Session 12-14 Dyes - Application Types
Session 12-14 Dyes - Application Types
Session 12-14 Dyes - Application Types
Direct Dyes
• Also called as Substantive dyes
• Bright Shades.
1. Exhaustion
2. Fixation, and
3. After- scouring
The following is a typical procedure for
exhaust dyeing at a high temperature:
Reduction (vatting)
Dyeing
Oxidation
Soap at boil
Reduction (Vatting)
► At this stage, the vat dye is converted into its
soluble form.
Soap at the boil increases the wash fastness of the dyes and yields their
final shade.
The dyeing procedure is then completed by rinsing with hot and cold
water.
Application conditions for Various Types of Vat Dyes
TYPE IN IW IK
IN – normal procedure
IW – warm temperature
IK – cold temperature
SOLUBLE VAT DYES
1. Naphtholation
2. Coupling or Diazotisation
3. After-treatment
Naphtholation
: with Turkey
Paste the Naphthol
red oil (TRO) or sulfonated oil,
and a small amount of water.
The purpose of this step is to remove, from the fiber’s surface, as much of
the naphtholate solution as possible in order to avoid crocking problems.
At this stage the dyed substrate undergoes a vigorous rinsing in order to:
• These dyeing assistants are called carriers, which alter the dispersion
properties of the dyes and the physical characteristics of the fibre so
that more of dyestuff can be transferred from dye bath to fibre
• They swell the fibres at boil to relax the spaces between inner
molecular structures of the fibre to accommodate the dye particles.
Advantages:
• The pH of the bath is maintained at 5.5 to 6.5, with the help of acetic
acid.
• After dyeing, the material is taken out and given cold wash.
• After treatment is given with soap(3 g/l), soda ash(1 g/l) at 50°C for
10 minutes.
• Since the thermoplastic fibres when heated to a high temperature, they soften, their internal
structure is opened up, facilitating the entry of disperse dye molecules in the fibre
• This plasticizing effect of heat on the fibres is responsible for rapid rate of diffusion of dye
into the fibre, requiring from only a few seconds to one minute at a sufficiently high
temperature
DYEING PROCESS
• The application is carried out continuously and consists of padding the polyester fabric with disperse dyes.
• The padding bath contains in addition to the dyes, acetic acid (pH 4.5-5.5 ) and a wetting agent(1-3 g/l ).
• Since the application medium is water, a drying step is required, thereby leaving only the dye on the surface of fibres
• Drying and then placing the fabric in a curing oven at 200-210°C for less than one minute.
• During which the dyes diffuses and becomes fast to remove even by the strongest laundering procedure
• Followed by scouring -to remove the assistants used in padding and to remove unfixed, residual dyes
• Advantage – large yardages can be used as it is continuous, no carrier used, excellent dye utilization(90%), open
width so no creases
Acid Dyes
• Water soluble anionic dyes
• Used for silk, wool, nylon & modified acrylic fibers
• Bright Colors.
• Non fast to washing.
• Excellent Fastness to Dry Cleaning
Process
• Characterized by Brilliance
and Intense hue.
BASIC DYE ON ACRYLIC
• Dye bath prepared with auxillaries at 50°C.
Receipe:
● Basic Dyes - x %
● Acetic Acid - 1 – 2 %
● Dye bath is set with acetic acid and the material is entered at the cold
condition.
● Dyes are dissolved separately using acetic acid.
● The dissolved dye is added to the dye bath in three instalments while the
temperature is being raised from cold to 80c
● Dyeing is continued at 80c for 40-60 min more.
● Dyed material is washed thoroughly to remove unfixed dyes.
● To improve the wet fastness, the dyed goods are worked in a bath containing
1% tannic acid at 60c for 20 min.
Cationic Dyes
• Brilliant shades with excellent fastness
properties on the acrylic fiber
Recipe:
● Basic Dye - x %
● Retarder - 1-2%
● Sodium acetate and acetic acid - Buffer
● Temperature - 95c
Solvent Dyes
• Soluble in an organic solvent.
• The dyes are formulated in such a way that the same shade is obtained on
both fibers, which facilitates shade matching
POLYESTER/COTTON BLENDS
• Three methods can be applied for 2. Single bath method
dyeing polyester/cotton blends:
3. Continuous dyeing
• In single bath, polyester and
(1) Two bath method cotton dyeing can be done in two
steps. • Disperse and reactive dyes are
padded in two padding
• Polyester is dyed using disperse
mangles continuously.
dye in the first bath. • Initially, the dye bath is prepared
using disperse dyes.
• Fabric is treated at very high
• A reduction clearing is applied speed (100 yards per minute).
• Temperature is raised to dye the
for removing unfixed disperse polyester.
dye. • Dwelling chamber for dye
fixation
• After dyeing polyester, the
• Then cotton is dyed with temperature is dropped for dyeing
cotton with reactive dye. • Reduction clearing done in
reactive or vat dye in the
between the padding
second bath
mangles.
• Reduction clearing cannot be
used.
• Best method for union dyeing
of cotton/polyester blends. • Saves time and energy.
• Rainbow fibers have the same physical • With Rainbow, the time needed for the
fiber properties (tenacity, water dyeing process could be reduced by up to
retention, etc.) as viscose fibers, except 70%.
dyeing properties.
• Further advantages of Rainbow are the
• This unique combination of properties reduced water and wastewater quantities
has been realized by incorporation of a (by 65 %) and reduced energy costs (by 65
cationic polymer into the viscose %) per kilogram of dyed fabric.
spinning dope, thus achieving
permanent modification
Dyeing of Cotton-Viscose
• Very difficult to dye in to a solid shade.