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WO2022148453A1 - 一种复合擦拭巾及其制造方法 - Google Patents

一种复合擦拭巾及其制造方法 Download PDF

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Publication number
WO2022148453A1
WO2022148453A1 PCT/CN2022/070907 CN2022070907W WO2022148453A1 WO 2022148453 A1 WO2022148453 A1 WO 2022148453A1 CN 2022070907 W CN2022070907 W CN 2022070907W WO 2022148453 A1 WO2022148453 A1 WO 2022148453A1
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WO
WIPO (PCT)
Prior art keywords
melt
blown
spunbond
fiber
wood pulp
Prior art date
Application number
PCT/CN2022/070907
Other languages
English (en)
French (fr)
Inventor
李世煌
郑庆中
刘幸幸
武丹聘
谢继华
Original Assignee
厦门延江新材料股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 厦门延江新材料股份有限公司 filed Critical 厦门延江新材料股份有限公司
Priority to US18/270,737 priority Critical patent/US20240052538A1/en
Publication of WO2022148453A1 publication Critical patent/WO2022148453A1/zh

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47KSANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K10/00Body-drying implements; Toilet paper; Holders therefor
    • A47K10/16Paper towels; Toilet paper; Holders therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/06Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by welding-together thermoplastic fibres, filaments, or yarns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/12Conjugate fibres, e.g. core/sheath or side-by-side
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14Mixture of at least two fibres made of different materials
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres

Definitions

  • the invention relates to the technical field of wipes, in particular to a composite wipe to prevent hair loss and increase mechanical strength for personal care and infant care and a manufacturing method thereof.
  • wipes are favored by consumers because they are quite convenient to carry and store, and are convenient to use. Wipes are often used in everyday life, such as when parents change diapers for babies, or when dining in restaurants, or when applying makeup to the skin. It can be seen that wipes are more and more widely used in personal care and infant care.
  • the wipe can be a spunlace non-woven product or a melt-blown composite non-woven product. Compared with the traditional cloth wipes, the production method is convenient, the price is low, and it can be used both dry and wet.
  • the existing melt-blown composite non-woven fabric is formed by compounding the melt-blown fiber layer as the surface layer and the wood pulp fiber layer as the middle layer. Because the wood pulp fiber has a short length, it is easy to fall off the melt-blown fiber layer. The so-called "hair loss" phenomenon occurs, and the melt-blown fiber layer is made of melt-blown fibers, and the melt-blown fibers are short fibers. After the fibers are consolidated, the mechanical properties of the formed melt-blown fiber layer are low. , thereby affecting the mechanical properties of the melt-blown composite wipes.
  • the purpose of the present invention is to provide a composite wipe that can effectively prevent hair loss and increase mechanical properties and a manufacturing method thereof, and overcome the defects of existing products and production methods.
  • the technical solution of the present invention is: a composite wipe, the upper surface layer and the lower surface layer of the wipe towel are melt-blown fiber webs, and the middle layer of the wipe towel is a wood pulp fiber web, There is a spunbond long fiber web composed of spunbond long fibers between the meltblown fiber web and the wood pulp fiber web of the upper surface layer or/and the lower surface layer, and the meltblown fiber web of the upper surface layer and the lower surface layer is The meltblown staple fibers in the web are interwoven into adjacent spunbond long fiber webs or wood pulp fiber webs.
  • the spunbond long fibers are single-component spunbond long fibers, bicomponent spunbond long fibers or blended spunbond long fibers of the two.
  • the grammage of the spunbond long fiber web is 2 ⁇ 20 g/m 2 .
  • melt-blown short fibers are single-component melt-blown short fibers, bi-component melt-blown short fibers, or melt-blown short fibers blended between the two.
  • the diameter of the meltblown short fibers is less than or equal to 10um.
  • the bi-component spunbond long fiber and the bi-component melt-blown short fiber are respectively composed of fibers with a melting point difference of more than 20 ° C and a surface containing a low-melting resin, and the fiber structure is a bi-component sheath-core type, double Component orange petal type or two-component side-by-side type.
  • the weight of the wood pulp fiber web is greater than 50% of the total weight of the wipe.
