Safety data sheet

According to 1907/2006/EC (REACH), 453/2010/EC

RUST CONVERTER - Rust converter

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SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: RUST CONVERTER - Rust converter
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1.2 Relevant identified uses of the substance or mixture and uses advised against:
Relevant uses: Painting, protection of iron surfaces
Uses advised against: All uses not specified in this section or in section 7.3
1.3 Details of the supplier of the safety data sheet: EVOCHEM S.A.
Tzaverdella Place
133 41 PHILI , ATTICA - GREECE
Phone.: 0030 210 5590460 , 0030 210 5590155 -
Fax: 0030 210 6254737 , 0030 210 5590244
info@evochem.gr; vmergoupis@evochem.gr;
sales@evochem.gr
www.evochem.gr
1.4 Emergency telephone number: National Poisoning Center 2107793777

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:
CLP Regulation (EC) nº 1272/2008:
The product is not classified as dangerous according to CLP Regulation (EC) nº 1272/2008.
2.2 Label elements:
CLP Regulation (EC) nº 1272/2008:
See sections 11 and 12.
2.3 Other hazards:
Non-applicable

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substance:
Non-applicable
3.2 Mixture:
Chemical description: Aqueous mixture composed of additives, aggregates, coalescents, pigments and resins
Components:
In accordance with Annex II of Regulation (EC) nº1907/2006 (point 3), the product contains:
Identification Chemical name/Classification Concentration
CAS: 1401-55-4 Tannins Self-classified
EC: 215-753-2 2,4 - <4,9 %
Index: Non-applicable Regulation 1272/2008 Eye Irrit. 2: H319 - Warning
REACH: Non-applicable
CAS: 34590-94-8 Dipropylene Glycol Methyl Ether Not classified
EC: 252-104-2 2,4 - <4,9 %
Index: Non-applicable Regulation 1272/2008
REACH: 01-2119450011-60-XXXX
To obtain more information on the risk of the substances consult sections 8, 11, 12 and 16.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:
The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for
direct exposure to the chemical product or persistent discomfort, showing the SDS of this product.
By inhalation:
This product does not contain substances classified as dangerous for inhalation, however, in case of symptoms of intoxication
remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse
or persist.
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SECTION 4: FIRST AID MEASURES (continue)

By skin contact:
In case of contact it is recommended to clean the affected area thoroughly with water and neutral soap. In case of modifications
on the skin (stinging, redness, rashes, blisters,…), seek medical advice with this Security Data Sheet
By eye contact:
This product does not contain substances classified as dangerous for eye contact. Rinse eyes thoroughly for at least 15 minutes
with lukewarm water, ensuring that the person affected does not rub or close their eyes.
By ingestion/aspiration:
In case of consumption, seek immediate medical assistance showing the SDS of this product.
4.2 Most important symptoms and effects, both acute and delayed:
Acute and delayed effects are indicated in sections 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed:
Non-applicable

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media:
Product is non-flammable under normal conditions of storage, manipulation and use. In the case of inflammation as a result of
improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the
Regulation on fire protection systems. IT IS NOT RECOMMENDED to use tap water as an extinguishing agent.
5.2 Special hazards arising from the substance or mixture:
As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and,
consequently, can present a serious health risk.
5.3 Advice for firefighters:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment.
Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance with
Directive 89/654/EC.
Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other
emergencies. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible
to inflammation, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire
into an aqueous medium.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:
Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be
used against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have
protection.
6.2 Environmental precautions:
This product is not classified as dangerous to the environment. Keep product away from drains, surface and underground water.
6.3 Methods and material for containment and cleaning up:
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible
absorbents. For any concern related to disposal consult section 13.
6.4 Reference to other sections:
See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:
A.- Precautions for safe manipulation

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SECTION 7: HANDLING AND STORAGE (continue)

Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control
spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and
cleanliness where dangerous products are used.
B.- Technical recommendations for the prevention of fires and explosions
Product is non-flammable under normal conditions of storage, manipulation and use. It is recommended to transfer at slow
speeds to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information
on conditions and materials that should be avoided.
C.- Technical recommendations to prevent ergonomic and toxicological risks
Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D.- Technical recommendations to prevent environmental risks
It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3)
7.2 Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage
Minimum Temp.: 5 ºC
Maximun Temp.: 35 ºC
Maximum time: 12 Months
B.- General conditions for storage
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this
product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:
Substances whose occupational exposure limits have to be monitored in the work environment
Identification Environmental limits
Dipropylene Glycol Methyl Ether IOELV (8h) 50 ppm 308 mg/m³
CAS: 34590-94-8 IOELV (STEL)
EC: 252-104-2 Year 2014

DNEL (Workers):
Short exposure Long exposure

Identification Systemic Local Systemic Local

Dipropylene Glycol Methyl Ether Oral Non-applicable Non-applicable Non-applicable Non-applicable
CAS: 34590-94-8 Dermal Non-applicable Non-applicable 65 mg/kg Non-applicable
EC: 252-104-2 Inhalation Non-applicable Non-applicable 310 mg/m³ Non-applicable

DNEL (General population):

Short exposure Long exposure

Identification Systemic Local Systemic Local

Dipropylene Glycol Methyl Ether Oral Non-applicable Non-applicable 1,67 mg/kg Non-applicable
CAS: 34590-94-8 Dermal Non-applicable Non-applicable 15 mg/kg Non-applicable
EC: 252-104-2 Inhalation Non-applicable Non-applicable 37,2 mg/m³ Non-applicable

PNEC:
Identification
Dipropylene Glycol Methyl Ether STP 4168 mg/L Fresh water 19 mg/L
CAS: 34590-94-8 Soil 2,74 mg/kg Marine water 1,9 mg/L
EC: 252-104-2 Intermittent 190 mg/L Sediment (Fresh water) 70,2 mg/kg
Oral Non-applicable Sediment (Marine water) 7,02 mg/kg
8.2 Exposure controls:
A.- General security and hygiene measures in the work place

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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)

As a preventative measure it is recommended to use basic Personal Protection Equipment, with the corresponding <<CE
marking>> in accordance with Directive 89/686/EC. For more information on Personal Protection Equipment (storage, use,
cleaning, maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more
information see subsection 7.1.
All information contained herein is a recommendation which needs some specification from the labour risk prevention services
as it is not known whether the company has additional measures at its disposal.
B.- Respiratory protection
The use of protection equipment will be necessary if a mist forms or if the professional exposure limits are exceeded.
C.- Specific protection for the hands
Pictogram PPE Labelling CEN Standard Remarks

EN 374-1:2003
Chemical protective gloves EN 374-3:2003/AC:2006 Replace the gloves at any sign of deterioration.
EN 420:2003+A1:2009
Mandatory hand
protection
D.- Ocular and facial protection
Pictogram PPE Labelling CEN Standard Remarks

EN 166:2001
Clean daily and disinfect periodically according to
Panoramic glasses against EN 172:1994/A1:2000
the manufacturer´s instructions. Use if there is a
liquid splash EN 172:1994/A2:2001
risk of splashing.
Mandatory face EN ISO 4007:2012
protection
E.- Bodily protection
Pictogram PPE Labelling CEN Standard Remarks

Work clothing EN ISO 13688:2013 For professional use only.

EN ISO 20347:2012
Anti-slip work shoes None
EN ISO 20344:2011

F.- Additional emergency measures

Emergency measure Standards Emergency measure Standards

ANSI Z358-1 DIN 12 899

ISO 3864-1:2002 ISO 3864-1:2002
Emergency shower Eyewash stations

Environmental exposure controls:

In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental
spillage of both the product and its container. For additional information see subsection 7.1.D
Volatile organic compounds:
With regard to Directive 2010/75/EU, this product has the following characteristics:
V.O.C. (Supply): 2,45 % weight
V.O.C. density at 20 ºC: 25,61 kg/m³ (25,61 g/L)
Average carbon number: 7
Average molecular weight: 148,2 g/mol

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:
For complete information see the product datasheet.
*Not relevant due to the nature of the product, not providing information property of its hazards.

