- Speaks fluent Italian, and lived in northern Italy for a few years in the early nineties.
- She started out as a dancer, but after an injury, attended and graduated from the Drama Centre in London.
- She has two children: Giorgio (born 1994) and Delilah (born 2000).
- Attended and graduated from Ballet Rambert School in Twickenham at age 16.
- Has worked with Ciaran Hinds and James Purefoy together three times, the trio first appeared in the Mayor of Casterbridge as the three principals before appearing in Rome and then John Carter.
- Appeared in a music video for The Quireboys - 'I don't love you anymore'.
- Frequent collaborator with Bruno Heller, who created Rome, The Mentalist and Pennyworth. Walker was a series lead in Rome and Pennyworth and had a special guest role in The Mentalist.
- Bridgerton reunites Walker with Ben Miller, who played her boyfriend in Jeffrey Archer: the truth. The pair are married in Bridgerton.
- Sister-in-law of Rupert Penry-Jones and Dervla Kirwan.
- Parents are Arthur Walker, runs a hotel, and Georgiana Walker, a school teacher.
- Has two sisters named Emma and Hannah and one brother named Daniel.
- Has worked with James Purefoy four times, Mayor of Casterbridge, Rome, John Carter and Pennyworth. In the first two, the Mayor of Casterbridge and Rome, the pair played lovers.
- Daughter-in-law of Peter Penry-Jones and Angela Thorne.
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