Search Results (98)

This study investigates the synthesis and photoluminescent properties of carbon quantum dots (CQDs) derived from Actinidia deliciosa using the hydrothermal method. The effect of concentration and pH on the composition, structure, and optical properties of CQDs was analyzed using characterization techniques such as TEM, EDS, FTIR, UV-Vis, and photoluminescence (PL) spectroscopy. The CQDs exhibited particle sizes ranging from 1 to 10 nm, with a graphitic structure and oxygen-containing functional groups, as identified by FTIR bands corresponding to OH, C=O, and C=C. The stability analysis revealed particle agglomeration over 30 days, increasing the size up to <40 nm. Regarding the optical properties, the CQDs displayed absorption peaks at 225 and 280 nm and a bandgap of ~3.78–3.82 eV. The PL characterization demonstrated tunable emission from violet to green, depending on the excitation wavelength. CQDs synthesized at an acidic pH of 2 exhibited enhanced luminescence due to protonation effects, whereas an alkaline pH led to a reduction in emission intensity. The hydrothermal method enabled a simple and eco-friendly synthesis, using water as the sole solvent, yielding stable CQDs with a luminescence lifespan exceeding 30 days. Their optical and electronic properties make them promising candidates for photocatalysis, heavy metal detection, and bioimaging applications. Full article

Neutral organic radicals with intrinsic spin-allowed doublet emission have emerged as a promising class of luminescent materials, garnering significant research interest. However, the development of stable luminescent radicals with tunable emission remains challenging. Herein, we present the synthesis of a series of 9-(2,4,6-trichlorophenyl)-substituted fluorenyl radicals functionalized with various substituents at the 3,6-positions. These radicals exhibit enhanced stability through efficient spin delocalization and kinetic protection. Notably, they display red-shifted photoluminescence compared to traditional polychlorotriphenylmethyl radicals, with maximum emission wavelengths ranging from 679 nm to 744 nm. The mechanisms underlying the doublet emission, as well as their electrochemical properties, have been thoroughly investigated. Full article

Metal halide perovskite quantum dots (MHP QDs), as a kind of fluorescent material, have attracted much attention due to their excellent photoluminescence (PL) quantum yield (QY), narrow full width at half maximum (FWHM), broad absorption, and tunable emission wavelength. However, the instability and biological incompatibility of MHP QDs greatly hinder their application in the field of biomedicine. Hydrogels are three-dimensional polymer networks that are widely used in biomedicine because of their high transparency and excellent biocompatibility. This review not only introduces the latest research progress in improving the mechanical and optical properties of hydrogels/MHP QDs but also combines it with the existing methods for enhancing the stability of MHP QDs in hydrogels, aiming to provide new ideas for researchers in material selection and methods for constructing MHP QD-embedded hydrogels. Finally, their application prospects and future challenges are introduced. Full article

Donor acceptor (D-$\mathsf{\pi }$-A) fluorophores containing a donor unit and an acceptor moiety at each end connected by a conjugated linker gained attention in the last decade due to their conjugated system and ease of tunability. These features make them good candidates for various applications such as bioimaging, photovoltaic devices and nonlinear optical materials. Upon excitation of the D-$\mathsf{\pi }$-A fluorophore, intramolecular charge transfer (ICT) occurs, and it polarizes the molecule resulting in the ‘push–pull’ system. The emission wavelengths of fluorophores can be altered from UV-vis to NIR region by modifying the donor unit, acceptor moiety and the $\mathsf{\pi }$ linker between them. The NIR emitting fluorophores with restricted molecular rotations are used in aggregation-induced emission (AIE). D-$\mathsf{\pi }$-A fluorophores with carboxylic acid and cyano groups are preferred in photovoltaic applications, and fluorophores with large surface area are used for two photon absorbing applications. Herein, we report the synthesis, optical properties, and applications of various D-$\mathsf{\pi }$-A fluorophores in UV-vis and NIR region. Full article

Stimulus-responsive luminescent materials are pivotal in the field of sensing. Fluorescent transition metal complexes with a charge transfer excited state, especially terpyridine-coordinated polymers, are of particular interest due to their tunable emission. In this paper, a novel bis-terpyridine ligand was synthesized and assembled into a coordination polymer, which showed intense visible light absorption and fluorescence emission in the solid state that could be regulated by an acidic or basic pH. After being protonated by acid, the fluorescence of the polymer P2 was quenched. The emission of the polymer split from 635 nm to two peaks of 674 and 440 nm, and then stabilized at 728 nm for 7 days, which showed a significant red-shift and good protonation stability. The fluorescence emission wavelength of the protonated polymers recovered after alkalization, and the fluorescence intensity of the polymer was greatly improved after alkalization, showing interesting acid–base-response luminescence characteristics. The sensitive response of the synthesized coordination polymers to acids and bases will contribute to expanding the application of linear coordination polymers in sensing and other fields. Full article

