PT.

PRIMA MANDIRI KENCANA

KOMP RUKO GALAXY BLOK K -18 TAMAN PALEM LESTARI
CENGKARENG JAKARTA BARAT

CHEMICAL AND PRINTING SUPPLIES

MATERIAL SAFETY DATA SHEET

Data Prepared : January 08, 2018

SECTION 1 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT
Product Name : ROLLER WASH SIC
 
COMPANY
Company Name : PT. PRIMA MANDIRI KENCANA
Address Ruko Galaxy Blok k No 18

In Case of Emergency : Bp. Iwan

SECTION 2 – COMPOSITION / INFORMATION ON INGREDIENTS

MATERIAL COMPONENT
Substance : Aliphatic / Dearomatised Hydrocarbons
Appearance : Liquid

Hazardous substance(s) or Complex Substance(s)

Name   CAS # Concentration * Symbols / Risk Phrases **
Naphtha ( Petroleum ),hydrotreated heavy 64742-48-9 100 % N/D

* All concentrationare percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
** See Section 3 – Classification of hazard

SECTION 3 – HAZARD IDENTIFICATION

This material is considered to be hazardous according to regulatory guidelines.

PHYSICAL / CHEMICAL HAZARDS

Highly flammable. Material can release vapors that readily from flammable mixtures. Vapor accumulation could flash
and/or explode if ignited. Material can accumulate static charges which may cause in incendiary electrical discharge.

HEALTH HAZARDS
Possible risk of impaired fertility. Harmful : danger of serious damage to health by prolonged exposure through
Inhalation. Harmful : may cause lung damage if swallowed. Irritating to skin. Vapors may cause drowsiness and
dizziness. Overexposure to n-hexane may cause effects on the peripheral nerves, resulting in weakness or numbness of
lower limbs. May cause central nervous system depression.

ENVIRONMENTAL HAZARDS
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
SECTION 4 – FIRST AID MEASURE

INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate
respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical
Assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.

SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse.

EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.

INGESTION
Seek immediate medical attention. Do not induce vomiting.

NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonia. Treat appropriately.

SECTION 5 – FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media : N/D
Inappropriate Extinguishing Media : Straight streams of water

FIRE FIGHTING
Fire Fighting Instructions : Evacuate area. If a leak or spill has not ignited, use water spray to disperse the vapors and
to protect personnel attempting to stop a leak. Prevent run-off-from fire control or dilution from entering streams, sewers
or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained
Breathing apparatus ( SCBA ). Use water spray to cool fire exposed surfaces and to protect personnel.

FLAMMABILITY PROPERTIES
Flash Point [ Method ] : - 15C (5F) [Approximate ASTM D-56]
Flammable Limits ( Approximate volume % in air ) : LEL : 1.0 UEL : 7.0
Auto ignition Temperature : > 2000C ( 3920F )

SECTION 6 – ACCIDENTAL RELEASE MEASURES

NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.

PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate in surrounding and downwind areas if required, due to toxicity or
flammability of the material. See Section 5 for the fire fighting information. See the Hazard Identification Section for
significant Hazards. See Section 4 for First Aid Advice. See Section 8 for Personal Protective Equipment.
 SPILL MANAGEMENT
Land Spill : Eliminate all ignition sources ( no smoking, flares, sparks or flames in immediate area ). Stop leak if you
can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through
spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapor-suppressing foam may be
used to reduce vapor. Use clean non –sparking tools to collect absorbed material.

Water Spill : Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the flash
point exceeds the ambient temperature by 10 deg C or more, use containment booms and remove from the surface by
skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air
temperature by at leas 10 deg C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the
advice of a specialist before using dispersants.

SECTION 7 – HANDLING AND STORAGE

HANDLING
Avoid breathing mists or vapor. Avoid contact with skin. Use non-sparking tools and explosion-proof equipment.
Potentially toxic/irritating fumes/vapor may be evolved from heated or agitated material. Use only with adequate
ventilation. Use proper bonding and/or earthing procedures. Prevent small spills and leakage to avoid slip hazard.
Material can accumulate static charges which may cause an electrical spark ( ignition source )
Loading / Unloading Temperature : [ ambient ]
Transport Temperature : [ ambient ]
Transport Pressure : [ ambient ]
Static Accumulator : This material is a static accumulator

