A Model For Pressure Drop and Liquid Saturation in Gas-Liquid Cocurrent Upflow Through Packed Beds
A Model For Pressure Drop and Liquid Saturation in Gas-Liquid Cocurrent Upflow Through Packed Beds
A Model For Pressure Drop and Liquid Saturation in Gas-Liquid Cocurrent Upflow Through Packed Beds
Abstract
A macroscopic model for pressure drop and liquid saturation in cocurrent gas–liquid upflow through packed beds was proposed. The
three model parameters: two accounting for the effect of reduction in cross sectional area available for each phase due to the presence of
the other, the third accounting for the effect of bubble formation were evaluated from the experimental data of the earlier investigation.
The validity of the model for predicting the pressure drop was tested with an independent data reported in literature.
© 2002 Published by Elsevier Science B.V.
Keywords: Gas–liquid cocurrent; Countercurrent; Two-phase flow; Pressure drop; Liquid saturation
The mechanical energy balance equation for the gas is Two-phase pressure drop for upward flow is given by
given by
PLG = PFLG + [βρL + (1 − β)ρG ] gh (15)
PLG (1 − β)SV G − ghS(1 − β)ρG V G The terms of order ρG /ρL can be neglected in comparison
with δ, the above equation reduces as follows:
= τLG ALG V iG − φG (4)
PLG
Similarly, for the liquid = δLG + β (16)
ρL gh
PLG βSV L − ghSβρL V L = −τLG ALG V iL − φL (5)
where δLG = PFLG /ρL gh. Substituting for PLG , PFG
The rate of energy dissipation, φ, is related to τ W in single and PFL of Eq. (11) from Eqs. (16), (12) and (13) respec-
phase as tively, the final equation obtained is as follows:
φ ρG
τW AW = − (6) δLG + β − γL − γG
V ρL
Assuming that there is no slip at the interface, Eqs. (4) and αG δG
0
−1 d 0
−γG + αB (6χ)2/3 (1.5δLG )1/3
(5) can be added to give (1 − β)3 dp
Table 2
Input parameters to the model
Packing Nominal size (mm) Equivalent particle diameter (m) Porosity
Packing characteristics
Ceramic spheres 6.0 0.00620 0.39
Ceramic raschig rings 6.0 0.00600 0.48
Ceramic berl saddles 6.0 0.00857 0.62
Fluid Density (kg m−3 ) Viscosity (kg m−1 s−1 ) Surface tension (N m−1 )
Column characteristics: diameter (m), 9.1 × 10−2 ; packing height (m), 1.0; liquid flow rate (kg m−2 s−1 ), 1.067–46.00; gas flow rate (kg m−2 s−1 ),
0.075–1.47.
H. Sindhu, P.S.T. Sai / Chemical Engineering Journal 4115 (2002) 1–8 5
Fig. 2. Variation in pressure drop with mass flow rate of the phases as predicted by the present model.
At low liquid rates (e.g. L = 0.1), the flow pattern cor- spray flow regions, the pressure drop is increasing rapidly
responds to bubble flow (0 < G < 0.2), pulse flow (0.2 < with an increase in gas flow rate while the liquid saturation
G < 0.6) and spray flow (G > 0.6). It is seen from the decreases. The slope of the pressure drop curve is less in
Fig. 2 that the calculated pressure drop is nearly independent spray flow region indicating greater effect of the gas flow
of the gas flow rate for values G < 0.2. There is a step rise rate on the pressure drop on the latter region.
in pressure drop of the gas flow rate for values of G > 0.2. At high liquid rates (L = 100) flow pattern indicates
Fig. 3 shows the total liquid saturation at low liquid rates the two major identified regions of flow, i.e. bubble flow
is similarly independent of the gas flow rate for G < 0.5. (0 < G < 1.6) and pulse flow (G > 1.6). Figs. 2 and 3
Thereafter, it decreases as gas flow rate increases. show that in bubble flow region, both the pressure drop
At intermediate flow rates of the liquid (L = 5), the flow and liquid saturation are independent of gas flow rate for
pattern corresponds to bubble flow (0 < G < 0.2), pulse G < 0.003. Thereafter, as G is increased, the two phase
flow (0.2 < G < 1.5) and spray flow (G > 1.5). In bubble pressure drop decrease at first slowly (0.003 < G < 0.3)
flow region both the pressure drop and liquid holdup are and then rapidly (G > 0.3). For G > 0.3, the slope of
nearly independent of the gas flow rate. In the pulse and the pressure drop curve is greater in pulse flow region
Fig. 3. Variation in liquid saturation with mass flow rate of the phases as predicted by the present model.