  • the weight of the wood pulp fiber web accounts for 65% to 80% of the total weight of the wiper.
  • a manufacturing method of a composite wipe comprising the following steps: (1) wood pulp is loosened and scattered by an opening roller, and a wood pulp fiber web is formed through a nozzle under the action of an auxiliary air flow; (2) a melt-blown process is adopted , heat the thermoplastic resin, and after melting, enter the melt-blown spinning device, and use the hot air flow in the melt-blown spinning device to blow the melt stream of the thermoplastic resin sprayed from the melt-blown spinneret of the melt-blown spinneret. Disperse into fiber bundles with a fiber diameter of ⁇ 10 ⁇ m, thereby forming a melt-blown fiber web with hot air flow; (3) Using a spunbond process, the thermoplastic resin is heated and melted into a spunbond spinning device.
  • the melt of the heated thermoplastic resin is changed into a thin stream of melt, which is then sprayed out through the spunbond spinneret hole of the spunbond spinneret, cooled by side blowing cold air, and the spunbond long fiber is drawn by the drawing device.
  • a spunbond long fiber web After stretching, a spunbond long fiber web is formed; (4) the formed meltblown fiber web is respectively intersected with the side of the adjacent wood pulp fiber web or spunbond long fiber web, forming a meltblown fiber web on both sides, and the middle is The multi-layer structure fiber web of wood pulp fiber web and spunbond long fiber web; (5) the multi-layer fiber web consolidates the fiber web together by a heating device to form the upper and lower layers as melt-blown fiber web, and the middle layer is a melt-blown fiber web.
  • the layer is a composite wipe of a wood pulp web and a spunbond filament web.
  • the structure types of the melt-blown spinneret holes and the spunbond spinneret holes are single-component spinneret holes, bi-component spinneret holes, or a mixed arrangement of the two.
  • the two-component spinneret holes are skin-core type, orange segment type or side-by-side type.
  • the heating device is a hot air oven, a hot roller or a combination of the two.
  • the composite wiper of the present invention also has a spunbond long fiber web between the surface layer melt-blown fiber web and the middle layer wood pulp fiber web, during the manufacturing process, the melt-blown fiber web in the melt-blown fiber web The short fibers are partially intertwined in the spunbond long fiber web and the wood pulp fiber web.
  • the spunbond long fiber web will be adhered to each other with the meltblown fiber web and the wood pulp fiber web.
  • an interwoven network structure is formed, which makes it difficult for the wood pulp staple fibers to move, and the formed wipes will not appear "hair loss" during use, effectively preventing the wood pulp staple fibers from absorbing water when the wipes are used with liquid.
  • the phenomenon of post-agglomeration occurs, and the spunbond long fiber web is composed of spunbond long fibers. Since the mechanical strength of the fiber itself is greatly improved compared with the meltblown short fibers, the mechanical strength of the composite wiper formed after the fiber web is consolidated It is also greatly improved, which solves the problems that the wipes are easily broken during use and have low mechanical strength.
  • FIG. 1 is a schematic diagram of the manufacture of the composite wipe in Example 1 of the present invention.
  • FIG. 2 is a cross-sectional view of the wipe in Example 1 of the present invention.
  • Example 3 is a schematic diagram of the manufacture of the composite wipe in Example 2 of the present invention.
  • Example 4 is a cross-sectional view of the composite wipe in Example 2 of the present invention.
  • 5A is a cross-sectional view of a sheath-core meltblown fiber of the present invention.
  • 5B is a cross-sectional view of a bicomponent side-by-side meltblown fiber of the present invention.
  • 5C is a cross-sectional view of a bicomponent orange-lobed meltblown fiber of the present invention.
  • Example 6 is a schematic diagram of the manufacture of the composite wipe of Example 3 of the present invention.
  • Example 7 is a cross-sectional view of the composite wipe of Example 3 of the present invention.
  • Example 1 Wood pulp 11, wood pulp fiber web 12, meltblown fiber web 13, 14, spunbond fiber web 15, multi-layer structure fiber web 16, wipe 17, opening roll A1, nozzle B1, melt Spinning device C1, C1', spunbonding spinning device D1, side blowing cold air E1, drafting device F1, hot roll G1.
