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DPP - 1

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Class : XIth Subject : CHEMISTRY

Date : DPP No. : 1

1. Topic :- Chemical Bonding and Molecular Structure


The true statements from the following are
1. P H 5 and BiC l 5 do not exist
2. pπ−dπ bond is present in S O 2
3.Electrons travel at the speed of light
4. Se F 4 and C H 4 have same shape
+¿¿
5. I 3 has bent geometry
a) 1,3 b) 1,2,5 c) 1,3,5 d) 1,2,4

2. 1,3-butadiene has:

a) 6 σ and 2 π -bonds b) 2 σ and 2 π -bonds c) 9 σ and 2 π -bonds d) 6 σ and 2 π -bonds

3. The bond between atoms of two elements of atomic number 37 and 53 is:

a) Covalent b) Ionic c) Coordinate d) Metallic

4. In methane the bond angle is

a) 180 ° b) 90 ° c) 109 ° d) 120 °

5. One would expect the elemental form of Cs at room temperature to be:

a) A network solid b) A metallic solid c) Non-polar liquid d) An ionic liquid

6. Which of the following is false?

a) Glycerol has strong hydrogen bonding

b) Glycol is a poisonous alcohols

c) Waxes are esters of higher alcohols with higher acids

d) Alkyl halides have higher b.p. than corresponding alcohols


7. Ionic radii are:

a) ∝ 1
effective nuclear charge
b) ∝ 1
( effective nuclear charge )2
c) ∝ effective nuclear charge

d) 2
∝ ( effective nuclear charge )
8. Which of the following statements is incorrect?

a) H e does not exist because its bond order is zero


2

b) O ,O −¿¿ and O +¿¿ are all paramagnetic


2 2 2

c) Any two atomic orbitals can combine to form two molecular orbitals

d) π (2 p ) and π (2 p )are degenerate molecular orbitals


x y

9. Which of the following pairs will from the most stable ionic bond?

a) Na and Cl b) Mg and F c) Li and F d) Na and F

10. Among NaF , NaCl NaBr∧NaI , the NaF has highest melting point because:

a) It has maximum ionic character

b) It has minimum ionic character

c) It has associated molecules

d) It has least molecular weight

11. The planar structure of B F 3 can be explained by the fact that B F 3 is

a) sp hybridized b) 2 c) 3 d) 3
s p hybridised s p hybridised s p d hybridized

12. The correct order of bond order value among the following is
−¿¿ +¿¿
(i) N O (ii) N O
(iii)NO (iv) N O2+¿ ¿
(v) N O2−¿¿
a) ( i ) < ( iv ) < ( iii ) < ( ii ) <(v ) b) ( iv ) =( ii ) < ( i ) < ( v )<(iii)

c) ( v )< ( i ) < (iv )=( iii ) <(ii) d) ( ii ) < ( iii ) < ( iv )< (i ) <(v )

13. The bond between chlorine and bromine in BrC l 3 is:

a) Ionic

b) Non-polar

c) Polar with negative end on B r−¿¿

d) Polar with negative end on C l −¿ ¿

14. Which of the following has regular tetrahedral shape?

a) 2−¿ ¿ b) S F c) B F −¿¿ d) Xe F
[ ¿ ( CN )4 ] 4 [ 4] 4

15. Which of the following will have large dipole moment?

NH2
NH2
NH2 NO2

a) b) c) d)

NO2
NO2

16. PC l 5 exists but NC l 5 does not because:

a) Nitrogen has no vacant 2d -orbitals

b) NC l is unstable
5

c) Nitrogen atom is much smaller than phosphorus

d) Nitrogen is highly mert

17. In which of the following pairs the two species are not isostructural?

a) PC l +¿¿ and SiC l b) P F and Br F c) Al F 3−¿¿ and S F d) C O2−¿¿ and N O−¿¿


4 4 5 5 6 6 3 3
18. The molecule having a pyramidal shape out of the following is

a) C O b) B F c) S F d) N H
2 3 4 3

19. If N a+¿ ¿ ion is larger than M g 2+¿¿ ion and S2−¿¿ is larger thanC l −¿ ¿ ion, which of the following
will be stable soluble in water?
a) Sodium chloride b) Sodium sulphide c) Magnesium chloride d) Magnesium sulphide

20. An atom of an element A has three electrons in its outermost orbit and that of B has six
electrons in its outermost orbit. The formula of the compound between these two will be
a) A B b) A B c) A B d) A B
3 6 2 3 3 2 2

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