Safety data sheet

According to 1907/2006/EC (REACH), 453/2010/EC

SEQUESTRANTE 549

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: SEQUESTRANTE 549
Diethylenetriamine penta(methylene phosphonic acid)
CAS: 15827-60-8
EC: 239-931-4
Index:
REACH:
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Relevant uses:
Auxiliary product for textile industry. For professional use only.

Uses advised against:

All uses not specified in this sheet or in section 7.3.
1.3 Details of the supplier of the safety data sheet: TECHNA ITALIA SRL
VIA MARCONI, 18
13900 BIELLA (BI) - ITALY
Tel. +39 015.8492913 - Fax. +39 015.8493206
A. Venier
info@officina39.com
1.4 Emergency telephone number: +39.015.8492913

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:
This product was classified in accordance with Directive 67/548/EC and Directive 1999/45/EC, adapting the requirements to
Regulation (EC) No.1907/2006 (REACH regulation).
This product was classified in accordance with Regulation (EC) No.1272/2008 (CLP regulation).
2.1.1 CLP Regulation (EC) No.1272/2008:
Classification and hazard indications:
Eye Irrit. 2: Eye irritation, category 2
Skin Irrit. 2: Skin irritation, category 2
2.1.2 Directive 67/548/EC and Directive 1999/45/EC:
Danger symbols:
Xi: Irritant
R Phrases:
R36: Irritating to eyes.
R38: Irritating to skin.
2.2 Label elements

Directive 67/548/EC and Directive 1999/45/EC:

CLP Regulation (EC) No.1272/2008:
Warning:
Wng: Warning
Pictograms:

Hazard indications:
H319: Causes serious eye irritation.
H315: Causes skin irritation.
Cautionary advice:

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

SEQUESTRANTE 549

SECTION 2: HAZARDS IDENTIFICATION (continue)

P264: Wash hands and face thoroughly after handling.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P321: Specific treatment (see on this label).
P332+P313: If skin irritation occurs: Get medical advice / attention.
P362: Take off contaminated clothing and wash before reuse.
2.3 Other hazards
Non-applicable.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Chemical description
Sequestrant.
3.2 Substances:

Directive 67/548/EC and Directive 1999/45/EC:

CLP Regulation (EC) No.1272/2008:

3.3 Mixtures:

Aminophosphonates derivatives 10 - <40 %

CAS:
EC:
Index:
REACH:
Directive 67/548/EC and Directive 1999/45/EC:
CLP Regulation (EC) No.1272/2008:
Eye Irrit. 2 Skin Irrit. 2
H319 H315

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:
The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct
exposure to the chemical product or persistent discomfort, showing the MSDS of this product.
By inhalation:
This product does not contain substances classified as dangerous for inhalation, however, in case of symptoms of intoxication remove
the person affected from the exposure area and provide with fresh air.
Seek medical attention if the symptoms get worse or persist.
By skin contact:
Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water and
neutral soap.
In serious cases see a doctor. If the mixture causes burns or freezing, clothing should not be removed as this could worsen the injury
caused if it is stuck to the skin.
If blisters form on the skin, these should never be burst as this will increase the risk of infection.
By eye contact:
Rinse eyes thoroughly with luke warm water for at least 15 minutes.
Do not allow the person affected to rub or close their eyes.
If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further
damage.

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

SEQUESTRANTE 549

SECTION 4: FIRST AID MEASURES (continue)

In all cases, after cleaning, a doctor should be consulted as quickly as possible with the MSDS of the product.
By consumption:
Do not induce vomiting, but if it does happen keep the head up to avoid inhalation.
Keep the person affected at rest.
Rinse out the mouth and throat, as they may have been affected during ingestion.
4.2 Most important symptoms and effects, both acute and delayed:
Acute and delayed effects are indicated in sections 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed:
Non-applicable.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media:
Product is non-flammable under normal conditions of storage, manipulation and use. In the case of inflammation as a result of
improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the
Regulation on fire protection systems.
IT IS NOT RECOMMENDED to use tap water as an extinguishing agent.
5.2 Special hazards arising from the substance or mixture:
As a result of combustion or thermal decomposition reactive subproducts are created that can become highly toxic and,
consequently, can present a serious health risk.
5.3 Advice for firefighters:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment.
Appropriate fire equipment (fire extinguishers, fire hoses, sprinklers, etc. depending on the fire load) or minimum emergency facilities
should be available (fire blankets, portable first aid kit, etc...) in accordance with Directive 89/654/EC.
Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other
emergencies. Destroy any source of ignition.
In case of fire, refrigerate the storage containers and tanks for products susceptible to inflammation, explosion or BLEVE as a result
of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:
Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be used
against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have protection.
6.2 Environmental precautions:
This product is not classified as dangerous to the environment. Keep product away from drains, surface and underground water.
6.3 Methods and material for containment cleaning up:
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible
absorbents. For any concern related to disposal consult section 13.
6.4 Reference to other sections:
See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:
A.- Precautions for safe manipulation
Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed.
Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

SEQUESTRANTE 549

SECTION 7: HANDLING AND STORAGE (continue)

cleanliness where dangerous products are used.

