Search Results (184)

Contamination of soil by spills of crude oil and oilfield brine is known to affect the species composition and functioning of soil microbial communities. However, the effect of such contamination on nitrogen cycling, an important biogeochemical cycle in tallgrass prairie soil, is less well known. Detecting nitrate-reducing (NR) and denitrifying (DN) bacteria via PCR amplification of the genes essential for these processes depends on how well PCR primers match the sequences of these bacteria. In this study, we enriched for NR and DN bacteria from oil/brine tallgrass prairie soil contaminated 5–10 years previously versus those cultured from uncontaminated soil, confirmed the capacity of 75 strains isolated from the enrichments to reduce nitrate and/nitrite, then screened the strains with primers specific to seven nitrogen cycle functional genes. The strains comprised a phylogenetically diverse group of NR and DN bacteria, with proportionately more γ-Proteobacteria in oil-contaminated sites and more Bacilli in brine-contaminated sites, suggesting some residual effect of the contaminants on the NR and DN species distribution. Around 82% of the strains shown to reduce nitrate/nitrite would not be identified as NR and DN bacteria by the battery of NR and DN primers used. Our results indicate an urgent need to expand the NR/DN functional gene primer database by first identifying novel NR/DN strains through their capacity to reduce nitrate/nitrite. Full article

Anning Refinery, a large-scale joint venture in southern China, possesses significant potential in regard to polluting local groundwater environments due to its extensive petroleum raw materials. This study aims to mitigate the substantial risks associated with oil spills and prevent consequential groundwater pollution by developing a robust groundwater flow model using the MODFLOW module in GMS software that aligns closely with natural and pumping test conditions. Furthermore, by integrating the MT3DMS model, a groundwater solute transport model is constructed and calibrated using sodium chloride tracer dispersion data. Notably, the wax hydrocracking unit and aviation coal finished product tank area are identified as key pollution sources warranting attention. By considering local constraints such as karst collapse, ground subsidence, and single-well water output capacity, the study introduces a tailored groundwater pollution management model. The research simulates various scenarios of petroleum pollutant migration in groundwater and proposes multi-objective emergency response optimization plans. In Scenario 1, simulations show that petroleum pollutants migrate within the unconfined aquifer and enter the karst aquifer as low-concentration plumes over an extended period. Detection of these plumes in karst water monitoring wells indicates upstream unconfined aquifer contamination at higher concentrations, necessitating immediate activation of the nearest monitoring or emergency wells in both layers. Conversely, in Scenario 2, pollutants reside briefly in the unconfined aquifer before entering the karst aquifer at relatively higher concentrations. Here, low-efficiency pollutant discharge through unconfined aquifer monitoring wells prompts the activation of nearby karst aquifer monitoring or emergency wells for effective pollution control. This model underscores the necessity for proactive monitoring and validates the efficacy of coupled numerical modeling in understanding pollutant behavior, offering valuable insights into pollution control scenario assessments. In summary, the study emphasizes the importance of targeted monitoring and emergency protocols, demonstrating the benefits of integrated modeling approaches in industrial areas prone to pollution risks, and provides critical theoretical and practical guidance for groundwater protection and pollution management, offering transferable insights for similar industrial settings worldwide. Full article

Oil spill SAR images are characterized by high noise, low contrast, and irregular boundaries, which lead to the problems of overfitting and insufficient capturing of detailed features of the oil spill region in the current method when processing oil spill SAR images. An improved DeepLabV3+ model is proposed to address the above problems. First, the original backbone network Xception is replaced by the lightweight MobileNetV2, which significantly improves the generalization ability of the model while drastically reducing the number of model parameters and effectively addresses the overfitting problem. Further, the spatial and channel Squeeze and Excitation module (scSE) is introduced and the joint loss function of Bce + Dice is adopted to enhance the sensitivity of the model to the detailed parts of the oil spill area, which effectively solves the problem of insufficient capture of the detailed features of the oil spill area. The experimental results show that the mIOU and F1-score of the improved model in an oil spill region in the Gulf of Mexico reach 80.26% and 88.66%, respectively. In an oil spill region in the Persian Gulf, the mIOU and F1-score reach 81.34% and 89.62%, respectively, which are better than the metrics of the control model. Full article

