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Msds-Hansa Ese 6960

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Safety Data Sheet


according to 1907/2006/EC
Printing date 06.02.2009 Version 3 Revision: 03.02.2009

1 Identification of substance / preparation and company


· Product details
· Trade name HANSA ESE 6960
· Application of the substance / the preparation
Textile auxiliary
Hair care product
Household care product
Car care product
· Manufacturer/Supplier:
CHT R. BEITLICH GMBH CHT R. BEITLICH GMBH
Werk Oyten Bismarckstraße 102
Rudolf-Diesel-Straße 19-21 D-72072 Tübingen
D-28876 Oyten
Tel.: +4207-603-0 Tel.: +7071-154-0
info@cht.com

Department issuing safety data sheet:


msds@cht.com
· Informing department: Product Safety
· Emergency information: Tel.: +7071-154-0 (Germany, 24 h)

2 Hazards identification
· Hazard designation: void
· Information pertaining to particular dangers for man and environment void
· Classification system:
The classification is in line with current EC lists. It is expanded, however, by information from
technical literature and by information furnished by supplier companies.

3 Composition/information on ingredients
· Chemical characterization
· Description: Emulsion of epoxy siloxane
· Dangerous components:
fatty alcohol, ethoxylated 1 - 2,5%
Xn, Xi; R 22-41
67-56-1 Methanol < 0,5%
T, F; R 11-23/24/25-39/23/24/25
· Additional information For the wording of the listed risk phrases refer to section 16.

4 First aid measures


· General information
Instantly remove any clothing soiled by the product.
It is advisable to present this safety data sheet when visiting the doctor.
· After inhalation Provide with fresh air; consult doctor in case of symptoms.
(Contd. on page 2)

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Page 2/6
Safety Data Sheet
according to 1907/2006/EC
Printing date 06.02.2009 Version 3 Revision: 03.02.2009

Trade name HANSA ESE 6960

(Contd. of page 1)
· After skin contact
Instantly wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
· After swallowing
Rinse mouth and throat with water.
Do not induce vomiting; instantly call for medical help.

5 Fire fighting measures


· Suitable extinguishing agents
CO2, extinguishing powder or water spray jet. Fight larger fires with water spray jet or foam.
Product itself does not burn, fire extinguishing measures have to be adjusted to the environment.
· Special hazards caused by the material, its products of combustion or flue gases:
Can be released in case of fire:
Oxides of carbon (COx)
Silicium dioxide (SiO2)
In case of fire or smouldering fires harmful substances are released.
· Protective equipment: Wear self-contained breathing apparatus.
· Additional information
The material itself does not burn, only after drying in through a large fire.
In case of fire do not inhale smoke, conflagration gases and steams
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

6 Accidental release measures


· Person-related safety precautions:
Keep away third parties.
Personal protection see point 8.
Particular danger of slipping on leaked/spilled product.
· Measures for environmental protection:
Do not allow to enter the ground, water or sewage water system.
Pay attention to local or official regulations.
· Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of the material collected according to regulations.
Clean thoroughly the soiled surfaces.

7 Handling and storage


· Handling
· Information for safe handling:
Prevent formation of aerosols.
Keep containers tightly sealed.
· Information about protection against explosions and fires: No special measures required.
(Contd. on page 3)

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Page 3/6
Safety Data Sheet
according to 1907/2006/EC
Printing date 06.02.2009 Version 3 Revision: 03.02.2009

Trade name HANSA ESE 6960

(Contd. of page 2)

· Storage
· Requirements to be met by storerooms and containers:
Do always store in containers which correspond to the original ones.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep containers tightly sealed.
Protect from frost.
Protect from temperatures over + 40 °C.
· Storage class: 12 (according to VCI-outline)

8 Exposure controls and personal protection


· Additional information about design of technical systems: No further data; see item 7.
· Components with critical values that require monitoring at the workplace:
67-56-1 Methanol (< 0,5%)
AGW (Germany) 270 mg/m³, 200 ppm
4(II);DFG, EU, H, Y
· Additional information: The lists that were valid during the compilation were used as basis.
· Personal protective equipment
· General protective and hygienic measures
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
Instantly remove any soiled and impregnated garments.
The usual precautionary measures when handling with chemicals should be observed.
· Breathing equipment:
In case the work place is not ventilated sufficiently and during spray processing, it is necessary to
wear respiratory protective equipment.
Combination filter A / P
· Protection of hands: Protective gloves.
· Material of gloves
suitable, e.g.:
PVC gloves
Recommended thickness of the material: ≥ 0,5 mm
Nitrile rubber, NBR
Recommended thickness of the material: ≥ 0,35 mm
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer.
· Penetration time of glove material
Value for the permeation: Level ≥ 6 (480 min)
The determined penetration times according to EN 374 part III are not performed under practical
conditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time,
is recommended.
· Eye protection: Tightly sealed safety glasses.
· Body protection: Protective work clothing.

