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Brilliant Public School, Sitamarhi: IX - Chemistry Chapter Notes

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BRILLIANT PUBLIC SCHOOL,

SITAMARHI
(Affiliated up to +2 level to C.B.S.E., New Delhi)

IX_Chemistry Chapter Notes

Session: 2014-15

Office: Rajopatti, Dumra Road, Sitamarhi (Bihar), Pin-843301


Ph.06226-252314 , Mobile:9431636758, 9931610902
Website: www.brilliantpublicschool.com; E-mail: brilliantpublic@yahoo.com
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Class: IX
Chapter 1 : Matter in our surroundings
Chapter notes

Top concepts

1. Anything that occupies space and has mass is known as matter.


2. Matter is not continuous but rather consists of large number of
particles.
3. Characteristics of Particle

 Large number of particles constitutes matter.


 Particles of matter are very small in size.
 Particles of matter have spaces between them
 Particles of matter are continuously moving

4. Solids have definite shape, distinct boundaries and fixed volume


5. Liquids have fixed volume but no fixed shape.
6. Gases neither have fixed shape nor volume.
7. Solids possess least compressibility.
8. Liquids possess higher compressibility than solids.
9. Gases possess highest compressibility as compared to solids and
liquids.

11. The process in which a solid changes to liquid state by absorbing heat
at constant temperature is called fusion.
12. The temperature at which a solid melts to become a liquid at the
atmospheric pressure is called as melting point.
13. SI unit of temperature is Kelvin. T (K)= T (oC) +273
14. The hidden heat which breaks the force of attraction between the
molecules during change of state is called latent heat.
15. Latent heat of fusion is the amount of heat energy required to change
1kg of solid into liquid at its melting point.
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16. The melting point of a solid is an indication of the strength of the


force of attraction between its particles.
17. The temperature at which a liquid changes to solid by giving out heat
at atmospheric pressure is called freezing point.
18. The temperature at which a liquid starts boiling at the atmospheric
pressure is known as boiling point.
19. Latent heat of vaporisation is the heat energy required to change 1kg
of liquid to gas at atmospheric pressure at its boiling point.
20. Boiling is a bulk phenomenon.
21. The phenomenon of change of a liquid into its gaseous state at any
temperature below its boiling point is known as evaporation.
22.In evaporation, the conversion of liquid to gaseous state occurs at a
much slower rate, compared to boiling.
23. Evaporation takes place only at the surface of the liquid while boiling
can take place in all parts of the liquid.
24. Evaporation is surface phenomenon
25. Boiling is a bulk phenomena
26. The amount of water vapour present in the air is called humidity.
27. Evaporation is a continuous or ongoing process.
28. Evaporation causes cooling.
29. The process of evaporation of water from the aerial parts of plants
especially leaves is known as transpiration.
30. The rate of evaporation is affected by the surface area exposed to
atmosphere, temperature, humidity and wind speed.
31. Since evaporation is a surface phenomenon, therefore, it increases
with an increase in surface area
32. Evaporation increases with an increase in temperature.
33. Evaporation decreases with an increase in humidity
34. Evaporation increases with the increase in wind speed
35. The process in which a gas changes into liquid state by giving out
heat at constant temperature is called condensation.
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Subject: Chemistry
Class: IX
Chapter Name: Is Matter Around Us Pure
Chapter Notes

Top Concepts

1. Anything which has mass and occupies space is called matter


2. Matter can be classified as pure substances or mixtures
3. A pure substance may either contain constituent particles of only one
kind or of different kinds. A pure substance has a fixed composition
4. An element is a basic form of matter which cannot be broken down
into simpler substances by any physical or chemical means
5. Elements can be broadly classified as metals, non-metals and
metalloids.
6. Metals are one category of elements that have lustre. They conduct
heat and electricity. They are sonorous .They are malleable and ductile
7. Non metals do not have lustre, are not sonorous and are bad
conductors of heat and electricity.
8. Metalloids are elements having properties intermediate between those
of metals and non metals
9. A compound is a pure substance composed of two or more elements
chemically combined in a fixed proportion. It can be broken down into
simpler substances by chemical or electrochemical methods
10.A mixture contains two or more elements or compounds which are
mixed together in any proportion. In a mixture no new compound is
formed. A mixture shows the properties of the constituent substances
11.Mixtures are classified are homogeneous or heterogeneous mixture
12.Mixtures whose components mix completely with each other to make
a uniform composition are called homogeneous mixtures
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13.Mixtures whose components mix completely with each other to make


