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WO2022136107A1 - Glazing having a light source - Google Patents

Glazing having a light source Download PDF

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Publication number
WO2022136107A1
WO2022136107A1 PCT/EP2021/086187 EP2021086187W WO2022136107A1 WO 2022136107 A1 WO2022136107 A1 WO 2022136107A1 EP 2021086187 W EP2021086187 W EP 2021086187W WO 2022136107 A1 WO2022136107 A1 WO 2022136107A1
Authority
WO
WIPO (PCT)
Prior art keywords
pane
glazing
light
metal
functional element
Prior art date
Application number
PCT/EP2021/086187
Other languages
German (de)
French (fr)
Inventor
Jefferson DO ROSARIO
Original Assignee
Saint-Gobain Glass France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint-Gobain Glass France filed Critical Saint-Gobain Glass France
Priority to CN202180005028.2A priority Critical patent/CN114981078A/en
Publication of WO2022136107A1 publication Critical patent/WO2022136107A1/en

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Classifications

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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/202Conductive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/402Coloured
    • B32B2307/4023Coloured on the layer surface, e.g. ink
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/41Opaque
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/416Reflective
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/538Roughness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2479/00Furniture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/08Cars
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/10Trains
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/12Ships
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033Means for improving the coupling-out of light from the light guide
    • G02B6/0035Means for improving the coupling-out of light from the light guide provided on the surface of the light guide or in the bulk of it
    • G02B6/00362-D arrangement of prisms, protrusions, indentations or roughened surfaces