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According to 1907/2006/EC (REACH), 453/2010/EC

RUST CONVERTER - Rust converter

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continue)

Appearance:
Physical state at 20 ºC: Liquid
Appearance: Opaque
Color: Beige
Odor: Characteristic
Volatility:
Boiling point at atmospheric pressure: 102 ºC
Vapour pressure at 20 ºC: 2340 Pa
Vapour pressure at 50 ºC: 12330 Pa (12 kPa)
Evaporation rate at 20 ºC: Non-applicable *
Product description:
Density at 20 ºC: 1045 kg/m³
Relative density at 20 ºC: 1,045
Dynamic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 40 ºC: Non-applicable *
Concentration: 1050 g/L (active ingredient)
pH: 1,6 - 2,6
Vapour density at 20 ºC: Non-applicable *
Partition coefficient n-octanol/water 20 ºC: Non-applicable *
Solubility in water at 20 ºC: Non-applicable *
Solubility properties: Non-applicable *
Decomposition temperature: Non-applicable *
Melting point/freezing point: Non-applicable *
Flammability:
Flash Point: Non Flammable (>60 ºC)
Autoignition temperature: 270 ºC
Lower flammability limit: Non-applicable *
Upper flammability limit: Non-applicable *
9.2 Other information:
Surface tension at 20 ºC: Non-applicable *
Refraction index: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity:
No hazardous reactions are expected if the following technical instructions storage of chemicals. See section 7.
10.2 Chemical stability:
Chemically stable under the conditions of storage, handling and use.
10.3 Possibility of hazardous reactions:
Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
10.4 Conditions to avoid:
Applicable for handling and storage at room temperature:
Shock and friction Contact with air Increase in temperature Sunlight Humidity
Not applicable Not applicable Not applicable Not applicable Not applicable

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SECTION 10: STABILITY AND REACTIVITY (continue)

10.5 Incompatible materials:
Acids Water Combustive materials Combustible materials Others
Not applicable Not applicable Not applicable Not applicable Not applicable

10.6 Hazardous decomposition products:

See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions,
complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic
compounds.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects:
The experimental information related to the toxicological properties of the product itself is not available
Contains glycols. With possibility of effects that are hazardous to the health, it is recommended not to breathe the vapours for
long periods of time.
Dangerous health implications:
In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure
limits, it may result in adverse effects on health depending on the means of exposure:
A.- Ingestion:
- Acute toxicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous for consumption. For more information see section 3.
- Corrosivity/Irritability: Based on available data, the classification criteria are not met, as it does not contain substances
classified as dangerous for this effect. For more information see section 3.
B- Inhalation:
- Acute toxicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous for inhalation. For more information see section 3.
- Corrosivity/Irritability: Based on available data, the classification criteria are not met, as it does not contain substances
classified as dangerous for this effect. For more information see section 3.
C- Contact with the skin and the eyes:
- Contact with the skin: Based on available data, the classification criteria are not met, as it does not contain substances
classified as dangerous for skin contact. For more information see section 3.
- Contact with the eyes: Based on available data, the classification criteria are not met, however, it contains substances
classified as dangerous for skin contact. For more information see section 3.
D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):
- Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified
as dangerous for the effects mentioned. For more information see section 3.
- Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous for this effect. For more information see section 3.
- Reproductive toxicity: Based on available data, the classification criteria are not met, as it does not contain substances
classified as dangerous for this effect. For more information see section 3.
E- Sensitizing effects:
- Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous with sensibilizising effects. For more information see section 3.
- Cutaneous: Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous for this effect. For more information see section 3.
F- Specific target organ toxicity (STOT)-time exposure:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for
this effect. For more information see section 3.
G- Specific target organ toxicity (STOT)-repeated exposure:
- Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met, as
it does not contain substances classified as dangerous for this effect. For more information see section 3.
- Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous for this effect. For more information see section 3.
H- Aspiration hazard:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for
this effect. For more information see section 3.
Other information:

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SECTION 11: TOXICOLOGICAL INFORMATION (continue)

Non-applicable
Specific toxicology information on the substances:
Identification Acute toxicity Genus
Tannins LD50 oral 3000 mg/kg Rat
CAS: 1401-55-4 LD50 dermal Non-applicable
EC: 215-753-2 LC50 inhalation Non-applicable