a uniform composition are called homogeneous mixtures
14.A heterogeneous mixture has a non – uniform composition
15.The ability of a substance to dissolve in another substance is called
solubility.
16.Homogeneous mixture of two or more substances is called a solution.
17.Component of a solution present in small quantity is called a solute.
18.Component of a solution present in large excess is called a solvent.
19.Solution with high solute concentration is called concentrated solution
and those with low concentration is called dilute solution
20. A solution that has dissolved maximum amount of solute at any
particular temperature is said to be a saturated solution.
21. If the amount of solute contained in a solution is less than the
saturation level, it is called an unsaturated solution.
22. The concentration of a solution is the amount of solute present in a
given amount (mass or volume) of solvent or solution.

23. Percentage by mass is one of the methods of expressing


concentration of solution
24. There are two kinds of heterogeneous mixtures, colloids and
suspensions
25. Colloids are mixtures with particle sizes from 1 nm to 1000 nm.
26. The component of colloid present in small amount is called dispersed
phase.
27.The medium in which colloidal particles dispersed or suspend
themselves is called dispersion medium.
28. In a colloidal system particles are always suspended and do not settle
down. This constant colliding of the particles in continuous motion is
called Brownian movement.
29. Scattering of a beam of light when light is passed through a colloidal
solution is called the Tyndall effect
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30. Colloids are classified according to the state (solid, liquid or gas) of
the dispersed medium or dispersing medium and the dispersed phase.
31. Colloid in which dispersed medium is a liquid and dispersed phase is
solid ,it is called as sol
32. Colloid in which both dispersed phase and dispersed medium are in
liquid state is called as an emulsion
33.Colloid in which dispersed phase is either liquid or a solid and
dispersed medium is a gas is called as aerosol.
34. A suspension is heterogeneous mixture in which the solute particles
do not dissolve but remain suspended throughout bulk of medium
.Particles of suspension are visible to naked eye. Suspensions are
heterogeneous mixtures with particles that have a size greater than
1000 nanometers
35. Magnetic impurities can be separated from non-magnetic impurities
by magnetic separation
36. Volatile compounds can be separated from non-volatile compound by
sublimation
37. Mixtures of two or more liquid components can be separated by
simple or fractional distillation or by using a separating funnel.
38. Simple distillation is used for separating liquids having a difference in
boiling points of more than or equal to 25 K.
39. Fractional Distillation is used for separating liquids having a difference
in boiling points of less than 25 K.
40. Liquids that are immiscible in each other differ in their densities and
so can be separated by making use of a separating funnel.
41. The process, by which a soluble solid can be obtained from a solution
by allowing the solvent to vaporize, is called evaporation.
42. Chromatography is used for separation of those solutes which
dissolve in same solvent
43. Chromatography is a method of separating and identifying various
components in a mixture, which are present in small trace quantities.
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44. Mixture containing two solid substances out of which one is soluble in
a particular solvent and other is insoluble can be separated by
dissolving the soluble constituent in a suitable solvent and then
separating the insoluble substance through filtration.
45. This process of separating the suspended particles of an insoluble
substance, from a liquid, by rotating it at high speed is called
centrifugation.
46. The change in which the shape, size, appearance or state of a
substance may alter but its chemical composition remains the same is
called a physical change. In a physical change no new substance is
formed.
47. Any change that involves the formation of a new substance and leads
to a transformation of chemical identity is called chemical change.
48. Chemical changes are usually accompanied with heat exchanges.
Chemical changes are permanent changes which are usually
irreversible.

