SAFETY DATA SHEET

Regulation (EC) No 1907/2006 (REACH) &

COMMISSION REGULATION (EU) 2015/830
Version 3 Issue Date 09-Jul-2015
Product Name Vinyl neodecanoate (Shivena-10) Revision date 28-Dec-2017
_____________________________________________________________________________________________

SECTION 1: Identification of the substance /mixture and of the company/undertaking

1.1. Product identifier

Product Name Vinyl neodecanoate (Shivena-10)
CAS NO 51000-52-3
EC NO 256-905-8
REACH registration number 01-2119429886-24-0003

1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Refer to the Exposure Scenarios for more information.
Uses advised against No information available

1.3. Details of the supplier of the safety data sheet

Only representative REACH24H CONSULTING GROUP
Address Paramount Court, Corrig Road, Sandyford, Dublin 18, Ireland
E-mail Info@reach24h.com

Supplier Hebei Shield Excellence Technology Co., Ltd

Address Xincheng Industrial Zone of Yangfengang Bazhou, Hebei Province, China
Postal Code 065700
Phone 0316-7555856
FAX 0316-7556499
E-mail quality@hbshield.com; sales@hbshield.com

Importer
Address
Postal Code
Phone
FAX
E-mail

1.4. Emergency telephone number

+86-13821236020

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute aquatic toxicity Category 1 - (H400)
Chronic aquatic toxicity Category 1 - (H410)

2.2. Label elements

Symbols/Pictograms

Signal word Warning

_____________________________________________________________________________________________
Page 1 / 8
Product Name Vinyl neodecanoate (Shivena-10) Revision date 28-Dec-2017
_____________________________________________________________________________________________

Hazard Statements H410 - Very toxic to aquatic life with long lasting effects.
Precautionary Statements P273 - Avoid release to the environment.
P391 - Collect spillage.
P501 - Dispose of contents/ container to an approved waste disposal plant.
EU Specific Hazard Statements None.

2.3. Other hazards

No information available.

SECTION 3: Composition/information on ingredients

3.1 Substance
Chemical Name EC No CAS No Classification according to Regulation (EC) No.
1272/2008 [CLP]
Vinyl neodecanoate 256-905-8 51000-52-3 Aquatic Acute 1 (H400)
(shivena-10) Aquatic Chronic 1 (H410)

SECTION 4: First aid measures

4.1. Description of first aid measures

General advice
In all cases of doubt, or when symptoms persist, seek medical attention.

Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention.

Skin Contact
Wash with soap and plenty of water.

Eye contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. Get medical attention.

Ingestion
Rinse mouth. Never give anything through mouth to an unconscious person. Get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
No information available.

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Water spray, extinguishing powder, foam, carbon dioxide.
Unsuitable extinguishing media No information available.

5.2. Special hazards arising from the substance or mixture

Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of
a subsequent explosion.
Thermal decomposition can lead to release of irritating and toxic gases and vapors, such as carbon dioxide, carbon
monoxide.

_____________________________________________________________________________________________
Page 2 / 8
Product Name Vinyl neodecanoate (Shivena-10) Revision date 28-Dec-2017
_____________________________________________________________________________________________

5.3. Advice for firefighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a
full face-piece operated in positive pressure mode.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate personnel to safe areas. Ensure adequate ventilation, especially in confined areas. ELIMINATE all
ignition sources (no smoking, flares, sparks or flames in immediate area). Avoid contact with skin, eyes or clothing.
Contaminated work clothing should not be allowed out of the workplace. Do not breathe
dust/fume/gas/mist/vapors/spray. Use personal protection recommended in Section 8. Wash thoroughly after
handling.

6.2. Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the
relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water
polluting material. May be harmful to the environment if released in large quantities.

6.3. Methods and material for containment and cleaning up

Small spill: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble
or absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Large spill: Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry
into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or
proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via
a licensed waste disposal contractor. Use spark-proof tools and explosion-proof equipment. Contaminated
absorbent material may pose the same hazard as the spilled product.

6.4. Reference to other sections

See Section 7 for more information
See section 8 for more information
See section 13 for more information

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation, especially in
confined areas. Use spark-proof tools and explosion-proof equipment. Avoid contact with skin, eyes or clothing.
Wash contaminated clothing before reuse. Do not breathe dust/fume/gas/mist/vapors/spray. Keep away from
heat/sparks/open flames/hot surfaces. — No smoking. Do not eat, drink or smoke when using this product. Use
personal protection recommended in Section 8. Wash thoroughly after handling. Avoid release to the environment.
Refer to special instructions/safety data sheet. Keep in the original container or an approved alternative made from
a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.

7.2. Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section
10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid
environmental contamination.

7.3. Specific end use(s)

_____________________________________________________________________________________________
Page 3 / 8
Product Name Vinyl neodecanoate (Shivena-10) Revision date 28-Dec-2017
_____________________________________________________________________________________________

Apart from the uses mentioned in SECTION 1.2 no other specific uses are stipulated.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

No data available

Derived No Effect Level (DNEL)

Route Type of effect DNEL
For the worker Inhalation Systemic effects - Long-term 5 mg/m³
Inhalation Systemic effects - Short-term 1130 mg/m³
Dermal Systemic effects - Long-term 1.67 mg/kg bw/day
For the general population Inhalation Systemic effects - Long-term 2.5 mg/m³
Inhalation Systemic effects - Short-term 565 mg/m³
Dermal Systemic effects - Long-term 0.835 mg/kg bw/day
Oral Systemic effects - Long-term 0.833 mg/kg bw/day

Predicted No Effect Concentration (PNEC)

Compartment PNEC
Water Freshwater: 0.00084 mg/L
Marine water: 0.00003 mg/L
Intermittent releases: 0.0042mg/L
STP 5 mg/L

8.2. Exposure controls

Engineering Controls
Provide local exhaust or process enclosure ventilation system.
Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.

Personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).
Hand Protection Wear protective gloves.
Skin and body protection Suitable protective clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.

Environmental exposure controls

Do not allow into any sewer, on the ground or into any body of water.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Liquid
Color Colorless
Odor Ester
Odor Threshold Not determined
pH Not determined
Melting point/freezing point ca. -73.5 °C
Boiling point / boiling range ca. 212 °C
Flash point 94 °C (101.325kPa)
Evaporation rate Not determined
Flammability Non flammable
Flammability Limit in Air Not determined
Vapor Pressure 38.6 Pa (25 °C)
_____________________________________________________________________________________________
Page 4 / 8
Product Name Vinyl neodecanoate (Shivena-10) Revision date 28-Dec-2017
_____________________________________________________________________________________________

Vapor density Not determined

Density ca. 0.88 g/mL (20 °C)
Relative density ca. 0.88 (20 °C)
Specific gravity Not determined
Water solubility 5.9 mg/L (20 °C)
Partition coefficient (LogPow) 4.9 (20 °C)
Autoignition temperature 267 - 279 °C
Decomposition temperature Not determined
Kinematic viscosity ca. 2.2 mm²/s (20 °C)
ca. 1.65 mm²/s (40 °C)
Dynamic viscosity Not determined
Explosive properties Not an explosive
Oxidizing properties No oxidizing properties

9.2. Other information

No information available.

SECTION 10: Stability and reactivity

10.1. Reactivity
No information available.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No hazardous reactions known.

10.4. Conditions to avoid

Heat, flames and sparks. Incompatible materials.

10.5. Incompatible materials

Strong oxidizing agents. Zinc, copper.

10.6. Hazardous decomposition products

Carbon dioxide, carbon monoxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Vinyl neodecanoate 23100 mg/kg ( Rat ) > 15400 mg/kg ( Rat ) > 2.6 mg/L ( Rat ) 4 h
(shivena-10)
(CAS #: 51000-52-3)

Skin corrosion/irritation
No adverse effect observed (not irritating).

Serious eye damage/eye irritation

No adverse effect observed (not irritating).

Sensitization
Vinyl Neodecanoate is not a skin sensitizer in the guinea pig maximization assay.

_____________________________________________________________________________________________
Page 5 / 8
Product Name Vinyl neodecanoate (Shivena-10) Revision date 28-Dec-2017
_____________________________________________________________________________________________

Germ cell mutagenicity

Vinyl Neodeconoate is not mutagenic.

Carcinogenicity
No information available.

Reproductive toxicity
No information available.

STOT - single exposure

No information available.

STOT - repeated exposure

No information available.

Aspiration hazard
No information available.

SECTION 12: Ecological information

12.1. Toxicity
Chemical Name Algae/aquatic plants EC50 Fish LC50 Crustacea EC50
Vinyl neodecanoate 2.8 - 4.4: 72 h Selenastrum 0.84: 96 h Oncorhynchus mykiss 1.8: 48 h Daphnia magna mg/L
(shivena-10) capricornutum mg/L EC50 mg/L LC50 semi-static EC50
(CAS #: 51000-52-3)

12.2. Persistence and degradability

Not readily biodegradable.

12.3. Bioaccumulative potential

Chemical Name Partition coefficient (LogPow)
Vinyl neodecanoate(shivena-10) (CAS #: 51000-52-3) 4.9

BCF: 1100 - 1390

12.4. Mobility in soil

No information available.

12.5. Results of PBT and vPvB assessment

The substance is not a PBT / vPvB substance.

12.6. Other adverse effects

No information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste from residues/unused Disposal should be in accordance with applicable regional, national and local laws
products and regulations
Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws
and regulations

SECTION 14: Transport information

_____________________________________________________________________________________________
Page 6 / 8
Product Name Vinyl neodecanoate (Shivena-10) Revision date 28-Dec-2017
_____________________________________________________________________________________________

14.1 UN Number 3082

14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE,

LIQUID, N.O.S. (Vinyl neodecanoate)

14.3 Hazard Class 9

14.4 Packing Group Ⅲ

14.5 Environmental hazards Marine pollutant

14.6 Special precautions No information available

14.7 Transport in bulk according to Annex II of Not applicable

MARPOL 73/78 and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to
chemical agents at work
Take note of Directive 94/33/EC on the protection of young people at work
Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work

International Inventories
Component TSCA DSL/NDSL EINECS/ELI ENCS IECSC KECL PICCS AICS
NCS
Vinyl neodecanoate X X X X X X X X
(shivena-10)
51000-52-3
"-" Not Listed
"X" Listed

15.2. Chemical safety assessment

A chemical safety assessment has been carried out for this substance.

SECTION 16: Other information

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Issue Date 09-Jul-2015

Revision date 28-Dec-2017
Revision Note Classification updated

Key or legend to abbreviations and acronyms used in the safety data sheet
TWA - TWA (time-weighted average)
STEL - STEL (Short Term Exposure Limit)
Ceiling - Maximum limit value
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
_____________________________________________________________________________________________
Page 7 / 8
Product Name Vinyl neodecanoate (Shivena-10) Revision date 28-Dec-2017
_____________________________________________________________________________________________

PICCS - Philippines Inventory of Chemicals and Chemical Substances

AICS - Australian Inventory of Chemical Substances

Full text of H-Statements referred to under section 3

H400 - Very toxic to aquatic life.
H410 - Very toxic to aquatic life with long lasting effects.

Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such material
used in combination with any other materials or in any process, unless specified in the text.

-------- End of Safety Data Sheet --------

_____________________________________________________________________________________________
Page 8 / 8