SECTION 12: ECOLOGICAL INFORMATION

The experimental information related to the eco-toxicological properties of the product itself is not available
12.1 Toxicity:
Identification Acute toxicity Specie Genus
Dipropylene Glycol Methyl Ether LC50 10000 mg/L (96 h) Pimephales promelas Fish
CAS: 34590-94-8 EC50 1919 mg/L (48 h) Daphnia magna Crustacean
EC: 252-104-2 EC50 Non-applicable
12.2 Persistence and degradability:
Identification Degradability Biodegradability
Dipropylene Glycol Methyl Ether BOD5 Non-applicable Concentration Non-applicable
CAS: 34590-94-8 COD 0.00202 g O2/g Period 28 days
EC: 252-104-2 BOD5/COD Non-applicable % Biodegradable 73 %
12.3 Bioaccumulative potential:
Identification Bioaccumulation potential
Dipropylene Glycol Methyl Ether BCF 1
CAS: 34590-94-8 Pow Log -0,06
EC: 252-104-2 Potential Low
12.4 Mobility in soil:
Not available
12.5 Results of PBT and vPvB assessment:
Non-applicable
12.6 Other adverse effects:
Not described

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:
Waste class (Regulation (EU) No
Code Description
1357/2014)
08 01 12 Waste paint and varnish other than those mentioned in 08 01 11 Non dangerous

Type of waste (Regulation (EU) No 1357/2014):

Non-applicable
Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex
2 (Directive 2008/98/EC). As under 15 01 (2014/955/EC) of the code and in case the container has been in direct contact with
the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue.
We do not recommended disposal down the drain. See paragraph 6.2.
Regulations related to waste management:
In accordance with Annex II of Regulation (EC) nº1907/2006 (REACH) the community or state provisions related to waste
management are stated
Community legislation: Directive 2008/98/EC, 2014/955/EU, Regulation (EU) No 1357/2014

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SECTION 14: TRANSPORT INFORMATION

This product is not regulated for transport (ADR/RID,IMDG,IATA)

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Candidate substances for authorisation under the Regulation (EC) 1907/2006 (REACH): Non-applicable
Substances included in Annex XIV of REACH ("Authorisation List") and sunset date: Non-applicable
Regulation (EC) 1005/2009, about substances that deplete the ozone layer: Non-applicable
Active substances for which a decision of non-inclusion onto Annex I (Regulation (EU) No 528/2012): Non-applicable
REGULATION (EU) No 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII, REACH):
Non-applicable
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local
circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this
product.
Other legislation:
The product could be affected by sectorial legislation
15.2 Chemical safety assessment:
The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:
This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of
Regulation (EC) Nº 1907/2006 (Regulation (EC) Nº 453/2010)
Modifications related to the previous security card which concerns the ways of managing risks. :
COMPOSITION/INFORMATION ON INGREDIENTS:
· Removed Content
Phosphoric Acid (7664-38-2)
Directive 67/548/EC and Directive 1999/45/EC:
· Pictograms
· R Phrases
· S Phrases
CLP Regulation (EC) nº 1272/2008:
· Pictograms
· Hazard statements
· Precautionary statements
TRANSPORT INFORMATION:
· UN number
· Packing group
Texts of the legislative phrases mentioned in section 3.:
The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the
individual components which appear in section 3
CLP Regulation (EC) nº 1272/2008:
Eye Irrit. 2: H319 - Causes serious eye irritation
Classification procedure:
Non-applicable
Advice related to training:
Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension
and interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://esis.jrc.ec.europa.eu
http://echa.europa.eu
http://eur-lex.europa.eu

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SECTION 16: OTHER INFORMATION (continue)

Abbreviations and acronyms:
- ADR: European agreement concerning the international carriage of dangerous goods by road
-IMDG: International maritime dangerous goods code
-IATA: International Air Transport Association
-ICAO: International Civil Aviation Organisation
-COD: Chemical Oxygen Demand
-BOD5: 5-day biochemical oxygen demand
-BCF: Bioconcentration factor
-LD50: Lethal Dose 50
-CL50: Lethal Concentration 50
-EC50: Effective concentration 50
-Log-POW: Octanol–water partition coefficient
-Koc: Partition coefficient of organic carbon

The information contained in this security data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy.
This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users
of this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the
manipulation, storage, use and disposal of chemical products. The information on this security data sheet only refers to this product, which should not be used for needs other than those
specified.

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