Version: 1.

1
Revision Date: 04/06/2020

Product name: ANCAMINE 2049

SAFETY DATA SHEET

Classified in accordance with 29 CFR 1910.1200
1. Identification

Product identifier: ANCAMINE 2049

Other means of identification

None.

Recommended restrictions
Recommended use: Epoxy curing agent
Restrictions on use: Not determined.

Manufacturer/Importer/Distributor Information

Company Name : Evonik Corporation

299 Jefferson Road
Parsippany, NJ 07054
USA

Telephone : +1 973 929 8000

Fax : +1 973 929 8040

E-mail : product-regulatory-services@evonik.com

Emergency telephone number:

24-Hour Health : +1 800 424 9300 (CHEMTREC - US & CANADA)
Emergency +1 800 681 9531 (CHEMTREC MEXICO)
+1 703 527 3887 (CHEMTREC WORLD)

2. Hazard(s) identification

Hazard Classification
Health Hazards
Serious Eye Damage/Eye Irritation Category 1
Acute toxicity (Oral) Category 4
Acute toxicity (Dermal) Category 3
Acute toxicity (Inhalation - vapor) Category 2
Acute toxicity (Inhalation - dust and Category 2
mist)
Skin Corrosion/Irritation Category 1B
Serious Eye Damage/Eye Irritation Category 1

Label Elements

Hazard Symbol:
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Signal Word: Danger

Hazard Statement: Fatal if inhaled.

Toxic in contact with skin.
Harmful if swallowed.
Causes severe skin burns and eye damage.

Precautionary
Statements

Prevention: Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a

well-ventilated area. [In case of inadequate ventilation] wear respiratory
protection. Wear protective gloves/protective clothing/eye protection/face
protection. Wash thoroughly after handling. Do not eat, drink or smoke when
using this product. Avoid release to the environment.

Response: IF INHALED: Remove person to fresh air and keep comfortable for
breathing. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. IF ON
SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water [or shower]. IF SWALLOWED: Call a POISON
CENTRE/doctor/… if you feel unwell. Rinse mouth. Do NOT induce
vomiting. Immediately call a POISON CENTER/doctor. Specific treatment is
urgent (see on this label). Take off immediately all contaminated clothing.
Wash contaminated clothing before reuse. Collect spillage.

Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked
up.

Disposal: Dispose of contents/container to an appropriate treatment and disposal

facility in accordance with applicable laws and regulations, and product
characteristics at time of disposal.

Hazard(s) not otherwise None.

classified (HNOC):

3. Composition/information on ingredients

Mixtures

Common
Content in percent
Chemical Identity name and CAS number
(%)*
synonyms

2,2'-dimethyl-4,4'- 6864-37-5 >99%

methylenebis(cyclohexylamine)
Water 7732-18-5 <1%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

Composition Comments: Chemical family Cycloaliphatic Amine

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The exact concentration has been withheld as a trade secret.

4. First-aid measures

Description of necessary first-aid measures

General information: Seek medical advice. If breathing is irregular or stopped, administer artificial
respiration. In case of cardiac arrest, begin with cardiopulmonary
reanimation (CPR) immediately.

Inhalation: Move to fresh air. If breathing is irregular or stopped, administer

artificial respiration.

Skin Contact: Wash off immediately with soap and plenty of water. Immediately
remove contaminated clothing, and any extraneous chemical, if
possible to do so without delay. Initiate and maintain continuous
irrigation until the patient receives medical care. If medical care is
not promptly available, continue to irrigate for one hour. Cover wound
with sterile dressing.

Eye contact: Rinse immediately with plenty of water for at least 15 minutes. Hold
eyelids apart, initiate and maintain gentle and continuous irrigation
until the patient receives medical care. If medical care is not promptly
available, continue to irrigate for one hour.

Ingestion: Prevent aspiration of vomit. Turn victim's head to the side. If a person
vomits when lying on his back, place him in the recovery position.
Never give anything by mouth to an unconscious person.

Personal Protection for First- Use personal protective equipment., Wear self-contained breathing
aid Responders: apparatus for firefighting if necessary. Avoid contact with skin., A face
shield should be worn.

Most important symptoms/effects, acute and delayed

Symptoms: Repeated and/or prolonged exposure to low concentrations of vapors

and/or aerosols may cause: Sore throat. Asthma Eye disease
Skin disorders Allergies.

Hazards: No data available.

Indication of immediate medical attention and special treatment needed

Treatment: Treat symptomatically.