  • Example 2 Wood pulp 21, wood pulp fiber web 22, meltblown fiber web 23, 24, spunbond fiber web 25, multi-layer structure fiber web 26, wipe 27, opening roll A2, nozzle B2, melt Jet spinning device C2, C2', spunbond spinning device D2, side blowing cold air E2, drafting device F2, hot air oven H2, sheath-core type meltblown fiber 28, two-component side-by-side meltblown fiber 29, double group Parts of orange-lobed meltblown fibers 30, core layer resin 28a, skin layer resin 28b, one resin 29b, 30b, the other resin 29a, 30a.
  • Example 3 Wood pulp 31, wood pulp fiber web 32, meltblown fiber web 33, 34, spunbond fiber web 35, 35', multi-layer structure fiber web 36, wipe 37, opening roll A3, nozzle B3, meltblown spinning device C3, C3', spunbond spinning device D3, D3', side blowing cold air E3, E3', drafting device F3, E3', hot roller G3, hot air oven H3.
  • the present invention discloses a manufacturing method of a composite wipe, which includes the following steps: (1) The wood pulp 11 is opened and scattered by the opening roller A1, and formed by the nozzle B1 under the action of the auxiliary air flow The wood pulp fiber web 12 .
  • thermoplastic resin polypropylene PP is heated, and after being melted, it enters the melt-blown spinning devices C1 and C1', and the melt-blown spinning devices C1 and C1' are used in the melt-blown spinning devices C1 and C1'.
  • the melt stream of thermoplastic resin ejected from the melt-blown spinneret holes of the plate is blown into fiber bundles with a fiber diameter of ⁇ 10 ⁇ m, and the melt-blown fiber webs 13 and 14 are formed with the hot air flow.
  • thermoplastic resin polypropylene PP is heated, melted and then entered into the spunbond spinning device D1, where the heated thermoplastic resin melt is turned into a melt stream in the spunbond spinning device D1 , and then sprayed through the spunbond spinneret holes of the spunbond spinneret, cooled by side-blown cold air E1, and drawn by the drafting device F1 to form the spunbond long fiber web 15.
  • meltblown fiber webs 13 and 14 intersect with the sides of the wood pulp fiber web 12 and the spunbond long fiber web 15 respectively, forming meltblown fiber webs 13 and 14 on both sides and wood pulp fibers in the middle.
  • the multi-layer fiber web 16 consolidates the fiber web together by the hot roller G1 to form the upper and lower layers are meltblown fiber webs 13 and 14, and the middle layer is wood pulp fiber web 12 and spunbond long fibers.
  • the present invention also discloses a composite wiper 17 that can be made by applying the above-mentioned manufacturing method of the composite wiper, wherein the upper and lower surface layers of the wiper are melt-blown fiber webs 13 and 14,
  • the middle layer is a wood pulp fiber web 12
  • a spunbond long fiber web 15 composed of spunbond long fibers is provided between the upper or lower surface layer meltblown fiber webs 13/14 and the wood pulp fiber web 12.
  • a spunbond long fiber web 15 composed of spunbond long fibers can also be simultaneously provided between the meltblown fibers 13 and 14 of the upper surface layer and the lower surface layer and the wood pulp fiber web 12 .
  • the meltblown short fibers in the meltblown fiber webs 13/14 of the upper or lower surface layer are partially interwoven into the spunbond long fiber web 15 or the wood pulp fiber web 12 adjacent to the meltblown fiber web.
  • the gram weight of the spunbond long fiber web 15 is 2 ⁇ 20 g/m 2
  • the gram weight of the spunbond long fiber web 15 in this embodiment is 10 g/m 2
  • the weight of the wood pulp fiber web 12 accounts for more than 50% of the total weight of the composite wiper 17, preferably 65% to 80%; in this embodiment, the weight of the wood pulp fiber web 12 accounts for the total weight of the composite wiper 17. The percentage by weight is 70%.
  • the meltblown short fibers in the meltblown fiber webs 13 and 14 are partially interwoven with the spunbond long fiber web 15 or wood pulp adjacent to the meltblown fiber webs 13 and 14.