Definitions

  • the present invention is in the technical field of pane production and relates to glazing with at least one pane and a light source for coupling light into the pane, as well as a method for producing the glazing. Furthermore, the invention relates to the use of the glazing according to the invention.
  • Glazing in buildings and vehicles is increasingly being provided with large, electrically conductive layers that are transparent to visible light and that have to fulfill certain functions.
  • These layers are usually metal-based, i.e. have at least one layer made of a metallic material, and are commonly referred to as functional layers.
  • low-E layers layers that reflect thermal radiation
  • a low-E layer reflects a significant part of the incoming solar radiation, especially in the infrared range, which leads to reduced heating of the interior in summer.
  • the Low-E layer also reduces the emission of long-wave thermal radiation from a heated pane into the interior when the Low-E layer is applied to the surface of a pane facing the interior. In winter, when outside temperatures are low, the heat from the interior is prevented from radiating to the outside environment.
  • Low-E layers for example based on niobium, tantalum, nickel, chromium, zirconium or alloys thereof, are well known to the person skilled in the art, for example from US7592068 B2, US7923131 B2 and WO2004076174 A1.
  • metal-based functional layers aims to keep the field of vision of a vehicle window free of ice and fog.
  • Electrical heating layers are known which cause targeted heating of the vehicle window by applying an electrical voltage (see, for example, WO 2010/043598 A1).
  • the metal-based functional layer is used as a planar antenna in motor vehicles.
  • the metal-based functional layer is galvanically or capacitively coupled to a coupling electrode and the antenna signal is made available in the edge area of the pane.
  • the antenna signal decoupled from the planar antenna is fed to an antenna amplifier, which is connected to the metal bodywork in motor vehicles, as a result of which a reference potential that is effective for high-frequency technology is specified for the antenna signal.
  • planar antennas are known, for example, from DE 10106125 A1, DE 10319606 A1, EP 0720249 A2, US 2003/0112190 A1 and DE 19843338 C2.
  • electro-optical functional elements are planar structures with electrically controllable optical properties of an active layer. This means that the optical properties of the active layer and in particular its transparency, scattering behavior or luminosity can be controlled by an electrical voltage.
  • Electro-optical functional elements such as SPD or PDLC functional elements
  • the active layer is arranged between two surface electrodes which are used to apply a voltage to control the active layer.
  • the two surface electrodes are arranged between two carrier foils, typically made of PET.
  • commercially available multilayer films are also covered on both sides with a protective film made of polypropylene or polyethylene, which serves to protect the carrier films from dirt or scratches.
  • the electro-optical functional element is cut out of the multilayer film in the desired size and shape and placed between the films of an intermediate layer, by means of which two glass panes are laminated together to form the laminated pane.
  • a typical application is windshields with electrically controllable sun visors, which are known, for example, from DE 102013001334 A1, DE 102005049081 B3, DE 102005007427 A1 and DE 102007027296 A1.
  • Devices for coupling light into a pane are known, for example, from WO 2015/101744 A1, WO 2015/118279 A1, WO 2016/102799 A1, WO 2016/102800 A1, WO 2019/105855 A1 or CN 109 606 251 A.
  • the object of the present invention is to provide improved glazing with a metal-based functional layer and/or an electro-optical functional element, the visibility of coupled-out light on an inside of the glazing preferably being improved.
  • the glazing should be simple and inexpensive to produce in industrial series production.
  • the method for producing the glazing should be easy and inexpensive to use in common production methods for panes.
  • a glazing comprises at least one pane, preferably a glass pane.
  • the glazing also has at least one light source arranged on the pane for coupling light into the pane, the pane having at least one light decoupling region for decoupling light that is totally reflected in the pane out of the pane.
  • the glazing and preferably the pane has at least one metal-based functional layer and/or at least one electro-optical functional element for electrically switching optical properties of the pane.
  • the metal-based functional layer is advantageously arranged directly on the pane or is connected to the pane via one or more, preferably polymeric, carrier and/or adhesive layers.
  • the electro-optical functional element is advantageously connected to the pane directly or via one or more, preferably polymeric, carrier and/or adhesive layers.
  • the adhesive layers can also contain or consist of optically transparent adhesives (so-called OCA, optically clear adhesive).
  • the contrast of the decoupled light through the at least one metal-based functional layer and / or the at least one electro-optical functional element for electrical switching of optical properties of the glazing and prefer the Disc can be improved in order to increase in particular the optical recognizability of information conveyed by the coupled-out light.
  • the light from the at least one light source is coupled into the pane, with the light source being arranged in a suitable manner relative to the pane for this purpose.
  • the at least one light source is preferably arranged to the side of the pane, i.e. at its edge, which enables good coupling of light into the pane. Equally preferred is the arrangement of the at least one light source in a recess or opening in the pane, which also enables good coupling of light into the pane.
  • the light coupled into the pane is totally reflected in the pane until it is coupled out of the pane at the at least one light decoupling region.
  • the at least one light decoupling region is designed to be suitable for decoupling light that is totally reflected in the pane.
  • the light decoupling area preferably has a higher roughness than areas of the pane that are not used for decoupling light that is totally reflected in the pane.
  • the at least one light decoupling region has a non-opaque paste that is printed and baked onto the surface of the pane.
  • the paste is at least semi-transparent or transparent for the light totally reflected in the pane.
  • the printed and burned-in paste increases the roughness of the pane so that light that is totally reflected in the pane can be effectively decoupled.
  • the at least one light decoupling region is formed by mechanically roughening the pane surface itself, for example by means of a laser. This measure can also be used to ensure that light that is totally reflected in the pane can be effectively decoupled.
  • the light can be coupled out on one or both sides of the pane.
  • the light is advantageously coupled out on a side of the pane which faces an interior space in the installed position.
  • the at least one electro-optical functional element is for the electrical switching of optical properties a Polymer Dispersed Liquid Crystal (PDLC) or a Suspended Particle Device (SPD) functional element), which is provided in particular in film form.
  • PDLC Polymer Dispersed Liquid Crystal
  • SPD Suspended Particle Device
  • electro-optical functional elements are well known to the person skilled in the art, so that they do not have to be discussed in more detail here.
  • electro-optical functional elements for electrical switching of optical properties give the pane a "milky" appearance, which, however, advantageously improves the contrast with respect to the light coupled out of the pane, so that the light coupled out by the the information conveyed becomes more recognizable.
  • the active layer contains liquid crystals embedded in a polymer network, with the functionality being otherwise analogous to that of the PDLC functional elements.
  • electrochromic functional elements or functional elements with liquid crystal dye cells so-called guest-host cells).
  • the at least one metal-based functional layer can in principle be formed in any way.
  • the at least one metal-based functional layer is designed to reflect thermal radiation at room temperature and in particular infrared radiation, which has longer wavelengths than the infrared component of solar radiation (so-called coating of low emissivity (Low-E coating)) and/or or to reflect or absorb incident infrared light, in particular the infrared portion of solar radiation. It is advantageously an electrically conductive coating that is transparent to visible light.
  • the metal-based functional layer can consist of an individual layer or layer made of the same material, it being equally possible for it to consist of several individual layers or layers made of at least two different materials.
  • the functional layer can thus consist of an individual layer or ply made of the same material.
  • the functional layer can consist of a number of individual layers or plies made of at least two different materials.
  • the metal-based functional layer is preferably applied to the pane over a large area.
  • the metal-based functional layer is arranged on a surface of the pane and covers or covers the surface of the pane completely or partially, but preferably over a large area.
  • the term “large area” means that at least 50%, at least 60%, at least 70%, at least 75% or preferably at least 90% of the surface of the pane is covered by the metal-based functional layer.
  • the metal-based functional layer can also extend over smaller portions of the surface of the pane.
  • the metal-based functional layer is an individual layer or a layer structure made up of several individual layers with a total thickness of, for example, less than or equal to 2 ⁇ m, preferably less than or equal to 1 ⁇ m.
  • the metal-based functional layer advantageously has a thickness of 80 nm to 1000 nm, in particular 80 nm to 600 nm, preferably 140 nm to 400 nm.
  • transparent means that the total transmission of the pane and in particular the glazing corresponds to the legal provisions for windshields and front side windows and preferably has a transmittance of more than 70% and in particular more than 75% for visible light.
  • transparent can also mean 10% to 70% light transmission.
  • opaque means a light transmission of less than 15%, preferably less than 5%, in particular 0%.
  • a transparent, electrically conductive functional layer contains at least one metal, for example silver, nickel, chromium, niobium, tin, titanium, copper, palladium, zinc, gold, cadmium, aluminum, silicon, tungsten or alloys thereof, and/or at least one metal oxide layer , preferably tin-doped indium oxide (ITO), aluminum-doped zinc oxide (AZO), fluorine-doped tin oxide (FTO, SnO2:F) or antimony-doped tin oxide (ATO, SnO2:Sb).
  • ITO indium oxide
  • AZO aluminum-doped zinc oxide
  • FTO, SnO2:F fluorine-doped tin oxide
  • ATO, SnO2:Sb antimony-doped tin oxide
  • a metal layer such as a silver layer or a layer of a metal alloy containing silver.
  • Typical silver layers preferably have thicknesses of 5 nm to 15 nm, more preferably 8 nm to 12 nm.
  • the metal layer may be sandwiched between at least two layers of metal oxide type dielectric material.
  • the metal oxide preferably includes zinc oxide, tin oxide, indium oxide, titanium oxide, silicon oxide, aluminum oxide, or the like, and combinations of one or more thereof. That dielectric material may also include silicon nitride, silicon carbide, aluminum nitride, and combinations of one or more of these.
  • Transparent, electrically conductive functional layers have, for example, a surface resistance of 0.1 ohms/square to 200 ohms/square, particularly preferably from 1 ohms/square to 50 ohms/square and very particularly preferably from 1 ohms/square to 10 ohms/square.
  • the transparent, electrically conductive functional layer serves as an antenna layer (surface antenna).
  • the metal-based functional layer is preferably a functional layer with a sun protection effect.
  • a layer with a sun protection effect has reflective properties in the infrared range and thus in the range of solar radiation, which advantageously reduces the heating of the interior of a building or motor vehicle as a result of solar radiation.
  • the TTS value of a composite vehicle pane provided with the coating is preferably less than 50%, particularly preferably less than 45%, very particularly preferably less than 40%.
  • the TTS value is the total transmitted solar energy, measured according to ISO 13837 - it is a measure of thermal comfort.
  • the coating can also be used as a heating coating if it is electrically contacted so that a current flows through it which heats the coating.
  • Functional layers with a sun protection effect are well known to the person skilled in the art and typically contain at least one metal, in particular silver or a silver-containing alloy.
  • the layer with a sun protection effect can comprise a sequence of several individual layers, in particular at least one metallic layer and dielectric layers, which contain at least one metal oxide, for example.
  • the metal oxide preferably includes zinc oxide, tin oxide, indium oxide, titanium oxide, silicon oxide, aluminum oxide, or the like, and combinations of one or more thereof.
  • the dielectric material contains silicon nitride, silicon carbide or aluminum nitride, for example.
  • Layers with a sun protection effect are known, for example, from DE 102009006062 A1, WO 2007/101964 A1, EP 0 912 455 B1, DE 199 27 683 C1, EP 1 218 307 B1 and EP 1 917 222 B1.
  • the thickness of a functional layer with a sun protection effect can vary widely and be adapted to the requirements of the individual case, with a layer thickness of 10 nm to 5 ⁇ m and in particular from 30 nm to 1 ⁇ m being preferred.
  • the surface resistance of a Functional layer with sun protection effect is preferably from 0.35 ohms/square to 200 ohms/square, preferably from 0.5 ohms/square to 200 ohms/square, very particularly preferably from 0.6 ohms/square to 30 ohms/square, and in particular from 2 ohms/square to 20 ohms/square.
  • the metal-based functional layer with a sun protection effect has, for example, good infrared-reflecting properties and/or particularly low emissivities (Low-E).
  • the metal-based functional layer can also be an electrically heatable layer, for example, which provides the pane with a heating function.
  • heatable layers are known per se to those skilled in the art. They typically contain one or more, for example two, three or four, electrically conductive layers. These layers preferably contain or consist of at least one metal, for example silver, gold, copper, nickel and/or chromium, or a metal alloy and preferably contain at least 90% by weight of the metal, in particular at least 99.9% by weight of the metal .
  • Such layers have a particularly advantageous electrical conductivity combined with high transmission in the visible spectral range.
  • the thickness of an individual layer is preferably from 5 nm to 50 nm, particularly preferably from 8 nm to 25 nm. With such a thickness, an advantageously high transmission in the visible spectral range and a particularly advantageous electrical conductivity are achieved.
  • the metal-based functional layer is deposited by methods known per se, for example by cathode sputtering supported by a magnetic field, which is particularly advantageous with regard to a simple, fast, inexpensive and uniform coating of the pane.
  • the cathode sputtering takes place in a protective gas atmosphere, for example argon, or in a reactive gas atmosphere, for example by adding oxygen, a hydrocarbon (for example methane) or nitrogen.
  • the metal-based functional layer can also be applied by other methods known to those skilled in the art, for example by vapor deposition or chemical vapor deposition (CVD), by atomic layer deposition (ALD), by plasma-enhanced vapor deposition (PECVD) or by wet-chemical methods .
  • the at least one pane contains or consists of non-tempered, partially tempered or tempered glass, preferably flat glass, float glass, quartz glass, borosilicate glass, soda-lime glass.
  • the disc includes or consists of clear plastics, preferably rigid clear plastics, in particular polyethylene, polypropylene, polycarbonate, polymethyl methacrylate, polystyrene, polyamide, polyester, polyvinyl chloride and/or mixtures thereof. Suitable glasses are known, for example, from EP 0847965 B1.
  • the thickness of the at least one pane can vary widely and can be adapted to the requirements of the individual case.
  • a disk with a standard thickness of 1.0 mm to 25 mm is used.
  • the thickness is from 0.5 mm to 15 mm, in particular from 1 mm to 5 mm.
  • the size of the disc can vary widely and depends on the use.
  • the at least one pane can have any three-dimensional shape.
  • the disk is planar or slightly or greatly curved in one or more directions of space.
  • the pane In a bending process, the pane is bent in one or more directions in space while it is heated.
  • the temperature to which the disk is heated is preferably from 500°C to 700°C. It goes without saying that further thermal treatment steps of the pane can take place before or after the bending process.
  • the disc can be colorless or colored.
  • the glazing according to the invention preferably serves to separate an interior space from an exterior environment.
  • the glazing comprises at least one pane.
  • the glazing can in principle be of any design, in particular as insulating glazing, in which at least two panes are arranged at a distance from one another by at least one spacer, or as thermally toughened single-pane safety glass or as a laminated pane.
  • the glazing is preferably designed as a composite pane and comprises a first pane with an outside and inside and a second pane with an inside and outside, which are firmly connected to one another by at least one thermoplastic intermediate layer (adhesive layer).
  • the first pane can also be referred to as an outer pane or inner pane, and the second pane accordingly as an inner pane or outer pane.
  • the surfaces or sides of the two individual panes usually turn from the outside inwards referred to as Page I, Page II, Page III and Page IV.
  • the two inner sides of the panes are firmly connected to one another by the at least one thermoplastic adhesive layer.
  • the thermoplastic intermediate layer contains or consists of at least one thermoplastic, preferably polyvinyl butyral (PVB), ethylene vinyl acetate (EVA) and/or polyethylene terephthalate (PET).
  • the thermoplastic intermediate layer can also be, for example, polyurethane (PU), polypropylene (PP), polyacrylate, polyethylene (PE), polycarbonate (PC), polymethyl methacrylate, polyvinyl chloride, polyacetate resin, cast resin, acrylate, fluorinated ethylene propylene, polyvinyl fluoride and/or ethylene Tetrafluoroethylene, or a copolymer or mixture thereof.
  • the thermoplastic intermediate layer can be formed by one or more thermoplastic films arranged one on top of the other, the thickness of a thermoplastic film being, for example, from 0.25 mm to 1 mm.
  • the at least one light decoupling region for decoupling from the pane light that is totally reflected in the pane is formed on the outside of the first pane and/or on the outside of the second pane.
  • the at least one light coupling-out area is preferably formed on the outside of that pane (i.e. inner pane) which faces an interior space (e.g. second pane).
  • the at least one electro-optical functional element is advantageously arranged between the first pane and the second pane, so that it is well protected from external influences.
  • the at least one metal-based functional layer which is designed to reflect or absorb incident infrared light, is arranged between the first pane and the second pane, which also means that it is well protected from external influences.
  • the at least one metal-based functional layer which is designed to reflect thermal radiation at room temperature, is advantageously arranged on the outside of the second pane, which faces an interior space. This enables this functional layer to function particularly well.
  • the invention also extends to a method for producing the glazing according to the invention.
  • the above statements in connection with the glazing apply equally to the method according to the invention.
  • the method includes providing at least one pane and arranging at least one metal-based functional layer and/or at least one electro-optical one Functional element for electrical switching of optical properties.
  • the method also includes generating at least one light decoupling region for decoupling light that is totally reflected in the pane out of the pane.
  • At least one opening or cutout for receiving at least one light source is produced in the pane.
  • the at least one light decoupling region is produced by removing the metal-based functional layer from the pane using a laser. This measure not only allows the metal-based functional layer to be removed in the light decoupling area, but also the surface of the pane to be roughened at the same time.
  • a first pane with the outside and inside and a second pane with the inside and outside, with the insides of the two panes facing each other are firmly connected to one another by at least one thermoplastic intermediate layer.
  • the method according to the invention for producing a glazing preferably serves to produce a laminated pane.
  • a composite pane at least two panes are connected (laminated) to one another, preferably under the action of heat, vacuum and/or pressure, by at least one thermoplastic adhesive layer.
  • Methods known per se can be used to produce a laminated pane. For example, so-called autoclave processes can be carried out at an increased pressure of about 10 bar to 15 bar and temperatures of 130° C. to 145° C. for about 2 hours.
  • Known vacuum bag or vacuum ring methods work, for example, at about 200 mbar and 130°C to 145°C.
  • the two panes and the thermoplastic intermediate layer can also be pressed in a calender between at least one pair of rollers to form a composite pane.
  • Plants of this type are known for the production of laminated panes and normally have at least one heating tunnel in front of a pressing plant.
  • the temperature during the pressing process is, for example, from 40°C to 150°C.
  • Combinations of calender and autoclave processes have proven particularly useful in practice.
  • vacuum laminators can be used. These consist of one or more heatable and evacuable chambers in which the first pane and the second pane within for example about 60 minutes at reduced pressures of 0.01 mbar to 800 mbar and temperatures of 80°C to 170°C.
  • the glazing according to the invention is preferably used in buildings, in particular in the access or window area, as a built-in part in furniture and appliances, or in means of transport for traffic on land, in the air or on water, in particular in trains, ships and motor vehicles, for example as a windscreen, rear window, Side window and/or roof window used.
  • FIG. 1 shows a schematic representation of a glazing
  • FIG. 4 shows an illustration of a pane with light decoupling areas.
  • the glazing 100 comprises a light source 101 arranged on the side for coupling light into a pane 103-2.
  • the light source 101 can be formed, for example, by a light-emitting diode (LED), which is arranged in the area next to the pane 103-2.
  • the light source 101 can be arranged in a recess or opening in the pane 103-2.
  • the radiation from the light source 101 can be coupled directly into the pane 103-2 or also via a reflection element 115, so that the light source 101 can also be arranged outside the plane of the pane 103-2.
  • the disk 103-2 comprises a lateral light coupling region 117, which is formed by the lateral edge of the disk 103-2.
  • the light decoupling area 105 is, for example, a light-diffusing coating, e.g. in the form of a paste applied in a screen printing process and burned in, which is applied to the pane 103-2 in this area or is integrated in the surface of the pane 103-2.
  • the disc 103-2 has an outside 109-1 and an inside 109-2.
  • the glazing 100 includes a further pane 103-1, which also has an outside 109-4 and an inside 109-3.
  • Disk 103-1 is bonded to disk 103-2 via an intervening polyvinyl butyral (PVB) layer, for example.
  • PVB polyvinyl butyral
  • a composite pane is created by connecting and laminating the two panes 103-1, 103-2. In general, the light extraction can take place on both sides of the disk 103-2.
  • An opaque cover layer 119 is additionally formed between the two panes 103 - 1 and 103 - 2 in the area of the light source 101 . This covering layer 119 prevents the light from the light source 101 from radiating directly to the outside.
  • the pane 103-2 includes a metal-based functional layer 107-1, which is arranged on the outside 109-1 of the pane 103-2.
  • the metal-based functional layer 107-1 is, for example, a LowE coating that is suitable for reflecting thermal radiation at room temperature.
  • the LowE coating is, for example, a multilayer with layers based on indium tin oxide (ITO), antimony-doped tin oxide (ATO) or fluorine-doped tin oxide (FTO).
  • the thermal comfort of the glazing 100 is increased by this metal-based functional layer 107-1.
  • the use of mechanical shutter technologies within the glazing 100 can be dispensed with. This achieves a simpler structure that does not require complicated mechanical devices.
  • the headroom in vehicles is increasing and there is more freedom to use the glass as a design element.
  • the two panes 103-1 and 103-2 can, for example, be non-tempered, partially tempered or tempered glass, preferably flat glass, float glass, quartz glass, borosilicate glass, soda-lime glass or clear plastics, preferably rigid clear plastics, in particular polyethylene, polypropylene, polycarbonate, polymethyl methacrylate , Polystyrene, polyamide, polyester, polyvinyl chloride and/or mixtures thereof and preferably have a thickness of 0.5 mm to 15 mm, particularly preferably 1 mm to 5 mm.
  • FIG. 2 shows another schematic representation of a glazing 100.
  • the structure of the glazing 100 corresponds to that shown in FIG.
  • the glazing 100 on the inside 109-2 of the pane 103-2 or on the inside 109-3 of the pane 103-1 includes a metal-based functional layer 107-2 or 107-3 for reflecting or absorbing infrared radiation (IRR - Infrared Reflective) .
  • the metal-based functional layer 107-2 or 107-3 comprises, for example, one or more metal layers, in particular silver layers.
  • metal-based functional layers 107-2 or 107-3 have increased reflection in the visible spectrum and serve to ensure that the light coupled out is less visible on the outside 109-4 of the pane 103-1, since the coatings 107-2 and 107 -3 have a higher reflection than the glass in the visible range.
  • the metal-based functional layer 107-1, 107-2, or 107-3 can have a thickness of 80 nm to 1000 nm, preferably 140 nm to 400 nm or preferably 700 nm to 900 nm.
  • FIG. 3 shows a further schematic representation of a glazing 100.
  • the structure of the glazing 100 corresponds to that shown in FIG.
  • the glazing 100 comprises a functional element 111 with electrically switchable optical properties, such as a switchable film.
  • the functional element 111 comprises, for example, a PDLC element or an SPD element or a combination of these.
  • the functional element 111 is arranged between the two discs 103-1 and 103-2.
  • the functional element 111 changes a light transmission (Light Transmission - TL) of the glazing 100, a color in the transmission (a*, b*) or a contrast between an extracted light pattern and the glaze. This makes the light pattern more visible, so that a contrast between the light pattern and the background is higher during the day.
  • shutter technologies can be avoided and light patterns can be darkened towards the outside and become more visible towards the inside.
  • 4 shows an illustration of a pane 103-2 with light decoupling regions 105.
  • a light-diffusing coating (light diffusing enamel) can be used to form the light decoupling regions 105 in order to scatter the light from the pane 103-2 to the outside.
  • a metal-based functional layer 107-1 such as a LowE coating
  • a metal-based functional layer 107-2 such as an IRR coating
  • a laser 113 can be used to create a light extraction region 105 .
  • the light decoupling region 105 produced in this way also ensures transparency in the high-frequency range (HF—High Frequency), so that mobile phone radiation can penetrate through the glazing 100 .
  • a LowE coating on the outside 109-1 of an extra-clear pane 103-2 can be removed in certain areas by means of the laser 113 in order to produce the light decoupling area 105 for the light pattern.
  • the disk 103-2 becomes transparent and transmissive to high-frequency electrical vibrations at the same time.
  • an IRR coating 107-3 is also used on the inside 109-3 of the pane 103-1, there is no transmission of high-frequency radiation.
  • the inside 109-2 of the extra-clear pane 103-2 can be provided with an IRR coating 107-2.
  • the IRR coating 107-2 is removed in regions by means of the laser 113 in order to produce the light decoupling region 105 for the light pattern.
  • the pane 103-2 is simultaneously transparent and permeable to high-frequency electrical vibrations.
  • the technical advantage achieved by the glazing 100 is that the visibility of light patterns in one direction (inwards), which are generated by the decoupled light, is increased. In contrast, the visibility of light patterns in the other direction (outward) is reduced.
  • the glazing 100 can be used, for example, as a laminated pane in an automobile or as a pane in a building. reference list

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Abstract

The present invention relates to a glazing (100), comprising - at least one pane (103-2), in particular a glass pane, - at least one light source (101) arranged at the pane (103-2) for coupling light into the pane (103-2), the pane (103-2) having at least one light-decoupling region (105) for decoupling light from the pane (103-2), which has been totally reflected by the pane (103-2), wherein the glazing (100) and preferably the pane (103-2) comprises at least one metal-based functional layer (107-1, 107-2, 107-3) and/or at least one electrooptical functional element (111) for electrically switching optical properties.