B.- Technical recommendations for the prevention of fires and explosions

Product is non-flammable under normal conditions of storage, manipulation and use. It is recommended to transfer at slow speeds to
avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on conditions and
materials that should be avoided.

C.- Technical recommendations for professional hygiene

Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.

D.- Technical recommendations to prevent environmental risks

It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3).
7.2 Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage
Minimum temperature: 5 °C
Maximun temperature: 30 °C
Maximum time: 24 months

B.- General conditions for storage

Avoid sources of heat, radiation, static electricity and contact with food.
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this
product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:
Substances whose occupational exposure limits have to be monitored in the work environment.
There are no environmental limits for the substances contained in the product.

DNEL (Workers):
Non-applicable

DNEL (Population):
Non-applicable

PNEC:
Non-applicable
8.2 Exposure controls:
As a preventative measure it is recommended to use basic Personal Protection Equipment, with the corresponding "CE marking". For
more information on Personal Protection Equipment (storage, use, cleaning, maintenance, class of protection, etc...) consult the
information leaflet provided by the manufacturer.
Information contained in this point refer to pure product.
Protection measures for diluted product may vary according to its dilution degree, use, method of application, etc...
To determine the requirement of emergency showers installation and / or collyrium in warehouses will take into consideration the
rules of chemicals storage applied to each case
For more infomation see subsection 7.1 and 7.2.

* Additional emergency measures:

Emergency shower. (Standard: ANSI Z358-1 / ISO 3864-1:2002)

Eyewash stations. (Standard: DIN 12 899 / ISO 3864-1:2002)

Specific protection for the hands

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

SEQUESTRANTE 549

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)

Specific protection for the hands
Mandatory hand protection.
Chemical protective gloves, CE CAT I.
Replace the gloves at any sign of deterioration.

CEN Standard:
EN 374-1:2003
EN 374-3:2003/AC:2006
EN 420:2003+A1:2009

Ocular and facial protection

Mandatory face protection.
Wear full-vision safety goggles or a chemical protective face shield, CE CAT II.
Clean daily and disinfect periodically according to the manufacturer´s instructions.

CEN Standard:
EN 166:2001
EN 172:1994/A1:2000
EN 172:1994/A2:2001
EN 165:2005

Bodily protection
Work clothing, CE CAT I.
For professional use only.

CEN Standard:
EN 340:2003

Anti-slip work shoes, CE CAT II.

CEN Standard:
EN ISO 20347:2004/A1:2007
EN ISO 20344:2011

Respiratory protection
The use of protection equipment will be necessary if a mist forms or if the professional exposure limits are exceeded.
Environmental exposure controls:
In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental
spillage of both the product and its container.
For additional information see subsection 7.1.D.
Volatil organic compounds:
With regard to Directive 1999/13/EC, this product has the following characteristics:

V.O.C. (Supply): 0 % weight

V.O.C. density at 20°C: 0 kg/m³ (0 g/l)

Average carbon number: Non-applicable

Average molecular weight: Non-applicable

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:

Physical state at 20°C Liquid
Appearance Characteristic

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

SEQUESTRANTE 549

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continue)

Colour Characteristic
Odour Characteristic
Boiling point at atmospheric pressure 100 °C
Vapour pressure at 20°C 2350 Pa
Vapour pressure at 50°C 12381 (12kPa) Pa
Evaporation rate at 20°C Non-applicable
Density at 20°C 1050 kg/m³
Relative density at 20°C Non-applicable
Dynamic viscosity at 20°C Non-applicable cP
Kinematic viscosity at 20°C Non-applicable cSt
Kinematic viscosity at 40°C Non-applicable cSt
Concentration Non-applicable
pH 4,5 - 6,5
Vapour density at 20°C Non-applicable
Partition coefficient n-octanol/water 20°C Non-applicable
Solubility in water at 20°C Non-applicable
Solubility property Non-applicable
Decomposition temperature Non-applicable °C
Flash point Non flammable (>60°C) °C
Autoignition temperature Non-applicable °C
Lower flammability limit Non-applicable
Upper flammability limit Non-applicable
9.2 Other information:
Surface tension at 20°C Non-applicable
Refraction index Non applicable

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity:
No hazardous reactions are expected if the following technical instructions storage of chemicals. See section 7.
10.2 Chemical stability:
Chemically stable under the conditions of storage, handling and use.
10.3 Possibility of hazardous reactions:
No hazardous reactions are expected for variation in temperature and/or pressure.
10.4 Conditions to avoid:
Applicable for handling and storage at room temperature:

Shock and friction: Not applicable

Contact with air: Not applicable

Increase in temperature: Not applicable

Sunlight: Not applicable

Humidity: Not applicable

10.5 Incompatible materials:
Acids: Not applicable

Water: Not applicable

Combustive materials: Not applicable

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

SEQUESTRANTE 549

SECTION 10: STABILITY AND REACTIVITY (continue)

Combustible materials: Not applicable

Others: Not applicable

10.6 Hazardous decomposition products:
See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products.
Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon
monoxide and other organic compounds.