6 H. Sindhu, P.S.T. Sai / Chemical Engineering Journal 4115 (2002) 1–8
Fig. 4. Comparison of the two-phase experimental pressure drop data for bubble flow with data obtained using the present model.
than in bubble flow region indicating a greater effect of the to cocurrent downflow. On comparison of αB values for up-
two-phase pressure drop on the former region. These obser- flow with that of downflow, it is observed that the contri-
vations are, in general, same as that reported for downflow bution towards total pressure drop due to bubble formation
[5] excepting that the ranges are slightly different. is more for upflow compared to that of downflow [5] indi-
Figs. 4 and 5 compare the experimental two-phase pres- cating the reduction of the gas phase pressure drop due to
sure drop with the pressure drop predicted using the model geometric interaction. It is also observed that the contribu-
for bubble flow and pulse flow respectively. The experimen- tion to the total pressure drop due to bubble formation is
tal liquid saturation is compared, typically for bubble flow, significant in both bubble flow and pulse flow regions and
with that predicted using the model in Fig. 6. in spray flow region it is less compared to the other two re-
Table 3 indicates the relative magnitude of different con- gions. On the other hand, there is no significant variation in
tributions to the total frictional pressure drop in two-phase the values of αL and αG for upflow and downflow.
flow for typical values of G and L in three different regions. The validity of the present model is tested with exper-
It is clear that the contribution to the total pressure drop due imental data obtained from two independent sources viz.
to bubble formation may be small but significant in both Srinivas and Chhabra [8]and PERC [9]. While PERC [9]
bubble flow and pulse flow regions. data covers low liquid rates and high gas rates thus yielding
From the model it is predicted that the total pressure drop spray and pulse flows, the data due to Srinivas and Chhabra
and liquid saturation are high for cocurrent upflow compared [8] cover high liquid rates and low gas rates yielding bub-
ble and pulse flows. The experimental pressure drop data is
Fig. 5. Comparison of the two-phase experimental pressure drop data for Fig. 6. Comparison of the two-phase experimental liquid saturation data
pulse flow with data obtained using the present model. for bubble flow with data obtained using the present model.
H. Sindhu, P.S.T. Sai / Chemical Engineering Journal 4115 (2002) 1–8 7
5. Eq. (17) can be written as an equation containing only [3] Z. Bensetiti, F. Larachi, B.P.A. Grandjean, G. Wild, Liquid saturation
δLG as an unknown quantity by substituting the above in cocurrent upflow fixed-bed reactors: a state-of-the-art correlation,
result for β and using (␦LG ␦LG +) for δLG . The resulting Chem. Eng. Sci. 52 (1997) 4239.
[4] F. Larachi, A. Laurent, G. Wild, N. Midoux, Some experimental
equation is solved by fsolve function in MATLAB. liquid saturation results in fixed bed reactors operated under elevated
For finding initial guess, two values of δLG are guessed pressure in cocurrent upflow and downflow of the gas and the liquid,
Ind. Eng. Chem. Res. 30 (1991) 2404.
such that the function values of the equation are in opposite [5] V.G. Rao, M.S. Ananth, Y.B.G. Varma, Hydrodynamics of two-phase
sign corresponding to these values. A linear interpolation concurrent downflow through packed beds, AIChE J. 29 (1983)
for f = 0 between these two values is used as initial guess 467.
input to fsolve function. From the calculated value of δLG [6] P.S.T. Sai, Y.B.G. Varma, Pressure drop in gas–liquid downflow
using Eq. (A.4), β value is calculated. Thus, δLG and β are through packed beds, AIChE J. 33 (1987) 2027.
[7] A. Khan, Flow pattern of the phases, phase holdup and pressure drop
estimated simultaneously. in concurrent gas–liquid upflow through packed beds, Ph.D Thesis,
Indian Institute of Technology Madras, India, 1998.
[8] K.V. Srinivas, R.P. Chhabra, Pressure drop in two-phase cocurr-
References ent upward flow in packed beds, Can. J. Chem. Eng. 72 (1994)
1085.
[1] A. Khan, A.A. Khan, Y.B.G. Varma, Flow regime identification and [9] Pittsburgh Energy Research Centre (PERC) quarterly report
pressure drop in cocurrent gas–liquid upflow through packed beds, 1975–1976 (as cited in Y.T. Shah, Dynamics of the cocurrent
Bioprocess Eng. 16 (1997) 355. upflow fixed-bed column, in: Gas–Liquid–Solid Reactor Design,
[2] A. Khan, A.A. Khan, Y.B.G. Varma, An analysis of the phase McGraw-Hill, New York, USA, 1979, p. 230.)
holdup in concurrent gas liquid upflow through packed beds using (I) [10] Ergun, Fluid Flow Through Packed Columns, Chem. Eng., Prog. 48
drift-flux model, and (II) slip ratio, Bioprocess Eng. 22 (2000) 165. (1952) 89.