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Syllabus Spring06

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Sediment Geochemistry (OCN/GG 644) Course Outline -- Spring 2006

Lecture
Date Day # Topic

Introduction and Fundamentals: General Diagenesis and Organic Matter Diagenesis


11-Jan Tu 1 Introduction, discussion of course structure and topics to be covered
13-Jan Th 2 Diagenetic physical and biological processes-A (derive diagenetic eqn - to w/o compaction)
18-Jan Tu 3 Diagenetic physical and biological processes-B (derive diagenetic eqn - from w/ compaction to BBL diffusion)
20-Jan Th 4 Diagenetic physical and biological processes-C (Einstein eqn, bioturbation, benthic flux, summary)
25-Jan Tu 5 Diagenetic Chemical Processes I-A: Equilibrium & Homogeneous Rxns (Keq & a to introdxn of radioactive decay eqn.)

27-Jan Th 6 Diagenetic Chemical Processes I-B: Homogeneous & Microbial Rxns (derive r-decay eqn., sed rates, hierarchy of ox)
1-Feb Tu 7 Diagenetic Chemical Processes I-C: Homogeneous & Microbial Rxns (hierarchy of ox, G- & power model, geogr distrib of ox)

3-Feb Th 8 Organic matter reactivity and preservation-A: sources and source signals (C:N:P, δ13C)
8-Feb Tu 9 Organic matter reactivity and preservation-A (cont'd.): sources and source signals (C:N:P, δ13C, van Krevelen diagrams, lignin)

10-Feb Th 10 Organic matter reactivity and preservation-A (cont'd.): sources and source signals (C:N:P, δ13C, van Krevelen diagrams, lignin)

15-Feb Tu 11 Organic matter reactivity and preservation-B: redox state and sediment accumulation rate
17-Feb Th 12 mini-lecture #1: OC Burial in Marine Sediments: Productivity or Preservation?

22-Feb Tu -- Ocean Sciences Meeting, no class


24-Feb Th -- Ocean Sciences Meeting, no class

1-Mar Tu 13 Organic matter reactivity and preservation-C: OC:SA, O2-Exposure time


3-Mar Th 14 mini-lecture #2: Hierarchy of oxidants in sediments: Departures from the Classical Sequence
8-Mar Tu - Guest Lecture: Redox reactive trace element diagenesis
10-Mar Th - Guest Lecture: Paleoceanography

Fundamentals: General Diagenesis and Precipitation & Dissolution


15-Mar Tu - Diagenetic Chemical Processes II-A: Precipitation and Dissolution
17-Mar Th - Mid-term review
22-Mar - Mid-term Exam
24-Mar 15 Diagenetic Chemical Processes II-B: Authigenic Processes (definition, list of examples, the Fe-S system, FE and S authingenic
minerals)
29-Mar Tu - Spring Recess
31-Mar Th - Spring Recess
5-Apr Tu 16 Diagenetic Chemical Processes II-B: Authigenic Processes (definition, list of examples, the Fe-S system, FE and S authingenic
minerals)

Diagenesis of Marine Sediments: Case Studies & Global Cycles


7-Apr Th 17
Mineral authigenesis and organic matter decomposition-A (stoichiometric nutrient regeneration, phosphorites, disseminated CFA)
12-Apr Tu 18 mini-lecture #3: Bacterial vs. mineral control of benthic P flux
14-Apr Th 19 Mineral authigenesis and organic matter decomposition-B vivianite, biomineraliz, global P-cycle, BIFs, C:N:P ratios (sanudo-
wilhelmy), other authigenic minerals)
19-Apr Tu 20 mini-lecture #4: Modeling effect of continental processes on marine C, P, Fe cycles, and atmospheric O 2: impact of assumptions

21-Apr Th 21 Deltaic Sediments: Case Studies (fluidized bed reactor; reverse weathering); Fe-biogeochemistry, redox oscillations
26-Apr Tu 22 Permeable Sediments; Benthic photosynthesis (C-fix'n, pH, O 2); Gas Hydrates

Carbonate Systems
28-Apr Th 23 Carbonate system chemistry, bottom water saturation state, Carbonate sediments today: distribution, lysocline and CCD, biogenic
nature of carbonate sediments, trap fluxes
Benthic carbonate dissolution: stoichiometery, pore water chemistry, & respiration-driven dissolution above the saturation horizon

3-May Tu 24 Andreas Andersson: guest lecture


5-May Th 25 Review Session

10-May FINAL EXAM: 12:00 - 2:00 pm

Class: Tuesday & Thursday, 1:30 - 2:45 pm, MSB 315


Instructor: Kathleen Ruttenberg
Office Hours: Wednesdays 1:00-2:00, or by appointment, MSB 222, 956-9371, kcr@soest.hawaii.edu
Required Readings: Excerpts from various texts and scientific journal articles, TBA
Final grade = mid-term exam (25%); final exam (30%); homework or in-class assignments (25%); class participation (20%)

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