Mogas Msds 2014-2
Mogas Msds 2014-2
Mogas Msds 2014-2
As of the revision date above, this (M)SDS meets the regulations in the United Kingdom & Ireland.
1.1. PRODUCT IDENTIFIER
Product Name: MOTOR GASOLINE (ADDITIZED)
Product Description:
Hydrocarbons and Additives
Product Code:
708593-60
Trade Names
ENERGY SUPREME
ESSO REGULAR PETROL UL95 (A)
ESSO UL95 MOGAS
SUPER PLUS UNLEADED ULS 100% A
ULS MOGAS 100% A
ULS MOGAS 97 RON
UNLEADED MOGAS 97 RON
Trade Names
ENERGY UNLEADED
ESSO SUPERPLUS PETROL UL97 (A)
MGBLEND
SUPERPLUS UNLEADED 97 MOGAS
ULS MOGAS 95 RON
UNLEADED MOGAS 87 RON
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST
Intended Use: Fuel
Identified Uses:
Manufacture of substance
Distribution of substance
Formulation and (re)packing of substances and mixtures
Use as a fuel - Industrial
Use as a fuel - Professional
Use as a fuel - Consumer
See Section 16 for list of REACH Use Descriptors for Identified Uses shown above.
Uses advised against: This product is not recommended for any industrial, professional or consumer use
other than the Identified Uses above.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
Supplier:
Esso Petroleum Company Ltd.
Ermyn Way
ExxonMobil House
KT22 8UX LEATHERHEAD, SURREY
Great Britain
E-Mail:
sds.uk@exxonmobil.com
SECTION 2
HAZARDS IDENTIFICATION
No additional hazards. Material does not meet the criteria for PBT or vPvB in accordance with REACH Annex
XIII.
SECTION 3
CAS#
EC#
Registration#
Concentration*
ethanol
64-17-5
200-578-6
01-2119457610-43 0 - 5%
2-ethoxy-2-methylpropane
637-92-3
216-653-1
01-2119452785-29 0 - 15%
Gasoline
86290-81-5
289-220-8
01-2119471335-39 > 85 %
ISOBUTYL ALCOHOL
78-83-1
201-148-0
NE
0 - 10%
propan-2-ol
67-63-0
200-661-7
01-2119457558-25 0 - 10%
Methanol
67-56-1
200-659-6
01-2119433307-44 0 - < 3%
2-methoxy-2-methylpropane
1634-04-4
216-653-1
01-2119452786-27 0 - 15%
TERT-BUTYL ALCOHOL
75-65-0
200-889-7
NE
0 - 7%
GHS/CLP
classification
Note - any classification in brackets is a GHS building block that was not adopted by the EU in the CLP regulation (No 1272/2008)
and therefore is not applicable in the EU or in non-EU countries which have implemented the CLP regulation and is shown for
informational purposes only.
Name
CAS#
EC#
Registration#
Concentration*
ethanol
64-17-5
200-578-6
01-2119457610-43 0 - 5%
F;R11
2-ethoxy-2-methylpropane
637-92-3
216-653-1
01-2119452785-29 0 - 15%
F;R11, Xi;R38
Gasoline
86290-81-5
289-220-8
01-2119471335-39 > 85 %
ISOBUTYL ALCOHOL
78-83-1
201-148-0
NE
propan-2-ol
67-63-0
200-661-7
01-2119457558-25 0 - 10%
Methanol
67-56-1
200-659-6
01-2119433307-44 0 - < 3%
F;R11, T;R23/24/25,
T;R39/23/24/25
2-methoxy-2-methylpropane
1634-04-4
216-653-1
01-2119452786-27 0 - 15%
F;R11, Xi;R38
TERT-BUTYL ALCOHOL
75-65-0
200-889-7
NE
F;R11, Xn;R20
0 - 10%
0 - 7%
DSD Symbols/Risk
Phrases
Reportable hazardous constituent(s) contained in UVCB- and/or multi-constituent substance(s) complying with
the classification criteria and/or with an exposure limit (OEL)
Name
CAS#
EC#
Concentration*
GHS/CLP
Classification
BENZENE
71-43-2
200-753-7
0.1 - 1.0%
TOLUENE
108-88-3
203-625-9
> 5.0 %
Note - any classification in brackets is a GHS building block that was not adopted by the EU in the CLP regulation (No 1272/2008)
and therefore is not applicable in the EU or in non-EU countries which have implemented the CLP regulation and is shown for
informational purposes only.