Top Formulae

Mass of a given substance


Mass by mass percentage of solution=  100
Total mass of solution

Mass of a given substance


Mass by volume percentage of solution=  100
Volume of solution
1

Chapter notes
Class: IX
Chapter Name: Atoms and molecules

Top concepts

1. Laws of chemical combination


 Law of conservation of mass: Mass can neither be created nor
destroyed in a chemical reaction
 Law of constant proportion or Law of definite proportion: In a
chemical substance the elements are always present in definite
proportions by mass

2. Postulates of Dalton’s atomic theory


 All matter is made of very tiny particles called atoms
 Atoms are indivisible particles, which cannot be created or
destroyed in a chemical reaction
 Atoms of a given element are identical in mass and chemical
properties
 Atoms of different elements have different masses and
chemical properties
 Atoms combine in the ratio of small whole numbers to form
compounds
 The relative number and kinds of atoms are constant in a given
compound

3. Some Limitations of Dalton’s atomic theory

 According to Dalton’s atomic theory atoms of a given element are


identical in mass and chemical properties. Atoms of different elements
have different masses and chemical properties. This is wrong because
atoms of some elements vary in their mass and density. Such atoms of
the same element having different masses are called isotopes. For
example, chlorine has two isotopes having mass numbers 35 a.m.u
and 37 a.m.u.

 According to Dalton’s atomic theory atoms of different elements have


different masses and chemical properties. This has been proved wrong
in certain cases like argon and calcium atoms, which have the same
atomic mass of 40. Such atoms of different elements that have the
same atomic mass are called isobar.

 According to Dalton’s atomic theory atoms combine in the ratio of


small whole numbers to form compounds. This is not seen in complex
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organic compounds like sugar C12H22O11. Ratio of C, H and O is


12:22:11 which is not simple.

4. Atoms are building block of all matter

5. Atomic radius is measured in nanometres (1 m = 109 nm)

6. Individual atoms can be observed using Scanning Tunnelling


Microscopes

7. Each element has a name and a unique symbol

8. Rules for assigning symbols for atoms of various elements

a. The abbreviation used to represent an element is generally the


first letter in capital of the English name of element

English name of element Symbol


Hydrogen H
Boron B
Oxygen O
Nitrogen N
Fluorine F

b. When the names of two or more elements begin with the same
initial letter, the initial letter followed by the letter appearing
later in the name is used to symbolize the element

Name of element Symbol


Barium Ba
Bismuth Bi
Bromine Br
Silicon Si
Cadmium Cd

c. Symbols of some elements are derived from their Latin names


Name of element Latin name Symbol
Sodium Natrium Na
Potassium Kalium K
Copper Cuprum Cu
Iron Ferrum Fe
3

Gold Aurum Au
Silver Argentum Ag

9. One atomic mass unit is a mass unit equal to exactly one


twelfth(1/12th) the mass of one atom of carbon-12

10.Relative atomic mass of the atom of an element is defined as the


average mass of the atom, as compared to 1/12th the mass of one
carbon-12 atom

11.Atoms of most elements are not able to exist independently. Atoms


form molecules and ions

12. A molecule can be defined as the smallest particle of an element or


a compound that is capable of an independent existence and shows
all the properties of that substance

13. Molecules of element are formed by the atoms of the same type

14. Atoms of different elements join together in definite proportions to


form molecules of compounds

Based upon atomicity we can classify molecules as follows.

 Monoatomic molecules: Noble gases like helium, neon, argon,


etc., exist in atomic forms, i.e., they are monoatomic. For
example, helium, neon and argon exist as He Ne and Ar
respectively.

 Diatomic molecules: These molecules consist of two atoms. For


example, hydrogen (H2 ) oxygen (O2), nitrogen (N2), chlorine
(Cl2), carbon monoxide (CO), hydrogen chloride (HCl) and
sodium chloride (NaCl).

 Triatomic molecules: These molecules consist of three atoms.


For example. ozone (O3) is a triatomic molecule. Similarly,
carbon dioxide (CO2), nitrogen dioxide (NO2) and hydrogen
sulphide (H2S) are examples of triatomic molecules.
4

 Tetraatomic molecules: These molecules consist of four atoms.


For example, P4 is a tetraatomic molecule of phosphorus.

 Polyatomic molecules: Any molecule containing more than four


atoms is called a polyatomic molecule. For example, sulphur
(S8), methane (CH4), nitric acid (HNO3), ethanol (C2H5OH).