5. Fire-fighting measures

General Fire Hazards: Do not allow run-off from fire fighting to enter drains or water courses.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing Carbon Dioxide. Dry chemical. Dry sand. Limestone powder Alcohol
media: resistant foam.

Unsuitable extinguishing No data available.

media:

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Specific hazards arising from May generate ammonia gas. May generate toxic nitrogen oxide gases. Use
the chemical: of water may result in the formation of very toxic aqueous solutions. Do not
allow run-off from fire fighting to enter drains or water courses. Incomplete
combustion may form carbon monoxide. Downwind personnel must be
evacuated. Burning produces noxious and toxic fumes.

Special protective equipment and precautions for firefighters

Special fire fighting No data available.

procedures:

Special protective equipment Use personal protective equipment. Wear self-contained breathing
for fire-fighters: apparatus for firefighting if necessary. Avoid contact with skin. A face shield
should be worn.

6. Accidental release measures

Personal precautions, Evacuate personnel to safe areas. Use self-contained breathing apparatus
protective equipment and and chemically protective clothing. Wear suitable protective clothing, gloves
emergency procedures: and eye/face protection.

Accidental release measures: If possible, stop flow of product. Open enclosed spaces to outside
atmosphere. Evacuate area and do not approach spilled product.

Methods and material for Place in appropriate chemical waste container. Approach suspected leak
containment and cleaning areas with caution. Call Emergency Response number for advice.
up:

Environmental Precautions: Construct a dike to prevent spreading.

7. Handling and storage

Handling

Technical measures (e.g. Local No data available.

and general ventilation):

Safe handling advice: Use personal protective equipment.Discard contaminated leather articles.
Remove contaminated clothing. Drench affected area with water for at least
15 minutes. Provide readily accessible eye wash stations and safety
showers. Wash hands at the end of each workshift and before eating,
smoking or using the toilet.Avoid contact with skin and eyes. Use only in
well-ventilated areas. Avoid breathing vapors and/or aerosols. Emergency
showers and eye wash stations should be readily accessible. Adhere to
work practice rules established by government regulations. Avoid contact
with eyes.

Contact avoidance measures: No data available.

Hygiene measures: Provide readily accessible eye wash stations and safety showers.

Storage

Safe storage conditions: Do not store in reactive metal containers.Store in steel containers
preferably located outdoors, above ground, and surrounded by dikes to
contain spills or leaks. Do not store near acids. Keep containers tightly
closed in a dry, cool and well-ventilated place.
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Safe packaging materials: No data available.

Storage Temperature: No data available.

8. Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits
None of the components have assigned exposure limits.

Appropriate Engineering No data available.

Controls

Individual protection measures, such as personal protective equipment

Eye/face protection: Full face shield with goggles underneath. Chemical resistant goggles must
be worn.

Skin Protection
Hand Protection: Additional Information: Chemical-resistant, impervious gloves complying
with an approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is
necessary.Additional Information: Neoprene gloves, Butyl rubber., Nitrile
rubber., Impervious gloves

Skin and Body Protection: No specific recommendations. Impervious clothing Full rubber suit (rain
gear). Rubber or plastic boots Long sleeve shirts and trousers without cuffs.
Slicker Suit.

Respiratory Protection: Not required for properly ventilated areas. Wear appropriate respirator
when ventilation is inadequate.

Hygiene measures: Provide readily accessible eye wash stations and safety showers.

9. Physical and chemical properties

Appearance
Physical state: liquid
Form: liquid
Color: Pale yellow
Odor: Irritating.
Odor Threshold: No data available., Not required by safety or application
considerations.
pH: 11 alkalines
Freezing point: No data available. Not required by safety or application
considerations. No data available.
Boiling Point: > 100 °C
Flash Point: 140.56 °C
Evaporation Rate: No data available. Not required by safety or application
considerations.
Flammability (solid, gas): No data available.
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Explosive limit - upper: see Explosiveness

Explosive limit - lower: see Explosiveness
Vapor pressure: < 0.1333 hPa
Vapor density (air=1): 30.1266
Density: 0.95 g/cm3 (21 °C)
Relative density: (water = 1) 0.95
Solubility in Water: Slightly Soluble
Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available. Not required by safety or application
considerations.
Self Ignition Temperature: The substance or mixture is not classified as pyrophoric.
The substance or mixture is not classified as self heating.
Decomposition Temperature: No decomposition in the field of application.
Kinematic viscosity: No data available.
Dynamic viscosity: No data available.