Description

Verglasung mit Lichtquelle Glazing with light source
Die vorliegende Erfindung liegt auf dem technischen Gebiet der Scheibenherstellung und betrifft eine Verglasung mit mindestens einer Scheibe und einer Lichtquelle zum Einkoppeln von Licht in die Scheibe, sowie ein Verfahren zum Herstellen der Verglasung. Des Weiteren betrifft die Erfindung die Verwendung der erfindungsgemäßen Verglasung. The present invention is in the technical field of pane production and relates to glazing with at least one pane and a light source for coupling light into the pane, as well as a method for producing the glazing. Furthermore, the invention relates to the use of the glazing according to the invention.
Verglasungen in Gebäuden und Fahrzeugen werden zunehmend mit großflächigen, elektrisch leitfähigen und für sichtbares Licht transparenten Schichten versehen, die bestimmte Funktionen zu erfüllen haben. Diese Schichten sind in aller Regel metallbasiert, d.h. weisen zumindest eine Schicht aus einem metallischen Material auf, und werden gemeinhin als Funktionsschichten bezeichnet. Glazing in buildings and vehicles is increasingly being provided with large, electrically conductive layers that are transparent to visible light and that have to fulfill certain functions. These layers are usually metal-based, i.e. have at least one layer made of a metallic material, and are commonly referred to as functional layers.
Beispielsweise werden aus Gründen der Energieeinsparung und des Komforts an Verglasungen hohe Anforderungen bezüglich ihrer wärmeisolierenden Eigenschaften gestellt. So ist es wünschenswert, einen hohen Wärmeeintrag durch Sonneneinstrahlung zu vermeiden, was zu einem übermäßigen Aufheizen des Innenraums führt und wiederum hohe Energiekosten für die notwendige Klimatisierung zur Folge hat. For example, high demands are placed on glazing with regard to its heat-insulating properties for reasons of energy saving and comfort. So it is desirable to avoid a high heat input through solar radiation, which leads to excessive heating of the interior and in turn results in high energy costs for the necessary air conditioning.
Bekannt ist auch die Verwendung von Wärmestrahlung reflektierenden Schichten (Low-E- Schichten). Eine Low-E-Schicht reflektiert einen erheblichen Teil der einfallenden Sonnenstrahlung, vor allem im Infrarotbereich, was im Sommer zu einer verringerten Erwärmung des Innenraums führt. Die Low-E-Schicht verringert außerdem die Aussendung von langwelliger Wärmestrahlung einer erwärmten Scheibe in den Innenraum hinein, wenn die Low-E-Schicht auf der dem Innenraum zugewandten Oberfläche einer Scheibe aufgebracht ist. Im Winter wird bei niedrigen Außentemperaturen die Abstrahlung der Wärme des Innenraums an die äußere Umgebung verhindert. Low-E-Schichten beispielsweise auf Basis von Niob, Tantal, Nickel, Chrom, Zirkonium oder Legierungen daraus, sind dem Fachmann wohlbekannt, beispielsweise aus US7592068 B2, US7923131 B2 und W02004076174 A1. The use of layers that reflect thermal radiation (low-E layers) is also known. A low-E layer reflects a significant part of the incoming solar radiation, especially in the infrared range, which leads to reduced heating of the interior in summer. The Low-E layer also reduces the emission of long-wave thermal radiation from a heated pane into the interior when the Low-E layer is applied to the surface of a pane facing the interior. In winter, when outside temperatures are low, the heat from the interior is prevented from radiating to the outside environment. Low-E layers, for example based on niobium, tantalum, nickel, chromium, zirconium or alloys thereof, are well known to the person skilled in the art, for example from US7592068 B2, US7923131 B2 and WO2004076174 A1.
Eine andere Anwendung von metallbasierten Funktionsschichten zielt darauf ab, das Sichtfeld einer Fahrzeugscheibe frei von Eis und Beschlag zu halten. Bekannt sind elektrische Heizschichten, die durch Anlegen einer elektrischen Spannung eine gezielte Erwärmung der Fahrzeugscheibe bewirken (siehe z.B. WO 2010/043598 A1). Bei einer weiteren Anwendung wird die metallbasierte Funktionsschicht als Flächenantenne in Kraftfahrzeugen eingesetzt. Dazu wird die metallbasierte Funktionsschicht mit einer Koppelelektrode galvanisch oder kapazitiv gekoppelt und das Antennensignal im Randbereich der Scheibe zur Verfügung gestellt. Das von der Flächenantenne ausgekoppelte Antennensignal wird einem Antennenverstärker zugeführt, der in Kraftfahrzeugen mit der metallischen Karosserie verbunden ist, wodurch ein hochfrequenztechnisch wirksames Bezugspotenzial für das Antennensignal vorgegeben wird. Derartige Flächenantennen sind beispielsweise aus DE 10106125 A1 , DE 10319606 A1 , EP 0720249 A2, US 2003/0112190 A1 und DE 19843338 C2 bekannt. Another application of metal-based functional layers aims to keep the field of vision of a vehicle window free of ice and fog. Electrical heating layers are known which cause targeted heating of the vehicle window by applying an electrical voltage (see, for example, WO 2010/043598 A1). In a further application, the metal-based functional layer is used as a planar antenna in motor vehicles. For this purpose, the metal-based functional layer is galvanically or capacitively coupled to a coupling electrode and the antenna signal is made available in the edge area of the pane. The antenna signal decoupled from the planar antenna is fed to an antenna amplifier, which is connected to the metal bodywork in motor vehicles, as a result of which a reference potential that is effective for high-frequency technology is specified for the antenna signal. Such planar antennas are known, for example, from DE 10106125 A1, DE 10319606 A1, EP 0720249 A2, US 2003/0112190 A1 and DE 19843338 C2.
Bekannt ist auch die Verwendung von elektrooptischen Funktionselementen. Hierbei handelt es sich um flächenhafte Strukturen mit elektrisch regelbaren optischen Eigenschaften einer aktiven Schicht. Das heißt, die optischen Eigenschaften der aktiven Schicht und insbesondere deren Transparenz, Streuverhalten oder Leuchtkraft sind durch eine elektrische Spannung steuerbar. Beispiele für elektrooptische Funktionselemente sind SPD-Funktionselemente (SPD = Suspended Particle Device), die beispielsweise aus EP 0876608 B1 und WO 2011033313 A1 bekannt sind, und PDLC-Funktionselemente (PDLC = Polymer Dispersed Liquid Crystal), die beispielsweise aus DE 102008026339 A1 bekannt sind. The use of electro-optical functional elements is also known. These are planar structures with electrically controllable optical properties of an active layer. This means that the optical properties of the active layer and in particular its transparency, scattering behavior or luminosity can be controlled by an electrical voltage. Examples of electro-optical functional elements are SPD functional elements (SPD=Suspended Particle Device), which are known, for example, from EP 0876608 B1 and WO 2011033313 A1, and PDLC functional elements (PDLC=Polymer Dispersed Liquid Crystal), which are known for example from DE 102008026339 A1 .
Elektrooptische Funktionselemente, wie SPD- oder PDLC-Funktionselemente, sind als Mehrschichtfolie kommerziell erhältlich, wobei die aktive Schicht zwischen zwei Flächenelektroden angeordnet ist, die zum Anlegen einer Spannung zur Steuerung der aktiven Schicht dienen. In aller Regel sind die beiden Flächenelektroden zwischen zwei Trägerfolien, typischerweise aus PET, angeordnet. Kommerziell erhältliche Mehrschichtfolien werden zudem beidseitig mit einer Schutzfolie aus Polypropylen oder Polyethylen abgedeckt, welche dazu dienen, die Trägerfolien vor Verschmutzungen oder Verkratzungen zu schützen. Insbesondere bei der Herstellung einer Verbundscheibe wird das elektrooptische Funktionselement in der gewünschten Größe und Form aus der Mehrschichtfolie ausgeschnitten und zwischen die Folien einer Zwischenschicht eingelegt, mittels derer zwei Glasscheiben miteinander zur Verbundscheibe laminiert werden. Eine typische Anwendung sind Windschutzscheiben mit elektrisch regelbaren Sonnenblenden, welche beispielsweise aus DE 102013001334 A1 , DE 102005049081 B3, DE 102005007427 A 1 und DE 102007027296 A1 bekannt sind. Vorrichtungen zum Einkoppeln von Licht in eine Scheibe sind beispielsweise aus WO 2015/101744 A1 , WO 2015/118279 A1 , WO 2016/102799 A1 , WO 2016/102800 A1 , WO 2019/105855 A1 oder CN 109 606 251 A bekannt. Electro-optical functional elements, such as SPD or PDLC functional elements, are commercially available as a multilayer film, with the active layer being arranged between two surface electrodes which are used to apply a voltage to control the active layer. As a rule, the two surface electrodes are arranged between two carrier foils, typically made of PET. Commercially available multilayer films are also covered on both sides with a protective film made of polypropylene or polyethylene, which serves to protect the carrier films from dirt or scratches. Particularly when producing a laminated pane, the electro-optical functional element is cut out of the multilayer film in the desired size and shape and placed between the films of an intermediate layer, by means of which two glass panes are laminated together to form the laminated pane. A typical application is windshields with electrically controllable sun visors, which are known, for example, from DE 102013001334 A1, DE 102005049081 B3, DE 102005007427 A1 and DE 102007027296 A1. Devices for coupling light into a pane are known, for example, from WO 2015/101744 A1, WO 2015/118279 A1, WO 2016/102799 A1, WO 2016/102800 A1, WO 2019/105855 A1 or CN 109 606 251 A.
Demgegenüber besteht die Aufgabe der vorliegenden Erfindung darin, eine verbesserte Verglasung mit einer metallbasierten Funktionsschicht und/oder einem elektrooptischen Funktionselement zur Verfügung zu stellen, wobei vorzugsweise die Sichtbarkeit von ausgekoppeltem Licht auf einer Innenseite der Verglasung verbessert werden soll. Die Verglasung soll in der industriellen Serienfertigung einfach und kostengünstig herzustellen sein. Zudem soll das Verfahren zur Herstellung der Verglasung in gängigen Herstellungsverfahren von Scheiben einfach und kostengünstig einsetzbar sein. In contrast, the object of the present invention is to provide improved glazing with a metal-based functional layer and/or an electro-optical functional element, the visibility of coupled-out light on an inside of the glazing preferably being improved. The glazing should be simple and inexpensive to produce in industrial series production. In addition, the method for producing the glazing should be easy and inexpensive to use in common production methods for panes.
Diese und weitere Aufgaben werden nach dem Vorschlag der Erfindung durch eine Verglasung und deren Herstellung gemäß den nebengeordneten Patentansprüchen gelöst. Vorteilhafte Ausgestaltungen der Erfindung ergeben sich aus den Unteransprüchen. According to the proposal of the invention, these and other objects are achieved by a glazing and its production according to the independent patent claims. Advantageous configurations of the invention result from the dependent claims.
Erfindungsgemäß ist eine Verglasung gezeigt. Die Verglasung umfasst mindestens eine Scheibe, bevorzugt eine Glasscheibe. Die Verglasung verfügt weiterhin über mindestens eine an der Scheibe angeordnete Lichtquelle zum Einkoppeln von Licht in die Scheibe, wobei die Scheibe mindestens einen Lichtauskoppelbereich zum Auskoppeln von in der Scheibe total reflektierten Lichts aus der Scheibe aufweist. Zudem weist die Verglasung und bevorzugt die Scheibe mindestens eine metallbasierte Funktionsschicht und/oder mindestens ein elektrooptisches Funktionselement zum elektrischen Schalten von optischen Eigenschaften der Scheibe auf. According to the invention, a glazing is shown. The glazing comprises at least one pane, preferably a glass pane. The glazing also has at least one light source arranged on the pane for coupling light into the pane, the pane having at least one light decoupling region for decoupling light that is totally reflected in the pane out of the pane. In addition, the glazing and preferably the pane has at least one metal-based functional layer and/or at least one electro-optical functional element for electrically switching optical properties of the pane.
Vorteilhafterweise ist die metallbasierte Funktionsschicht unmittelbar auf der Scheibe angeordnet oder über eine oder mehrere, bevorzugt polymere, Träger- und/oder Klebeschichten mit der Scheibe verbunden. Vorteilhafterweise ist das elektrooptische Funktionselement mit der Scheibe unmittelbar oder über eine oder mehrere, bevorzugt polymere, Träger- und/oder Klebeschichten verbunden. Die Klebeschichten können auch optische transparente Kleber (sogenannte OCA, optical clear adhesive) enthalten oder daraus bestehen. The metal-based functional layer is advantageously arranged directly on the pane or is connected to the pane via one or more, preferably polymeric, carrier and/or adhesive layers. The electro-optical functional element is advantageously connected to the pane directly or via one or more, preferably polymeric, carrier and/or adhesive layers. The adhesive layers can also contain or consist of optically transparent adhesives (so-called OCA, optically clear adhesive).
In vorteilhafter Weise kann der Kontrast des ausgekoppelten Lichts durch die mindestens eine metallbasierte Funktionsschicht und/oder das mindestens eine elektrooptische Funktionselement zum elektrischen Schalten von optischen Eigenschaften der Verglasung und bevorzgut der Scheibe verbessert werden, um so insbesondere die optische Erkennbarkeit einer durch das ausgekoppelte Licht vermittelten Information zu erhöhen. Advantageously, the contrast of the decoupled light through the at least one metal-based functional layer and / or the at least one electro-optical functional element for electrical switching of optical properties of the glazing and prefer the Disc can be improved in order to increase in particular the optical recognizability of information conveyed by the coupled-out light.
