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Demulsifier EB Safety Data Sheet

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Demulsifier EB

Safety Data Sheet


Issue Date: 01-Aug-2017 Revision Date: 01-Oct-2017 Version 1

1. IDENTIFICATION

Product Identifier
Product Name DEMULSIFIER EB

Other means of identification


SDS # BELL-233

UN/ID No UN1993

Recommended use of the chemical and restrictions on use


Recommended Use Emulsion breaking fuel additive

Details of the supplier of the safety data sheet


Supplier Address
Bell Performance Inc
1340 Bennett Drive
Longwood, FL 32750

Emergency Telephone Number


Company Phone Number 407-831-5021
Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International)
1-800-535-5053 (North America) CONTRACT #:106344

2. HAZARDS IDENTIFICATION

Appearance Brown Physical State Liquid Odor Hydrocarbon odor

Classification

Carcinogenicity Category 2
Skin Irritation Category 2
Inhalation Category 3
Flammable Liquids Category 3

Signal Word
Warning

Hazard Statements
Suspected of causing cancer
Flammable liquid and vapor

Hazard Pictograms

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BELL-233 - DEMULSIFIER EB Revision Date: 01-Oct-2017
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Precautionary Statements - Prevention

Obtain special instructions before use.


Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools.
Take precautionary measures against static discharge.
Wear protective gloves/ eye protection/ face protection.
Use personal protective equipment as required.

Precautionary Statements - Response

If exposed or concerned: Get medical advice/attention


IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IN CASE OF FIRE: Use dry sand, dry chemical, or alcohol-resistant foam for extinction.

Precautionary Statements - Storage

Store locked up.


Store in a well-ventilated place. Keep cool.

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant.

Other Hazards

None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-%


2-Ethylhexanol 104-76-7 45-60%
Naphthalene 91-20-3 < 10%
Naphtha (petroleum), heavy aromatic 64742-94-5 5-15%
1,2,4-Trimethylbenzene 95-63-6 < 10%
Kerosene 8008-20-6 5-15%
Ethylbenzene 100-41-4 < 5%

4. FIRST-AID MEASURES

First Aid Measures

Eye Contact Rinse immediately with plenty of water. Get medical attention if symptoms occur.

Skin Contact Wash off with soap and plenty of water. If irritation persists, seek medical attention.

Inhalation Get medical attention if symptoms occur.

Ingestion Do not induce vomiting. Rinse mouth. Get medical attention if symptoms occur.

Protection of first-aiders In event of emergency, assess the danger before taking action. Do not put yourself at risk
of injury. If in doubt, contact emergency responders. Use person protective equipment as
required.
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Most important symptoms and effects

Symptoms See Section 11 for more detailed information on health effects and symptoms.

Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media


Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media


High volume water jet

Specific Hazards Arising from the Chemical


Fire Hazard
Keep away from heat and sources of ignition.
Flash back possible over considerable distance.
Beware of vapours accumulating to form explosive concentrations.
Vapours can accumulate in low areas.

Hazardous Combustion Products


Carbon oxides.

Protective equipment and precautions for firefighters


Use personal protective equipment.

Specific Extinguishing Methods


Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Remove all sources of ignition. Refer to protective measures listed in Sections 7 & 8.

Environmental Precautions Do not allow contact with soil, surface or ground water.

Methods and material for containment and cleaning up


Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local /
national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain
material to ensure runoff does not reach a waterway.

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7. HANDLING AND STORAGE

Precautions for safe handling

Advice on Safe Handling Take necessary action to avoid static electricity discharge (which might cause ignition of
organic vapours). Keep away from fire, sparks and heated surfaces. Wash hands
thoroughly after handling. Use only with adequate ventilation.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep away from heat and sources of ignition. Keep in a cool, well-ventilated place. Keep
away from oxidizing agents. Keep out of reach of children. Keep container tightly closed.
Store in suitable labeled containers.