Name
CAS#
EC#
Concentration*
DSD Symbols/Risk
Phrases
BENZENE
71-43-2
200-753-7
0.1 - 1.0%
F;R11, Xi;R36/38,
T;Carc. Cat. 1;R45,
T;Mut. Cat. 2;R46,
T;R48/23/24/25, Xn;R65,
Note E
TOLUENE
108-88-3
203-625-9
> 5.0 %
F;R11, Xi;R38,
Xn;R48/20, Xn;Repro.
Cat. 3;R63, Xn;R65, R67
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
NOTE: Oxygenates may be present up to the maximum permitted by European Standard EN228.
Note: See (M)SDS Section 16 for full text of the R-Phrases. See (M)SDS Section 16 for full text of hazard statements.
SECTION 4
SECTION 5
SECTION 6
ventilated area. Outside or detached storage preferred. Keep away from incompatible materials. Storage
containers should be earthed and bonded. Fixed storage containers, transfer containers and associated
equipment should be earthed and bonded to prevent accumulation of static charge.
7.3. SPECIFIC END USES: Section 1 informs about identified end-uses. No industrial or sector specific guidance
available.
SECTION 8
Form
Limit/Standard
STEL
367 mg/m3
TWA
183.5
mg/m3
TWA
25 ppm
STEL
367 mg/m3
TWA
183.5
mg/m3
TWA
50 ppm
TWA
3.25 mg/m3
STEL
1 ppm
TWA
0.5 ppm
STEL
200 ppm
TWA
100 ppm
STEL
231 mg/m3
TWA
154 mg/m3
TWA
50 ppm
STEL
333 mg/m3
TWA
266 mg/m3
STEL
250 ppm
TWA
200 ppm
STEL
462 mg/m3
TWA
308 mg/m3
TWA
100 ppm
TWA
1920 mg/m3
STEL
1000 ppm
STEL
1250 mg/m3
TWA
999 mg/m3
STEL
400 ppm
TWA
200 ppm
STEL
384 mg/m3
TWA
191 mg/m3
TWA
20 ppm
100 ppm
50 ppm
Note
Source
UK EH40
UK EH40
100 ppm
50 ppm
ACGIH
UK EH40
UK EH40
1 ppm
Skin
75 ppm
50 ppm
250 ppm
200 ppm
Skin
Skin
Skin
Skin
150 ppm
100 ppm
1000 ppm
500 ppm
400 ppm
100 ppm
50 ppm
Skin
Skin
ACGIH
UK EH40
ExxonMobil
ExxonMobil
ExxonMobil
ExxonMobil
UK EH40
UK EH40
ACGIH
UK EH40
UK EH40
ACGIH
ACGIH
UK EH40
UK EH40
ACGIH
UK EH40
ACGIH
UK EH40
UK EH40
ACGIH
ACGIH
UK EH40
UK EH40
ACGIH
UK EH40 Workplace Exposure Limits. Exposure limits for use with Control of Substances Hazardous to Health
Regulations 2002 (as amended)
Note: Information about recommended monitoring procedures can be obtained from the relevant
agency(ies)/institute(s):
UK
Health and Safety Executive (HSE)
Dermal
NA
Inhalation
840 mg/m3 DNEL, Chronic Exposure,
Local Effects
888 mg/kg bw/day DNEL, Chronic Exposure,
500 mg/m3 DNEL, Chronic Exposure,
Systemic Effects
Systemic Effects
5100 mg/kg bw/day DNEL, Chronic Exposure, 178.5 mg/m3 DNEL, Chronic
Systemic Effects
Exposure, Systemic Effects
propan-2-ol
2-methoxy-2-methylpropane
Consumer
Substance Name
propan-2-ol
Dermal
319 mg/kg bw/day DNEL,
Chronic Exposure, Systemic
Effects
3570 mg/kg bw/day DNEL,
Chronic Exposure, Systemic
Effects
NA
2-methoxy-2-methylpropane
Gasoline
Inhalation
Oral
89 mg/m3 DNEL, Chronic 26 mg/kg bw/day DNEL,
Exposure, Systemic Effects Chronic Exposure,
Systemic Effects
53.6 mg/m3 DNEL, Chronic 7.1 mg/kg bw/day DNEL,
Exposure, Systemic Effects Chronic Exposure,
