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Hydrochloric Acid Concentrated

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Material Safety Data Sheet

Hydrochloric Acid, 12M, Concentrated


Revised: 02/16/2011
Replaces: 02/10/2011
Printed: 09/28/2011

Section 1 - Product Description


Product Name: Hydrochloric Acid
Product Code(s): 86-7760, 86-7762, 86-7790, 86-7792, 86-7791, 86-7793, 86-7730, C70178
Size: 500 mL, 2.5 L
Chemical Name: Hydrochloric Acid
CAS Number: 7647-01-0
Formula: HCl
Synonyms: Muriatic Acid
Distributor: Carolina Biological Supply Company, 2700 York Road, Burlington, NC 27215
Chemical Information: 800-227-1150 (8am-5pm (ET) M-F) Chemtrec 800-424-9300 (Transportation Spill Response 24
hours)

Section 2 - Hazard Identification


Emergency Overview: Causes severe burns. Very toxic by inhalation and if swallowed. May be fatal if swallowed or inhaled.
Potential Health Effects:
Eyes: May cause irritation. Skin: May cause irritation to skin.
Ingestion: May cause gastrointestinal discomfort. Inhalation: May cause irritation to respiratory tract.

Section 3 - Composition / Information on Ingredients


Principal Hazardous Components: Hyrochloric Acid (CAS#7647-01-0) 37%
TLV units: ACGIH-TLV 5 ppm (Ceiling)
PEL units: OSHA-PEL 5 ppm (Ceiling)

Section 4 - First Aid Measures


Emergency and First Aid Procedures:
Eyes - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Skin - After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of water.
Ingestion - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
Inhalation - In case of accident by inhalation: remove casualty to fresh air and keep at rest.

Section 5 - Firefighting Procedures


Flash Point (Method Used): Non-combustible
NFPA Rating:

Product Name: Hydrochloric Acid, 12M, Concentrated Page 1 of 3


Health: 3
Fire: 0
Reactivity: 2
Extinguisher Media: Use media suitable to extinguish surrounding fire.
Flammable Limits in Air % by Volume: N/A
Autoignition Temperature: N/A
Special Firefighting Procedures: Firefighters should wear full protective equipment and NIOSH approved self-contained
breathing apparatus.
Unusual Fire and Explosion Hazards: Fire or excessive heat may produce hazardous decomposition products.
Flammable Hydrogen gas may be produced over long periods of exposure to Aluminum, Tin, Lead, and Zinc.

Section 6 - Spill or Leak Procedures


Steps to Take in Case Material Is Released or Spilled: Ventilate area of spill. Eliminate all sources of ignition. Remove all
non-essential personnel from area. Clean-up personnel should wear proper protective equipment and clothing. Absorb
material with suitable absorbent and containerize for disposal.

Section 7 - Special Precautions


Precautions to Take in Handling or Storing: Keep container tightly closed in a cool, well-ventilated place.

Section 8 - Protection Information


Respiratory Protection (Specify Type): None needed under normal conditions of use with adequate ventilation. A
NIOSH/MSHA chemical cartridge respirator should be worn if PEL or TLV is exceeded.
Ventilation:
Local Exhaust: Yes
Mechanical(General): Yes
Special: No
Other: No
Protective Gloves: Natural rubber, Neoprene, PVC or equivalent.
Eye Protection: Splash proof chemical safety goggles should be worn.
Other Protective Clothing or Equipment: Lab coat, apron, eye wash, safety shower.

Section 9 - Physical Data


Molecular Weight: 36.46 Melting Point: -74 C
Boiling Point: 110 C Vapor Pressure: 160 mmHg at 20C
Vapor Density(Air=1): 1.267 Specific Gravity (H2O=1): 1.1885
Percent Volatile by Volume: 99+% Evaporation Rate (BuAc=1): 2.0
Solubility in Water: Soluble Appearance and Odor: Clear, colorless liquid; pungent, choking
odor.

Section 10 - Reactivity Data


Stability: Stable
Conditions to Avoid: Heat and sources of ignition.
Metals,
Incompatibility (Materials to Avoid): Bases, Alkalis, Amines, Metals,
Hazardous Decomposition Products: HCl,
Hazardous Polymerization: Will not occur

Section 11 - Toxicity Data


Toxicity Data: ihl-rat LC50 3124 ppm/1H
ihl-hmn LCLo 75 mg/m3
Effects of Overexposure:

Product Name: Hydrochloric Acid, 12M, Concentrated Page 2 of 3


Acute: See Section 2
Chronic: Tests on laboratory animals indicate material may produce adverse mutagenic and reproductive effects.
Conditions Aggravated by Overexposure: Respiratory disorders,
Target Organs: N/A
Primary Route(s) of Entry: Inhalation, ingestion, eye or skin contact.

Section 12 - Ecological Data


EPA Waste Numbers: D002

Section 13 - Disposal Information


Waste Disposal Methods: Dispose in accordance with all applicable Federal, State and Local regulations. Always contact a
permitted waste disposer (TSD) to assure compliance.

Section 14 - Transport Information


DOT Proper Shipping Name: UN1789, Hydrochloric acid, 8, II, 5000 lbs.

Section 15 - Regulatory Information


EPA TSCA Status: On TSCA Inventory
Hazard Category for SARA Section 311/312 Reporting: Acute

Name List: Chemical Category:


Hydrochloric acid - Yes Hydrochloric acid - No

CERCLA Section 103 RQ(lb.): Hydrochloric acid - 5000


RCRA Section 261.33: Hydrochloric acid - No

Section 16 - Additional Information


The information provided in this Material Safety Data Sheet represents a compilation of data drawn directly from various
sources available to us. Carolina Biological Supply makes no representation or guarantee as to the suitability of this information
to a particular application of the substance covered in the Material Safety Data Sheet. Any employer must carefully assess the
applicability of any information contained herein in regards to the particular use to which the employer puts the material.

Glossary
ACGIH American Conference of Governmental Industrial Hygienists
CAS Number Chemical Services Abstract Number
CERCLA Comprehensive Environmental Response, Compensation, and Liability Act
DOT U.S. Department of Transportation
IARC International Agency of Research on Cancer
N/A Not Available
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
ppm Parts per million
RCRA Resource Conservation and Recovery Act
SARA Superfund Amendments and Reauthorization Act
TLV Threshold Limit Value
TSCA Toxic Substances Control Act

Product Name: Hydrochloric Acid, 12M, Concentrated Page 3 of 3

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