STORAGE
Ample fire water supply should be available. A fixed sprinkle/deluge system is recommended. Keep container closed.
Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated
area. Outside or detached storage preferred. Storage containers should be earthed and bonded. Drums must be earthed
snd bonded and equipped with self-closing valves, pressure vacuum bungs and flame arresters.
Storage Temperature : [ ambient ]
Storage Pressure : [ ambient ]
Suitable Containers / Packing : Tank Cars, Tank Trucks, Barges, Drums
Suitable Material and coatings : Carbon Steel, Stainless Steel, Polyethylene, Polypropylene, Polyester, Teflon
Unsuitable Material and coatings : Natural Rubber, Butyl Rubber, Ethylene-Propylene-Diene Monomer (EPDM)

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE LIMIT VALUES

Substance Name Form Limit / Standard Note Source Year
Naphta( Petroleum), Hydrotreated Heavy vapor RCP -TWA 1000 mg/m3 159 ppm Hydrocarbons Exxon Mobil 2008
Note : Limits/standards shown for guidance only. Follow applicable regulations.

ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling
practices, concentration and ventilation. Information on the selection of protective equipment for use with this material,
as provided below, is base upon intended, normal usage.

Respiratory protection : If engineering controls do not maintain airborne contaminant concentration at a level which is
adequate to protect worker health, an approved respirator may be appropriate.

Hand protection : Any specific glove information provided is base on published literature and glove manufacturer data.

Eye protection : If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection : Any specific clothing information provided is based on published literature or manufacturer
data. The type of clothing to be considered for this material include. Chemical resistant clothing is recommended

Specific Hygiene Measures : Always observe good personal hygiene measures, such as washing after handling the
material and before eating, drinking and/or smoking.

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES

GENERAL INFORMATION
PhysicalState : Liquid
Form : Clear
Color : colorless
Odor : mild petroleum / solvent
Odor Threshold : N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density ( at 150C ) : 0.72
Density ( at 150C ) : 720 kg/m3 ( 6.01 lbs / gal, 0.72 kg/ dm3 )
Flash Point [ method ] : - 15C (5F) [approximate ASTM D-56]
Auto ignition Temperature : > 2000C ( 3920F )
Boiling Point / Range : 75C (167F) – 115C (239F)
Vapor Density ( air = 1 ) : N/D
Vapor Pressure : 8.65 kPa ( 64.88 mmHg ) at 20 C
Evaporation Rate ( N-Butyl Acetate = 1 ) : 3
pH : N/A
Log Pow ( n-octanol / water partition coefficient ) : N/D
Solubility in water : Negligible

OTHER INFORMATION
Freezing Point : < 00C (320F)
Melting Point : N/D
Molecular Weight : 94 ( Approximate )
Hygroscopic : No
Coefficient of Thermal Expansion : 0.00126 V/V/DEG C
SECTION 10 – STABILITY AND REACTIVITY

STABILITY : Material is stable under normal conditions.

CONDITIONS TO AVOID : Avoid heat, sparks, open flames and other ignition source

MATERIAL TO AVOID : Strong Oxidizers

HAZARDOUS DECOMPOSITION PRODUCTS : Material does not decompose at ambient temperatures.

SECTION 11 – TOXICOLOGICAL INFORMATION

Acute Toxicity
Route of Exposure Conclusion / Remarks
 
Toxicity : Data available Minimally Toxic. Based on available literature
Irritation : No end point data Negligible hazard at ambient/normal handling temperature.
  Based on available literatures
   
INGESTION  
Toxicity : LD50 > 15000 mg/kg Minimally Toxic. Based on available literature
   
SKIN  
Toxicity : LD50 > 2000 mg/kg Minimally Toxic. Based on available literature
Irritation : Data available Moderately irritating to skin with prolonged exposure.
  Based on available literature
   
EYE  
Irritation : No end point data May cause mild, short-lasting discomfort to eyes
  Based on available literature

SECTION 12 – ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.

ECOTOXICITY
Material – Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

MOBILITY
Material – Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater solids.

PERSISTENCE AND DEGRADABILITY

Biodegradation :
Material – Expected to be readily biodegradable
Atmospheric Oxidation :
Material – Expected to degrade rapidly in air
SECTION 13 – DISPOSAL CONSIDERATION

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and
regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at
very high temperature to prevent formation of undesirable combustion products.

SECTION 14 – TRANSPORT INFORMATION

LAND
Proper Shipping Name : Hydrocarbons, liquid
Hazard Class : 3
UN Number : 3295
Label(s) / Mark(s) : 3

SEA and AIR

Proper Shipping Name : Hydrocarbons, liquid
Hazard class & Division : 3
EMS Number : F-E, S-D
UN Number : 3295

SECTION 15 – REGULATORY INFORMATION

Material is hazardous as defined by the EU Dangerous Substances / Preparations Directive

SECTION 16 – OTHER INFORMATION

N/D = Not Determined, N/A = Not Applicable