Systemic Effects
180 mg/m3 DNEL, Chronic NA
Exposure, Local Effects
Note: The Derived No Effect Level (DNEL) is an estimated safe level of exposure that is derived from toxicity data in
accord with specific guidance within the European REACH regulation. The DNEL may differ from an Occupational
Exposure Limit (OEL) for the same chemical. OELs may be recommended by an individual company, a governmental
regulatory body or an expert organization, such as the Scientific Committee for Occupational Exposure Limits (SCOEL)
or the American Conference of Governmental Industrial Hygienists (ACGIH). OELs are considered to be safe exposure
levels for a typical worker in an occupational setting for an 8-hour work shift, 40 hour work week, as a time weighted
average (TWA) or a 15 minute short-term exposure limit (STEL). While also considered to be protective of health, OELs
are derived by a process different from that of REACH.
PREDICTED NO EFFECT CONCENTRATION (PNEC)
Substance Name
Aqua
(fresh
water)
140.9 mg/l
Aqua
(marine
water)
140.9 mg/l
Aqua
(intermittent
release)
140.9 mg/l
Sewage Sediment
Soil
treatment
plant
2251 mg/l 552 mg/kg (dry 28 mg/kg
wt)
Oral (secondary
poisoning)
2-methoxy-2methylpropane
5.1 mg/l
0.26 mg/l
47.2 mg/l
71 mg/l
23 mg/kg (dry
wt)
1.62 mg/kg
NA
Gasoline
NA
NA
NA
NA
NA
NA
NA
propan-2-ol
160 mg / kg
(food)
For hydrocarbon UVCBs, no single PNEC value is identified for the overall substance or used in risk assessment
calculations. Therefore, no PNEC values are disclosed in the above table. For further information, please contact
ExxonMobil.
8.2. EXPOSURE CONTROLS
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
Use explosion-proof ventilation equipment to stay below exposure limits.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a
level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
Half-face filter respirator Type AX filter material, European Committee for Standardization (CEN)
standards EN 136, 140 and 405 provide respirator masks and EN 149 and 143 provide filter
recommendations.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
Chemical resistant gloves are recommended. Nitrile, Viton, CEN standards EN 420 and EN 374
provide general requirements and lists of glove types.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
Chemical/oil resistant clothing is recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
For Summary of Risk Management Measures across all identified uses, see Annex.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and
soil. Protect the environment by applying appropriate control measures to prevent or limit
emissions.
SECTION 9
Note: Physical and chemical properties are provided for safety, health and environmental considerations only
and may not fully represent product specifications. Contact the Supplier for additional information.