We propose and demonstrate a tunable and switchable multi-wavelength fiber ring laser configuration based on a Mach–Zehnder interferometer (MZI) filter. The MZI was fabricated using a core-offset splicing technique, with a 2 cm piece of thin-core erbium-doped fiber (TCEDF), with a core diameter of 2.90 µm, coupled in the central region of the MZI between two segments of single-mode fiber (SMF). By applying curvature to the MZI filter, we generated lasing single-, double-, triple-, and quadruple-emission lines with a curvature range from 2.3452 m⁻¹ to 6.0495 m⁻¹. A single-emission lasing line can be tuned from 1556.63 nm to 1564.25 nm with a tuning span of 7.62 nm and an SMSR of 49.80 dB. The laser emission can be switched to quadruple- and triple-emission lasing signals, with SMSR values of 39.96 dB and 36.83 dB, respectively. The dual-narrow emission lasing signal can be tuned from 1564.56 nm to 1561.34 nm, with an SMSR of 40.46 dB. Another lasing dual-emission signal can be tuned from 1585.69 nm to 1576.89 nm, producing an 8.8 nm tuning range, and from 1572.53 nm to 1563.66 nm, producing an 8.87 nm range, with the best SMSR of 42.35 dB. Full article

A wavelength-switchable ring-cavity ytterbium-doped fiber laser utilizing an all-fiber Lyot interferometer filter was proposed and experimentally demonstrated. Firstly, the Lyot filter was constructed using a polarization-maintaining fiber (PMF) to obtain a comb interferometer effect, and the free spectrum ranges corresponding to 2.5 and 1 m PMF were 2.2 and 6.4 nm, respectively. Then, wavelength-switchable ytterbium-doped fiber emission was realized in the experiment, and the tunable range for the single-wavelength laser was from 1073.76 to 1086.78 nm, with a power variation of less than 1.959 dB. During the experiment, four different sets of double-wavelength lasers were achieved by adjusting the polarization controller (PC) from 1071.64 to 1081.65 nm; in addition, three different sets of triple-wavelength lasers were realized, and the signal-to-noise ratio (SNR) was more than 33.031 dB. For stable single-, double-, and triple-wavelength lasers, the power shifts were less than 0.574, 0.631, and 1.195 dB, respectively. Through adjusting the PC, quadruple-wavelength-switchable lasers could be realized with an SNR exceeding 26.233 dB. Full article

The enduring interest in carbon quantum dots (CQDs) as photoluminescent material arises from their significant advantages over inorganic quantum dots (QDs), such as low toxicity and biocompatibility, which enables their application in bioimaging and drug delivery. This review is focused on the use of CQDs for light emitting devices (LED) technology and provides a guide on how to synthesize CQDs that emit blue, green, and red light, which is necessary to produce RGB LEDs. Consideration was given to the precursors, solvents, methods, and conditions of the processes, the excitation wavelength, the emission wavelength, and the photoluminescence quantum yield (QY). These unique, organic nanoparticles have the potential to revolutionize lighting and, above all, the electronics market due to their low cost and eco-friendliness, as well as the possibility of using various precursors, including waste. Full article

Tunable color emissions, emerging from a single CdTe nanowire, are demonstrated experimentally based on optical transverse nonlinear effects. The pumping light at different wavelengths (e.g., 1064 nm and 980 nm) is coupled to a nanowire at both ends via evanescent-field coupling. The light at different wavelengths (e.g., 510 nm, 532 nm, and 713 nm) can be simultaneously assessed using complex optical transverse nonlinear effects, including transverse sum-frequency generation (TSFG), transverse second-harmonic generation (TSHG), and two-photon absorption (TPA)-induced fluorescence. By changing the wavelength and the power of the pumping lights, the spectra of the transverse light emissions change as well, leading to tunable color emissions at the single-nanowire level with a Rec. 2020 coverage of ~21.6%. The results indicate the potential of transverse nonlinear effects in applications ranging from optical display and spectroscopy to communication. Full article

This paper presents a tunable, switchable multi-wavelength emission from an erbium-doped fiber ring laser, enabled by adjusting the spectral fringe visibility of a fiber interferometer filter. The filter is formed with specially designed concatenated tapered fibers to configure a Mach-Zehnder fiber interferometer (MZFI). The laser emission is highly flexible and reconfigurable, allowing for tuning between single- and dual-wavelength operation. The laser can switch sequentially from one up to six wavelengths by fixing the curvature and adjusting the polarization state. The lasing emission is generated over a stable wavelength range between 1559.59 nm and 1563.54 nm, exhibiting an optical signal-to-noise ratio (OSNR) exceeding ~35 dB. The performance of amplitude and wavelength fluctuations were evaluated, indicating an appropriate stability of ~3 dB and a shift less than 0.1 nm within a 45 min period at room temperature. A detailed comparison with the literature is given. Full article