Other information
Explosive properties: Not explosive
Oxidizing properties: The substance or mixture is not classified as oxidizing.

10. Stability and reactivity

Reactivity: see section "Possibility of hazardous reactions"

Chemical Stability: Stable under normal conditions.

Possibility of hazardous No data available.

reactions:

Conditions to avoid: No data available.

Incompatible Materials: Sodium hypochlorite. Organic acids (i.e. acetic acid, citric acid etc.). Mineral
Acid Product slowly corrodes copper, aluminum, zinc and galvanized
surfaces. Reaction with peroxides may result in violent decomposition of
peroxide possibly creating an explosion. Oxidizing agents.

Hazardous Decomposition Nitric acid. Ammonia Nitrogen Oxides Nitrogen oxide can react with water
Products: vapors to form corrosive nitric acid. Carbon Monoxide. Carbon Dioxide.

11. Toxicological information

Information on likely routes of exposure

Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation: No data available.

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Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Oral
Product: LD 50 (Rat): > 320 - < 460 mg/kg

Dermal
Product: LD 50 (Rabbit): > 200 mg/kg

Inhalation
Product: Aerosols
LC 50 (Rat): 0.42 mg/l
Dusts, mists and fumes
Acute toxicity estimate : 0.42 mg/l
ATEmix : 0.52 mg/l Vapour

Repeated dose toxicity

Product: No data available.

Skin Corrosion/Irritation
Product: Corrosive. (Rabbit, > 3.01 min - < 1 h): Corrosive.

Serious Eye Damage/Eye Irritation

Product: Severe eye irritation

Respiratory or Skin Sensitization

Product: No data available.

Carcinogenicity
Product: No data available.

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

No carcinogens present or none present in regulated quantities

US. National Toxicology Program (NTP) Report on Carcinogens:

No carcinogens present or none present in regulated quantities

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050), as amended:

No carcinogens present or none present in regulated quantities

Germ Cell Mutagenicity

In vitro
Product: No data available.

In vivo
Product: No data available.

Reproductive toxicity
Product: No data is available on the product itself.
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Specific Target Organ Toxicity - Single Exposure

Product: No data available.

Specific Target Organ Toxicity - Repeated Exposure

Product: No data available.

Aspiration Hazard
Product: No data available.

Other effects: No data available.

12. Ecological information

Ecotoxicity:

Acute hazards to the aquatic environment:

Fish
Product: No data available.
LC 50 (Leuciscus idus (Golden orfe), 96 h): > 22 - < 45 mg/l

Aquatic Invertebrates
Product: No data available.
EC 50 (Daphnia (water flea), 40 h): 15.2 mg/l

Chronic hazards to the aquatic environment:

Fish
Product: No data available.

Aquatic Invertebrates
Product: No data available.

Toxicity to Aquatic Plants

Product: No data available.
EC 50 (Desmodesmus subspicatus (green algae), 72 h): 2.1 mg/l

Persistence and Degradability

Biodegradation
Product: No data available.

Components:
2,2'-dimethyl-4,4'- Not readily degradable.
methylenebis(cyclohexyla
mine)

BOD/COD Ratio
Product: No data available.

Bioaccumulative potential
Bioconcentration Factor (BCF)

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Product: No data available.

Partition Coefficient n-octanol / water (log Kow)

Product: Log Kow: No data available. Not required by safety or application
considerations.

Mobility in soil: No data available.

Components:
2,2'-dimethyl-4,4'- This substance does not evaporate into the atmosphere from the surface
methylenebis(cyclohexyla of the water. Adsorption on the floor occurs
mine) This substance does not evaporate into the atmosphere from the surface
of the water. Adsorption on the floor occurs
Water No data available.

Other adverse effects: Do not allow to enter soil, waterways or waste water canal.

13. Disposal considerations

Disposal methods: Contact supplier if guidance is required.

Contaminated Packaging: Dispose of container and unused contents in accordance with federal,
state, and local requirements.