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Colour: Pale Yellow
Odour: Characteristic
Odour Threshold: No data available
pH: Not technically feasible
Melting Point: No data available
Freezing Point: No data available
Initial Boiling Point / and Boiling Range: 28C (82F) - 210C (410F) [ASTM D86]
Flash Point [Method]: <-35C (-31F) [IP 170/70]
Evaporation Rate (n-butyl acetate = 1): No data available
Flammability (Solid, Gas): Not technically feasible
Upper/Lower Flammable Limits (Approximate volume % in air): UEL: 7.6 LEL: 1.4 [test method
unavailable]
Vapour Pressure: [N/D at 20C] | 4 kPa (30 mm Hg) at 37.8 C - 240 kPa (1800 mm Hg) at 37.8C [test
method unavailable]
Vapour Density (Air = 1): > 1 at 101 kPa [test method unavailable]
Relative Density (at 15 C): < 1 [test method unavailable]
Solubility(ies): water Moderate
Partition coefficient (n-Octanol/Water Partition Coefficient): > 3.5 [test method unavailable]
Autoignition Temperature: >250C (482F) [test method unavailable]
Decomposition Temperature: No data available
Viscosity: <1 cSt (1 mm2/sec) at 40C [test method unavailable]
Explosive Properties: None
Oxidizing Properties: None
9.2. OTHER INFORMATION
Density (at 15 C): 620 kg/m3 (5.17 lbs/gal, 0.62 kg/dm3) - 880 kg/m3 (7.34 lbs/gal, 0.88 kg/dm3) [test
method unavailable]
SECTION 10
SECTION 11
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Inhalation
Acute Toxicity: (Rat) LC50 > 5000 mg/m3
Minimally Toxic. Based on test data for structurally similar materials.
(Vapour) Test scores or other study results do Test(s) equivalent or similar to OECD Guideline 403
not meet criteria for classification.
Irritation: No end point data for material.
Ingestion
Acute Toxicity (Rat): LD50 > 5000 mg/kg Test Minimally Toxic. Based on test data for structurally similar materials.
scores or other study results do not meet
Test(s) equivalent or similar to OECD Guideline 401
criteria for classification.
Skin
Acute Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials.
Test scores or other study results do not meet Test(s) equivalent or similar to OECD Guideline 402
criteria for classification.
Skin Corrosion/Irritation (Rabbit): Data
available. Test scores or other study results
meet criteria for classification.
Eye
Serious Eye Damage/Irritation (Rabbit): Data May cause mild, short-lasting discomfort to eyes. Based on test data
available. Test scores or other study results for structurally similar materials. Test(s) equivalent or similar to
do not meet criteria for classification.
OECD Guideline 405
Sensitisation
Respiratory Sensitization: No end point data Not expected to be a respiratory sensitizer.
for material.
Skin Sensitization: Data available. Test
scores or other study results do not meet
criteria for classification.
May be fatal if swallowed and enters airways. Based on physicochemical properties of the material.
ACUTE TOXICITY
Oral Lethality: LD 50 4000 mg/kg (Rat)
Oral Lethality: LD 50 2743 mg/kg (Rat)
OTHER INFORMATION
For the product itself:
Laboratory animal studies have shown that prolonged and repeated inhalation exposure to light hydrocarbon vapours in
the same boiling range as this product can produce adverse kidney effects in male rats. However, these effects were
not observed in similar studies with female rats, male and female mice, or in limited studies with other animal species.
Additionally, in a number of human studies, there was no clinical evidence of such effects at normal occupational levels.
In 1991, The U.S. EPA determined that the male rat kidney is not useful for assessing human risk. Vapour
concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract, may cause
headaches and dizziness, are anaesthetic and may have other central nervous system effects. Small amounts of liquid
aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Very
high exposure (confined spaces / abuse) to light hydrocarbons may result in abnormal heart rhythm (arrhythmias).
Concurrent high stress levels and/or co-exposure to high levels of hydrocarbons (above occupational exposure limits),
and to heart-stimulating substances like epinephrine, nasal decongestants, asthma drugs, or cardiovascular drugs may
initiate arrhythmias.
Gasoline unleaded: Carcinogenic in animal tests. Chronic inhalation studies resulted in liver tumours in female mice
and kidney tumours in male rats. Neither result considered significant for human health risk assessment by the United
States EPA and others. Did not cause mutations in-vitro or in-vivo. Negative in inhalation developmental studies and
reproductive tox studies. Inhalation of high concentrations in animals resulted in reversible central nervous system
depression, but no persistent toxic effect on the nervous system. Non-sensitizing in test animals. Caused nerve damage
in humans from abusive use (sniffing).
Contains:
BENZENE: Caused cancer (acute myeloid leukemia and myelodysplastic syndrome), damage to the blood-producing
system, and serious blood disorders in human studies. Caused genetic effects and effects on the immune system in
laboratory animal and some human studies. Caused toxicity to the fetus and cancer in laboratory animal studies.