Das Licht der mindestens einen Lichtquelle wird in die Scheibe eingekoppelt, wobei die Lichtquelle zu diesem Zweck in geeigneter Weise relativ zur Scheibe angeordnet ist. Vorzugsweise ist die mindestens eine Lichtquelle seitlich zur Scheibe, d.h. an deren Kante, angeordnet, was eine gute Einkopplung von Licht in die Scheibe ermöglicht. Gleichermaßen bevorzugt ist die Anordnung der mindestens einen Lichtquelle in einer Aussparung oder Durchbrechung der Scheibe, was ebenso eine gute Einkopplung von Licht in die Scheibe ermöglicht. Das in die Scheibe eingekoppelte Licht wird in der Scheibe totalreflektiert, bis es an dem mindestens einen Lichtauskoppelbereich aus der Scheibe ausgekoppelt wird. The light from the at least one light source is coupled into the pane, with the light source being arranged in a suitable manner relative to the pane for this purpose. The at least one light source is preferably arranged to the side of the pane, i.e. at its edge, which enables good coupling of light into the pane. Equally preferred is the arrangement of the at least one light source in a recess or opening in the pane, which also enables good coupling of light into the pane. The light coupled into the pane is totally reflected in the pane until it is coupled out of the pane at the at least one light decoupling region.
Der mindestens eine Lichtauskoppelbereich ist zum Auskoppeln von in der Scheibe totalreflektierten Lichts geeignet ausgebildet. Der Lichtauskoppelbereich weist zu diesem Zweck bevorzugt eine höhere Rauigkeit auf, als Bereiche der Scheibe, die nicht zum Auskoppeln von in der Scheibe totalreflektierten Lichts dienen. The at least one light decoupling region is designed to be suitable for decoupling light that is totally reflected in the pane. For this purpose, the light decoupling area preferably has a higher roughness than areas of the pane that are not used for decoupling light that is totally reflected in the pane.
Gemäß einer bevorzugten Ausgestaltung der erfindungsgemäßen Verglasung weist der mindestens eine Lichtauskoppelbereich eine auf die Scheibenoberfläche aufgedruckte und eingebrannte, nicht-opake Paste auf. Die Paste ist zumindest semi-transparent oder transparent für das in der Scheibe total reflektierte Licht. Die aufgedruckte und eingebrannte Paste erhöht die Rauigkeit der Scheibe, so dass in der Scheibe totalreflektiertes Licht effektiv ausgekoppelt werden kann. According to a preferred embodiment of the glazing according to the invention, the at least one light decoupling region has a non-opaque paste that is printed and baked onto the surface of the pane. The paste is at least semi-transparent or transparent for the light totally reflected in the pane. The printed and burned-in paste increases the roughness of the pane so that light that is totally reflected in the pane can be effectively decoupled.
Gemäß einer weiteren bevorzugten Ausgestaltung der erfindungsgemäßen Verglasung ist der mindestens eine Lichtauskoppelbereich durch mechanisches Aufrauen der Scheibenoberfläche selbst, beispielsweise mittels eines Lasers, ausgebildet. Auch durch diese Maßnahme kann erreicht werden, dass in der Scheibe totalreflektiertes Licht effektiv ausgekoppelt werden kann. According to a further preferred embodiment of the glazing according to the invention, the at least one light decoupling region is formed by mechanically roughening the pane surface itself, for example by means of a laser. This measure can also be used to ensure that light that is totally reflected in the pane can be effectively decoupled.
Das Auskoppeln des Lichts kann auf einer oder beiden Seiten der Scheibe erfolgen. Vorteilhaft erfolgt die Lichtauskopplung auf einer Scheibenseite, welche in Einbaulage einem Innenraum zugewandt ist. The light can be coupled out on one or both sides of the pane. The light is advantageously coupled out on a side of the pane which faces an interior space in the installed position.
Gemäß einer bevorzugten Ausgestaltung der erfindungsgemäßen Verglasung ist das mindestens eine elektrooptische Funktionselement zum elektrischen Schalten von optischen Eigenschaften ein Polymer Dispersed Liquid Crystal (PDLC)- oder ein Suspended Particle Device (SPD)- Funktionselement) ist, welches insbesondere in Folienform bereitgestellt wird. Wie eingangs bereits erläutert, sind solche elektrooptischen Funktionselemente dem Fachmann wohlbekannt, so dass hier nicht näher darauf eingegangen werden muss. In der Praxis zeigt sich, dass elektrooptische Funktionselemente zum elektrischen Schalten von optischen Eigenschaften der Scheibe eine "milchige" Anmutung geben, wodurch jedoch in vorteilhafter Weise der Kontrast in Bezug auf das aus der Scheibe ausgekoppelte Licht verbessert wird, so dass die durch das ausgekoppelte Licht vermittelte Information besser erkennbar wird. According to a preferred embodiment of the glazing according to the invention, the at least one electro-optical functional element is for the electrical switching of optical properties a Polymer Dispersed Liquid Crystal (PDLC) or a Suspended Particle Device (SPD) functional element), which is provided in particular in film form. As already explained at the beginning, such electro-optical functional elements are well known to the person skilled in the art, so that they do not have to be discussed in more detail here. In practice, it has been found that electro-optical functional elements for electrical switching of optical properties give the pane a "milky" appearance, which, however, advantageously improves the contrast with respect to the light coupled out of the pane, so that the light coupled out by the the information conveyed becomes more recognizable.
Ein weiteres Beispiel elektrooptische Funktionselemente sind PNLC-Funktionselemente (PNLC = polymer network liquid crystal). Die aktive Schicht enthält dabei Flüssigkristalle, welche in ein Polymernetzwerk eingelagert sind, wobei die Funktionsweise ansonsten analog wie bei den PDLC-Funktionselementen ist. Weitere Beispiele sind elektrochrome Funktionselemente oder Funktionselemente mit Flüssigkristall-Farbstoffzellen (sogenannte Guest-Host-Zellen). Another example of electro-optical functional elements are PNLC functional elements (PNLC=polymer network liquid crystal). The active layer contains liquid crystals embedded in a polymer network, with the functionality being otherwise analogous to that of the PDLC functional elements. Further examples are electrochromic functional elements or functional elements with liquid crystal dye cells (so-called guest-host cells).
SPD-, PDLC und PNLC-Funktionselemente, elektrochrome Funktionselemente sowie Funktionselemente mit Flüssigkristall-Farbstoffzellen sind als Funktionselemente kommerziell erhältlich. SPD, PDLC and PNLC functional elements, electrochromic functional elements and functional elements with liquid crystal dye cells are commercially available as functional elements.
Die mindestens eine metallbasierte Funktionsschicht kann grundsätzlich in beliebiger Weise ausgebildet sein. Gemäß einer bevorzugten Ausgestaltung der erfindungsgemäßen Verglasung ist die mindestens eine metallbasierte Funktionsschicht dazu ausgebildet ist, Wärmestrahlung bei Raumtemperatur und insbesondere Infrarotstrahlung, die längerwellig ist als der Infrarotanteil der Sonnenstrahlung, zu reflektieren (sogenannte Beschichtung niedriger Emissivität (Low-E- Beschichtung)) und/oder auftreffendes Infrarotlicht, insbesondere den Infrarotanteil der Sonnenstrahlung, zu reflektieren oder zu absorbieren. Vorteilhaft handelt es sich um eine elektrisch leitfähige und für sichtbares Licht transparente Beschichtung. The at least one metal-based functional layer can in principle be formed in any way. According to a preferred embodiment of the glazing according to the invention, the at least one metal-based functional layer is designed to reflect thermal radiation at room temperature and in particular infrared radiation, which has longer wavelengths than the infrared component of solar radiation (so-called coating of low emissivity (Low-E coating)) and/or or to reflect or absorb incident infrared light, in particular the infrared portion of solar radiation. It is advantageously an electrically conductive coating that is transparent to visible light.
Die metallbasierte Funktionsschicht kann aus einer Einzelschicht bzw. Lage aus einem selben Material bestehen, wobei gleichermaßen möglich ist, dass sie aus mehreren Einzelschichten bzw. Lagen aus zumindest zwei verschiedenen Materialien besteht. Die Funktionsschicht kann somit aus einer Einzelschicht bzw. Lage aus einem selben Material bestehen. Alternativ kann die Funktionsschicht aus einer mehreren Einzelschichten bzw. Lagen aus zumindest zwei verschiedenen Materialien bestehen. Wie eingangs dargestellt, ist es gängige Praxis eine metallbasierte Funktionsschicht in Form eines Schichtensystems aus voneinander verschiedenen Einzelschichten auszubilden. Die metallbasierte Funktionsschicht wird vorzugsweise großflächig auf die Scheibe aufgebracht. Die metallbasierte Funktionsschicht ist auf einer Oberfläche der Scheibe angeordnet und bedeckt bzw. überdeckt die Oberfläche der Scheibe vollständig oder teilweise, jedoch vorzugsweise großflächig. Der Ausdruck "großflächig" bedeutet, dass mindestens 50%, mindestens 60%, mindestens 70%, mindestens 75% oder bevorzugt mindestens 90% der Oberfläche der Scheibe von der metallbasierten Funktionsschicht bedeckt sind. Die metallbasierte Funktionsschicht kann sich aber auch über kleinere Anteile der Oberfläche der Scheibe erstrecken. The metal-based functional layer can consist of an individual layer or layer made of the same material, it being equally possible for it to consist of several individual layers or layers made of at least two different materials. The functional layer can thus consist of an individual layer or ply made of the same material. Alternatively, the functional layer can consist of a number of individual layers or plies made of at least two different materials. As explained at the outset, it is common practice to form a metal-based functional layer in the form of a layer system made up of individual layers that are different from one another. The metal-based functional layer is preferably applied to the pane over a large area. The metal-based functional layer is arranged on a surface of the pane and covers or covers the surface of the pane completely or partially, but preferably over a large area. The term “large area” means that at least 50%, at least 60%, at least 70%, at least 75% or preferably at least 90% of the surface of the pane is covered by the metal-based functional layer. However, the metal-based functional layer can also extend over smaller portions of the surface of the pane.
Die metallbasierte Funktionsschicht ist eine Einzelschicht oder ein Schichtaufbau aus mehreren Einzelschichten mit einer Gesamtdicke von beispielsweise kleiner oder gleich 2 pm, bevorzugt kleiner oder gleich 1 pm. Vorteilhaft weist die metallbasierte Funktionsschicht eine Dicke von 80 nm bis 1000 nm, insbesondere von 80 nm bis 600 n, bevorzugt von 140 nm bis 400 nm, auf. The metal-based functional layer is an individual layer or a layer structure made up of several individual layers with a total thickness of, for example, less than or equal to 2 μm, preferably less than or equal to 1 μm. The metal-based functional layer advantageously has a thickness of 80 nm to 1000 nm, in particular 80 nm to 600 nm, preferably 140 nm to 400 nm.
Im Sinne vorliegender Erfindung bedeutet "transparent", dass die Gesamttransmission der Scheibe und insbesondere der Verglasung den gesetzlichen Bestimmungen für Windschutzscheiben und vordere Seitenscheiben entspricht und für sichtbares Licht bevorzugt eine Durchlässigkeit von mehr als 70% und insbesondere von mehr als 75% aufweist. Für hintere Seitenscheiben und Heckscheiben kann "transparent" auch 10% bis 70% Lichttransmission bedeuten. Entsprechend bedeutet "opak" eine Lichttransmission von weniger als 15%, vorzugsweise weniger als 5%, insbesondere 0%. In the context of the present invention, "transparent" means that the total transmission of the pane and in particular the glazing corresponds to the legal provisions for windshields and front side windows and preferably has a transmittance of more than 70% and in particular more than 75% for visible light. For rear side windows and rear windows, "transparent" can also mean 10% to 70% light transmission. Correspondingly, "opaque" means a light transmission of less than 15%, preferably less than 5%, in particular 0%.
Beispielsweise enthält eine transparente, elektrisch leitfähige Funktionsschicht mindestens ein Metall, beispielsweise Silber, Nickel, Chrom, Niob, Zinn, Titan, Kupfer, Palladium, Zink, Gold, Cadmium, Aluminium, Silizium, Wolfram oder Legierungen daraus, und/oder mindestens eine Metalloxidschicht, bevorzugt Zinn-dotiertes Indiumoxid (ITO), Aluminium-dotiertes Zinkoxid (AZO), Fluor-dotiertes Zinnoxid (FTO, SnO2:F) oder Antimon-dotiertes Zinnoxid (ATO, SnO2:Sb). Solche Funktionsschichten sind beispielsweise aus DE 20 2008 017 611 U1 und EP 0 847 965 B1 bekannt. Sie bestehen beispielsweise aus einer Metallschicht wie einer Silberschicht oder einer Schicht aus einer silberhaltigen Metalllegierung. Typische Silberschichten weisen bevorzugt Dicken von 5 nm bis 15 nm auf, besonders bevorzugt von 8 nm bis 12 nm. Die Metallschicht kann zwischen mindestens zwei Schichten aus dielektrischem Material vom Typ Metalloxid eingebettet sein. Das Metalloxid enthält bevorzugt Zinkoxid, Zinnoxid, Indiumoxid, Titanoxid, Siliziumoxid, Aluminiumoxid oder dergleichen sowie Kombinationen von einem oder mehreren daraus. Das dielektrische Material kann auch Siliziumnitrid, Siliziumcarbid, Aluminiumnitrid sowie Kombinationen von einem oder mehreren davon enthalten. For example, a transparent, electrically conductive functional layer contains at least one metal, for example silver, nickel, chromium, niobium, tin, titanium, copper, palladium, zinc, gold, cadmium, aluminum, silicon, tungsten or alloys thereof, and/or at least one metal oxide layer , preferably tin-doped indium oxide (ITO), aluminum-doped zinc oxide (AZO), fluorine-doped tin oxide (FTO, SnO2:F) or antimony-doped tin oxide (ATO, SnO2:Sb). Such functional layers are known, for example, from DE 20 2008 017 611 U1 and EP 0 847 965 B1. They consist, for example, of a metal layer such as a silver layer or a layer of a metal alloy containing silver. Typical silver layers preferably have thicknesses of 5 nm to 15 nm, more preferably 8 nm to 12 nm. The metal layer may be sandwiched between at least two layers of metal oxide type dielectric material. The metal oxide preferably includes zinc oxide, tin oxide, indium oxide, titanium oxide, silicon oxide, aluminum oxide, or the like, and combinations of one or more thereof. That dielectric material may also include silicon nitride, silicon carbide, aluminum nitride, and combinations of one or more of these.
