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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 23.10.2015 Version number 4 Revision: 23.10.2015

1 Identification of the substance/mixture and of the company/undertaking

· Product identifier
· Trade name: BOLIDT THICKENER CS
· Article number: 95.1238.00.EN
· CAS Number:
67762-90-7
· EC number:
272-697-1
· Relevant identified uses of the substance or mixture and uses advised against
· Sector of Use SU12 Manufacture of plastics products, including compounding and conversion
· Product category PC32 Polymer preparations and compounds
· Article category AC13 Plastic articles
· Application of the substance / the mixture Construction chemicals
· Details of the supplier of the safety data sheet
· Manufacturer:
Bolidt Kunststoftoepassing B.V.
Nijverheidsweg 37
NL-3341 LJ Hendrik-Ido-Ambacht
Netherlands
· Further information obtainable from: Ing. J. van den Boogert
· Emergency telephone number: +31(0)6 21 26 18 90

2 Hazards identification
· Classification of the substance or mixture
The substance is not classified according to the Globally Harmonised System (GHS).
· Label elements
· GHS label elements Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterisation: Substances
· CAS No. Description
67762-90-7 reactieproduct van hoog gedispergeerde amorfe
siliciumdioxide (SiO2) en polymethylsiloxaan
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.10.2015 Version number 4 Revision: 23.10.2015

Trade name: BOLIDT THICKENER CS

(Contd. of page 1)
· Identification number(s)
· EC number: 272-697-1

4 First aid measures

· Description of first aid measures
· General information: No special measures required.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions: Do not allow product to reach sewage system or any water course.
· Methods and material for containment and cleaning up: Pick up mechanically.
· Reference to other sections
No dangerous substances are released.
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage

· Handling:
· Precautions for safe handling No special measures required.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.10.2015 Version number 4 Revision: 23.10.2015

Trade name: BOLIDT THICKENER CS

(Contd. of page 2)
· Information about fire - and explosion protection: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: None.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
· Respiratory protection: Suitable respiratory protective device recommended.
· Protection of hands:
Not required.
No chemical-protective gloves required.
· Material of gloves Natural rubber, NR
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
· Eye protection: Not required.

9 Physical and chemical properties

· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Powder
Colour: White
· Odour: Odourless
· Odour threshold: Not determined.
· pH-value: Not applicable.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.10.2015 Version number 4 Revision: 23.10.2015

Trade name: BOLIDT THICKENER CS

(Contd. of page 3)

· Change in condition
Melting point/Melting range: 1700 °C
Boiling point/Boiling range: - °C
· Flash point: Not applicable.
· Flammability (solid, gaseous): Product is not flammable.
· Ignition temperature:
Decomposition temperature: Not deternimed.
· Self-igniting: Not determined.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not applicable.
· Density at 20 °C: 2,2 g/cm³
· Bulk density at 20 °C: .05 kg/m³
· Relative density Not determined.
· Vapour density Not applicable.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
water: Insoluble.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.10.2015 Version number 4 Revision: 23.10.2015

Trade name: BOLIDT THICKENER CS

(Contd. of page 4)
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity
· LD/LC50 values relevant for classification:
67762-90-7 reactieproduct van hoog gedispergeerde amorfe siliciumdioxide (SiO2) en
polymethylsiloxaan
Oral LD50 >5000 mg/kg (rat)
· Primary irritant effect:
· Skin corrosion/irritation No irritant effect.
· Serious eye damage/irritation No irritating effect.
· Respiratory or skin sensitisation No sensitising effects known.
· Additional toxicological information:
When used and handled according to specifications, the product does not have any harmful effects to
our experience and the information provided to us.
The substance is not subject to classification according to the latest version of the EU lists.

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or
sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
GB
(Contd. on page 6)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.10.2015 Version number 4 Revision: 23.10.2015

Trade name: BOLIDT THICKENER CS

(Contd. of page 5)

13 Disposal considerations
· Waste treatment methods
· Recommendation Smaller quantities can be disposed of with household waste.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· UN-Number
· ADR, ADN, IMDG, IATA Void
· UN proper shipping name
· ADR, ADN, IMDG, IATA Void
· Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class Void
· Packing group
· ADR, IMDG, IATA Void
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Not applicable.
· Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· Transport/Additional information: Not dangerous according to the above specifications.
· UN "Model Regulation": Void

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· GHS label elements Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I Substance is not listed.
(Contd. on page 7)
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 Page 7/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.10.2015 Version number 4 Revision: 23.10.2015

Trade name: BOLIDT THICKENER CS

(Contd. of page 6)

· National regulations:
· Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
· Department issuing MSDS: Technicum
· Contact: Ing. J. van den Boogert
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations
Concerning the International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative

Our advice with respect to the technical application, either verbal or in writing or by means of test, is
given to the best of our knowledge, however is only an indication without engagement, also regarding
possible rights of third parties. They do not take away the necessity of testing the product deliverd for
their suitability to intended use and purpose. Application, use, and working up of the products take
place beyond our control and therefore are your responsibility. It goes without saying we guarantee
the good quality of our products. Entered in the Rigister of Commerce and Industry at Dordrecht
under No. 23035272. All our contracts, offers, deliveries and executions are made in accordance with
our General Condition, filed at the Registry of the district Court at Dordrecht.

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41.2.6