Unsuitable Materials Buna-N, EPDM, Ethylene propylene, HDPE (high density polyethylene), Neoprene, PVC,
Polyurethane, Polypropylene, Polyethylene, Rubber, Polytetrafluoroethylene/polypropylene
copolymer, Chlorosulfonated polyethylene rubber

Suitable Materials Stainless Steel 304, Stainless Steel 316L, Carbon Steel C1018, Aluminum, Brass, Copper,
Hastelloy C-276, PTFE, Surface fluorinated polyethylene, Fluoroelastomer,
Perfluoroelastomer, Compatibility with Plastic Materials can vary; we therefore recommend
that compatibility is tested prior to use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH


2-Ethylhexanol TWA: 50 ppm
104-76-7

Heavy Aromatic Naphtha TWA: 500 ppm


64742-94-5

Kerosene TWA: 200 mg/m3 TWA: 500 ppm TWA: 100 mg/m3
8008-20-6

Naphthalene STEL: 15 ppm TWA: 10 ppm IDLH: 250 ppm


91-20-3 TWA: 10 ppm TWA: 50 mg/m3 TWA: 10 ppm
(vacated) TWA: 10 ppm TWA: 50 mg/m3
(vacated) TWA: 50 mg/m3 STEL: 15 ppm
(vacated) STEL: 15 ppm STEL: 75 mg/m3
(vacated) STEL: 75 mg/m3
1,2,4-Trimethylbenzene TWA: 25 ppm
95-63-6

Ethylbenzene TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3


100-41-4

Appropriate engineering controls

Engineering Controls Effective exhaust ventilation system.


Maintain air concentrations below occupational exposure standards.

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Individual protection measures, such as personal protective equipment

Eye/Face Protection Safety glasses

Skin and Body Protection Wear protective gloves and suitable protective clothying.. Gloves should be discarded and
replaced if there is any indication of degradation or chemical breakthrough.

Respiratory Protection When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Remove and wash
contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly
after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical State Liquid


Appearance Brown liquid Odor Hydrocarbon-like
Color Brown Odor Threshold Not determined

Property Values Remarks • Method


pH Not determined
Melting Point/Freezing Point Not determined
Boiling Point/Boiling Range 158-208 °C / 318-408 °F
Flash Point 56 °C / 132.8 °F Pensky-Martens Closed Cup (PMCC)
Evaporation Rate Not determined (Ether = 1)
Flammability (Solid, Gas) Not determined
Upper Flammability Limits Not determined
Lower Flammability Limit Not determined
Vapor Pressure Not determined
Vapor Density Not determined (Air=1)
Specific Gravity 0.97 (15.5 °C) (1=Water)
Water Solubility Mostly insoluble
Solubility in other solvents Not determined
Partition Coefficient Not determined
Auto-ignition Temperature Not determined
Decomposition Temperature Not determined
Kinematic Viscosity Not determined
Dynamic Viscosity Not determined
Explosive Properties Not determined
Oxidizing Properties Not determined

10. STABILITY AND REACTIVITY

Reactivity
Not reactive under normal conditions.

Chemical Stability
Stable under recommended storage conditions.

Possibility of Hazardous Reactions


None under normal processing.

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Conditions to Avoid
Keep out of reach of children. Keep away from sources of ignition such as heat, sparks or open flames.

Incompatible Materials
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate)
may generate heat, fires, explosions and/or toxic vapors.

Hazardous Decomposition Products


Carbon oxides

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Eye Contact Avoid contact with eyes.

Skin Contact Health injuries are not known or expected under normal use.

Inhalation Health injuries are not known or expected under normal use

Ingestion Harmful if swallowed. Produces methemoglobin.

Information on physical, chemical and toxicological effects

Symptoms No symptoms known or expected.

Product Toxicological Information

Acute oral toxicity Acute toxicity estimate: > 5,000 mg/kg

Acute inhalation toxicity Acute toxicity estimate: > 40 mg/l (Exposure time 4 hr)

Skin corrosion/irritation No data available

Serious eye damage/eye No data available


irritation

Respiratory or skin sensitization No data available

Carcinogenicity

Chemical Name ACGIH IARC NTP OSHA


Naphthalene X Group 2B Reasonably Anticipated X
91-20-3
Ethylbenzene X Group 2B X
100-41-4

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Reproductive effects No data available

Germ cell mutagenicity No data available

Teratogenicity No data available

STOT – single exposure No data available

STOT – repeated exposure No data available

Aspiration toxicity No data available

Components

Acute dermal toxicity Ethylbenzene – LD50 rabbit: 15,400 mg.kg

12. ECOLOGICAL INFORMATION

Ecotoxicity
Toxic to aquatic life with long lasting effects.