ETHANOL: Prolonged or repeated exposure to high concentrations of ethanol vapour or overexposure by ingestion
may produce adverse effects to brain, kidney, liver, and reproductive organs, birth defects in offspring, and
developmental toxicity in offspring. METHANOL: Human exposure to methanol may result in illness, systemic
poisoning, blindness, optic nerve damage and perhaps death, after being ingested, absorbed through the skin or
inhaled. Death due to cardiac or respiratory failure has been reported in some cases from consumption of as little as 30
mls. Exposure to high concentrations of methanol has been shown to cause developmental effects in rodent offspring.
Methyl tertiary butyl ether (MTBE): Carcinogenic in animal tests. Inhalation exposure to high concentrations resulted in
higher than expected mortality in male mice due to urinary tract obstructions and female mice displayed benign liver
tumours. Inhalation exposure to high concentrations resulted in higher than expected mortality in male rats due to
progressive kidney damage as well as increased benign and malignant kidney tumours, and benign testicular tumours.
Did not cause mutations in-vitro or in-vivo. Rabbits exposed to high vapour concentrations did not have any offspring
with adverse developmental effects. Mice exposed to high vapour concentrations (maternally toxic) had offspring with
embryo/fetal toxicity and birth defects. Rats exposed to high vapour concentrations did not display any treatmentrelated effects in a two generation reproduction study.The significance of the animal findings at high exposures are not
believed to be directly related to potential human health hazards in the workplace. TOLUENE : Concentrated,
prolonged or deliberate inhalation may cause brain and nervous system damage. Prolonged and repeated exposure of
pregnant animals (> 1500 ppm) have been reported to cause adverse fetal developmental effects.
SECTION 12
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
12.1. TOXICITY
Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.
12.2. PERSISTENCE AND DEGRADABILITY
Biodegradation:
Material -- Expected to be inherently biodegradable
Atmospheric Oxidation:
Majority of components -- Expected to degrade rapidly in air
12.3. BIOACCUMULATIVE POTENTIAL
Majority of components -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.
12.4. MOBILITY IN SOIL
Majority of components -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and
wastewater solids.
Low molecular wt. component -- Moderate potential to migrate through soil.
High molecular wt. component -- Low potential to migrate through soil.
12.5. PERSISTENCE, BIOACCUMULATION AND TOXICITY FOR SUBSTANCE(S)
This product is not, or does not contain, a substance that is a PBT or a vPvB.
12.6. OTHER ADVERSE EFFECTS
No adverse effects are expected.
ECOLOGICAL DATA
Ecotoxicity
Test
Duration
Organism Type
Test Results
96 hour(s)
Fish
48 hour(s)
Daphnia magna
72 hour(s)
Pseudokirchneriella
subcapitata
72 hour(s)
Pseudokirchneriella
subcapitata
21 day(s)
Daphnia magna
Test Type
Duration
Water
Ready Biodegradability
28 day(s)
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
13.1. WASTE TREATMENT METHODS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION
European Waste Code: 13 07 02*
NOTE: These codes are assigned based upon the most common uses for this material and may not reflect
contaminants resulting from actual use. Waste producers need to assess the actual process used when
generating the waste and its contaminants in order to assign the proper waste disposal code(s).
This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and
subject to the provisions of that Directive unless Article 1(5) of that Directive applies.
