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Soal Kuis Kimia Fisik II

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Soal Kuis Kimia Fisik II

Nina Ariesta S.Pd., M.Si.


1. The following temperature/composition data were obtained for a mixture of octane (O) and
methylbenzene (M) at 1.00 atm, where x is the mole fraction in the liquid and y the mole fraction
in the vapour at equilibrium.
θ /°C 110.9 112.0 114.0 115.8 117.3 119.0 121.1 123.0
xM 0.908 0.795 0.615 0.527 0.408 0.300 0.203 0.097
yM 0.923 0.836 0.698 0.624 0.527 0.410 0.297 0.164
The boiling points are 110.6°C and 125.6°C for M and O, respectively. Plot the
temperature/composition diagram for the mixture. What is the composition
of the vapour in equilibrium with the liquid of composition (a) xM = 0.250
and (b) xO = 0.250?
2. Draw ternary diagram based on data below:
The leftcorner of the plot represents 100% (Na2O+K2O). The
right hand corner reprsents 100% MgO. The top corner
represents 100% (FeO+Fe2O3). Mark these points on your graph
and then plot the follwoing data related volcanic rocks.
(i) 10% (Na2O+K2O), 45% MgO, 45% (FeO+Fe2O3)
(ii) 10% (Na2O+K2O), 35% MgO, 55% (FeO+Fe2O3)
(iii) 10% (Na2O+K2O), 25% MgO, 65% (FeO+Fe2O3)
(iv) 12% (Na2O+K2O), 20% MgO, 68% (FeO+Fe2O3)
(v) 15% (Na2O+K2O), 15% MgO, 70% (FeO+Fe2O3)
(vi) 10% (Na2O+K2O), 45% MgO, 45% (FeO+Fe2O3)
(vii) 18% (Na2O+K2O), 12% MgO, 70% (FeO+Fe2O3)
(viii) 23% (Na2O+K2O), 12% MgO, 65% (FeO+Fe2O3)
3. Nyatakan keadaan zat pada komposisi a1 jika dipanaskan hingga suhu 350 oC!
4. The dimerization of ClO in the Antarctic winter stratosphere is believed to play an important
part in that region’s severe seasonal depletion of ozone. The following equilibrium constants
are based on measurements by R.A. Cox and C.A. Hayman (Nature 332, 796 (1988)) on the
reaction 2ClO (g) →(ClO)2 (g).Determine the values of ΔrHo and ΔrSo for this reaction.
T/K 233 248 258 268 273 280 288 295 303
4
K (.10 ) 41300 5000 1450 537 320 96,2 42,8 16,7 7,02
5. Berdasarkan diagram Ellingham
tersebut, perkirakan reduktor yang
sesuai untuk memisahkan logam Mg
dari bijihnya. Sertakan reaksinya
dengan penjelasan tentang harga ΔGo
6. Determine ΔGo at 25°C for the
following hydrogenation reaction if
ΔGof C6H6 124,3 Kj/mol and C6H12
26,8 kj/mol
C6H6 (ℓ) + H2 (g) → C6H12 (ℓ).
Is the reaction spontaneous?

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