A dual-wavelength spaceborne Martian polarized wind imaging Michelson interferometer based on liquid crystal tunable filters (LCTF-MPWIMI) has been proposed for the remote sensing detection of dynamic parameters such as wind speed and temperature in the middle and upper atmosphere of Mars. Using the detected Martian oxygen atom emission lines at 557.7 nm and 630.0 nm as observation spectral lines, this technology extends the detection altitude range for Martian atmospheric wind speed and temperature to 60–180 km. By leveraging the different spectral line visibility of the interferograms at the two wavelengths, a novel method for measuring Martian atmospheric temperature is proposed: the dual-wavelength spectral line visibility product method. This new approach reduces the uncertainty of temperature detection compared to traditional single spectral line visibility methods, while maintaining the precision of wind speed measurements. The feasibility of the LCTF-MPWIMI for measuring wind and temperature fields in the Martian middle and upper atmosphere has been validated through theoretical modeling and computer simulations. The interferometer, as a key component of the system, has been designed and analyzed. The proposed LCTF-MPWIMI instrument is free of mechanical moving parts, offering flexible wavelength selection and facilitating miniaturization. The dual-wavelength temperature measurement method introduced in this work provides superior temperature measurement precision compared to any single spectral line when the signal-to-noise ratio (SNR) of the interferograms is comparable. Moreover, this method does not impose specific requirements on the atomic state of the spectral lines, making it broadly applicable to similar interferometric wind measurement instruments. These innovations offer advanced tools and methodologies for measuring wind speeds and temperatures in the atmospheres of Mars and other planets. Full article

Deep-red light has significant application value in various fields, including biomedicine, plant cultivation, and displays. The development of high-efficiency deep-red luminescent materials is therefore of great importance. Semiconductor nanocrystals have been extensively studied as novel luminescent materials due to their wavelength tunability, narrow emission linewidth, and high luminescence efficiency. However, the advancement of deep-red nanocrystals has lagged behind that of red, green, and blue nanocrystals, primarily due to material selection limitations. This review summarizes the recent progress in the synthesis of deep-red nanocrystals based on their material composition, including II-VI, III-V, I-III-VI, and perovskite nanocrystals. Full article

Polymer-stabilized cholesteric liquid crystals (PSCLCs) have emerged as promising candidates for one-dimensional photonic lattices that enable precise tuning of the photonic band gap (PBG). This work systematically investigates the effect of polymer concentrations on the AC electric field-induced tuning of the PBG in PSCLCs, in so doing it explores a range of concentrations and provides new insights into how polymer concentration affects both the stabilization of cholesteric textures and the electro-optic response. We demonstrate that low polymer concentrations (≈3 wt. %) cause a blue shift in the short wavelength band edge, while high concentrations (≈10 wt. %) lead to a contraction and deterioration of the reflection band. Polarization optical microscopy was conducted to confirm the phase transition induced by the application of an electric field. The observations confirm that increased polymer concentration stabilizes the cholesteric texture. Particularly, the highly desired fingerprint texture was stabilized in a sample with 10 wt. % of the polymer, whereas it was unstable for lower polymer concentrations. Additionally, higher polymer concentrations also improved the dissymmetry factor and stability of the lasing emission, with the dissymmetry factor reaching the value of around 2 for samples with 10 wt. % of polymer additive. Our results provide valuable comprehension into the design of advanced PSCLC structures with tunable optical properties, enhancing device performance and paving the way for innovative photonic applications. Full article

Tunable diode laser spectroscopy (TDLS) is a measurement technique with high spectral resolution. It is based on tuning the emission wavelength of a semiconductor laser by altering its current and/or its temperature. However, adjusting the wavelength leads to a change in emission intensity. For applications that rely on modulated radiation, the challenge is to isolate the true spectrum from the influence of extraneous instrumental contributions, particularly residual intensity and wavelength modulation. We present a novel approach combining TDLS with interferometric techniques, exemplified by the use of a Mach–Zehnder interferometer, to enable the separation of intensity and wavelength modulation. With interferometrically enhanced intensity modulation, we reduced the residual wavelength modulation by 83%, and with interferometrically enhanced wavelength modulation, we almost completely removed the residual derivative of the signal. A reduction in residual wavelength modulation enhances the spectral resolution of intensity-modulated measurements, whereas a reduction in residual intensity modulation improves the signal-to-noise ratio and the sensitivity of wavelength-modulated measurements. Full article

The utilization of optical antennas for active control of far-field radiation at the subwavelength scale is crucial in various scientific and technological applications. We propose a thermally tunable disk design of indium tin oxide (ITO) and aluminum gallium nitride (${\mathrm{Al}}_{0.18}{\mathrm{Ga}}_{0.82}\mathrm{As}$), enabling a switch between absorption and scattering. Furthermore, the control of far-field radiation pattern can be easily realized by combining ITO and ${\mathrm{Al}}_{0.18}{\mathrm{Ga}}_{0.82}\mathrm{As}$ to enhance or suppress emission. Our results demonstrate that hybrid structures can be dynamically tuned with temperature variations. In the proposed design, a frequency is achieved at the wavelength of 1240 nm. The thermal tunability of hybrid structures introduces new multifunctional possibilities for light manipulation, thereby enhancing the potential applications of new devices in the near-infrared range. Full article