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and
can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be
completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken
for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14
TRANSPORT INFORMATION
LAND (ADR/RID)
14.1. UN Number: 1203
14.2. UN Proper Shipping Name (Technical Name): MOTOR SPIRIT or GASOLINE or PETROL
14.3. Transport Hazard Class(es): 3
14.4. Packing Group: II
14.5. Environmental Hazards: Yes
14.6. Special Precautions for users:
Classification Code: F1
Label(s) / Mark(s): 3, EHS
Hazard ID Number: 33
Hazchem EAC: 3YE
INLAND WATERWAYS (ADNR/ADN)
14.1. UN (or ID) Number: 1203
14.2. UN Proper Shipping Name (Technical Name): MOTOR SPIRIT or GASOLINE or PETROL
14.3. Transport Hazard Class(es):
3
14.4. Packing Group: II
14.5. Environmental Hazards: Yes
14.6. Special Precautions for users:
Hazard ID Number: 33
Label(s) / Mark(s): 3 (N2, CMR, F), EHS
SEA (IMDG)
14.1. UN Number: 1203
14.2. UN Proper Shipping Name (Technical Name): MOTOR SPIRIT or GASOLINE or PETROL
14.3. Transport Hazard Class(es): 3
14.4. Packing Group: II
14.5. Environmental Hazards: Marine Pollutant
14.6. Special Precautions for users:
Label(s): 3
EMS Number: F-E, S-E
Transport Document Name: UN1203, MOTOR SPIRIT or GASOLINE or PETROL, 3, PG II, (-35C c.c.),
MARINE POLLUTANT
SEA (MARPOL 73/78 Convention - Annex II):
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not classified according to Annex II
AIR (IATA)
14.1. UN Number: 1203
14.2. UN Proper Shipping Name (Technical Name): MOTOR SPIRIT or GASOLINE or PETROL
SECTION 15
REGULATORY INFORMATION
15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE
OR MIXTURE
Applicable EU Directives and Regulations:
1907/2006 [... on the Registration, Evaluation, Authorisation and Restriction of Chemicals ... and
amendments thereto]
Annex XVII restrictions on the manufacture, placing on the market and use of certain dangerous
substances, preparations and articles identified in Regulation 1907/2006/EC [...on the Registration, Evaluation,
Authorisation and Restrictions of Chemicals ... and amendments thereto]
92/85/EEC [...pregnant workers...recently given birth or...breastfeeding directive]
2004/42/CE [on the limitation of emissions of volatile organic compounds due to the use of organic
solvents in certain paints and varnishes and vehicle refinishing products and amending Directive 1999/13/EC.]
94/33/EC [...on the protection of young people at work]
96/82/EC as extended by 2003/105/EC [ ... on the control of major-accident hazards involving
dangerous substances]. Product contains a substance that falls within the criteria defined in Annex I. Refer to
Directive for details of requirements taking into account the volume of product stored on site.
111/2005/EC [...laying down rules for drug precursors ... ]
2004/37/EC [... on the protection of workers from the risks related to carcinogens or mutagens...]
98/24/EC [... on the protection of workers from the risk related to chemical agents at work ...]. Refer to
Directive for details of requirements.
1272/2008 [on classification, labelling and packaging of substances and mixtures.. and amendments
thereto]
Refer to the relevant EU/national regulation for details of any actions or restrictions required by the above
Regulation(s)/Directive(s).
material.
SECTION 16
OTHER INFORMATION
IDENTIFIED USES:
Manufacture of substance (PROC1, PROC15, PROC2, PROC3, PROC8a, PROC8b, SU10, SU3, SU8, SU9)
Distribution of substance (PROC1, PROC15, PROC2, PROC3, PROC8a, PROC8b, SU3, SU8, SU9)
Formulation and (re)packing of substances and mixtures (PROC1, PROC15, PROC2, PROC3, PROC8a, PROC8b,
SU10, SU3)
Use as a fuel - Industrial (PROC1, PROC16, PROC2, PROC3, PROC8a, PROC8b, SU3)
Use as a fuel - Professional (PROC1, PROC16, PROC2, PROC3, PROC8a, PROC8b, SU22)
Use as a fuel - Consumer (PC13, SU21)
REFERENCES: Sources of information used in preparing this SDS included one or more of the following: results from
in house or supplier toxicology studies, CONCAWE Product Dossiers, publications from other trade associations, such
as the EU Hydrocarbon Solvents REACH Consortium, U.S. HPV Program Robust Summaries, the EU IUCLID Data
Base, U.S. NTP publications, and other sources, as appropriate.
