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Persistent Organic Pollutants (Pops)

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Persistent Organic Pollutants (POPs)

Persistent organic pollutants (POPs) are toxic chemicals that adversely affect human health and
the environment around the world. Because they can be transported by wind and water, most POPs
generated in one country can and do affect people and wildlife far from where they are used and released.
They persist for long periods of time in the environment and can accumulate and pass from one species
to the next through the food chain.

What Are POPs?


Many POPs were widely used during the boom in industrial production after World War II, when
thousands of synthetic chemicals were introduced into commercial use. Many of these chemicals proved
beneficial in pest and disease control, crop production, and industry. These same chemicals, however,
have had unforeseen effects on human health and the environment.

Many people are familiar with some of the most well-known POPs, such as PCBs, DDT, and dioxins.
POPs include a range of substances that include:

1. Intentionally produced chemicals currently or once used in agriculture, disease control,


manufacturing, or industrial processes. Examples include PCBs, which have been useful in a
variety of industrial applications (e.g., in electrical transformers and large capacitors, as hydraulic
and heat exchange fluids, and as additives to paints and lubricants) and DDT, which is still used to
control mosquitoes that carry malaria in some parts of the world.

2. Unintentionally produced chemicals, such as dioxins, that result from some industrial processes
and from combustion (for example, municipal and medical waste incineration and backyard
burning of trash).

The 12 initial POPs under the Stockholm Convention


Initially, twelve POPs have been recognized as causing adverse effects on humans and the ecosystem
and these can be placed in 3 categories:

 Pesticides: aldrin, chlordane, DDT, dieldrin, endrin, heptachlor, hexachlorobenzene, mirex,


toxaphene;

 Industrial chemicals: hexachlorobenzene, polychlorinated biphenyls (PCBs); and

 By-products: hexachlorobenzene; polychlorinated dibenzo-p-dioxins and polychlorinated


dibenzofurans (PCDD/PCDF), and PCBs.
Health effects
POP exposure may cause developmental defects, chronic illnesses, and death. Some are carcinogens
per IARC, possibly including breast cancer. Many POPs are capable of endocrine disruption within
the reproductive system, the central nervous system, or the immune system. People and animals are
exposed to POPs mostly through their diet, occupationally, or while growing in the womb. For humans not
exposed to POPs through accidental or occupational means, over 90% of exposure comes from animal
product foods due to bioaccumulation in fat tissues and bioaccumulate through the food chain. In general,
POP serum levels increase with age and tend to be higher in females than males.

Studies have investigated the correlation between low level exposure of POPs and various diseases. In
order to assess disease risk due to POPs in a particular location, government agencies may produce
a human health risk assessment which takes into account the pollutants' bioavailability and their dose-
response relationships.

Control and removal in the environment


Current studies aimed at minimizing POPs in the environment are investigating their behavior in photo
catalytic oxidation reactions. POPs that are found in humans and in aquatic environments the most are
the main subjects of these experiments. Aromatic and aliphatic degradation products have been
identified in these reactions. Photochemical degradation is negligible compared to photocatalytic
degradation.[26] A method of removal of POPs from marine environments that has been explored is
adsorption. It occurs when an absorbable solute comes into contact with a solid with a porous surface
structure. This technique was investigated by Mohamed Nageeb Rashed of Aswan University,
Egypt.[27] Current efforts are more focused on banning the use and production of POPs worldwide rather
than removal of POPs.[28]

http://chm.pops.int/TheConvention/ThePOPs/The12InitialPOPs/tabid/296/Default.aspx

https://www.epa.gov/international-cooperation/persistent-organic-pollutants-global-issue-global-
response

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