Transparente, elektrisch leitfähige Funktionsschichten haben beispielsweise einen Flächenwiderstand von 0,1 Ohm/Quadrat bis 200 Ohm/Quadrat, besonders bevorzugt von 1 Ohm/Quadrat bis 50 Ohm/Quadrat und ganz besonders bevorzugt von 1 Ohm/Quadrat bis 10 Ohm/Quadrat. Transparent, electrically conductive functional layers have, for example, a surface resistance of 0.1 ohms/square to 200 ohms/square, particularly preferably from 1 ohms/square to 50 ohms/square and very particularly preferably from 1 ohms/square to 10 ohms/square.
Beispielsweise dient die transparente, elektrisch leitfähige Funktionsschicht als Antennenschicht (Flächenantenne). For example, the transparent, electrically conductive functional layer serves as an antenna layer (surface antenna).
Vorzugsweise ist die metallbasierte Funktionsschicht eine Funktionsschicht mit Sonnenschutz- Wirkung. Eine solche Schicht mit Sonnenschutzwirkung weist reflektierende Eigenschaften im Infrarot-Bereich und damit im Bereich der Sonneneinstrahlung auf, wodurch ein Aufheizen des Innenraums eines Gebäudes oder Kraftfahrzeugs infolge von Sonnenstrahlung vorteilhaft vermindert wird. Der TTS-Wert einer mit der Beschichtung versehenen Fahrzeugverbundscheibe beträgt dabei bevorzugt kleiner 50%, besonders bevorzugt kleiner 45%, ganz besonders bevorzugt kleiner 40 %. Mit TTS-Wert wird die insgesamt transmittierte Sonnenenergie, gemessen nach ISO 13837, bezeichnet - er ist ein Maß für den thermischen Komfort. Die Beschichtung kann auch als Heizbeschichtung verwendet werden, wenn sie elektrisch kontaktiert wird, so dass ein Strom durch sie fließt, welcher die Beschichtung erwärmt. Funktionsschichten mit Sonnenschutzwirkung sind dem Fachmann wohlbekannt und enthalten typischerweise zumindest ein Metall, insbesondere Silber oder eine silberhaltige Legierung. Die Schicht mit Sonnenschutzwirkung kann eine Abfolge mehrerer Einzelschichten umfassen, insbesondere zumindest eine metallische Schicht und dielektrische Schichten, die beispielsweise zumindest ein Metalloxid enthalten. Das Metalloxid enthält bevorzugt Zinkoxid, Zinnoxid, Indiumoxid, Titanoxid, Siliziumoxid, Aluminiumoxid oder dergleichen sowie Kombinationen von einem oder mehreren daraus. Das dielektrische Material enthält beispielsweise Siliziumnitrid, Siliziumcarbid oder Aluminiumnitrid. Schichten mit Sonnenschutzwirkung sind beispielsweise bekannt aus DE 102009006062 A1 , WO 2007/101964 A1 , EP 0 912 455 B1 , DE 199 27 683 C1 , EP 1 218 307 B1 und EP 1 917 222 B1. The metal-based functional layer is preferably a functional layer with a sun protection effect. Such a layer with a sun protection effect has reflective properties in the infrared range and thus in the range of solar radiation, which advantageously reduces the heating of the interior of a building or motor vehicle as a result of solar radiation. The TTS value of a composite vehicle pane provided with the coating is preferably less than 50%, particularly preferably less than 45%, very particularly preferably less than 40%. The TTS value is the total transmitted solar energy, measured according to ISO 13837 - it is a measure of thermal comfort. The coating can also be used as a heating coating if it is electrically contacted so that a current flows through it which heats the coating. Functional layers with a sun protection effect are well known to the person skilled in the art and typically contain at least one metal, in particular silver or a silver-containing alloy. The layer with a sun protection effect can comprise a sequence of several individual layers, in particular at least one metallic layer and dielectric layers, which contain at least one metal oxide, for example. The metal oxide preferably includes zinc oxide, tin oxide, indium oxide, titanium oxide, silicon oxide, aluminum oxide, or the like, and combinations of one or more thereof. The dielectric material contains silicon nitride, silicon carbide or aluminum nitride, for example. Layers with a sun protection effect are known, for example, from DE 102009006062 A1, WO 2007/101964 A1, EP 0 912 455 B1, DE 199 27 683 C1, EP 1 218 307 B1 and EP 1 917 222 B1.
Die Dicke einer Funktionsschicht mit Sonnenschutzwirkung kann breit variieren und den Erfordernissen des Einzelfalls angepasst werden, wobei eine Schichtdicke von 10 nm bis 5 pm und insbesondere von 30 nm bis 1 pm bevorzugt ist. Der Flächenwiderstand einer Funktionsschicht mit Sonnenschutzwirkung beträgt bevorzugt von 0,35 Ohm/Quadrat bis 200 Ohm/Quadrat, bevorzugt 0,5 Ohm/Quadrat bis 200 Ohm/Quadrat, ganz besonders bevorzugt von 0,6 Ohm/Quadrat bis 30 Ohm/Quadrat, und insbesondere von 2 Ohm/Quadrat bis 20 Ohm/Quadrat. Die Metallbasierte Funktionsschicht mit Sonnenschutzwirkung weist beispielsweise gute infrarotreflektierende Eigenschaften und/oder besonders niedrige Emissivitäten (Low-E) auf. The thickness of a functional layer with a sun protection effect can vary widely and be adapted to the requirements of the individual case, with a layer thickness of 10 nm to 5 μm and in particular from 30 nm to 1 μm being preferred. The surface resistance of a Functional layer with sun protection effect is preferably from 0.35 ohms/square to 200 ohms/square, preferably from 0.5 ohms/square to 200 ohms/square, very particularly preferably from 0.6 ohms/square to 30 ohms/square, and in particular from 2 ohms/square to 20 ohms/square. The metal-based functional layer with a sun protection effect has, for example, good infrared-reflecting properties and/or particularly low emissivities (Low-E).
Die metallbasierte Funktionsschicht kann beispielsweise auch eine elektrisch beheizbare Schicht sein, durch welche die Scheibe mit einer Heizfunktion versehen wird. Solche beheizbaren Schichten sind dem Fachmann an sich bekannt. Sie enthalten typischerweise eine oder mehrere, beispielsweise zwei, drei oder vier elektrisch leitfähige Schichten. Diese Schichten enthalten oder bestehen bevorzugt aus zumindest einem Metall, beispielsweise Silber, Gold, Kupfer, Nickel und/oder Chrom, oder einer Metalllegierung und enthalten bevorzugt mindestens 90 Gew.-% des Metalls, insbesondere mindestens 99,9 Gew.-% des Metalls. Solche Schichten weisen eine besonders vorteilhafte elektrische Leitfähigkeit bei gleichzeitiger hoher Transmission im sichtbaren Spektral be re ich auf. Die Dicke einer Einzelschicht beträgt bevorzugt von 5 nm bis 50 nm, besonders bevorzugt von 8 nm bis 25 nm. Bei einer solchen Dicke wird eine vorteilhaft hohe Transmission im sichtbaren Spektral be re ich und eine besonders vorteilhafte elektrische Leitfähigkeit erreicht. The metal-based functional layer can also be an electrically heatable layer, for example, which provides the pane with a heating function. Such heatable layers are known per se to those skilled in the art. They typically contain one or more, for example two, three or four, electrically conductive layers. These layers preferably contain or consist of at least one metal, for example silver, gold, copper, nickel and/or chromium, or a metal alloy and preferably contain at least 90% by weight of the metal, in particular at least 99.9% by weight of the metal . Such layers have a particularly advantageous electrical conductivity combined with high transmission in the visible spectral range. The thickness of an individual layer is preferably from 5 nm to 50 nm, particularly preferably from 8 nm to 25 nm. With such a thickness, an advantageously high transmission in the visible spectral range and a particularly advantageous electrical conductivity are achieved.
Die metallbasierte Funktionsschicht wird durch an sich bekannte Verfahren abgeschieden, beispielsweise durch magnetfeldunterstützte Kathodenzerstäubung, was besonders vorteilhaft im Hinblick auf eine einfache, schnelle, kostengünstige und gleichmäßige Beschichtung der Scheibe ist. Die Kathodenzerstäubung erfolgt in einer Schutzgasatmosphäre, beispielsweise aus Argon, beziehungsweise in einer Reaktivgasatmosphäre, beispielsweise durch Zugabe von Sauerstoff, einem Kohlenwasserstoff (beispielsweise Methan) oder Stickstoff. Die metallbasierte Funktionsschicht kann aber auch durch andere, dem Fachmann bekannte Verfahren aufgebracht werden, beispielsweise durch Aufdampfen oder chemische Gasphasenabscheidung (chemical vapour deposition, CVD), durch Atomlagenabscheidung (atomic layer deposition, ALD), durch plasmagestützte Gasphasenabscheidung (PECVD) oder durch nasschemische Verfahren. The metal-based functional layer is deposited by methods known per se, for example by cathode sputtering supported by a magnetic field, which is particularly advantageous with regard to a simple, fast, inexpensive and uniform coating of the pane. The cathode sputtering takes place in a protective gas atmosphere, for example argon, or in a reactive gas atmosphere, for example by adding oxygen, a hydrocarbon (for example methane) or nitrogen. However, the metal-based functional layer can also be applied by other methods known to those skilled in the art, for example by vapor deposition or chemical vapor deposition (CVD), by atomic layer deposition (ALD), by plasma-enhanced vapor deposition (PECVD) or by wet-chemical methods .
In einer vorteilhaften Ausführungsform des erfindungsgemäßen Verfahrens enthält oder besteht die mindestens eine Scheibe aus nichtvorgespanntem, teilvorgespanntem oder vorgespanntem Glas, bevorzugt Flachglas, Floatglas, Quarzglas, Borosilikatglas, Kalk- Natron-Glas. Alternativ enthält oder besteht die Scheibe aus klaren Kunststoffen, bevorzugt starre klare Kunststoffe, insbesondere Polyethylen, Polypropylen, Polycarbonat, Polymethylmethacrylat, Polystyrol, Polyamid, Polyester, Polyvinylchlorid und/oder Gemische davon. Geeignete Gläser sind beispielsweise aus EP 0847965 B1 bekannt. In an advantageous embodiment of the method according to the invention, the at least one pane contains or consists of non-tempered, partially tempered or tempered glass, preferably flat glass, float glass, quartz glass, borosilicate glass, soda-lime glass. Alternatively, the disc includes or consists of clear plastics, preferably rigid clear plastics, in particular polyethylene, polypropylene, polycarbonate, polymethyl methacrylate, polystyrene, polyamide, polyester, polyvinyl chloride and/or mixtures thereof. Suitable glasses are known, for example, from EP 0847965 B1.
Die Dicke der mindestens einen Scheibe kann breit variieren und den Erfordernissen des Einzelfalls angepasst werden. Beispielsweise wird eine Scheibe mit einer Standardstärke von 1 ,0 mm bis 25 mm verwendet. Beispielsweise beträgt die Dicke von 0,5 mm bis 15 mm, insbesondere von 1 mm bis 5 mm. Die Größe der Scheibe kann breit variieren und richtet sich nach der Verwendung. The thickness of the at least one pane can vary widely and can be adapted to the requirements of the individual case. For example, a disk with a standard thickness of 1.0 mm to 25 mm is used. For example, the thickness is from 0.5 mm to 15 mm, in particular from 1 mm to 5 mm. The size of the disc can vary widely and depends on the use.
Die mindestens einen Scheibe kann eine beliebige dreidimensionale Form aufweisen. Bevorzugt ist die Scheibe planar oder leicht oder stark in eine Richtung oder in mehrere Richtungen des Raumes gebogen. The at least one pane can have any three-dimensional shape. Preferably the disk is planar or slightly or greatly curved in one or more directions of space.
Bei einem Biegeprozess wird die Scheibe im erhitzten Zustand in eine oder mehrere Richtungen des Raumes gebogen. Die Temperatur, auf die die Scheibe erhitzt wird, beträgt bevorzugt von 500°C bis 700°C. Es versteht sich, dass zeitlich vor oder nach dem Biegeprozess weitere Temperaturbehandlungsschritte der Scheibe erfolgen können. In a bending process, the pane is bent in one or more directions in space while it is heated. The temperature to which the disk is heated is preferably from 500°C to 700°C. It goes without saying that further thermal treatment steps of the pane can take place before or after the bending process.
Die Scheibe kann farblos oder gefärbt sein. The disc can be colorless or colored.
Die erfindungsgemäße Verglasung dient vorzugsweise der Abtrennung eines Innenraums von einer äußeren Umgebung. Die Verglasung umfasst mindestens eine Scheibe. Die Verglasung kann grundsätzlich beliebig ausgebildet sein, insbesondere als Isolierverglasung, bei der mindestens zwei Scheiben durch mindestens einen Abstandhalter in einem Abstand zueinander angeordnet sind, oder als thermisch vorgespanntes Einscheibensicherheitsglas oder als Verbundscheibe. The glazing according to the invention preferably serves to separate an interior space from an exterior environment. The glazing comprises at least one pane. The glazing can in principle be of any design, in particular as insulating glazing, in which at least two panes are arranged at a distance from one another by at least one spacer, or as thermally toughened single-pane safety glass or as a laminated pane.
