Reviewed: July 1, 2022 Safety Data Sheet

SECTION 1: MANUFACTURER AND PRODUCT IDENTIFICATION

1.1 Product Identifier: Igniter

GHS Product Identifier Pyrotechnic Article
Chemical Name Not applicable
Trade Name Igniter (ZPP)
CAS No. Mixture
ENIECS No. Mixture
1.2 Description and Use of Product: Pyrotechnic Article for technical purposes. Users are recommended to
seek further advice.
1.3 Supplier/Company:
Daicel Safety Systems (Thailand) Co.,Ltd.
76 Moo 1 Pukamjan
Praputthabath Saraburi
18120 Thailand
+66-36-298-300
E-Mail (competent person): MSD-SDS@jp.daicel.com
1.4 Emergency Telephone No.: +66-37-270-900

SECTION 2: HAZARD IDENTIFICATION

2.1 Classification: Pyrotechnic Article

2.2 Signal Word: Warning
2.3 Hazard Labels, Hazard Symbol:
Hazard H204 Fire or projection hazard.
Statement(s) H240 Heating may cause an explosion.
H302 Harmful if swallowed.
Precautionary P102 Keep out of reach of children.
Statement(s) P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flame/hot surfaces – no smoking.
P243 Take precautionary measures against static discharge.
P250 Do not subject to grinding/shock/mechanical loads/crush/impact/friction.
P270 Do not eat, drink or smoke when using this product.
P281 Use personal protective equipment as required.
P301 + P313 If swallowed: Get medical advice/attention.
P370 + P373 In case of fire: DO NOT fight fire when fire reaches explosives.
P402 + P405 Store in a dry place. Store locked up.
P501 Dispose of contents/containers to: a licensed recycler, reclaimer or incinerator.
Risk Phrase(s) R2 Risk of explosion by shock, friction, fire or other sources of ignition.
R5 Heating may cause an explosion.
Safety S1/S2 Keep locked up. Keep out of reach of children.
Phrase(s) S15/S16 Keep away from heat. Keep away from sources of ignition – no smoking.
S22/S24 Do not breathe dust. Avoid contact with skin.
S33/S34 Take precautionary measures against static discharges. Avoid shock or friction.
S35 This material and its container must be disposed of in a safe way.
S36/S37/S39 Wear suitable protective clothing and eye/face protection.
S60 This material and its container must be disposed of as hazardous waste.

1 Revision 4.2
Reviewed: July 1, 2022 Safety Data Sheet
2.4 Other Hazards Summary: Pyrotechnic mixtures are known to burn with intense heat and give off toxic
fumes. Confining a pyrotechnic mixture while burning may result in severe consequences.
• Uncontrolled activation may result in burn injuries from combustion products (particles, gases).
• Uncontrolled activation may result in blast trauma.
• Uncontrolled activation may result in eye or airway irritation through combustion products.
• Hazard Communication Standard (HMIS): Health-2, Flammability-2, Physical-1
• This is a sealed device. Under anticipated handling, storage and use conditions, chronic exposure to
chemical ingredients is highly unlikely. Prolonged or repeated skin contact may cause more severe
irritation or dermatitis. Prolonged or repeated inhalation may cause more severe irritation and possibly
lung damage. Potassium perchlorate may cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis (bluish skin
due to deficient oxygenation of blood), rapid heart rate, unconsciousness and possible death. Zirconium
may cause skin granulomas with prolonged or repeated skin contact. May cause liver and kidney damage.

SECTION 3: COMPOSITION/INGREDIENT/COMPONENT INFORMATION

3.1 Pyrotechnic Article: Pyrotechnic ingredients in this article are sealed from the environment (delivery
condition) and cannot be released under normal or foreseeable conditions of use including professional
disposal without destroying the article. Typically, this pyrotechnic article has a glass-to-metal seal header,
bridge wire ignition element, charge sleeve, can, insulator cup and injection molding. The pyrotechnic
ignition charge and output charge are sealed inside the completed assembly.
3.2 EC Classification No. 1272/2008/EC
Ignition Charge
Hazardous Ingredients WW% CAS No. EC No. Hazard Pictogram
Zirconium 40-60 7440-67-7 231-176-9