15. An ion is a charged particle and can be negatively or positively


charged

16. A negatively charged ion is called an ‘anion’

17.A positively charged ion is called ‘cation’

18. Ions may consist of a single charged atom or a group of atoms that
have a net charge on them

19. Ionic compounds contain charged species called ions as their


smallest unit

20.A group of atoms carrying a fixed charge on them are called


polyatomic ions or radicals

21. The chemical formula of a compound is a symbolic representation


of its composition

22. Valency is the combining capacity of an element

23. Valency can be used to find out how the atoms of an element will
combine with the atom(s) of another element to form a chemical
compound
5

24. Names and symbols of some ions

25.Rules for writing formula of compound:


 Formula of compound is given by writing side by side the
symbols of constituent elements
 Symbol of the more metallic element is written first in formula
 Number of atoms of each of the constituent element present in
the molecule is indicated by subscript
 When either of the ions or both the ions are polyatomic and
their valency is more than 1, we enclose the polyatomic ions in
brackets. No brackets are necessary if the valency(ies) of
polyatomic ion(s) is(are) 1
 While writing formula of compound if the valency numbers have
a highest common factor (H.C.F), divide the valency numbers by
H.C.F to get the simple ratio between the combining elements

26.The simplest compounds, which are made up of two different


elements are called binary compounds

27.Formula of a binary compound is written by criss crossing the


valencies of elements present in a molecule of the compound

28.A chemical compound is always electrically neutral, so the positive


and negative valencies or charges of the ions in the compound must
add up to zero
6

29. The molecular mass of a substance is the sum of the atomic masses
of all the atoms in a molecule of the substance. It is therefore the
relative mass of molecule expressed in atomic mass units (u)

30.The formula unit mass of a substance is a sum of the atomic masses


of all atoms in a formula unit of a compound

31. 1mole of any substance = 6.022 x 1023units

32. The mole is the amount of substance that contains the same number
of particles (atoms/ ions/ molecules/ formula units etc.) as there are
atoms in exactly 12 g of carbon-12

33.Mass of 1 mole of a substance is called its molar mass

34.Atoms of different elements are of different sizes and masses. A mole


of one type of atoms will have a different mass from a mole of
another type of atoms

35. Molar mass = Mass of one mole of any substance = Gram atomic
mass or gram molecular mass or gram formula mass of the
substance

36. Number of moles = Given number of particles/Avogadro’s number

37.Molar mass is expressed in g/mol

38. Atomic mass of an element expressed in grams is called gram


atomic mass

39.Molecular mass of a substance expressed in grams is called gram


molecular mass

40.Mass of one mole of atoms of any element is equal to gram atomic


mass of that element
1

Chapter notes
Class: IX
Chapter Name: Structure of atom

Top concepts

1. Ionisation of gases in the discharge tube proved that atoms have subatomic
particles

2. Summary of characteristics of electrons, protons and neutrons

Particle Electron Proton Neutron

Symbol e p n

Relative charge -1 +1 0

Nature Negatively Positively Neutral

charged charged

Discovered by JJ Thomson E. Goldstein Chadwick

3. Thomson model of atom :

An atom is a uniform sphere of positive charges (due to presence of protons) as well


as negative charges (due to presence of electrons). Atom as a whole is electrically
neutral because the negative and positive charges are equal in magnitude

4. Limitations of Thomson model of atom:


Model failed to explain how protons and electrons were arranged in atom so close to
each other

5.  -particles are charged particles having two units of positive charge and 4 units
of mass, i.e. they are doubly charged helium ions(He2+)

6. Observations predicted from  -particle scattering experiment by Rutherford based


on Thomson model of atom:
2

Rutherford expected that if the model proposed earlier by J.J Thomson, according to
which there is uniform distribution of positive and negative charge, was correct then
 -particle particles striking the gold atoms would be uniformly deflected which was
not the case. Since the  -particles were much heavier than the protons, he did not
expect to see large deflections

7. Selection of gold metal for Rutherford's  -particle scattering experiment:

Since  -particles are easily absorbed by objects; he wanted to ensure that alpha
particles pass through foil without getting absorbed. If  -particles were absorbed in
matter then they would not be able to give any useful information about insight of
atom. Only if  -particles were deflected then only it can give useful information
about insight of atom. Gold is easily malleable and can be beaten into very thin
sheets.

