Roban Blocks - SDS PDF
Roban Blocks - SDS PDF
Roban Blocks - SDS PDF
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Ready for use Rodenticide containing 50ppm Difenacoum.
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Supplemental label EUH 208 Contains 1, 2- Benzisothiazolin-3-one. May produce an allergic reaction.
information EUH401 To avoid risks to human health and the environment, comply with the instructions for
use.
P102 Keep out of reach of children.
P103 Read label before use.
P220 Keep / Store away from foodstuffs, beverages and animal feeding stuffs.
P262 Do not get on skin.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves [Professional users].
P273 Avoid release to the environment.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P404 Store in a closed container.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.
3.2. Mixtures
1,2-BENZISOTHIAZOL-3(2H)-ONE <0.02%
CAS number: 2634-33-5 EC number: 220-120-9
M factor (Acute) = 10
Classification
Acute Tox. 4 - H302
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Aquatic Acute 1 - H400
2,2'-Iminodiethanol <0.1%
CAS number: 111-42-2 EC number: 203-868-0
Classification
Eye Dam. 1 - H318
STOT RE 2 - H373
DIFENACOUM 0.005%
CAS number: 56073-07-5 EC number: 259-978-4
M factor (Acute) = 1 M factor (Chronic) = 1
Classification
Acute Tox. 2 - H300
STOT RE 1 - H372
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410
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Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H332
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Aquatic Chronic 3 - H412
The full text for all hazard statements is displayed in Section 16.
Skin contact No specific recommendations. Rinse with water. Get medical attention if any discomfort
continues.
Eye contact Rinse with water. Get medical attention if any discomfort continues.
Protection of first aiders Use protective equipment appropriate for surrounding materials.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Ingestion Rinse mouth. Do not induce vomiting. Call a medical doctor immediately.
Skin contact Prolonged contact may cause dryness of the skin. May cause irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
Specific treatments See 'General information' in section 4.1 of this Safety Data Sheet.
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Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Hazardous combustion Thermal decomposition or combustion products may include the following substances:
products Harmful gases or vapours.
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing. Firefighter's clothing conforming to European standard EN469 (including helmets,
protective boots and gloves) will provide a basic level of protection for chemical incidents.
Advice on general Wash promptly if skin becomes contaminated. Take off contaminated clothing. Wash
occupational hygiene contaminated clothing before reuse.
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Sugar (Sucrose) WEL 8-Hr limit mg/M3: 10 WEL 15 min limit mg/M3: 20
Propane-1,2-diol (Propane-1,2-diol Particulates) WEL 8-Hr limit mg/M3: 10
Propane-1,2-diol (Propane-1,2-diol total vapour and particulates) WEL 8-Hr limit ppm: 150
WEL 8Hr limit mg/M3: 474
Paraffin Wax WEL 8-Hr limit mg/M3: 2
WEL 15 min limit mg/M3: 6
Eye/face protection No specific eye protection required during normal use. Large Spillages: Eyewear complying
with an approved standard should be worn if a risk assessment indicates eye contact is
possible.
Hand protection No specific hand protection recommended. Large Spillages: Wear protective gloves.
Hygiene measures Wash hands thoroughly after handling. Wash at the end of each work shift and before eating,
smoking and using the toilet. Do not eat, drink or smoke when using this product.
Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is
inadequate, suitable respiratory protection must be worn.
Odour Slight.
pH No information available.
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Oxidising properties Does not meet the criteria for classification as oxidising.
10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.
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Notes (inhalation LC₅₀) Based on available data the classification criteria are not met.
Skin corrosion/irritation
Animal data Based on available data the classification criteria are not met.
Respiratory sensitisation
Respiratory sensitisation Based on available data the classification criteria are not met.
Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.
Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.
Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.
Reproductive toxicity - Based on available data the classification criteria are not met.
development
Aspiration hazard
Aspiration hazard Not relevant. Solid.
General information No specific health hazards known. The severity of the symptoms described will vary
dependent on the concentration and the length of exposure.
Toxicity of ingredients Difenacoum Acute Oral (Rat) Category 2 from CLP Denatonium Benzoate Oral (Rat)
LD50 = 584 mg/kg
Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have
hazardous effects on the environment. Toxic to mammals, including domesticated animals,
and birds if ingested. Exposure to non-target animals should be prevented.
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12.1. Toxicity
Toxicity Based on available data the classification criteria are not met.
Toxicity of ingredients Difenacoum Daphnia EC50/48Hr = 0.91 mg/l Rainbow trout LC50/96Hr = 0.33 mg/l
Disposal methods Dispose of in accordance with applicable regional, national, and local laws and regulations.
Dispose of Contaminated packaging as unused product unless fully cleaned. The European
waste disposal key number from EWC is 20 01 19 (Pesticides).
General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).
14.1. UN number
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Health and Safety at Work etc. Act 1974 (as amended).
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009
No. 716).
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment
Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"].
EH40/2005 Workplace exposure limits.
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Commission Regulation (EU) No 453/2010 of 20 May 2010.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Dangerous Preparations Directive 1999/45/EC.
Dangerous Substances Directive 67/548/EEC.
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This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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