Monitoring oil drift by integrating multi-source satellite imagery has been a relatively underexplored practice due to the limited time-sampling of datasets. However, this limitation has been mitigated by the emergence of new satellite constellations equipped with both Synthetic Aperture Radar (SAR) and optical sensors. In this manuscript, we take advantage of multi-temporal and multi-source satellite imagery, incorporating SAR (Sentinel-1 and ICEYE-X) and optical data (Sentinel-2/3 and Landsat-8/9), to provide insights into the spatio-temporal variations of oil spills. We also analyze the impact of met–ocean conditions on oil drift, focusing on two specific scenarios: marine floating oil slicks off the coast of Qatar and oil spills resulting from a shipwreck off the coast of Mauritius. By overlaying oils detected from various sources, we observe their short-term and long-term evolution. Our analysis highlights the finding that changes in oil structure and size are influenced by strong surface winds, while surface currents predominantly affect the spread of oil spills. Moreover, to detect oil slicks across different datasets, we propose an innovative unsupervised algorithm that combines a Bayesian approach used to detect oil and look-alike objects with an oil contours approach distinguishing oil from look-alikes. This algorithm can be applied to both SAR and optical data, and the results demonstrate its ability to accurately identify oil slicks, even in the presence of oil look-alikes and under varying met–ocean conditions. Full article

Detecting oil spills in marine environments is crucial for avoiding environmental damage and facilitating rapid response efforts. In this study, we propose a robust method for oil spill detection leveraging state-of-the-art (SOTA) deep learning techniques. We constructed an extensive dataset comprising images and frames extracted from video sourced from Google, significantly augmenting the dataset through frame extraction techniques. Each image is meticulously labeled to ensure high-quality training data. Utilizing the Yolov8 segmentation model, we trained our oil spill detection model to accurately identify and segment oil spills in ocean environments. K-means and Truncated Linear Stretching algorithms are combined with trained model weight to increase model detection accuracy. The model demonstrated exceptional performance, yielding high detection accuracy and precise segmentation capabilities. Our results indicate that this approach is highly effective for real-time oil spill detection, offering a promising tool for environmental monitoring and disaster management. In training metrics, the model reached over 97% accuracy in 100 epochs. In evaluation, model achieved its best detection rates by 94% accuracy in F1, 93.9% accuracy in Precision, and 95.5% [email protected] accuracy in Recall curves. Full article

With the development of the marine oil industry, leakage accidents are one of the most serious problems threatening maritime and national security. The spilt crude oil can float and sink in the water column, posing a serious long-term threat to the marine environment. High-frequency sonar detection is currently the most efficient method for identifying sunken oil. However, due to the complicated environment of the deep seabed and the interference of the sunken oil signals with homogeneous information, sonar detection data are usually difficult to interpret, resulting in low efficiency and a high failure rate. Previous works have focused on features designed by experts according to the detection environments and the identification of sunken oil targets regardless of the feature extraction step. To automatically identify sunken oil targets without a prior knowledge of the complex seabed conditions during the image acquisition process for sonar detection, a systematic framework is contrived for identifying sunken oil targets that combines image enhancement with a convolutional neural network (CNN) classifier for the final decision on sunken oil targets examined in this work. Case studies are conducted using datasets obtained from a sunken oil release experiment in an outdoor water basin. The experimental results show that (i) the method can effectively distinguish between the sunken oil target, the background, and the interference target; (ii) it achieved an identification accuracy of 83.33%, outperforming feature-based recognition systems, including SVM; and (iii) it provides important information about sunken oil such as the location of the leak, which is useful for decision-making in emergency response to oil spills at sea. This line of research offers a more robust and, above all, more objective option for the difficult task of automatically identifying sunken oils under complex seabed conditions. Full article