List of abbreviations and acronyms that could be (but not necessarily are) used in this safety data sheet:
Acronym
N/A
N/D
NE
VOC
AICS
AIHA WEEL
ASTM
DSL
EINECS
ELINCS
ENCS
IECSC
KECI
NDSL
NZIoC
PICCS
TLV
TSCA
UVCB
LC
LD
LL
EC
EL
NOEC
NOELR
Full text
Not applicable
Not determined
Not established
Volatile Organic Compound
Australian Inventory of Chemical Substances
American Industrial Hygiene Association Workplace Environmental Exposure Limits
ASTM International, originally known as the American Society for Testing and Materials (ASTM)
Domestic Substance List (Canada)
European Inventory of Existing Commercial Substances
European List of Notified Chemical Substances
Existing and new Chemical Substances (Japanese inventory)
Inventory of Existing Chemical Substances in China
Korean Existing Chemicals Inventory
Non-Domestic Substances List (Canada)
New Zealand Inventory of Chemicals
Philippine Inventory of Chemicals and Chemical Substances
Threshold Limit Value (American Conference of Governmental Industrial Hygienists)
Toxic Substances Control Act (U.S. inventory)
Substances of Unknown or Variable composition, Complex reaction products or Biological materials
Lethal Concentration
Lethal Dose
Lethal Loading
Effective Concentration
Effective Loading
No Observable Effect Concentration
No Observable Effect Loading Rate
Classification procedure
Calculation
Bridging, structurally similar materials
Based on test data
Bridging, structurally similar materials
Bridging, structurally similar materials
Bridging, structurally similar materials
KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only):
R10; Flammable.
R11; Highly flammable.
R12; Extremely flammable.
R20; Harmful by inhalation.
R23; Toxic by inhalation.
R24; Toxic in contact with skin.
R25; Toxic if swallowed.
R36; Irritating to eyes.
R37; Irritating to respiratory system.
R38; Irritating to skin.
R39/23; Toxic: danger of very serious irreversible effects through inhalation.
R39/24; Toxic: danger of very serious irreversible effects in contact with skin.
R39/25; Toxic: danger of very serious irreversible effects if swallowed.
R41; Risk of serious damage to eyes.
R45; May cause cancer.
R46; May cause heritable genetic damage.
R48/20; Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R48/23; Toxic: danger of serious damage to health by prolonged exposure through inhalation.
R48/24; Toxic: danger of serious damage to health by prolonged exposure in contact with skin.
R48/25; Toxic: danger of serious damage to health by prolonged exposure if swallowed.
R51/53; Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R63; Possible risk of harm to the unborn child.
R65; Harmful: may cause lung damage if swallowed.
R67; Vapours may cause drowsiness and dizziness.
KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):
Flam. Liq. 1 H224: Extremely flammable liquid and vapor; Flammable Liquid, Cat 1
Flam. Liq. 2 H225: Highly flammable liquid and vapor; Flammable Liquid, Cat 2
Flam. Liq. 3 H226: Flammable liquid and vapor; Flammable Liquid, Cat 3
Acute Tox. 3 H301: Toxic if swallowed; Acute Tox Oral, Cat 3
[Acute Tox. 5 H303]: May be harmful if swallowed; Acute Tox Oral, Cat 5
Asp. Tox. 1 H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1
[Asp. Tox. 2 H305]: May be harmful if swallowed and enters airways; Aspiration, Cat 2
Acute Tox. 3 H311: Toxic in contact with skin; Acute Tox Dermal, Cat 3
Skin Irrit. 2 H315: Causes skin irritation; Skin Corr/Irritation, Cat 2
Eye Dam. 1 H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1
Eye Irrit. 2 H319: Causes serious eye irritation; Serious Eye Damage/Irr, Cat 2
Acute Tox. 3 H331: Toxic if inhaled; Acute Tox Inh, Cat 3
Acute Tox. 4 H332: Harmful if inhaled; Acute Tox Inh, Cat 4
STOT SE 3 H335: May cause respiratory irritation; Target Organ Single, Resp Irr
STOT SE 3 H336: May cause drowsiness or dizziness; Target Organ Single, Narcotic
Muta. 1B H340: May cause genetic defects; Germ Cell Mutagenicity, Cat 1B
Carc. 1A H350: May cause cancer; Carcinogenicity, Cat 1A
Carc. 1B H350: May cause cancer; Carcinogenicity, Cat 1B
Repr. 2 H361d: Suspected of damaging the unborn child; Repro Tox, Cat 2 (Develop)
STOT SE 1 H370: Causes damage to organs; Target Organ, Single, Cat 1
STOT RE 1 H372: Causes damage to organs through prolonged or repeated exposure; Target Organ, Repeated, Cat 1
STOT RE 2 H373: May cause damage to organs through prolonged or repeated exposure; Target Organ, Repeated, Cat
2
[Aquatic Acute 2 H401]: Toxic to aquatic life; Acute Env Tox, Cat 2
Aquatic Chronic 2 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
Revision Changes:
GHS Precautionary Statements - Prevention information was modified.
