SDS Metallurgical Coke - NA
SDS Metallurgical Coke - NA
SDS Metallurgical Coke - NA
1 Identification
· Product identifier
· Trade name: Metallurgical Coke
· Product code: No other identifiers
· CAS Number: 65996-77-2
· Recommended use and restriction on use
· Recommended use: Industrial uses.
· Restrictions on use: Not intended for food and drug use.
· Details of the supplier of the Safety Data Sheet
· Manufacturer/Supplier:
Asbury Carbons, Inc.
PO Box 144
405 Old Main Street
Asbury, NJ 08802
USA
+1 908-537-2155
· Emergency telephone number:
ChemTel
(800)255-3924 (North America)
+1 (813)248-0585 (International)
2 Hazard(s) identification
· Classification of the substance or mixture
Carc. 1A H350 May cause cancer. Route of exposure: Inhalation.
STOT RE 1 H372 Causes damage to the lung through prolonged or repeated exposure. Route of
exposure: Inhalation.
Combustible Dust May form combustible dust concentrations in air.
· Label elements
· GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms:
GHS08
50.1.3
Page: 2/8
Safety Data Sheet
according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations
Revision: June 09, 2020
(Cont'd. of page 1)
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Additional information:
Read the label and safety data sheet before use. Prevent dust accumulations to minimize explosion
hazard. Keep away from all ignition sources including heat, sparks and flame.
3 Composition/information on ingredients
· Chemical characterization: Substances
· CAS No. Description
65996-77-2
Coke (coal)
· Components:
14808-60-7 Quartz (SiO2) 1-2%
Carc. 1A, H350; STOT RE 1, H372
4 First-aid measures
· Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Brush off loose particles from skin.
If skin irritation is experienced, consult a doctor.
· After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: Do not induce vomiting; immediately call for medical help.
· Most important symptoms and effects, both acute and delayed: No relevant information available.
· Danger:
Causes damage to the lung through prolonged or repeated exposure. Route of exposure: Inhalation.
May cause cancer. Route of exposure: Inhalation.
· Indication of any immediate medical attention and special treatment needed:
If medical advice is needed, have product container or label at hand.
If necessary oxygen respiration treatment.
5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents: Use fire fighting measures that suit the environment.
· For safety reasons unsuitable extinguishing agents: No relevant information available.
· Special hazards arising from the substance or mixture
Can pose a dust explosion hazard if dispersed in air. Avoid ignition sources.
During heating or in case of fire poisonous gases are produced.
(Cont'd. on page 3)
50.1.3
Page: 3/8
Safety Data Sheet
according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations
Revision: June 09, 2020
(Cont'd. of page 2)
· Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
50.1.3
Page: 4/8
Safety Data Sheet
according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations
Revision: June 09, 2020
(Cont'd. of page 3)
PEL (USA) Long-term value: 0.05* mg/m³
*resp. dust; 30mg/m3/%SiO2+2
REL (USA) Long-term value: 0.05* mg/m³
*respirable dust; See Pocket Guide App. A
TLV (USA) Long-term value: 0.025* mg/m³
*as respirable fraction
EL (Canada) Long-term value: 0.025 mg/m³
ACGIH A2; IARC 1
EV (Canada) Long-term value: 0.10* mg/m³
*respirable fraction
LMPE (Mexico) Long-term value: 0.025* mg/m³
A2, *fracción respirable
· Exposure controls
· General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
· Engineering controls: Provide adequate ventilation.
· Breathing equipment:
Wear appropriate NIOSH respirator when ventilation is inadequate and occupational exposure limits are
exceeded.
· Protection of hands:
Protective gloves
Safety glasses
50.1.3
Page: 5/8
Safety Data Sheet
according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations
Revision: June 09, 2020
(Cont'd. of page 4)
Form: Solid
Granulate
Powder
Color: Grey to Black.
· Odor: Odorless
· Odor threshold: Not determined.
· pH-value: Not applicable.
· Melting point/Melting range: Not determined.
· Boiling point/Boiling range: Not determined.
· Flash point: The product is not flammable.
· Flammability (solid, gaseous): Not determined.
· Auto-ignition temperature: Not determined.
· Decomposition temperature: Not determined.
· Danger of explosion: Can pose a dust explosion hazard if dispersed in air.
· Explosion limits
Lower: Not determined.
Upper: Not determined.
· Oxidizing properties: Non-oxidizing.
· Vapor pressure: Not determined.
· Density at 20 °C (68 °F): 1.8-2 g/cm³ (15.02-16.69 lbs/gal)
· Relative density: Not determined.
· Vapor density: Not applicable.
· Evaporation rate: Not applicable.
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Insoluble.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity
Dynamic: Not applicable.