Bevorzugt ist die Verglasung als Verbundscheibe ausgebildet und umfasst eine erste Scheibe mit Außenseite und Innenseite sowie eine zweite Scheibe mit Innenseite und Außenseite, welche durch mindestens eine thermoplastische Zwischenschicht (Klebeschicht) fest miteinander verbunden sind. Die erste Scheibe kann auch als Außenscheibe oder Innenscheibe, die zweite Scheibe dementsprechend als Innenscheibe oder Außenscheibe bezeichnet werden. Die Oberflächen bzw. Seiten der beiden Einzelscheiben werden von außen nach innen üblicherweise als Seite I, Seite II, Seite III und Seite IV bezeichnet. Die beiden Innenseiten der Scheiben sind durch die mindestens eine thermoplastische Klebeschicht fest miteinander verbunden. The glazing is preferably designed as a composite pane and comprises a first pane with an outside and inside and a second pane with an inside and outside, which are firmly connected to one another by at least one thermoplastic intermediate layer (adhesive layer). The first pane can also be referred to as an outer pane or inner pane, and the second pane accordingly as an inner pane or outer pane. The surfaces or sides of the two individual panes usually turn from the outside inwards referred to as Page I, Page II, Page III and Page IV. The two inner sides of the panes are firmly connected to one another by the at least one thermoplastic adhesive layer.
Die thermoplastische Zwischenschicht enthält oder besteht aus mindestens einem thermoplastischen Kunststoff, bevorzugt Polyvinylbutyral (PVB), Ethylenvinylacetat (EVA) und/oder Polyethylenterephthalat (PET). Die thermoplastische Zwischenschicht kann aber auch beispielsweise Polyurethan (PU), Polypropylen (PP), Polyacrylat, Polyethylen (PE), Polycarbonat (PC), Polymethylmetacrylat, Polyvinylchlorid, Polyacetatharz, Gießharz, Acrylat, fluorinierte Ethylen-Propylen, Polyvinylfluorid und/oder Ethylen-Tetrafluorethylen, oder ein Copolymer oder Gemisch davon enthalten. Die thermoplastische Zwischenschicht kann durch eine oder mehrere übereinander angeordnete thermoplastische Folien ausgebildet werden, wobei die Dicke einer thermoplastischen Folie beispielsweise von 0,25 mm bis 1 mm beträgt. The thermoplastic intermediate layer contains or consists of at least one thermoplastic, preferably polyvinyl butyral (PVB), ethylene vinyl acetate (EVA) and/or polyethylene terephthalate (PET). However, the thermoplastic intermediate layer can also be, for example, polyurethane (PU), polypropylene (PP), polyacrylate, polyethylene (PE), polycarbonate (PC), polymethyl methacrylate, polyvinyl chloride, polyacetate resin, cast resin, acrylate, fluorinated ethylene propylene, polyvinyl fluoride and/or ethylene Tetrafluoroethylene, or a copolymer or mixture thereof. The thermoplastic intermediate layer can be formed by one or more thermoplastic films arranged one on top of the other, the thickness of a thermoplastic film being, for example, from 0.25 mm to 1 mm.
Der mindestens eine Lichtauskoppelbereich zum Auskoppeln von in der Scheibe totalreflektierten Lichts aus der Scheibe ist auf der Außenseite der ersten Scheibe und/oder auf der Außenseite der zweiten Scheibe ausgebildet. Vorzugsweise ist der mindestens eine Lichtauskoppelbereich auf der Außenseite jener Scheibe (d.h. Innenscheibe) ausgebildet, welche einem Innenraum zugewandt ist (z.B. zweite Scheibe) The at least one light decoupling region for decoupling from the pane light that is totally reflected in the pane is formed on the outside of the first pane and/or on the outside of the second pane. The at least one light coupling-out area is preferably formed on the outside of that pane (i.e. inner pane) which faces an interior space (e.g. second pane).
Vorteilhaft ist das mindestens eine elektrooptische Funktionselement zwischen der ersten Scheibe der zweiten Scheibe angeordnet, so dass es gut vor äußeren Einflüssen geschützt ist. Gleichermaßen vorteilhaft ist die mindestens eine metallbasierte Funktionsschicht, welche dazu ausgebildet ist, auftreffendes Infrarotlicht zu reflektieren oder zu absorbieren, zwischen der ersten Scheibe der zweiten Scheibe angeordnet, was ebenfalls dazu führt, dass sie gut vor äußeren Einflüssen geschützt ist. Die mindestens eine metallbasierte Funktionsschicht, welche dazu ausgebildet ist, Wärmestrahlung bei Raumtemperatur zu reflektieren, ist vorteilhaft auf der Außenseite der zweiten Scheibe angeordnet, welche einem Innenraum zugewandt ist. Dies ermöglicht eine besonders gute Funktion dieser Funktionsschicht. The at least one electro-optical functional element is advantageously arranged between the first pane and the second pane, so that it is well protected from external influences. Equally advantageously, the at least one metal-based functional layer, which is designed to reflect or absorb incident infrared light, is arranged between the first pane and the second pane, which also means that it is well protected from external influences. The at least one metal-based functional layer, which is designed to reflect thermal radiation at room temperature, is advantageously arranged on the outside of the second pane, which faces an interior space. This enables this functional layer to function particularly well.
Die Erfindung erstreckt sich weiterhin auf ein Verfahren zum Herstellen der erfindungsgemäßen Verglasung. Obige Ausführungen im Zusammenhang mit der Verglasung gelten gleichermaßen für das erfindungsgemäße Verfahren. The invention also extends to a method for producing the glazing according to the invention. The above statements in connection with the glazing apply equally to the method according to the invention.
Das Verfahren umfasst das Bereitstellen mindestens einer Scheibe und Anordnen mindestens einer metallbasierten Funktionsschicht und/oder mindestens eines elektrooptischen Funktionselement zum elektrischen Schalten von optischen Eigenschaften. Das Verfahren umfasst weiterhin das Erzeugen mindestens eines Lichtauskoppelbereichs zum Auskoppeln von in der Scheibe totalreflektierten Lichts aus der Scheibe. The method includes providing at least one pane and arranging at least one metal-based functional layer and/or at least one electro-optical one Functional element for electrical switching of optical properties. The method also includes generating at least one light decoupling region for decoupling light that is totally reflected in the pane out of the pane.
Gemäß einer vorteilhaften Ausgestaltung des Verfahrens wird mindestens eine Durchbrechung oder Aussparung zum Aufnehmen mindestens einer Lichtquelle in der Scheibe erzeugt. According to an advantageous embodiment of the method, at least one opening or cutout for receiving at least one light source is produced in the pane.
Gemäß einer weiteren vorteilhaften Ausgestaltung des Verfahrens wird der mindestens eine Lichtauskoppelbereich durch Entfernen der metallbasierten Funktionsschicht von der Scheibe mittels eines Lasers erzeugt. Durch diese Maßnahme kann nicht nur die metallbasierte Funktionsschicht im Lichtauskoppelbereich entfernt, sondern gleichzeitig die Oberfläche der Scheibe aufgeraut werden. According to a further advantageous embodiment of the method, the at least one light decoupling region is produced by removing the metal-based functional layer from the pane using a laser. This measure not only allows the metal-based functional layer to be removed in the light decoupling area, but also the surface of the pane to be roughened at the same time.
Gemäß einer weiteren vorteilhaften Ausgestaltung des Verfahrens werden eine erste Scheibe Außenseite und Innenseite und eine zweite Scheibe mit Innenseite und Außenseite, wobei die Innenseiten der beiden Scheiben zueinander weisen, durch mindestens eine thermoplastische Zwischenschicht fest miteinander verbunden. According to a further advantageous embodiment of the method, a first pane with the outside and inside and a second pane with the inside and outside, with the insides of the two panes facing each other, are firmly connected to one another by at least one thermoplastic intermediate layer.
Demnach dient das erfindungsgemäße Verfahren zum Herstellen einer Verglasung vorzugsweise der Herstellung einer Verbundscheibe. Für die Herstellung einer Verbundscheibe werden mindestens zwei Scheiben bevorzugt unter Einwirkung von Hitze, Vakuum und/oder Druck durch mindestens eine thermoplastische Klebeschicht miteinander verbunden (laminiert). Es können an sich bekannte Verfahren zur Herstellung einer Verbundscheibe verwendet werden. Es können beispielsweise sogenannte Autoklavverfahren bei einem erhöhten Druck von etwa 10 bar bis 15 bar und Temperaturen von 130 °C bis 145 °C über etwa 2 Stunden durchgeführt werden. An sich bekannte Vakuumsack- oder Vakuumringverfahren arbeiten beispielsweise bei etwa 200 mbar und 130 °C bis 145 °C. Die beiden Scheiben und die thermoplastische Zwischenschicht können auch in einem Kalander zwischen mindestens einem Walzenpaar zu einer Verbundscheibe verpresst werden. Anlagen dieser Art sind zur Herstellung von Verbundscheiben bekannt und verfügen normalerweise über mindestens einen Heiztunnel vor einem Presswerk. Die Temperatur während des Pressvorgangs beträgt beispielsweise von 40 °C bis 150 °C. Kombinationen von Kalander- und Autoklavverfahren haben sich in der Praxis besonders bewährt. Alternativ können Vakuumlaminatoren eingesetzt werden. Diese bestehen aus einer oder mehreren beheizbaren und evakuierbaren Kammern, in denen die erste Scheibe und die zweite Scheibe innerhalb von beispielsweise etwa 60 Minuten bei verminderten Drücken von 0,01 mbar bis 800 mbar und Temperaturen von 80°C bis 170°C laminiert werden können. Accordingly, the method according to the invention for producing a glazing preferably serves to produce a laminated pane. To produce a composite pane, at least two panes are connected (laminated) to one another, preferably under the action of heat, vacuum and/or pressure, by at least one thermoplastic adhesive layer. Methods known per se can be used to produce a laminated pane. For example, so-called autoclave processes can be carried out at an increased pressure of about 10 bar to 15 bar and temperatures of 130° C. to 145° C. for about 2 hours. Known vacuum bag or vacuum ring methods work, for example, at about 200 mbar and 130°C to 145°C. The two panes and the thermoplastic intermediate layer can also be pressed in a calender between at least one pair of rollers to form a composite pane. Plants of this type are known for the production of laminated panes and normally have at least one heating tunnel in front of a pressing plant. The temperature during the pressing process is, for example, from 40°C to 150°C. Combinations of calender and autoclave processes have proven particularly useful in practice. Alternatively, vacuum laminators can be used. These consist of one or more heatable and evacuable chambers in which the first pane and the second pane within for example about 60 minutes at reduced pressures of 0.01 mbar to 800 mbar and temperatures of 80°C to 170°C.
Die erfindungsgemäße Verglasung wird vorzugsweise in Gebäuden, insbesondere im Zugangsoder Fensterbereich, als Einbauteil in Möbeln und Geräten, oder in Fortbewegungsmitteln für den Verkehr auf dem Lande, in der Luft oder zu Wasser, insbesondere in Zügen, Schiffen und Kraftfahrzeugen beispielsweise als Windschutzscheibe, Heckscheibe, Seitenscheibe und/oder Dachscheibe verwendet. The glazing according to the invention is preferably used in buildings, in particular in the access or window area, as a built-in part in furniture and appliances, or in means of transport for traffic on land, in the air or on water, in particular in trains, ships and motor vehicles, for example as a windscreen, rear window, Side window and/or roof window used.
Die verschiedenen Ausgestaltungen der Erfindung können einzeln oder in beliebigen Kombinationen realisiert sein. Insbesondere sind die vorstehend genannten und nachstehend zu erläuternden Merkmale nicht nur in den angegebenen Kombinationen, sondern auch in anderen Kombinationen oder in Alleinstellung einsetzbar, ohne den Rahmen der vorliegenden Erfindung zu verlassen. The various configurations of the invention can be implemented individually or in any combination. In particular, the features mentioned above and to be explained below can be used not only in the specified combinations, but also in other combinations or on their own, without departing from the scope of the present invention.
Die Erfindung wird nachfolgend anhand von Ausführungsbeispielen näher erläutert, wobei Bezug auf die beigefügten Figuren genommen wird. Es zeigen in vereinfachter, nicht maßstabsgetreuer Darstellung: The invention is explained in more detail below using exemplary embodiments, reference being made to the attached figures. They show in a simplified representation that is not true to scale:
Fig. 1 eine schematische Darstellung einer Verglasung; 1 shows a schematic representation of a glazing;
Fig. 2 eine weitere schematische Darstellung einer Verglasung; 2 shows a further schematic representation of a glazing;
Fig. 3 eine weitere schematische Darstellung einer Verglasung; 3 shows a further schematic representation of a glazing;
Fig. 4 eine Darstellung einer Scheibe mit Lichtauskoppelbereichen. 4 shows an illustration of a pane with light decoupling areas.
Fig. 1 zeigt eine schematische Darstellung einer Verglasung 100. Die Verglasung 100 umfasst eine seitlich angeordnete Lichtquelle 101 zum Einkoppeln von Licht in eine Scheibe 103-2. Die Lichtquelle 101 kann beispielsweise durch eine Leuchtdiode (LED) gebildet sein, die im Bereich neben der Scheibe 103-2 angeordnet ist. Alternativ kann die Lichtquelle 101 in einer Aussparung oder Durchbrechung der Scheibe 103-2 angeordnet sein. Die Strahlung der Lichtquelle 101 kann direkt in die Scheibe 103-2 eingekoppelt werden oder auch über ein Reflexionselement 115, so dass die Lichtquelle 101 auch außerhalb der Ebene der Scheibe 103-2 angeordnet sein kann. Zum Einkoppeln des Lichts umfasst die Scheibe 103-2 einen seitlichen Lichteinkoppelbereich 117, der durch die seitliche Kante der Scheibe 103-2 gebildet ist. 1 shows a schematic representation of a glazing 100. The glazing 100 comprises a light source 101 arranged on the side for coupling light into a pane 103-2. The light source 101 can be formed, for example, by a light-emitting diode (LED), which is arranged in the area next to the pane 103-2. Alternatively, the light source 101 can be arranged in a recess or opening in the pane 103-2. The radiation from the light source 101 can be coupled directly into the pane 103-2 or also via a reflection element 115, so that the light source 101 can also be arranged outside the plane of the pane 103-2. In order to couple in the light, the disk 103-2 comprises a lateral light coupling region 117, which is formed by the lateral edge of the disk 103-2.