Product Information

Toxicity to fish LC50 Pimephales promelas (fathead minnow): 5.52 mg/l


Exposure time: 96 hrs
Test substance: Product

NOEC Pimephales promelas (fathead minnow): 2.5 mg/l


Exposure time: 96 hrs
Test substance: Product

LC50 Rainbow Trout: 13.9 mg/l


Exposure time: 96 h
Test substance: Product

Toxicity to daphnia & other LC50 Ceriodaphnia dubia: 4.67 mg/l


aquatic invertebrates Exposure time: 48 hrs
Test substance: Product
Test Type: Static

NOEC Ceriodaphnia dubia: 2.5 mg/l


Exposure time: 48 hrs
Test substance: Product
Test Type: Static

EC50 Daphnia magna: 1.55 mg/l


Exposure time: 48 h
Test substance: Product
Test Type: Static

Component Information

Toxicity to algae Kerosene – EC50: 5 mg/l (Exposure time 72 hr)

Persistence/Degradability
The organic portion of this product is expected to be inherently biodegradable.

Bioaccumulation
Component substances have a potential to bioaccumulate.

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Mobility
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite
TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model
does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate
of the environmental fate of this product under the defined conditions of the models.

If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate
respective percentages:

Air: < 5%
Water: 5-10%
Soil: 70-90%

The portion in water is expected to float on the surface.

13. DISPOSAL CONSIDERATIONS

Waste Treatment Methods

Disposal of Wastes The product should not be allowed to enter drains, water courses or the soil. Where
possible recycling is preferred to disposal or incineration. If recycling is not practicable,
dispose of in compliance with local regulations. Dispose of wastes in an approved waste
disposal facility.

Disposal Considerations Dispose of as unused product. Empty containers should be taken to an approved waste
handling site for recycling or disposal. Do not re-use empty containers.

Hazardous Waste D001, D018

14. TRANSPORT INFORMATION

Note The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and
markings are in compliance with the selected mode of transport.

DOT In containers of 119 gallons capacity or less this product is not regulated by DOT
UN/ID No UN1993
Proper Shipping Name Flammable liquid, N.O.S. (2-Ethylhexanol)
Hazard Class 3
Packing Group III
Reportable Quantity (per 2,506 lbs
package)
RQ Component Naphthalene

IATA
UN/ID No UN1993
Proper Shipping Name Flammable liquid, N.O.S. (2-Ethylhexanol)
Hazard Class 3
Packing Group III
Reportable Quantity (per 2,506 lbs
package)
RQ Component Napthalene

IMDG
UN/ID No UN1993
Proper Shipping Name Flammable liquid, N.O.S. (2-Ethylhexanol)
Hazard Class 3
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Packing Group III
Marine Pollutant* Naphthalene

*Note: This product is regulated as a Marine Pollutant when shipped by Rail, Highway (in
bulk quantities), or Air (if no other hazard class applies), and when shipped by water in all
quantities.

15. REGULATORY INFORMATION

International Inventories

TSCA (United States) Listed or Exempted


CEPA (Canada) Listed or Exempted
NICNAS (Australia) All substances comply
IECSC (China) Listed or Exempted
EINECS (Europe) All substances comply
ENCS (Japan) All substances comply
TCCL (Korea) All substances comply
HSNO (New Zealand) All substances comply
PICCS (Philippines) All substances comply

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

US Federal Regulations

EPCRA – Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)


Naphthalene 100 lb 2506
91-20-3

SARA 304 Extremely Hazardous This material does not contain any components with a section 304 EHS R.Q.
Substances Reportable Quantity

SARA 311/312 Fire Hazard


Chronic Health Hazard

SARA 302 No chemicals in this material are subject to the reporting requirements of SARA Title III,
Section 302.

SARA 313 – the following components are subject to reporting levels established by SARA Title III, Section 313:

Chemical Name CAS No Weight-% SARA 313 - Threshold


Values %
Naphthalene - 91-20-3 91-20-3 Proprietary 1 – 5%
1,2,4-Trimethylbenzene 95-63-6 Proprietary 1 – 5%
Ethylbenzene 100-41-4 Proprietary 0.1 – 1%

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California Proposition 65
This product contains the following Proposition 65 chemicals.

Chemical Name California Proposition 65


Naphthalene - 91-20-3 Carcinogen
Ethylbenzene 100-41-4 Carcinogen

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania


Naphthalene X X X
91-20-3

16. OTHER INFORMATION

NFPA Health Hazards Flammability Instability Special Hazards


2* 2 0 Not determined
HMIS Health Hazards Flammability Physical Hazards Personal Protection
Not determined Not determined 0 Not determined

Issue Date: 01-Aug-2017


Revision Date: 01-Oct-2017
Revision Note: Corrections

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

End of Safety Data Sheet

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