8. Observations made by Rutherford from  -particle scattering experiment:

1. Most of the  -particles passed straight through gold foil without suffering any
deflection from their original path
2. Some of the  -particles were deflected by the foil by small angles
3. One out of every 12000 particles appeared to rebound

9. Conclusions from Rutherford’s model of an atom

1. Most of the space between inside atoms is empty; hence it allows the  particles
to pass straight through it without any deflection
2. Very few particles were deflected from their path which suggests that the positive
charge of the atom occupies very little space
3. The total volume occupied by a nucleus is very small compared to the total
volume of the atom, as very few  particles are reflected by 180o and all the positive
charge and mass of the gold atom were concentrated in a very small volume within
atom.

10. Rutherford’s model of an atom

1. There is positively charged centre in an atom called the nucleus and the entire
mass of atom resides in the nucleus
2. Electrons revolve around the nucleus in well defined orbits
3. Size of nucleus is very small as compared to size of atom
3

11. Defects in Rutherford model of atom:

1. Rutherford had proposed that electrons move around a positively charged nucleus
at very high speed in circular orbits. To remain in a circular orbit electron would have
to be accelerated centripetally (tending to move toward a center). But according to
electromagnetic theory if charged body (electron) is accelerated around another
charged body (nucleus) then there would be continuous radiation of the moving body
(i.e. electron). This loss of energy would slow down speed of electron and eventually
electron would fall into nucleus. But Rutherford’s model could not explain such a
collapse

2. Rutherford had proposed that electrons revolve around the nucleus in fixed orbits.
He did not specify the number of electrons in each orbit

12. Postulates put forward by Bohr regarding model of atom:

1. Electrons revolve around the nucleus in a limited number of orbits called discrete
orbits of electrons or also called as permissible orbits
2. While revolving in discrete orbits the electrons does not radiate energy i.e. energy
of an electron remains constant so long as it stays in a given orbit. Electrons present
in different orbits have different energies
3. When an electron jumps from lower energy level to higher energy level some
energy is absorbed, while energy is released when electron jumps from higher
energy to lower one
Orbits or shells are represented by the letters K, L, M, N… or the numbers, n=1, 2, 3,
4…

13. Bohr-Bury scheme for distribution of electrons in different orbits

1. Maximum number of electrons that can be accommodated in a shell is given by


2n2 ,where n is the shell number i.e. first shell can accommodate 2 electrons, second
shell can accommodate 8 electrons, third shell can accommodate 18 electrons and so
on
2. Outermost orbit of an atom can accommodate a maximum number of 8 electrons
3. Electrons are not accommodated in a given shell, unless the inner shells are filled
i.e. the shells are filled in a step-wise manner

14. Combining capacity of an atom is called its valency

15. Outermost shell of an atom is called valence shell

16. Electrons present in valence shell is called valence electrons

17. If the outermost shell of an atom is completely, its valency is 0


4

18. Valency of elements having 1-4 electrons in outermost shell are generally
determined by the rule: Valency = Number of electrons in outermost shell

19. Valency of elements having number of electrons in outermost shell close to 8 is


determined by the formula: Valency=8- Number of electrons in outermost shell

20.Significance of valence electrons:


1. Valence electrons are responsible for chemical changes
2. Elements having same number of valence electrons in their atoms possess similar
chemical properties because chemical properties of an element are determined by
the number of valence electrons in an atom
3. Elements having different number of valence electrons in their atoms possess
different chemical properties

21. Atomic number(Z) is defined as the total number of protons present in nucleus
of an atom

22.Protons and neutrons together are called nucleons

23.Mass number (A) is defined as the sum of the total number of protons and
neutrons present in the nucleus of an atom.

24. Isotopes:

 Isotopes are the atoms of same element having same atomic number but
different mass number

 Isotopes have similar chemical properties because they have same number of
valence electrons
 Isotopes have different physical properties like boiling point, melting point etc
because they have different mass number

 Fractional atomic mass of elements are due fact that all elements have isotope

 Applications of isotopes:

235
1. Uranium isotope( 92 U ) is used in nuclear reaction
60
2. Cobalt isotope ( 27 U ) is used to remove brain tumours and in their treatment
24
3. Isotope of sodium ( 11 Na )has been used to diagnose restricted circulation of blood
5

25. Isobars are the atoms of different element with different atomic number but
same mass number

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