrogen Bonds by Cobalt and Iron Complexes and Subsequent C− C Bond Formation
Zhang et al. Electron-rich, bulky ruthenium PNP-type complexes. Acceptorless catalytic alcohol dehydrogenation
Kimura et al. PCP pincer palladium complexes and their catalytic properties: Synthesis via the electrophilic ligand introduction route
van der Boom et al. Carbon− Carbon Bond Activation by Rhodium (I) in Solution. Comparison of sp2− sp3 vs sp3− sp3 C− C, C− H vs C− C, and Ar− CH3 vs Ar− CH2CH3 Activation
Kawamoto et al. Pd⊙⊙⊙ H− C Interactions. Preparation and Structure of Orthometalated Tetranuclear Complexes of Palladium (II) and Platinum (II)
Coalter et al. Cleavage of H− C (sp2) and C (sp2)− X Bonds (X= Alkyl, Aryl, OR, NR2): Facile Decarbonylation, Isonitrile Abstraction, or Dehydrogenation of Aldehydes, Esters, Amides, Amines, and Imines by [RuHCl (PiPr3) 2] 2
Kent et al. Cobalt PCP pincer complexes via an unexpected sequence of ortho metalations
Reid et al. Syntheses and structures of dinuclear double-stranded helicates of divalent manganese, iron, cobalt, and zinc
Petuker et al. Controlled Flexible Coordination in Tripodal Iron (II) Phosphane Complexes: Effects on Reactivity
Allen et al. Ruthenium complexes of CP3: A new carbon-centered polydentate podand ligand
Chang et al. C–H bond cleavage of acetonitrile by iridium complexes bearing PNP-pincer-type phosphaalkene ligands
Mungur et al. Titanium (IV) alkoxy-N-heterocyclic carbenes: Structural preferences of alkoxide and bromide adducts
Yuki et al. Synthesis and Reactivity of Tungsten− and Molybdenum− Dinitrogen Complexes Bearing Ferrocenyldiphosphines toward Protonolysis
Lamac et al. Preparation of chiral phosphinoferrocene carboxamide ligands and their application to palladium-catalyzed asymmetric allylic alkylation
Kawamura et al. 2-Phenylimidazole− PdCl2 and 2-Phenylimidazoline− PdCl2 Complexes: Single-Crystal and Powder X-ray Diffractometry, 1H NMR Spectra, and Comparison of Catalytic Activities in Coupling Reactions
Mulford et al. Reactions of alkynes and olefins with tantalum hydrides containing aryloxide ancillary ligation: relevance to catalytic hydrogenation
Atkinson et al. Synthesis, coordination chemistry, and catalytic application of a novel unsymmetrical P/O ferrocenediyl ligand
Hosokawa et al. NCN-pincer cobalt complexes containing bis (oxazolinyl) phenyl ligands
Allouch et al. Converging and diverging synthetic strategies to tetradentate (N, N′)-diaminomethyl,(P, P′)-ferrocenyl ligands: influence of tert-butyl groups on ferrocene backbone conformation
Gibson et al. The synthesis and metal coordination chemistry of a novel phosphine-and thiolate-substituted ferrocenediyl ligand
Andrieu et al. Synthesis of new phosphino amino alcohol ligands via ortho-alkyllithiation reactions. Versatile coordination behavior toward copper (I) and palladium (II)
Ciganda et al. Reactions of Hydridoirida-β-diketones with Amines or with 2-Aminopyridines: Formation of Hydridoirida-β-ketoimines, PCN Terdentate Ligands, and Acyl Decarbonylation
Tejel et al. Crescent-shaped rhodium (I) complexes with bis (o-carboxymethylphenyl) triazenide
Derdau et al. Cobalt− Alkyne Complexes with Diphosphine Ligands as Mechanistic Probes for the Pauson− Khand Reaction
Massard et al. (Cycloheptadienyl) diphenylphosphine: A Versatile Hybrid Ligand