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Alkenes Group

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Alkenes

( Description and Nomenclature)

Ramos, Dana Remylyn


Avila, John Mark
Macasiab, Deinard - Al
“Organic Compounds”
-is any of a large class of chemical compounds in which one or more
atoms of carbon are covalently bonded to atoms of other elements. The
simplest organic compound is called Hydrocarbons.

Hydrocarbons
-is any of a class of organic chemical compounds composed only of the
elements Carbon ( C ) and Hydrogen ( H ).

Types of Hydrocarbons
Name Definition General Formula
Alkane Hydrocarbon with only single CnH2n+2
bonds between carbon atoms

Alkene Hydrocarbon with at least one CnH2n


double bond

Alkyne Hydrocarbon with at least one CnH2n-2


triple bond
Alkenes
contain carbon-carbon double bonds.
also called as olefins.
are considered as unsaturated compounds.
use -ene as suffix.

Molecular Formula
CnH2n
Where:
n is the number of carbons.
Examples:
1. n = 1
2. n = 4
3. n = 9
4.n = 5
5. n = 7

 Note: Always followed the rule in


Covalent Bonding.
“Nomeclature of
Alkenes”
 The IUPAC Nomenclature of Organic Chemistry is
a systematic method of naming organic chemical
compound as recommended by the International Union
of Pure and Applied Chemistry ( IUPAC ).
Important Things to Remember:
# of Carbon Prefix Common Substituent Group
Atoms Group Name

1 Meth- -CH3 Methyl

2 Eth- -C2H5 Ethyl

3 Prop- -C3H7 Propyl

4 But- -C4H9 Butyl

5 Pent- -C5H11 Pentyl

6 Hex-

7 Hept-

8 Oct-

9 Non-

10 Dec-
“IUPAC Rules for Alkene and Cycloalkene
Nomenclature”
 1.   The -ene suffix (ending) indicates an alkene or cycloalkene.
 2.  The longest chain chosen for the root name must include both
carbon atoms of the double bond. 
 3.  The root chain must be numbered from the end nearest a double
bond carbon atom. If the double bond is in the center of the chain,
the nearest substituent rule is used to determine the end where
numbering starts.
 4.  The smaller of the two numbers designating the carbon atoms of
the double bond is used as the double bond locator. If more than
one double bond is present the compound is named as a diene,
triene or equivalent prefix indicating the number of double bonds,
and each double bond is assigned a locator number.
 5.  In cycloalkenes the double bond carbons are assigned ring
locations #1 and #2. Which of the two is #1 may be determined by
the nearest substituent rule.
 

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