SECTION 11: TOXICOLOGICAL INFORMATION

No experimental information is available on the product itself in relation to the toxicological properties.
When performing the danger classification on corrosive or irritant effects the recommendations included in section 3.2.5 of Annex VI
of Directive 67/548/EC, in paragraphs b) and c) of section 3 of article 6 of Directive 1999/45/EC and in section 3.2.3.3.5. of Annex I
of Regulation (EC) No. 1272/2008 were taken into account.

Contains glycols, with possibility of effects that are hazardous to the health, it is recommended not to breathe the vapours for long
periods of time.
11.1 Information on toxicological effects:
* Dangerous health implications:
In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits,
it may result in adverse effects on health depending on the means of exposure:

A.- Ingestion:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for ingestion.
For more information see section 3.

B- Inhalation:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for
inhalation. For more information see section 3.

C- Contact with the skin and the eyes:

Produces skin inflammation.

D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):

Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for the
effects mentioned. For more information see section 3.

E- Sensitizing effects:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous with
sensibilizing effects. For more information see section 3.

F- Specific target organ toxicity (STOT) - time exposure:

Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.

G- Specific target organ toxicity (STOT) - repeated exposure:

Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.

H- Aspiration hazard:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this
effect. For more information see section 3.

* Other information:
Non-applicable

* Specific toxicology information on the substances:

Not available

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

SEQUESTRANTE 549

SECTION 11: TOXICOLOGICAL INFORMATION (continue)

SECTION 12: ECOLOGICAL INFORMATION

The experimental information related to the ecotoxicological properties of the mixture itself is not available.
12.1 Toxicity:
Not available.

12.2 Persistence and degradability:

Not available.

12.3 Bioaccumulative potential:

Not available.

12.4 Mobility in soil

Not available.

12.5 Results of PBT and vPvB assessment:

Non-applicable.

12.6 Other adverse effects:

Not described.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:
Code:
04 02 14*

Description:
Wastes from finishing containing organic solvents.

Waste class (Directive 2008/98/EC):

Dangerous.

* Waste management (disposal and evaluation):

Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex 2
(Directive 2008/98/EC). As under 15 01 (2000/532/EC) of the code and in case the container has been in direct contact with the
product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue. We do
not recommended disposal down the drain. See paragraph 6.2.

* Regulations related to waste management:

In accordance with Annex II of Regulation (EC) no. 1907/2006 (REACH) the community or state provisions related to waste
management are stated.

- Community legislation:
Directive 2008/98/EC, 2000/532/EC: Commission Decision of 3 May 2000.

SECTION 14: TRANSPORT INFORMATION

This product is not dangerous for transport (ADR/RID, IMDG, IATA).

SECTION 15: REGULATORY INFORMATION

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

SEQUESTRANTE 549

SECTION 15: REGULATORY INFORMATION (continue)

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Candidate substances for authorisation under the Regulation (EC) No. 1907/2006 (REACH): Non-applicable

Regulation (EC) No. 1005/2009, about substances that deplete the ozone layer: Non-applicable

Active substances for which a decision of non-inclusion onto Annex I (Regulation (EU) No. 528/2012): Non-applicable

Regulation (EC) No. 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII, REACH):
Non-applicable.
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local
circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this
product.
Other legislation:
Regulation (EC) No. 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and
packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation
(EC) No. 1907/2006.
Chemical safety assessment:
The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:
This safety data sheet has been designed in accordance with annex II-Guide to the compilation of safety data sheets of Regulation
(EC) No. 1907/2006 (Regulation (EC) No. 453/2010).
Modifications related to the previous security card which concerns the ways of managing risks:

Text of R-phrases considered in section 3:

CLP Regulation (EC) No.1272/2008:
Eye Irrit. 2: Eye irritation, category 2
Skin Irrit. 2: Skin irritation, category 2

H315: Causes skin irritation.

H319: Causes serious eye irritation.
Advice related to training:
Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and
interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://esis.jrc.ec.europa.eu
http://echa.europa.eu
http://eur-lex.europa.eu

Note for users:

The information contained in the present sheet are based on our own knowledge on the date of the last version.
Users must verify the suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the
current health and safety laws and regulations.
The producer is relieved from any liability arising from improper uses.

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 Safety data sheet
According to 1907/2006/EC (REACH), 453/2010/EC

SEQUESTRANTE 549

SECTION 16: OTHER INFORMATION (continue)

Abbreviations and acronyms:

- ADR: European agreement concerning the international carriage of dangerous goods by road
- IMDG: International maritime dangerous goods code
- IATA: International Air Transport Association
- ICAO: International Civil Aviation Organisation
- COD: Chemical Oxygen Demand
- BOD5: 5-day biochemical oxygen demand
- BCF: Bioconcentration factor
- LD50: Lethal Dose 50
- CL50: Lethal Concentration 50
- EC50: Effective concentration 50
- Log-POW: Octanol–water partition coefficient
- Koc: Partition coefficient of organic carbon

The information contained in this security data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its
accuracy. This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and
conditions for users of this product are not within our awareness or control, and is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements
concerning the manipulation, storage, use and disposal of chemical products. The information on this security data sheet only refers to this product, which should not be used for needs
other than those specified.
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