The document contains 6 questions about physical chemistry concepts:
1. A temperature-composition diagram is to be plotted for an octane-methylbenzene mixture and vapor-liquid compositions calculated.
2. A ternary diagram is to be drawn using composition data for various volcanic rocks.
3. The state of a substance at a given composition is to be identified if heated to 350°C.
4. Thermodynamic values are to be calculated for a dimerization reaction based on equilibrium constants.
5. A suitable reductant is to be identified to extract magnesium from its ore based on an Ellingham diagram.
6. The Gibbs free energy is to be calculated for a hydrogenation reaction to determine
The document contains 6 questions about physical chemistry concepts:
1. A temperature-composition diagram is to be plotted for an octane-methylbenzene mixture and vapor-liquid compositions calculated.
2. A ternary diagram is to be drawn using composition data for various volcanic rocks.
3. The state of a substance at a given composition is to be identified if heated to 350°C.
4. Thermodynamic values are to be calculated for a dimerization reaction based on equilibrium constants.
5. A suitable reductant is to be identified to extract magnesium from its ore based on an Ellingham diagram.
6. The Gibbs free energy is to be calculated for a hydrogenation reaction to determine
The document contains 6 questions about physical chemistry concepts:
1. A temperature-composition diagram is to be plotted for an octane-methylbenzene mixture and vapor-liquid compositions calculated.
2. A ternary diagram is to be drawn using composition data for various volcanic rocks.
3. The state of a substance at a given composition is to be identified if heated to 350°C.
4. Thermodynamic values are to be calculated for a dimerization reaction based on equilibrium constants.
5. A suitable reductant is to be identified to extract magnesium from its ore based on an Ellingham diagram.
6. The Gibbs free energy is to be calculated for a hydrogenation reaction to determine
The document contains 6 questions about physical chemistry concepts:
1. A temperature-composition diagram is to be plotted for an octane-methylbenzene mixture and vapor-liquid compositions calculated.
2. A ternary diagram is to be drawn using composition data for various volcanic rocks.
3. The state of a substance at a given composition is to be identified if heated to 350°C.
4. Thermodynamic values are to be calculated for a dimerization reaction based on equilibrium constants.
5. A suitable reductant is to be identified to extract magnesium from its ore based on an Ellingham diagram.
6. The Gibbs free energy is to be calculated for a hydrogenation reaction to determine
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Soal Kuis Kimia Fisik II
Nina Ariesta S.Pd., M.Si.
1. The following temperature/composition data were obtained for a mixture of octane (O) and methylbenzene (M) at 1.00 atm, where x is the mole fraction in the liquid and y the mole fraction in the vapour at equilibrium. θ /°C 110.9 112.0 114.0 115.8 117.3 119.0 121.1 123.0 xM 0.908 0.795 0.615 0.527 0.408 0.300 0.203 0.097 yM 0.923 0.836 0.698 0.624 0.527 0.410 0.297 0.164 The boiling points are 110.6°C and 125.6°C for M and O, respectively. Plot the temperature/composition diagram for the mixture. What is the composition of the vapour in equilibrium with the liquid of composition (a) xM = 0.250 and (b) xO = 0.250? 2. Draw ternary diagram based on data below: The leftcorner of the plot represents 100% (Na2O+K2O). The right hand corner reprsents 100% MgO. The top corner represents 100% (FeO+Fe2O3). Mark these points on your graph and then plot the follwoing data related volcanic rocks. (i) 10% (Na2O+K2O), 45% MgO, 45% (FeO+Fe2O3) (ii) 10% (Na2O+K2O), 35% MgO, 55% (FeO+Fe2O3) (iii) 10% (Na2O+K2O), 25% MgO, 65% (FeO+Fe2O3) (iv) 12% (Na2O+K2O), 20% MgO, 68% (FeO+Fe2O3) (v) 15% (Na2O+K2O), 15% MgO, 70% (FeO+Fe2O3) (vi) 10% (Na2O+K2O), 45% MgO, 45% (FeO+Fe2O3) (vii) 18% (Na2O+K2O), 12% MgO, 70% (FeO+Fe2O3) (viii) 23% (Na2O+K2O), 12% MgO, 65% (FeO+Fe2O3) 3. Nyatakan keadaan zat pada komposisi a1 jika dipanaskan hingga suhu 350 oC! 4. The dimerization of ClO in the Antarctic winter stratosphere is believed to play an important part in that region’s severe seasonal depletion of ozone. The following equilibrium constants are based on measurements by R.A. Cox and C.A. Hayman (Nature 332, 796 (1988)) on the reaction 2ClO (g) →(ClO)2 (g).Determine the values of ΔrHo and ΔrSo for this reaction. T/K 233 248 258 268 273 280 288 295 303 4 K (.10 ) 41300 5000 1450 537 320 96,2 42,8 16,7 7,02 5. Berdasarkan diagram Ellingham tersebut, perkirakan reduktor yang sesuai untuk memisahkan logam Mg dari bijihnya. Sertakan reaksinya dengan penjelasan tentang harga ΔGo 6. Determine ΔGo at 25°C for the following hydrogenation reaction if ΔGof C6H6 124,3 Kj/mol and C6H12 26,8 kj/mol C6H6 (ℓ) + H2 (g) → C6H12 (ℓ). Is the reaction spontaneous?