Potassium Perchlorate 40-60 7778-74-7 231-912-9

Viton B Binder 1-5 9011-17-0 N/A None

Carbon <1 7440-44-0 231-153-3 None

SECTION 4: FIRST AID MEASURES

4.1 First Aid Measures: General first-aid rules should be followed.
Inhalation: Remove from danger, supply fresh air, and seek medical attention.
Eyes: Rinse with clear water and seek medical attention.
Skin: Wash skin thoroughly with soap and seek medical attention.
Ingestion: Drink plenty of water and seek medical attention.
4.2 Acute Trauma: Blast injuries may occur should the product deploy accidentally. Immediate medical
treatment is essential to achieve ideal patient outcome and recovery. Treat potential skeletal and soft
tissue injuries symptomatically. These injuries may not be immediately recognized. Occupational exposure
levels for pre- and post-product use is highly unlikely due to the manufacture of this product which isolates
hazardous ingredients by a welded, hermetic sealing process.

2 Revision 4.2
Reviewed: July 1, 2022 Safety Data Sheet

SECTION 5: FIRE FIGHTING MEASURES

5.1 Fire and Explosion Hazard: An external fire will not cause the device or the entire packaged contents to
activate or ignite all at one time.
5.2 Advice for Fire Fighters:
♦ Try to keep fire away from packaging or pyrotechnic articles.
♦ Evacuate the area if fire reaches packaging or pyrotechnic articles.
♦ Never fight explosive fires!
5.3 Extinguishing Media: Use dry chemical, foam or water spray or media suitable on surrounding material
for cooling purposes.
5.4 Products of Decomposition: See Section 10 (Stability and Reactivity).

SECTION 6: ACCIDENTAL RELEASE OR SPILL

6.1 Precautionary Measures: In the case of destruction or damage of the pyrotechnic article (discharge of
the pyrotechnic ingredients), remove potential ignition sources. This pyrotechnic article may activate when
exposed to fire, heat, electrical energy, electrostatic energy, shock or mechanical loads (crush or impact).
6.2 Environmental Precautions: Ventilation recommended. Do not allow pyrotechnic articles or ingredients
to get into bodies of water, wastewater or soil.
6.3 Process for Clearing: Put on protective equipment before entering the area (e.g., safety glasses w/ side
shields, flame-resistant shop coat, gloves). Igniter – Carefully pick up the igniter and place in a non-static
generating container. Pyrotechnic powder – Saturate the pyrotechnic material with water (spray bottle).
Wipe contaminated surfaces with a wet cloth and place all contents (powder and cloth) in a sealable, non-
static generating container. Seal the container to prevent the pyrotechnic material from drying out. This
pyrotechnic material is less sensitive to ignition sources when properly wetted with water. Contact an
authorized environmental firm and dispose in accordance with applicable laws, regulations or ordinances.
6.4 Reference to other sections: See sections 7, 8 & 13.

SECTION 7: HANDLING AND STORAGE

7.1 General Precautions: Keep fire away, keep away from ignition sources, heat and sparks.
7.2 Handling:
Do not connect this device to an electrical source improperly. Consult product installation instructions or
request assistance from the supplier.
Do not attempt to open or breach this device.
Do not attempt to make repairs on this device. Consult supplier for return or disposal instructions.
Do not attempt to remove or allow damage to the wire leads, if applicable.
Do not misuse or mistreat this device.
Limit and prevent electrostatic charging or discharge.
7.3 Storage:
Safeguard from theft, unauthorized use or unauthorized removal.
This pyrotechnic article is guaranteed for fifteen (15) years and will store well in a cool, dry location.
Keep pyrotechnic articles away from materials that may increase storage hazards.
Protect pyrotechnic article and packaging from fire, heat, electrical energy, shock, friction or impact.

3 Revision 4.2
Reviewed: July 1, 2022 Safety Data Sheet
SECTION 8: EXPOSURE CONTROL / PERSONAL PROTECTION

8.1 General Requirements: None. Pyrotechnic ingredients in this article are sealed from the environment
(delivery condition) and cannot be released under normal or foreseeable conditions of use including
professional disposal without destroying the article.
8.2 General Exposure Controls: Do not eat, drink or smoke when handling, testing or installing this product.
8.3 Occupational Exposure Limits: None. This is a hermetically sealed pyrotechnic article.
8.4 Recommended Personal Protective Equipment:
Respiratory Protection No personal respiratory protection is necessary.
Hand Protection No special hand protection is necessary.
Eye Protection Safety glasses for activities involving test and installation.
Body Protection Avoid static generating footwear or clothing when handling this article.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Activation: Likely to occur beginning a 300°C (572°F) and electrical current beginning at 0.35A.
9.2 Information on basic physical and chemical properties:
Appearance: Metal and plastic shell (may have lead wires)
Odor: No specific odor, no odor threshold available Color: Polished metal
Melting Point: Not available Boiling Point: Not available
Flash Point: Not available Explosive limit: Not available
Explosive Properties: Explosive Oxidizing Properties: Not available
Flammability: Not available pH Value: Not applicable
Vapor Pressure: Not available Evaporation Rate: Not available
Vapor Density: Not available Density: Not applicable
Solubility (water): Not available Solubility (other): Not applicable
Partition Coefficient: Not available Viscosity: Not applicable