Innerhalb der Scheibe 103-2 findet eine Totalreflexion des eingekoppelten Lichtes statt, bis das Licht auf einen Lichtauskoppelbereich 105 trifft. In diesem Fall wird das Licht an dieser Stelle aus der Scheibe 103-2 ausgekoppelt und nach außen gestreut. Durch den Lichtauskoppelbereich 105 lassen sich sichtbare Lichtmuster auf der Scheibe 103-2 erzeugen. Der Lichtauskoppelbereich 105 ist beispielsweise eine lichtdiffundierende Beschichtung, z.B. in Form einer im Siebdruckverfahren aufgebrachten und eingebrannten Paste, die in diesem Bereich auf die Scheibe 103-2 aufgebracht ist oder in der Oberfläche der Scheibe 103-2 integriert ist. Total reflection of the coupled-in light takes place within the pane 103 - 2 until the light strikes a light coupling-out region 105 . In this case, the light is coupled out of the pane 103-2 at this point and scattered to the outside. Visible light patterns can be generated on pane 103-2 by light decoupling region 105. The light decoupling area 105 is, for example, a light-diffusing coating, e.g. in the form of a paste applied in a screen printing process and burned in, which is applied to the pane 103-2 in this area or is integrated in the surface of the pane 103-2.
Die Scheibe 103-2 weist eine Außenseite 109-1 und eine Innenseite 109-2 auf. Zusätzlich umfasst die Verglasung 100 eine weitere Scheibe 103-1 , die ebenfalls eine Außenseite 109-4 und eine Innenseite 109-3 aufweist. Die Scheibe 103-1 ist mit der Scheibe 103-2 beispielsweise über eine zwischenliegende Polyvinylbutyral-Schicht (PVB-Schicht) verbunden. Durch die Verbindung und Laminierung der beiden Scheiben 103-1 , 103-2 entsteht eine Verbundscheibe. Im Allgemeinen kann das Auskoppeln des Lichts auf beiden Seiten der Scheibe 103-2 stattfinden. Zwischen den beiden Scheiben 103-1 und 103-2 ist im Bereich der Lichtquelle 101 zusätzlich eine intransparente Abdeckschicht 119 gebildet. Diese Abdeckschicht 119 verhindert, dass das Licht von der Lichtquelle 101 direkt nach außen strahlt. The disc 103-2 has an outside 109-1 and an inside 109-2. In addition, the glazing 100 includes a further pane 103-1, which also has an outside 109-4 and an inside 109-3. Disk 103-1 is bonded to disk 103-2 via an intervening polyvinyl butyral (PVB) layer, for example. A composite pane is created by connecting and laminating the two panes 103-1, 103-2. In general, the light extraction can take place on both sides of the disk 103-2. An opaque cover layer 119 is additionally formed between the two panes 103 - 1 and 103 - 2 in the area of the light source 101 . This covering layer 119 prevents the light from the light source 101 from radiating directly to the outside.
Die Scheibe 103-2 umfasst eine metallbasierte Funktionsschicht 107-1 , die auf der Außenseite 109-1 der Scheibe 103-2 angeordnet ist. Bei der metallbasierte Funktionsschicht 107-1 handelt es sich beispielsweise um eine LowE-Beschichtung, die dazu geeignet ist, Wärmestrahlung bei Raumtemperatur zu reflektieren. Die LowE-Beschichtung ist beispielsweise eine Mehrfachschicht mit Schichten, die auf Indium-Zinnoxid (ITO), antimondotiertem Zinnoxid (ATO) oder fluordotiertem Zinnoxid (FTO) basieren. The pane 103-2 includes a metal-based functional layer 107-1, which is arranged on the outside 109-1 of the pane 103-2. The metal-based functional layer 107-1 is, for example, a LowE coating that is suitable for reflecting thermal radiation at room temperature. The LowE coating is, for example, a multilayer with layers based on indium tin oxide (ITO), antimony-doped tin oxide (ATO) or fluorine-doped tin oxide (FTO).
Durch diese metallbasierte Funktionsschicht 107-1 wird der thermische Komfort der Verglasung 100 erhöht. Auf die Verwendung von mechanischen Shutter-Technologien innerhalb des Verglasung 100 kann verzichtet werden. Hierdurch wird ein einfacherer Aufbau erzielt, bei dem keine komplizierten mechanischen Vorrichtungen erforderlich sind. In Fahrzeugen vergrößert sich der Kopfraum und es entsteht mehr Freiheit, das Glas als Gestaltungselement zu verwenden. Die beiden Scheiben 103-1 und 103-2 können beispielsweise nichtvorgespanntes, teilvorgespanntes oder vorgespanntes Glas, bevorzugt Flachglas, Floatglas, Quarzglas, Borosilikatglas, Kalk- Natron-Glas oder klare Kunststoffe, bevorzugt starre klare Kunststoffe, insbesondere Polyethylen, Polypropylen, Polycarbonat, Polymethylmethacrylat, Polystyrol, Polyamid, Polyester, Polyvinylchlorid und/oder Gemische davon umfassen und bevorzugt eine Dicke von 0,5 mm bis 15 mm, besonders bevorzugt von 1 mm bis 5 mm aufweisen. The thermal comfort of the glazing 100 is increased by this metal-based functional layer 107-1. The use of mechanical shutter technologies within the glazing 100 can be dispensed with. This achieves a simpler structure that does not require complicated mechanical devices. The headroom in vehicles is increasing and there is more freedom to use the glass as a design element. The two panes 103-1 and 103-2 can, for example, be non-tempered, partially tempered or tempered glass, preferably flat glass, float glass, quartz glass, borosilicate glass, soda-lime glass or clear plastics, preferably rigid clear plastics, in particular polyethylene, polypropylene, polycarbonate, polymethyl methacrylate , Polystyrene, polyamide, polyester, polyvinyl chloride and/or mixtures thereof and preferably have a thickness of 0.5 mm to 15 mm, particularly preferably 1 mm to 5 mm.
Fig. 2 zeigt eine weitere schematische Darstellung einer Verglasung 100. Der Aufbau der Verglasung 100 entspricht demjenigen, der in Fig. 1 gezeigt ist. Allerdings umfasst die Verglasung 100 auf der Innenseite 109-2 der Scheibe 103-2 oder auf der Innenseite 109-3 der Scheibe 103- 1 eine metallbasierte Funktionsschicht 107-2 oder 107-3 zum Reflektieren oder Absorbieren von Infrarotstrahlung (IRR - Infrared Reflective). Die metallbasierte Funktionsschicht 107-2 oder 107- 3 umfasst beispielsweise ein oder mehrere Metallschichten, insbesondere Silberschichten. Diese metallbasierte Funktionsschichten 107-2 oder 107-3 weisen eine erhöhte Reflexion im sichtbaren Spektrum auf und dienen dazu, dass eine Sichtbarkeit des ausgekoppelten Lichtes auf der Außenseite 109-4 der Scheibe 103-1 geringer ist, da die Beschichtungen 107-2 und 107-3 im sichtbaren Bereich eine höhere Reflexion als das Glas aufweisen. Die metallbasierte Funktionsschicht 107-1 , 107-2, oder 107-3 kann eine Dicke von 80 nm bis 1000 nm aufweisen, bevorzugt von 140 nm bis 400 nm oder bevorzugt 700 nm bis 900 nm. FIG. 2 shows another schematic representation of a glazing 100. The structure of the glazing 100 corresponds to that shown in FIG. However, the glazing 100 on the inside 109-2 of the pane 103-2 or on the inside 109-3 of the pane 103-1 includes a metal-based functional layer 107-2 or 107-3 for reflecting or absorbing infrared radiation (IRR - Infrared Reflective) . The metal-based functional layer 107-2 or 107-3 comprises, for example, one or more metal layers, in particular silver layers. These metal-based functional layers 107-2 or 107-3 have increased reflection in the visible spectrum and serve to ensure that the light coupled out is less visible on the outside 109-4 of the pane 103-1, since the coatings 107-2 and 107 -3 have a higher reflection than the glass in the visible range. The metal-based functional layer 107-1, 107-2, or 107-3 can have a thickness of 80 nm to 1000 nm, preferably 140 nm to 400 nm or preferably 700 nm to 900 nm.
Fig. 3 zeigt eine weitere schematische Darstellung einer Verglasung 100. Der Aufbau der Verglasung 100 entspricht demjenigen, der in Fig. 1 gezeigt ist. In dieser Ausführungsform umfasst die Verglasung 100 ein Funktionselement 111 mit elektrisch schaltbaren optischen Eigenschaften, wie beispielsweise eine schaltbare Folie. Das Funktionselement 111 umfasst beispielsweise ein PDLC-Element oder ein SPD-Element oder eine Kombination aus diesen. FIG. 3 shows a further schematic representation of a glazing 100. The structure of the glazing 100 corresponds to that shown in FIG. In this embodiment, the glazing 100 comprises a functional element 111 with electrically switchable optical properties, such as a switchable film. The functional element 111 comprises, for example, a PDLC element or an SPD element or a combination of these.
Die Funktionselement 111 ist zwischen den beiden Scheiben 103-1 und 103-2 angeordnet. Die Funktionselement 111 ändert eine Lichttransmission (Light Transmission - TL) der Verglasung 100, eine Farbe in der Transmission (a*, b*) odereinen Kontrast zwischen einem ausgekoppeltem Lichtmuster und der Glasur. Dadurch wird das Lichtmuster sichtbarer, so dass ein Kontrast zwischen Lichtmuster und Hintergrund während dem Tag höher ist. Durch das Funktionselement 111 können Shutter-Technologien vermieden werden und Lichtmuster nach außen hin verdunkelt und nach Innen hin sichtbarer werden. Fig. 4 zeigt eine Darstellung einer Scheibe 103-2 mit Lichtauskoppelbereichen 105. Zum Bilden der Lichtauskoppelbereiche 105 kann eine lichtdiffundierende Beschichtung (Light Diffusing Enamel) verwendet werden, um das Licht aus der Scheibe 103-2 nach außen zu streuen. The functional element 111 is arranged between the two discs 103-1 and 103-2. The functional element 111 changes a light transmission (Light Transmission - TL) of the glazing 100, a color in the transmission (a*, b*) or a contrast between an extracted light pattern and the glaze. This makes the light pattern more visible, so that a contrast between the light pattern and the background is higher during the day. With the functional element 111, shutter technologies can be avoided and light patterns can be darkened towards the outside and become more visible towards the inside. 4 shows an illustration of a pane 103-2 with light decoupling regions 105. A light-diffusing coating (light diffusing enamel) can be used to form the light decoupling regions 105 in order to scatter the light from the pane 103-2 to the outside.
Allerdings kann auch eine metallbasierte Funktionsschicht 107-1 , wie beispielsweise eine LowE- Beschichtung, auf der Außenseite 109-1 der Scheibe 103-2 oder eine metallbasierte Funktionsschicht 107-2 wie beispielsweise eine IRR-Beschichtung, auf der Innenseite 109-2 der Scheibe 103-2 vorhanden sein. In diesen Fällen kann ein Laser 113 verwendet werden, um einen Lichtauskoppelbereich 105 zu erzeugen. Der so erzeugte Lichtauskoppelbereich 105 sorgt ebenfalls für eine Transparenz im Hochfrequenzbereich (HF - High Frequency), so dass Mobilfunkstrahlung durch das Verglasung 100 dringen kann. However, a metal-based functional layer 107-1, such as a LowE coating, on the outside 109-1 of the pane 103-2 or a metal-based functional layer 107-2, such as an IRR coating, on the inside 109-2 of the pane 103-2 may be present. In these cases, a laser 113 can be used to create a light extraction region 105 . The light decoupling region 105 produced in this way also ensures transparency in the high-frequency range (HF—High Frequency), so that mobile phone radiation can penetrate through the glazing 100 .
In einer Ausführungsform kann eine LowE-Beschichtung auf der Außenseite 109-1 einer extraklaren Scheibe 103-2 mittels des Lasers 113 bereichsweise entfernt werden, um den Lichtauskoppelbereich 105 für das Lichtmuster zu erzeugen. In diesem Fall wird die Scheibe 103- 2 gleichzeitig für elektrische Hochfrequenzschwingungen transparent und durchlässig. Wird jedoch zusätzlich eine IRR-Beschichtung 107-3 auf der Innenseite 109-3 der Scheibe 103-1 verwendet, findet keine Transmission von Hochfrequenzstrahlung statt. In one embodiment, a LowE coating on the outside 109-1 of an extra-clear pane 103-2 can be removed in certain areas by means of the laser 113 in order to produce the light decoupling area 105 for the light pattern. In this case, the disk 103-2 becomes transparent and transmissive to high-frequency electrical vibrations at the same time. However, if an IRR coating 107-3 is also used on the inside 109-3 of the pane 103-1, there is no transmission of high-frequency radiation.
In einer anderen Ausführungsform kann die Innenseite 109-2 der extraklaren Scheibe 103-2 mit einer IRR-Beschichtung 107-2 versehen sein. In diesem Fall wird die IRR-Beschichtung 107-2 mittels des Lasers 113 bereichsweise entfernt, um den Lichtauskoppelbereich 105 für das Lichtmuster zu erzeugen. Auch hierbei wird die Scheibe 103-2 gleichzeitig für elektrische Hochfrequenzschwingungen transparent und durchlässig. In another embodiment, the inside 109-2 of the extra-clear pane 103-2 can be provided with an IRR coating 107-2. In this case, the IRR coating 107-2 is removed in regions by means of the laser 113 in order to produce the light decoupling region 105 for the light pattern. Here, too, the pane 103-2 is simultaneously transparent and permeable to high-frequency electrical vibrations.
Durch die Verglasung 100 wird der technische Vorteil erreicht, dass sich die Sichtbarkeit von Lichtmustern in eine Richtung (nach innen) erhöht, die durch das ausgekoppelte Licht erzeugt werden. Demgegenüber wird die Sichtbarkeit von Lichtmustern in die andere Richtung (nach außen) verringert. Das Verglasung 100 kann beispielsweise als eine Verbundscheibe in einem Kraftfahrzeug oder als Scheibe in einem Gebäude verwendet werden. Bezugszeichenliste The technical advantage achieved by the glazing 100 is that the visibility of light patterns in one direction (inwards), which are generated by the decoupled light, is increased. In contrast, the visibility of light patterns in the other direction (outward) is reduced. The glazing 100 can be used, for example, as a laminated pane in an automobile or as a pane in a building. reference list
100 Verglasung 100 glazing
101 Lichtquelle 103 Scheibe 101 light source 103 disc
105 Lichtauskoppelbereich 105 light decoupling area
107 metallbasierte Funktionsschicht107 metal-based functional layer
109 Außenseite/Innenseite 109 outside/inside
111 elektrooptisches Funktionselement 113 Laser 111 electro-optical functional element 113 laser
115 Reflexionselement 115 reflective element
117 Lichteinkoppelbereich 117 light coupling area
119 Abdeckschicht 119 cover layer