GHS Precautionary Statements - Response information was modified.
PNEC table information was modified.
Section 11: Mutagen Conclusion information was modified.
Section 11 Substance Toxicology table information was modified.
Section 09: Vapour Pressure information was modified.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
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affiliates in which they directly or indirectly hold any interest.
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MHC: 1A, 0B, 0, 0, 4, 1
PPEC: CF
Product characteristics
Predominantly hydrophobic.
Substance is complex UVCB.
Duration, frequency and amount
Annual site tonnage (tonnes/year): 37500 tons/yr
Continuous release.
Emission Days (days/year): 300 days/yr
Fraction of EU tonnage used in region: 0.1
Fraction of Regional tonnage used Locally: 0.002
Maximum daily site tonnage (kg/d): 120000 kg / day
Regional use tonnage (tonnes/year): 18700000 tons/yr
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1] 10
Local marine water dilution factor: [EF2] 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 0.001
Release fraction to soil from process (initial release prior to RMM): 1e-005
Release fraction to wastewater from process (initial release prior to RMM): 1e-005
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required.
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: >= 0
%
Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation).
Treat air emissions to provide a typical removal (or abatement?) efficiency of: 90 %
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) efficiency of
=: >= 12 %
Organisation measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day
Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 %
The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 1100000 kg / day
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is: 95.5 %
Conditions and measures related to external treatment of waste for disposal
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3]
Conditions and measures related to external recovery of waste
External recovery an recycling of waste should comply with applicable local and/or national regulations [ERW1]
Section 3 Exposure Estimation
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21]
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational
Conditions outlined in Section 2 are implemented. [G22]
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3]
Conditions and measures related to external recovery of waste
External recovery an recycling of waste should comply with applicable local and/or national regulations [ERW1]
Section 3 Exposure Estimation
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21]
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational
Conditions outlined in Section 2 are implemented. [G22]
Risk Management Measures are based on qualitative risk characterisation. [G37]
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are
managed to at least equivalent levels.[G23]
4.2. Environment
Further details on scaling and control technologies are provided in factsheet
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be
necessary to define appropriate site-specific risk management measures.
Maximum Risk Characterisation Ratio for Air Emisions [RCRair] 0.768963
Maximum Risk Characterisation Ratio for Wastewater Emisions [RCRwater] 0.851624
Required removal efficiency for air can be achieved using on-site technologies, either alone or in combination.
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in
combination.
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is: 95.5 %
Conditions and measures related to external treatment of waste for disposal
Combustion emissions considered in regional exposure assessment [ETW2]
Combustion emissions limited by required exhaust emission controls [ETW1]
Conditions and measures related to external recovery of waste
This substance is consumed during use and no waste of the substance is generated [ERW3]
Section 3 Exposure Estimation
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21]
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational
Conditions outlined in Section 2 are implemented. [G22]
Risk Management Measures are based on qualitative risk characterisation. [G37]
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are
managed to at least equivalent levels.[G23]
4.2. Environment
Further details on scaling and control technologies are provided in factsheet
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be
necessary to define appropriate site-specific risk management measures.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in combination.
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in
combination.