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity and Conditions to Avoid: Keep fire away. Avoid electrical energy and heat sources.
10.2 Chemical Stability: Stable under normal handling and storage conditions.
10.3 Incompatible Materials: None known. Pyrotechnic ingredients in this article are sealed from the
environment (delivery condition) and cannot be released under normal or foreseeable conditions of
use including professional disposal without destroying the article.
10.4 Hazardous Decomposition Product(s):Z Oxides of carbon, nitrogen, potassium and zirconium;
potassium chloride, and trace amounts of other potentially irritating and toxic fumes and gases.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 General Precautions: None.
11.2 Other Information: Under normal or reasonably foreseeable conditions, the pyrotechnic ingredients
are sealed from the environment in the article and cannot be released without destroying this article.
11.3 Toxicity:

Chemical Substance CAS No. LD50 (Oral, Rat) LC50 (Inhalation, Rat) LD50 (Dermal, Rat)
Potassium Perchlorate 7778-74-7 2100 mg/kg Not established Not established
Zirconium 7440-67-7 Not established Not established Not established
Viton B Binder 9011-17-0 Not established Not established Not established

4 Revision 4.2
Reviewed: July 1, 2022 Safety Data Sheet

SECTION 12: ECOLOGICAL INFORMATION

12.1 General Precautions: Unknown. Under normal or reasonably foreseeable conditions, no

environmental harm is expected or anticipated when used as intended.
12.2 California Only: Contains perchlorates – special handling may apply (see notice online at
www.dtsc.ca.gov/hazardouswaste/perchlorate).
12.3 Other adverse effects: Unknown. Consult supplier or local regulations for advice.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste Management: Pyrotechnic articles which have not been activated must be disposed by
specialized companies licensed in this area with respect to existing regulations (see also Section 8:
Handling and Storage). Pyrotechnic articles damaged by fire, heat or an accident must be disposed of
as non-activated articles or objects.
13.2 Other Information: Consult with an accredited waste disposal contractor or the local authority for
advice regarding waste disposal.

SECTION 14: TRANSPORT INFORMATION

14.1 Shipping: Consult with accredited, authorized transport provider

Land Transport (US/ADR/RID) / Sea Transport (IMDG) / Air Transport (ICAO/IATA)
UN Number 0454
Proper Shipping Name Igniters
Transportation Hazard Class 1.4S

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the mixture:
15.2 US Regulations:
TSCA: All chemicals listed or otherwise exempt from reporting rules.
SARA 311/312: Listed – None
SARA 302/313: Listed – None
CERCLA/CAA/CWA: Listed – None
State Right to Know Lists: See state toxic and hazardous substances lists.
15.3 Canada
WHMIS Classification: Exempt as explosive
15.4 EU Regulations:
Authorizations and/or
restrictions on use: Consult supplier
European Union
(EINECS/ELINCS): Consult supplier
SVHC List: Listed - None
CE Registration: Consult supplier and shipping documents.
German WGK number: Consult supplier

5 Revision 4.2
Reviewed: July 1, 2022 Safety Data Sheet

SECTION 16: OTHER INFORMATION

16.1 Other Information:

This Safety Data Sheet (SDS) is provided for information only, and the information presented herein is
considered accurate as of the date of preparation. Most data is company derived or obtained from literature
and sources deemed to be reliable. Users, employees and all other persons who handle or store the product
must be provided access to the SDS.
Daicel Corporation makes no warranty with respect to the accuracy or suitability of the recommendations, and
assumes no liability for any damages, losses, injuries or consequential damaged which may result from the
use of reliance on any information contained herein.
The information in the SDS relates only to the explosive substance or article described herein and does not
relate to use in combination with any other substance, article, or in any process.
It is the user’s obligation to determine the conditions of safe use of the explosive substance or article.
Users are responsible to meet applicable laws and regulations.

End of Safety Data Sheet

6 Revision 4.2