Kinematic: Not applicable.
· Other information No relevant information available.
50.1.3
Page: 6/8
Safety Data Sheet
according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations
Revision: June 09, 2020
(Cont'd. of page 5)
Reacts with strong oxidizing agents.
· Conditions to avoid Excessive heat.
· Incompatible materials Oxidizers
· Hazardous decomposition products Carbon monoxide and carbon dioxide
11 Toxicological information
· Information on toxicological effects
· Acute toxicity: Based on available data, the classification criteria are not met.
· LD/LC50 values that are relevant for classification: None.
· Primary irritant effect:
· On the skin: Based on available data, the classification criteria are not met.
· On the eye: Based on available data, the classification criteria are not met.
· Sensitization: Based on available data, the classification criteria are not met.
· IARC (International Agency for Research on Cancer):
14808-60-7 Quartz (SiO2) 1
· NTP (National Toxicology Program):
14808-60-7 Quartz (SiO2) K
· OSHA-Ca (Occupational Safety & Health Administration):
None of the ingredients are listed.
· Probable route(s) of exposure:
Ingestion.
Inhalation.
Eye contact.
Skin contact.
· Germ cell mutagenicity: Based on available data, the classification criteria are not met.
· Carcinogenicity: May cause cancer. Route of exposure: Inhalation.
· Reproductive toxicity: Based on available data, the classification criteria are not met.
· STOT-single exposure: Based on available data, the classification criteria are not met.
· STOT-repeated exposure:
Causes damage to the lung through prolonged or repeated exposure. Route of exposure: Inhalation.
· Aspiration hazard: Based on available data, the classification criteria are not met.
12 Ecological information
· Toxicity
· Aquatic toxicity No relevant information available.
· Persistence and degradability No relevant information available.
· Bioaccumulative potential: No relevant information available.
· Mobility in soil: No relevant information available.
· Additional ecological information
· General notes:
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
· Other adverse effects No relevant information available.
(Cont'd. on page 7)
50.1.3
Page: 7/8
Safety Data Sheet
according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations
Revision: June 09, 2020
13 Disposal considerations
· Waste treatment methods
· Recommendation:
The user of this material has the responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and
disposal for hazardous and nonhazardous wastes.
· Uncleaned packagings
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· DOT, ADR/RID/ADN, IMDG, IATA Not regulated.
· UN proper shipping name
· DOT, ADR/RID/ADN, IMDG, IATA Not regulated.
· Transport hazard class(es)
· DOT, ADR/RID/ADN, IMDG, IATA
· Class Not regulated.
· Packing group
· DOT, ADR/RID/ADN, IMDG, IATA Not regulated.
· Environmental hazards
· Marine pollutant: No
· Special precautions for user Not applicable.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or
mixture
· United States (USA)
· SARA
· Section 302 (extremely hazardous substances):
None of the ingredients are listed.
· Section 313 (Specific toxic chemical listings):
None of the ingredients are listed.
· TSCA (Toxic Substances Control Act)
All components have the value ACTIVE or EXEMPT.
(Cont'd. on page 8)
50.1.3
Page: 8/8
Safety Data Sheet
according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations
Revision: June 09, 2020
(Cont'd. of page 7)
· Proposition 65 (California)
· Chemicals known to cause cancer:
14808-60-7 Quartz (SiO2)
· Chemicals known to cause developmental toxicity for females:
None of the ingredients are listed.
· Chemicals known to cause developmental toxicity for males:
None of the ingredients are listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients are listed.
· EPA (Environmental Protection Agency):
None of the ingredients are listed.
· IARC (International Agency for Research on Cancer):
14808-60-7 Quartz (SiO2) 1
· Canadian Domestic Substances List (DSL):
All ingredients are listed or exempt.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Abbreviations and acronyms:
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
OSHA: Occupational Safety & Health Administration
Carc. 1A: Carcinogenicity – Category 1A
STOT RE 1: Specific target organ toxicity (repeated exposure) – Category 1
· Sources
Website, European Chemicals Agency (echa.europa.eu)
Website, US EPA Substance Registry Services (ofmpub.epa.gov/sor internet/registry/substreg/home/
overview/home.do)
Website, Chemical Abstracts Registry, American Chemical Society (www.cas.org)
Patty's Industrial Hygiene, 6th ed., Rose, Vernon, ed. ISBN: 978-0-470-07488-6
Casarett and Doull's Toxicology: The Basic Science of Poisons, 8th Ed., Klaasen, Curtis D., ed., ISBN:
978-0-07-176923-5.
Safety Data Sheets, Individual Manufacturers
SDS Prepared by:
ChemTel
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtel.com
50.1.3