Oil spillages on a sea’s or an ocean’s surface are a threat to marine and coastal ecosystems. They are mainly caused by ship accidents, illegal discharge of oil from ships during cleaning and oil seepage from natural reservoirs. Synthetic-Aperture Radar (SAR) has proved to be a useful tool for analyzing oil spills, because it operates in all-day, all-weather conditions. An oil spill can typically be seen as a dark stretch in SAR images and can often be detected through visual inspection. The major challenge is to differentiate oil spills from look-alikes, i.e., low-wind areas, algae blooms and grease ice, etc., that have a dark signature similar to that of an oil spill. It has been noted over time that oil spill events in Pakistan’s territorial waters often remain undetected until the oil reaches the coastal regions or it is located by concerned authorities during patrolling. A formal remote sensing-based operational framework for oil spills detection in Pakistan’s Exclusive Economic Zone (EEZ) in the Arabian Sea is urgently needed. In this paper, we report the use of an encoder–decoder-based convolutional neural network trained on an annotated dataset comprising selected oil spill events verified by the European Maritime Safety Agency (EMSA). The dataset encompasses multiple classes, viz., sea surface, oil spill, look-alikes, ships and land. We processed Sentinel-1 acquisitions over the EEZ from January 2017 to December 2023, and we thereby prepared a repository of SAR images for the aforementioned duration. This repository contained images that had been vetted by SAR experts, to trace and confirm oil spills. We tested the repository using the trained model, and, to our surprise, we detected 92 previously unreported oil spill events within those seven years. In 2020, our model detected 26 oil spills in the EEZ, which corresponds to the highest number of spills detected in a single year; whereas in 2023, our model detected 10 oil spill events. In terms of the total surface area covered by the spills, the worst year was 2021, with a cumulative 395 sq. km covered in oil or an oil-like substance. On the whole, these are alarming figures. Full article

Oil spill detection plays an important role in marine environment protection. The technique of global navigation satellite system-reflectometry (GNSS-R) has the advantage of a short revisit time, which could help with timely cleanup of marine oil pollution. The conventional GNSS-R oil spill detection algorithm can resolve only the dielectric constant of oil based on power ratio measurements, while that of water cannot be realized. This is because the dielectric constant of water is much larger than that of oil such that the range of the equation used in the conventional algorithm is inadequate. To resolve this problem, we proposed a new algorithm containing a new equation with a larger scope, which has never been applied previously to GNSS-R oil spill detection. We derived a lookup method to resolve the dielectric constant of both oil and water. To validate our method, a drone-borne GNSS-R experiment based on dual-frequency QZSS reflection signals was conducted on 17 July 2023 using experimental pools simulating oil spills. Raw IF data in the L1 and L5 bands, collected using dual antennas and a data recorder, were processed using a software-defined receiver to deduce the power ratios and SNR of the GNSS signals. Results showed that the proposed algorithm is capable of resolving the dielectric constants of the reflected surface. In addition, the L5 signal was found to provide more detail and better contrast than the L1 C/A signal. Full article

Studying the fates of oil components and their interactions with ecological systems is essential for developing comprehensive management strategies and enhancing restoration following oil spill incidents. The potential expansion of Kazakhstan’s role in the global oil market necessitates the existence of land-specific studies that contribute to the field of bioremediation. In this study, a set of experiments was designed to assess the growth and biodegradation capacities of eight fungal strains sourced from Kazakhstan soil when exposed to the hydrocarbon substrates from which they were initially isolated. The strains were identified as Aspergillus sp. SBUG-M1743, Penicillium javanicum SBUG-M1744, SBUG-M1770, Trichoderma harzianum SBUG-M1750 and Fusarium oxysporum SBUG-1746, SBUG-M1748, SBUG-M1768 and SBUG-M1769 using the internal transcribed spacer (ITS) region. Furthermore, microscopic and macroscopic evaluations agreed with the sequence-based identification. Aspergillus sp. SBUG-M1743 and P. javanicum SBUG-M1744 displayed remarkable biodegradation capabilities in the presence of tetradecane with up to a 9-fold biomass increase in the static cultures. T. harzianum SBUG-M1750 exhibited poor growth, which was a consequence of its low efficiency of tetradecane degradation. Monocarboxylic acids were the main degradation products by SBUG-M1743, SBUG-M1744, SBUG-M1750, and SBUG-M1770 indicating the monoterminal degradation pathway through β-oxidation, while the additional detection of dicarboxylic acid in SBUG-M1768 and SBUG-M1769 cultures was indicative of the fungus’ ability to undertake both monoterminal and diterminal degradation pathways. F. oxysporum SBUG-M1746 and SBUG-M1748 in the presence of cyclohexanone showed a doubling of the biomass with the ability to degrade the substrate almost completely in shake cultures. F. oxysporum SBUG-M1746 was also able to degrade cyclohexane completely and excreted all possible metabolites of the degradation pathway. Understanding the degradation potential of these fungal isolates to different hydrocarbon substrates will help in developing effective bioremediation strategies tailored to local conditions. Full article

