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Caulk PSC A GHS

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DATE PRINTED 3/15/2022

SDS REF. No : #CLKPSC

SAFETY DATA SHEET


CAULK PSC COMPONENT A
1. PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: CAULK PSC COMPONENT A

PRODUCT CODE: #CLKPSC


PRODUCT USE: Curative for hybrid polysulfide/epoxy system.
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBER
DUDICK, a DIVISION OF CARBOLINE GLOBAL CHEM-TEL (US Transportation): (800)255-3924
INC. CHEM-TEL (International : +01-813-248-
1818 MILLER PARKWAY 0585
Transportation)
STREETSBORO, OH, 44241
330-562-1970

2. HAZARDS IDENTIFICATION

CLASSIFICATION:
Acute Toxicity - Oral - Category 4

GHS LABEL ELEMENTS:

SIGNAL WORD: Warning

HAZARD STATEMENTS:
H302 Harmful if swallowed.

PRECAUTIONARY STATEMENTS :
P264 Wash all contacted body parts thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P330 Rinse mouth.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

Chemical Name Weight % CAS Number


2,4,6-Tris(dimethylaminomethyl)phenol 0-5% 90-72-2

Bis[(dimethylamino)methyl]phenol 0-5% 71074-89-0


4. FIRST AID MEASURES

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EYES: Hold open eyelids and flush with copious amounts of water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If irritation persists, get medical
advice/attention.
SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical
advice/attention. Take off contaminated clothing and wash before reuse.
INGESTION: Rinse mouth out with water.
Do not induce vomiting. Do not give liquids.
Consult physician.
INHALATION: If inhaled, remove to fresh air and keep at rest in a position comfortable for
breathing. Obtain medical attention if breathing difficulty persists.
NOTES TO PHYSICIAN: NOTE TO PHYSICIANS: Application of corticosteroid cream has been
effective in treating skin irritation.

5. FIRE FIGHTING MEASURES

SUITABLE EXTINGUISHING MEDIA: Alcohol resistant foam; Carbon Dioxide (CO2); dry
chemical; dry sand; limestone powder; use water to keep containers cool.
UNSUITABLE EXTINGUISHING MEDIA: Do not use high pressure water jet as this may spread
the area of the fire.
SPECIFIC HAZARDS IN CASE OF FIRE: Burning may produce noxious and toxic fumes. Incomplete
combustion may generate ammonia gas, toxic nitrogen oxide gasses. carbon monoxide, sulfur oxide, hydrogen
sulfide, acetaldehyde, and low molecular weight hydrocarbons. Downwind personnel should be evacuated.
Closed containers may rupture (due to build up in pressure) when exposed to extreme heat.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTION FOR FIRE FIGHTERS: Face Shield should be
worn.
Wear self-contained breathing apparatus (SCBA) in positive pressure mode and full protective
clothing.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Isolate area. Keep unnecessary and unprotected personnel from
entering the area. Use appropriate safety equipment.
ENVIRONMENTAL PRECAUTIONS: Halt the flow of material as soon as practical using
appropriate barriers; Prevent contamination of soil and water. Prevent from spreading or
entering into drains, ditches, waterways by using sand, earth or appropriate barriers.
METHOD AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Contain spilled material if
possible. Absorb with materials such as: Sand. Polypropylene fiber products. Polyethylene fiber
products. Remove residual with soap and hot water. Collect in suitable and properly labeled
containers. Residual can be removed with solvent. Solvents are not recommended for clean-up
unless the recommended exposure guidelines and safe handling practices for the specific solvent
are followed. Consult appropriate solvent Safety Data Sheet for handling information and
exposure guidelines.

7. HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING: Use only in well-ventilated areas. Avoid contact with
skin and eyes. Avoid breathing vapors and/or aerosols. Emergency showers and eye wash
stations should be readily accessible. Use personal protective equipment. When using, do not eat,
drink or smoke.
CONDITIONS FOR SAFE STORAGE, INCLUDING INCOMPATIBILITIES: Do not store near
incompatibles (strong oxidizers, acids, alkalis). Keep container tightly closed when not in use to
prevent contamination from environmental moisture..

8. EXPOSURE CONTROLS\PERSONAL PROTECTION

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SDS REF. No : #CLKPSC

EXPOSURE LIMITS

ENGINEERING CONTROLS: Ventilation:


Use local exhaust ventilation, or other engineering controls to maintain airborne levels
requirements or guidelines, general ventilation should be sufficient for most operations.
PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY PROTECTION: If ventilation is inadequate or if irritation or other symptoms are
experienced, wear a NIOSH/MHSA approved respirator with organic vapor cartridge.
EYES PROTECTION: Protective goggles.
SKIN PROTECTION: Selection of specific items such as face shield, boots, apron, or full body
suit will depend on the task.
Hand protection: Use chemical resistant gloves. Consult glove manufacturer for
recommendations.
WORK HYGIENIC PRACTICES: Use good personal hygiene. Do not consume or store food in the
work area. Wash hands before smoking or eating. Wash contaminated clothing before reuse.
OTHER USE PRECAUTIONS: The type and degree of personal protective equipment will depend
on the specific work operation. Eye wash stations and emergency showers should be available.
Inspect and replace personal protective equipment at regular intervals; use professional care in
their selection, use and care.
COMMENTS: None.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: Viscous liquid