Claims

Patentansprüche patent claims
1. Verglasung (100), welche umfasst: mindestens eine Scheibe (103-2), insbesondere eine Glasscheibe, mindestens eine an der Scheibe (103-2) angeordnete Lichtquelle (101) zum Einkoppeln von Licht in die Scheibe (103-2), wobei die Scheibe (103-2) mindestens einen Lichtauskoppelbereich (105) zum Auskoppeln von in der Scheibe (103-2) totalreflektierten Lichts aus der Scheibe (103-2) aufweist, wobei die Verglasung (100) und bevorzugt die Scheibe (103-2) mindestens eine metallbasierte Funktionsschicht (107-1, 107-2, 107-3) und/oder mindestens ein elektrooptisches Funktionselement (111) zum elektrischen Schalten von optischen Eigenschaften aufweist. 1. Glazing (100), which comprises: at least one pane (103-2), in particular a glass pane, at least one light source (101) arranged on the pane (103-2) for coupling light into the pane (103-2) , wherein the pane (103-2) has at least one light decoupling region (105) for decoupling light that is totally reflected in the pane (103-2) out of the pane (103-2), wherein the glazing (100) and preferably the pane (103 -2) has at least one metal-based functional layer (107-1, 107-2, 107-3) and/or at least one electro-optical functional element (111) for electrically switching optical properties.
2. Verglasung (100) nach Anspruch 1 , bei welcher die mindestens eine Lichtquelle (101) seitlich der Scheibe (103-2) oder in einer Aussparung oder Durchbrechung der Scheibe (103-2) angeordnet ist. 2. Glazing (100) according to claim 1, in which the at least one light source (101) is arranged on the side of the pane (103-2) or in a recess or opening in the pane (103-2).
3. Verglasung (100) nach einem der Ansprüche 1 oder 2, bei welcher der mindestens eine Lichtauskoppelbereich (105) durch Aufdrucken und Einbrennen einer nicht-opaken Paste ausgebildet ist. 3. Glazing (100) according to one of claims 1 or 2, in which the at least one light decoupling region (105) is formed by imprinting and firing a non-opaque paste.
4. Verglasung (100) nach Anspruch einem der Ansprüche 1 bis 3, bei welcher der mindestens eine Lichtauskoppelbereich (105) durch mechanisches Aufrauen der Scheibenoberfläche im Lichtauskoppelbereich (105) ausgebildet ist. 4. Glazing (100) according to claim one of claims 1 to 3, in which the at least one light decoupling region (105) is formed by mechanically roughening the pane surface in the light decoupling region (105).
5. Verglasung (100) nach Anspruch einem der Ansprüche 1 bis 4, bei welcher der mindestens eine Lichtauskoppelbereich (105) auf einer Seite der Scheibe ausgebildet ist, die in Einbaulage einem Innenraum zugewandt ist. 5. Glazing (100) according to claim one of claims 1 to 4, in which the at least one light decoupling region (105) is formed on a side of the pane which faces an interior space in the installed position.
6. Verglasung (100) einem der Ansprüche 1 bis 5, bei welcher das mindestens eine elektrooptische Funktionselement (111) ein PDLC-Funktionselement, ein SPD- Funktionselement, ein PNLC-Funktionselement, ein elektrochromes Funktionselement oder ein Funktionselement mit Flüssigkristall-Farbstoffzellen ist. 6. Glazing (100) according to one of Claims 1 to 5, in which the at least one electro-optical functional element (111) is a PDLC functional element, an SPD functional element, a PNLC functional element, an electrochromic functional element or a functional element with liquid crystal dye cells.
7. Verglasung (100) nach einem der Ansprüche 1 bis 6, bei welcher die mindestens eine metallbasierte Funktionsschicht (107-1, 107-2, 107-3) dazu ausgebildet ist, Wärmestrahlung bei Raumtemperatur zu reflektieren und/oder auftreffendes Infrarotlicht zu reflektieren oder zu absorbieren. 7. Glazing (100) according to one of Claims 1 to 6, in which the at least one metal-based functional layer (107-1, 107-2, 107-3) is designed to absorb thermal radiation To reflect room temperature and / or to reflect or absorb incident infrared light.
8. Verglasung (100) nach einem der Ansprüche 1 bis 6, welche eine erste Scheibe (103-1) mit Außenseite und Innenseite und eine zweite Scheibe (103-2) mit Innenseite und Außenseite umfasst, wobei die Innenseiten der beiden Scheiben (103-1 , 103-2) zueinander weisen und die beiden Scheiben (103-1 , 103-2) durch mindestens eine thermoplastische Zwischenschicht fest miteinander verbunden sind, wobei in Einbaulage die Außenseite der ersten Scheibe (103-1) einer äußeren Umgebung und die Außenseite der zweiten Scheibe (103-2) einem Innenraum zugewandt ist, wobei der mindestens eine Lichtauskoppelbereich (105) zum Auskoppeln von in der Scheibe (103-2) total reflektierten Lichts aus der Scheibe (103-2) auf der Außenseite der ersten Scheibe (103-1) und/oder auf der Außenseite der zweiten Scheibe (103-2) ausgebildet ist. 8. Glazing (100) according to one of Claims 1 to 6, comprising a first pane (103-1) with an outer side and an inner side and a second pane (103-2) with an inner side and an outer side, the inner sides of the two panes (103 -1, 103-2) have to each other and the two panes (103-1, 103-2) are firmly connected to each other by at least one thermoplastic intermediate layer, wherein in the installed position the outside of the first pane (103-1) an external environment and the Outside of the second pane (103-2) faces an interior, the at least one light decoupling region (105) for decoupling light totally reflected in the pane (103-2) from the pane (103-2) on the outside of the first pane (103-1) and/or on the outside of the second pane (103-2).
9. Verglasung (100) nach Anspruch 8, bei welcher das mindestens eine elektrooptische Funktionselement (111) zwischen der ersten Scheibe (103-1) und der zweiten Scheibe (103-2) angeordnet ist. 9. Glazing (100) according to claim 8, in which the at least one electro-optical functional element (111) is arranged between the first pane (103-1) and the second pane (103-2).
10. Verglasung (100) nach Anspruch 8 oder 9, bei welcher die mindestens eine metallbasierte Funktionsschicht (107-1 , 107-2, 107-3), welche dazu ausgebildet ist, auftreffendes Infrarotlicht zu reflektieren oder zu absorbieren, zwischen der ersten Scheibe (103-1) und der zweiten Scheibe (103-2) angeordnet ist. 10. Glazing (100) according to claim 8 or 9, in which the at least one metal-based functional layer (107-1, 107-2, 107-3), which is designed to reflect or absorb incident infrared light, between the first pane (103-1) and the second disc (103-2) is arranged.
11. Verglasung (100) nach einem der Ansprüche 8 bis 10, bei welcher die mindestens eine metallbasierte Funktionsschicht (107-1 , 107-2, 107-3), welche dazu ausgebildet ist, Wärmestrahlung bei Raumtemperatur zu reflektieren, auf der Außenseite der zweiten Scheibe (103-2) angeordnet ist. 11. Glazing (100) according to one of claims 8 to 10, in which the at least one metal-based functional layer (107-1, 107-2, 107-3), which is designed to reflect thermal radiation at room temperature, on the outside of the second disc (103-2) is arranged.
12. Verfahren zum Herstellen einer Verglasung (100) nach einem der Ansprüche 1 bis 11 , mit den Schritten: 12. A method for producing a glazing (100) according to any one of claims 1 to 11, with the steps:
Bereitstellen mindestens einer Scheibe (103-2) und Anordnen mindestens einer metallbasierten Funktionsschicht (107-1 , 107-2, 107-3), und/oder mindestens eines elektrooptischen Funktionselement (111) zum elektrischen Schalten von optischen Eigenschaften,Providing at least one pane (103-2) and arranging at least one metal-based functional layer (107-1, 107-2, 107-3), and/or at least one electro-optical functional element (111) for electrical switching of optical properties,
Erzeugen mindestens eines Lichtauskoppelbereichs (105) zum Auskoppeln von in der Scheibe (103-2) totalreflektierten Lichts aus der Scheibe (103-2). 19 Generating at least one light decoupling region (105) for decoupling light totally reflected in the pane (103-2) out of the pane (103-2). 19
13. Verfahren zum Herstellen einer Verglasung (100) nach Anspruch 12, bei welchem mindestens eine Durchbrechung oder Aussparung zum Aufnehmen mindestens einer Lichtquelle (101) in der Scheibe (103-2) erzeugt wird. 13. Method for producing a glazing (100) according to claim 12, in which at least one opening or recess for receiving at least one light source (101) is produced in the pane (103-2).
14. Verfahren zum Herstellen einer Verglasung (100) nach einem der Ansprüche 12 oder 13, bei welchem eine erste Scheibe (103-1) mit Außenseite und Innenseite und eine zweite Scheibe (103-2) mit Innenseite und Außenseite, wobei die Innenseiten der beiden Scheiben (103-1 , 103- 2) zueinander weisen, durch mindestens eine thermoplastische Zwischenschicht fest miteinander verbunden werden. 14. Method for producing a glazing (100) according to one of claims 12 or 13, in which a first pane (103-1) with outside and inside and a second pane (103-2) with inside and outside, the insides of the both discs (103-1, 103- 2) facing each other are firmly connected to each other by at least one thermoplastic intermediate layer.
15. Verwendung der Verglasung (100) nach einem der Ansprüche 1 bis 11 in Gebäuden, insbesondere im Zugangs- oder Fensterbereich, als Einbauteil in Möbeln und Geräten, oder in Fortbewegungsmitteln für den Verkehr auf dem Lande, in der Luft oder zu Wasser, insbesondere in Zügen, Schiffen und Kraftfahrzeugen beispielsweise als Windschutzscheibe, Heckscheibe, Seitenscheibe und/oder Dachscheibe. 15. Use of the glazing (100) according to any one of claims 1 to 11 in buildings, in particular in the access or window area, as a built-in part in furniture and appliances, or in means of locomotion for traffic on land, in the air or on water, in particular in trains, ships and motor vehicles, for example as a windshield, rear window, side window and/or roof window.
PCT/EP2021/086187 2020-12-21 2021-12-16 Glazing having a light source WO2022136107A1 (en)

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WO2023031074A1 (en) 2021-08-31 2023-03-09 Saint-Gobain Glass France Vehicle laminated pane
WO2024047008A1 (en) * 2022-08-30 2024-03-07 Saint-Gobain Glass France Composite pane with electro-optical functional element and design element
WO2024126859A1 (en) * 2022-12-16 2024-06-20 Valeo Vision Vehicle lighting device having a light guide provided with a multilayer structure
WO2024149843A1 (en) 2023-01-13 2024-07-18 Saint-Gobain Glass France Illuminated glazing element with emissivity-reducing coating
WO2024165247A1 (en) * 2023-02-08 2024-08-15 Saint-Gobain Glass France Illuminable glazing with improved light coupling

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WO2015101744A1 (en) 2013-12-31 2015-07-09 Saint-Gobain Glass France Illuminated glass panel with optical isolator and manufacture thereof
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CN109606251A (en) 2018-12-26 2019-04-12 江苏铁锚玻璃股份有限公司 A kind of vehicle dormer window optical texture having both illumination and colored atmosphere light efficiency

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023031074A1 (en) 2021-08-31 2023-03-09 Saint-Gobain Glass France Vehicle laminated pane
WO2024047008A1 (en) * 2022-08-30 2024-03-07 Saint-Gobain Glass France Composite pane with electro-optical functional element and design element
WO2024126859A1 (en) * 2022-12-16 2024-06-20 Valeo Vision Vehicle lighting device having a light guide provided with a multilayer structure
FR3143716A1 (en) * 2022-12-16 2024-06-21 Valeo Vision Vehicle lighting device comprising a light guide provided with a multilayer structure
WO2024149843A1 (en) 2023-01-13 2024-07-18 Saint-Gobain Glass France Illuminated glazing element with emissivity-reducing coating
WO2024165247A1 (en) * 2023-02-08 2024-08-15 Saint-Gobain Glass France Illuminable glazing with improved light coupling

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