(Contd. on page 4)

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Page 4/6
Safety Data Sheet
according to 1907/2006/EC
Printing date 06.02.2009 Version 3 Revision: 03.02.2009

Trade name HANSA ESE 6960

(Contd. of page 3)

9 Physical and chemical properties:


· General Information
Form: Fluid
Emulsion
Colour: White
Smell: Characteristic
Melting point/Melting range: Not determined
Boiling point/Boiling range: ca. 100°C
· Flash point: > 100°C
· Self-inflammability: Product is not selfigniting.
· Danger of explosion: Product is not explosive.
· Critical values for explosion:
Oxidizing properties Not applicable
· Steam pressure: Not determined
· Density at 20°C ca. 1 g/cm³ (DIN 51575)
· Relative steam density (air = 1): Not applicable
· Evaporation rate Not applicable
· Solubility in / Miscibility with
Water: miscible
· pH-value at 20°C: 5,0 - 6,0
· Segregation coefficient (n-octanol/water): Not applicable
· Viscosity:
dynamic: Not determined

10 Stability and reactivity


· Conditions to be avoided: No decomposition if used according to specifications.
· Hazardous decomposition products:
No dangerous decomposition if stored and handled appropriately.
Can be released in case of fire:
see Section 5

11 Toxicological information
· Acute toxicity:
· LD/LC50 values that are relevant for classification: Not determined
· Primary irritant effect:
· on the skin: In case of longer, direct contact with the skin slight irritations of the skin are possible.
· on the eye: In case of direct contact irritations are possible.
· In case of ingestion no damaging effect is known.
(Contd. on page 5)

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Page 5/6
Safety Data Sheet
according to 1907/2006/EC
Printing date 06.02.2009 Version 3 Revision: 03.02.2009

Trade name HANSA ESE 6960

(Contd. of page 4)
· Sensitization: No sensitizing effect known.
· Other information (about experimental toxicology): Experimental tests are not available.
· Additional toxicological information:
If used and handled according to specifications, the product does not have any harmful effects
according to our experience and the information provided to us.
The product is not subject to classification according to the calculation method of the General EC
Classification Guidelines for Preparations as issued in the latest version.

12 Ecological information:
· Persistence and degradability:
· Method OECD 302B (Zahn-Wellens-Test)
· Analysing method DOC- or COD-measurement
· Degree of elimination: > 90 %
· Evaluation text: The product is "inherently biodegradable" according to the criteria of the OECD.
· Ecotoxical effects:
· Aquatic toxicity:
· Daphnia toxicity EC 50 (OECD 202 part 1, DIN 38412 part 11, DEV L11):
438 mg/l (Daphnia magna, 48 h)
· Behaviour in sewage processing plants:
· Bacteria toxicity EC 50: > 1000 mg/l (OECD 209)
· Other information:
It is nearly completely eliminated in appropriate purification plants by biological decomposition,
stripping and mechanical separation.
· Additional ecological information:
· Chemical oxygen demand COD (DIN 38 409 part 41, 43; DEV H 41,43): ca. 450 mg O2/g
· Biochemical oxygen demand BOD5 (DIN 38 409 part 51; DEV H51): ca. 20 mg O2/g
· AOX (DIN 38 409 dalis 14; DEV H 14):
· AOX information:
Because of the components, which do not contain any organic halogens, this product does not
increase the AOX-values in the waste water.
· According to recipe contains the following heavy metals and compounds according to EC
directive 2000/60 EC:
According to our knowledge, the product does not contain heavy metals and other compounds of
EC directive 2000/60 EC.
· General notes: The ecological data indicated was determined by analogism.

13 Disposal considerations
· Product:
· Recommendation Disposal must be made according to official regulations.
(Contd. on page 6)

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Page 6/6
Safety Data Sheet
according to 1907/2006/EC
Printing date 06.02.2009 Version 3 Revision: 03.02.2009

Trade name HANSA ESE 6960

(Contd. of page 5)

· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· Transport/Additional information: No dangerous goods according to transport regulations.

15 Regulatory information
· Designation according to EC guidelines:
The product is not subject to identification regulations under EC Directives and the Ordinance on
Hazardous Materials (GefStoffV).
Observe the normal safety regulations when handling chemicals.

16 Other information:
This data is based on our present knowledge. However, it shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant R-phrases
11 Highly flammable.
22 Harmful if swallowed.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with
skin and if swallowed.
41 Risk of serious damage to eyes.
· Department issuing data specification sheet: Product Safety
· Contact: Mr. Knörzer
· * Data compared to the previous version altered. Chapter 1, 16

DR

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