14. Transport information

Domestic regulation

49 CFR
UN/ID/NA number : UN 2922
Proper shipping name : Corrosive liquids, toxic, n.o.s.
(2,2'-dimethyl-4,4'-methylenebis(cyclohexylamine))
Class : 8
Subsidiary risk : 6.1
Packing group : II
Labels : 8 (6.1)
ERG Code : 154
Marine pollutant : no
Remarks : Keep separate from foodstuffs, luxury foods, feedstuffs

International Regulations

IATA-DGR
UN/ID No. : UN 2922
Proper shipping name : Corrosive liquid, toxic, n.o.s.
(2,2'-dimethyl-4,4'-methylenebis(cyclohexylamine))
Class : 8
Subsidiary risk : 6.1
Packing group : II
Labels : 8 (6.1)
Packing instruction (cargo : 855
aircraft)
Packing instruction : 851
(passenger aircraft)
Environmentally hazardous : yes

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IMDG-Code
UN number : UN 2922
Proper shipping name : CORROSIVE LIQUID, TOXIC, N.O.S.
(2,2'-dimethyl-4,4'-methylenebis(cyclohexylamine))
Class : 8
Subsidiary risk : 6.1
Packing group : II
Labels : 8 (6.1)
EmS Code : F-A, S-B
Marine pollutant : yes
Remarks : Clear of living quarters.IMDG Code Segregation Group 18 –
Alkalis
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based upon the
properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation
classifications may vary by mode of transportation, package sizes, and variations in regional or country
regulations.

15. Regulatory information

US Federal Regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

None present or none present in regulated quantities.

US. Toxic Substances Control Act (TSCA) Section 5(a)(2) Final Significant New Use Rules (SNURs) (40
CFR 721, Subpt E)
None present or none present in regulated quantities.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050), as amended

None present or none present in regulated quantities.

CERCLA Hazardous Substance List (40 CFR 302.4):

None present or none present in regulated quantities.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories
Acute toxicity (any route of exposure), Skin Corrosion or Irritation, Serious eye damage or eye
irritation

US. EPCRA (SARA Title III) Section 304 Extremely Hazardous Substances Reporting Quantities and the
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Hazardous
Substances
None present or none present in regulated quantities.

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313
Toxic Chemicals (40 CFR 372.65) - Supplier Notification Required
None present or none present in regulated quantities.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
None present or none present in regulated quantities.

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
None present or none present in regulated quantities.

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US State Regulations

US. California Proposition 65

No ingredient requiring a warning under CA Prop 65.

US. New Jersey Worker and Community Right-to-Know Act

No ingredient regulated by NJ Right-to-Know Law present.

US. Massachusetts RTK - Substance List

No ingredient regulated by MA Right-to-Know Law present.

US. Pennsylvania RTK - Hazardous Substances

No ingredient regulated by PA Right-to-Know Law present.

US. Rhode Island RTK

No ingredient regulated by RI Right-to-Know Law present.

Inventory Status:
US TSCA Inventory: Included on Inventory.
EU EINECS List: On or in compliance with the
inventory
Canada DSL Inventory List: Included on Inventory.
Australia AICS: Included on Inventory.
Japan (ENCS) List: Included on Inventory.
Korea Existing Chemicals Inv. Included on Inventory.
(KECI):
China Inv. Existing Chemical Included on Inventory.
Substances:
Philippines PICCS: Included on Inventory.

16.Other information, including date of preparation or last revision

HMIS Hazard ID

Health 3

Flammability 1

Physical Hazards 0

PERSONAL PROTECTION

Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe; RNP - Rating not
possible; *Chronic health effect

Issue Date: 04/06/2020

Version #: 1.1

Further Information: No data available.

Revision Information Changes since the last version are highlighted in the margin. This version
replaces all previous versions.

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Disclaimer: This information and any recommendations, technical or otherwise, are

presented in good faith and believed to be correct as of the date prepared.
Recipients of this information and recommendations must make their own
determination as to its suitability for their purposes. In no event shall Evonik
assume liability for damages or losses of any kind or nature that result from
the use of or reliance upon this information and recommendations. EVONIK
EXPRESSLY DISCLAIMS ANY REPRESENTATIONS AND WARRANTIES
OF ANY KIND, WHETHER EXPRESS OR IMPLIED, AS TO THE
ACCURACY, COMPLETENESS, NON-INFRINGEMENT,
MERCHANTABILITY AND/OR FITNESS FOR A PARTICULAR PURPOSE
(EVEN IF EVONIK IS AWARE OF SUCH PURPOSE) WITH RESPECT TO
ANY INFORMATION AND RECOMMENDATIONS PROVIDED. Reference to
any trade names used by other companies is neither a recommendation nor
an endorsement of the corresponding product, and does not imply that similar
products could not be used. Evonik reserves the right to make any changes
to the information and/or recommendations at any time, without prior or
subsequent notice.

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