COLOR: Varies
FLASH POINT AND METHOD: No data available for this product. No data available for this
product.
AUTO-IGNITION TEMPERATURE: Not Determined.
BOILING POINT/RANGE: No data available for this product.
MELTING POINT: Not Determined.
VAPOUR PRESSURE: Not determined.
VAPOUR DENSITY: Heavier than air.
SOLUBILITY: Not determined.
ODOR/THRESHOLD: Characteristic mercaptan (sulfurous).
LOWER / UPPER FLAMMABLE LIMITS: No data available for this product. TO No data
available for this product.
DENSITY: 1.5413
EVAPORATION RATE: Slower than ether.
PARTITION COEFFICIENT: Not determined.
pH: Not Applicable.
DECOMPOSITION TEMPERATURE: Not determined.

10. STABILITY AND REACTIVITY

CHEMICAL STABILITY: This product is stable under normal storage conditions.


POSSIBILITY OF HAZARDOUS REACTIONS: Will not occur under normal conditions.
CONDITIONS TO AVOID: Avoid elevated temperatures and sources of ignition.
MATERIALS TO AVOID: Avoid contact with oxidizing materials. Avoid contact with: Acids,
Bases. Avoid unintended contact with amines.
HAZARDOUS DECOMPOSITION PRODUCTS: Toxic gases will form upon combustion : carbon
monoxide, sulfur oxide, hydrogen sulfide, acetaldehyde, and low molecular weight hydrocarbons.

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SDS REF. No : #CLKPSC

11. TOXICOLOGICAL INFORMATION


SIGNS AND SYMPTOMS OF OVEREXPOSURE:

ACUTE EFFECTS:

EYE CONTACT: May cause eye irritation. Corneal injury is unlikely.

SKIN CONTACT: Prolonged contact may cause skin irritation with local redness. Repeated
contact may cause skin irritation with local redness.

INHALATION: This product is of low volatility and not expected to be a major inhalation
hazard.

INGESTION: Overexposure may cause nausea, diarrhea, and/or vomiting. Ingestion may
cause gastrointestinal tract irritation.

TARGET ORGAN: No data available for this product.

CHRONIC EFFECTS: Not determined

TOXICITY VALUES: Not determined

12. ECOLOGICAL INFORMATION


PERSISTENCE AND DEGRADABILITY:
Not determined.
BIO-ACCUMULATIVE POTENTIAL:
No data available for this product.
MOBILITY IN SOIL:
Not determined.
OTHER ADVERSE EFFECTS:
Not known.
ECOTOXICOLOGICAL OTHER INFORMATION:
No data available for this product.

13. DISPOSAL CONSIDERATIONS

DISPOSAL METHOD: Dispose of according to local, state, and federal regulations through a
licensed disposal facility.

14. TRANSPORT INFORMATION

UN NUMBER: Not regulated.


UN PROPER SHIPPING NAME: Not regulated.
TRANSPORT HAZARD CLASS:
Not applicable.
TRANSPORT HAZARD SUBCLASS:
Not applicable.
PACKING GROUP: N/A
MARINE POLLUTANT Y/N:
No
SPECIAL PRE-CAUTIONS: None

15. REGULATORY INFORMATION

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SDS REF. No : #CLKPSC

U.S. REGULATIONS:
All components of this product are listed on or exempt from the TSCA Inventory.
U.S. SARA TITLE III (SUPERFUND AMENDMENRS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES:
FIRE: No
PRESSURE GENERATING: No
REACTIVITY: No
ACUTE: Yes
CHRONIC: No

313 REPORTABLE INGREDIENTS:


313 REPORTABLE INGREDIENTS

302/304 EMERGENCY PLANNING


EMERGENCY PLAN: No reportable components

STATE REGULATIONS:
The following chemicals are California Proposition 65 reportable:

This product contains a chemical(s) known to the State of California to cause cancer and
birth defects or other reproductive harm.

Formaldehyde 50-00-0
Trace* Cancer Hazard.
Ethylene oxide 75-21-8
Trace* Cancer and
reproductive Hazard.
*Trace=present at less than 1ppm.
Massachusetts Right To Know Components
Pennsylvania Right To Know Components

Chemical Name CAS


2,4,6-Tris(dimethylaminomethyl)phenol 90-72-2

New Jersey Right To Know Components

Chemical Name CAS


2,4,6-Tris(dimethylaminomethyl)phenol 90-72-2

OTHER GOVT. REGULATIONS: No other information available

16. OTHER INFORMATION

DATE CREATED 03-15-22


MANUFACTURER DISCLAIMER: The information contained herein is accurate to the best of our
knowledge. Dudick, Inc. makes no warranty of any kind, express or implied, concerning the safe
use of this material in your process or in combination with other substances and with respect to
the completeness or continuing accuracy of the information contained herein and disclaims all
liability for reliance thereon. The information contained on this MSDS has been compiled from
information obtained from raw material suppliers and is believed to be accurate. It is the

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SDS REF. No : #CLKPSC

responsibility of the user to ensure that he/she has all of the current data and MSDS relevant to
the material thereon and to comply with all Federal, State and Local Regulations.

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