In the midst of a rapidly evolving economic landscape, the global demand for oil is steadily escalating. This increased demand has fueled marine extraction and maritime transportation of oil, resulting in a consequential and uneven surge in maritime oil spills. Characterized by their abrupt onset, rapid pollution dissemination, prolonged harm, and challenges in short-term containment, oil spill accidents pose significant economic and environmental threats. Consequently, it is imperative to adopt effective and reliable methods for timely detection of oil spills to minimize the damage inflicted by such incidents. Leveraging the YOLO deep learning network, this paper introduces a methodology for the automated detection of oil spill targets. The experimental data pre-processing incorporated denoise, grayscale modification, and contrast boost. Subsequently, realistic radar oil spill images were employed as extensive training samples in the YOLOv8 network model. The trained detection model demonstrated rapid and precise identification of valid oil spill regions. Ultimately, the oil films within the identified spill regions were extracted utilizing the simulated annealing particle swarm optimization (SA-PSO) algorithm. The proposed method for offshore oil spill survey presented here can offer immediate and valid data support for regular patrols and emergency reaction efforts. Full article

The detrimental impact of toxic chemicals, gas, and oil spills in aquatic environments poses a severe threat to plants, animals, and human life. Regions such as Cancer Alley exemplify the profound consequences of inadequately controlled chemical spills, significantly affecting the local community. Given the far-reaching effects of these spills, it has become imperative to devise an efficient method for early monitoring, estimation, and cleanup, utilizing affordable and effective techniques. In this research, we explore the application of U-shaped neural Network (UNET) and U-shaped neural network transformer (UNETR) neural network models designed for the image segmentation of chemical and oil spills. Our models undergo training using the Commonwealth Scientific and Industrial Research Organization (CSIRO) dataset and the Oil Spill Detection dataset, employing a specialized filtering technique to enhance detection accuracy. We achieved training accuracies of 95.35% and 91% by applying UNET on the Oil Spill and the CSIRO datasets after 50 epochs of training, respectively. We also achieved a training accuracy of 75% by applying UNETR to the Oil Spill dataset. Additionally, we integrated mixed precision to expedite the model training process, thus maximizing data throughput. To further accelerate our implementation, we propose the utilization of the Field Programmable Gate Array (FPGA) architecture. The results obtained from our study demonstrate improvements in inference latency on FPGA. Full article

Oil spills are a major threat to marine and coastal environments. Their unique radar backscatter intensity can be captured by synthetic aperture radar (SAR), resulting in dark regions in the images. However, many marine phenomena can lead to erroneous detections of oil spills. In addition, SAR images of the ocean include multiple targets, such as sea surface, land, ships, and oil spills and their look-alikes. The training of a multi-category classifier will encounter significant challenges due to the inherent class imbalance. Addressing this issue requires extracting target features more effectively. In this study, a lightweight U-Net-based model, Full-Scale Aggregated MobileUNet (FA-MobileUNet), was proposed to improve the detection performance for oil spills using SAR images. First, a lightweight MobileNetv3 model was used as the backbone of the U-Net encoder for feature extraction. Next, atrous spatial pyramid pooling (ASPP) and a convolutional block attention module (CBAM) were used to improve the capacity of the network to extract multi-scale features and to increase the speed of module calculation. Finally, full-scale features from the encoder were aggregated to enhance the network’s competence in extracting features. The proposed modified network enhanced the extraction and integration of features at different scales to improve the accuracy of detecting diverse marine targets. The experimental results showed that the mean intersection over union (mIoU) of the proposed model reached more than 80% for the detection of five types of marine targets including sea surface, land, ships, and oil spills and their look-alikes. In addition, the IoU of the proposed model reached 75.85 and 72.67% for oil spill and look-alike detection, which was 18.94% and 25.55% higher than that of the original U-Net model, respectively. Compared with other segmentation models, the proposed network can more accurately classify the black regions in SAR images into oil spills and their look-alikes. Furthermore, the detection performance and computational efficiency of the proposed model were also validated against other semantic segmentation models. Full article

