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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 10.08.2020 Version number 1 Revision: 10.08.2020

* SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: Guard Resin (GR) - B & R
· Article number: GR-B25-B, GR-B50-B, GR-B100-B, GR-B200-B, GR-R10-B
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
· Sector of Use SU24 Scientific research and development
· Application of the substance / the mixture Extraction of organic compounds
· 1.3 Details of the supplier of the safety data sheet
· Further information obtainable from: Product safety department
· 1.4 Emergency telephone number: During normal opening times: +33 2 99 05 00 09

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS07

Eye Irrit. 2 H319 Causes serious eye irritation.

STOT SE 3 H335 May cause respiratory irritation.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS07

· Signal word Warning

· Hazard statements
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
· Precautionary statements
P281 Use personal protective equipment as required.
P314 Get medical advice/attention if you feel unwell.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
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(Contd. on page 2)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.08.2020 Version number 1 Revision: 10.08.2020

Trade name: Guard Resin (GR) - B & R

(Contd. of page 1)

SECTION 3: Composition/information on ingredients

· 3.1 Chemical characterisation: Substances
· CAS No. Description
Guard Resin (GR)

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.
· 5.2 Special hazards arising from the substance or mixture
Under certain fire conditions, traces of other toxic gases cannot be excluded, e.g.:
Carbon monoxide (CO)
· 5.3 Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Particular danger of slipping on leaked/spilled product.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Absorb liquid components with liquid-binding material.
Pick up mechanically.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling No special precautions are necessary if used correctly.
· Information about fire - and explosion protection: No special measures required.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.08.2020 Version number 1 Revision: 10.08.2020

Trade name: Guard Resin (GR) - B & R

(Contd. of page 2)

· 7.2 Conditions for safe storage, including any incompatibilities

· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep container tightly sealed.
Protect from exposure to the light.
· 7.3 Specific end use(s) Advised temperature of use: 20-25°C

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Do not eat, drink, smoke or sniff while working.
· Respiratory protection: Not required.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
· Eye protection:

Safety glasses

· Body protection: Protective work clothing

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: Not determined.
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.08.2020 Version number 1 Revision: 10.08.2020

Trade name: Guard Resin (GR) - B & R

(Contd. of page 3)

· Change in condition
Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: Undetermined.
· Flash point: Not applicable.
· Flammability (solid, gas): Not applicable.
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Not determined.
· Explosive properties: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not determined.
· Density: Not determined.
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not determined.
· Particle size 100-200µm
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions
Reacts with strong oxidising agents.
Reacts with flammable substances.
Toxic fumes may be released if heated above the decomposition point.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· Primary irritant effect:
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation
Causes serious eye irritation.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.08.2020 Version number 1 Revision: 10.08.2020

Trade name: Guard Resin (GR) - B & R

(Contd. of page 4)
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure
May cause respiratory irritation.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA Void
· 14.2 UN proper shipping name -
· ADR, IMDG, IATA Void
· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class Void
· 14.4 Packing group -
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· UN "Model Regulation": Void
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.08.2020 Version number 1 Revision: 10.08.2020

Trade name: Guard Resin (GR) - B & R

(Contd. of page 5)

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I Substance is not listed.
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Contact: Aude Bombard
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
CAS: Chemical Abstracts Service (division of the American Chemical Society)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
· * Data compared to the previous version altered.
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