Aircraft failures can result in the leakage of fuel, hydraulic oil, or other lubricants onto the runway during landing or taxiing. Damage to fuel tanks or oil lines during hard landings or accidents can also contribute to these spills. Further, improper maintenance or operational errors may leave oil traces on the runway before take-off or after landing. Identifying oil spills in airport runway videos is crucial to flight safety and accident investigation. Advanced image processing techniques can overcome the limitations of conventional RGB-based detection, which struggles to differentiate between oil spills and sewage due to similar coloration; given that oil and sewage have distinct spectral absorption patterns, precise detection can be performed based on multispectral images. In this study, we developed a method for spectrally enhancing RGB images of oil spills on airport runways to generate HSI images, facilitating oil spill detection in conventional RGB imagery. To this end, we employed the MST++ spectral reconstruction network model to effectively reconstruct RGB images into multispectral images, yielding improved accuracy in oil detection compared with other models. Additionally, we utilized the Fast R-CNN oil spill detection model, resulting in a 5% increase in Intersection over Union (IOU) for HSI images. Moreover, compared with RGB images, this approach significantly enhanced detection accuracy and completeness by 25.3% and 26.5%, respectively. These findings clearly demonstrate the superior precision and accuracy of HSI images based on spectral reconstruction in oil spill detection compared with traditional RGB images. With the spectral reconstruction technique, we can effectively make use of the spectral information inherent in oil spills, thereby enhancing detection accuracy. Future research could delve deeper into optimization techniques and conduct extensive validation in real airport environments. In conclusion, this spectral reconstruction-based technique for detecting oil spills on airport runways offers a novel and efficient approach that upholds both efficacy and accuracy. Its wide-scale implementation in airport operations holds great potential for improving aviation safety and environmental protection. Full article

There is a heightened risk of an oil spill occurring in the Arctic, as climate change driven sea ice loss permits an increase in Arctic marine transportation. The ability to detect an oil spill and monitor its progression is key to enacting an effective response. Microwave scatterometer systems may be used detect changes in sea ice thermodynamic and physical properties, so we examined the potential of C-band polarimetric radar for detecting diesel fuel beneath a thin sea ice layer. Sea ice physical properties, including thickness, temperature, and salinity, were measured before and after diesel addition beneath the ice. Time-series polarimetric C-band scatterometer measurements monitored the sea ice evolution and diesel migration to the sea ice surface. We characterized the temporal evolution of the diesel-contaminated seawater and sea ice by monitoring the normalized radar cross section (NRCS) and polarimetric parameters (conformity coefficient (μ), copolarization correlation coefficient (ρco)) at 20° and 25° incidence angles. We delineated three stages, with distinct NRCS and polarimetric results, which could be connected to the thermophysical state and the presence of diesel on the surface. Stage 1 described the initial formation of sea ice, while in Stage 2, we injected 20L of diesel beneath the sea ice. No immediate response was noted in the radar measurements. With the emergence of diesel on the sea ice surface, denoted by Stage 3, the NRCS dropped substantially. The largest response was for VV and HH polarizations at 20° incidence angle. Physical sampling indicated that diesel emerged to the surface of the sea ice and trended towards the tub edge and the polarimetric scatterometer was sensitive to these physical changes. This study contributes to a greater understanding of how C-band frequencies can be used to monitor oil products in the Arctic and act as a baseline for the interpretation of satellite data. Additionally, these findings will assist in the development of standards for oil and diesel fuel detection in the Canadian Arctic in association with the Canadian Standards Association Group. Full article