  • an interwoven network structure is formed after passing through the hot roller G1, which makes it difficult for the wood pulp short fibers to move, so as to prevent the "hair loss” phenomenon that occurs when the composite wiper 17 is used, and also effectively prevent wiping.
  • the towel is used with liquid, the phenomenon that the wood pulp short fibers agglomerate after absorbing water, and the spunbond long fiber web 15 is composed of spunbond long fibers.
  • the mechanical strength of the fibers themselves will be greatly improved, thus solving the problem.
  • the wipes are easy to break when used, and the mechanical strength is low.
  • the present invention discloses a manufacturing method of a composite wipe, which includes the following steps: (1) The wood pulp 21 is opened and scattered by the opening roller A2, and formed by the nozzle B2 under the action of the auxiliary air flow The wood pulp fiber web 22 .
  • thermoplastic resin polypropylene PP and high-density polyethylene HDPE are heated respectively, and after melting, they enter the melt-blown spinning devices C2 and C2', and the heat is used in the melt-blown spinning devices C2 and C2'.
  • the air flow will blow the melt thin stream of thermoplastic resin ejected from the two-component melt-blown spinneret of the melt-blown spinneret into a fiber bundle with a fiber diameter of ⁇ 10 ⁇ m, and the hot air will form a fiber bundle composed of polypropylene PP and high-density polymer.
  • Meltblown fiber webs 23 and 24 composed of ethylene HDPE and bicomponent meltblown fibers containing high density polyethylene HDPE on the surface.
  • thermoplastic resin polypropylene PP and the high density polyethylene HDPE are heated respectively, and after being melted, they enter the spunbond spinning device D2, and the heated thermoplastic resin is melted in the spunbond spinning device D2.
  • the body becomes a thin stream of melt, and then it is sprayed out through the bi-component spunbond spinneret of the spunbond spinneret, cooled by side-blown cold air E2, and the spunbond long fiber is drawn by the drawing device F2 to form Spunbond long fiber web 25, wherein the spunbond long fiber is composed of polypropylene PP and high density polyethylene HDPE, and the surface contains bicomponent spunbond long fiber of high density polyethylene HDPE.
  • melt-blown fiber webs 23 and 24 intersect with the sides of the wood pulp fiber web 22 and the spunbond long fiber web 25 respectively, forming melt-blown fiber webs 23 and 24 on both sides and wood pulp fibers in the middle.
  • the multi-layer fiber web 26 consolidates the fiber web together by the hot air oven H2 to form the upper and lower layers are melt-blown fiber webs 23 and 24, and the middle layer is the wood pulp fiber web 22 and the spunbond long fiber Composite wiper 27 of mesh 25.
  • the present invention also discloses a composite wiper 27 that can be made by applying the above-mentioned manufacturing method of the composite wiper.
  • the upper and lower surface layers of the wiper are melt-blown fiber webs 23 and 24.
  • the middle layer is a wood pulp fiber web 22, and a spunbond long fiber web 25 composed of spunbond long fibers is provided between the upper or lower surface layer meltblown fiber webs 23/24 and the wood pulp fiber web 22.
  • a spunbond long fiber web 25 composed of spunbond long fibers can also be simultaneously disposed between the meltblown fibers 23 and 24 of the upper surface layer and the lower surface layer and the wood pulp fiber web 22 .
  • the meltblown short fibers in the meltblown fiber webs 23/24 of the upper or lower surface layers are partially interwoven into the spunbond long fiber web 25 or the wood pulp fiber web 22 adjacent to the meltblown fiber web.
  • the weight of the wood pulp fiber web 22 accounts for more than 50% of the total weight of the composite wiper 27, preferably 65% to 80%; in this embodiment, the weight of the wood pulp fiber web 12 accounts for the composite wiper. 17 The percentage of total weight is 70%.
  • the gram weight of the spunbond long fiber web 25 is 2-20 g/m 2
  • the gram weight of the spunbond long fiber web 15 in this embodiment is 15 g/m 2
  • the fiber structure of the melt-blown short fiber is a two-component skin-core type 28 (the core layer resin 28a is polypropylene PP, the skin layer resin 28b is high-density polyethylene HDPE, and the melting point of polypropylene PP and high-density polyethylene HDPE is 20 ° C difference.
  • two-component orange petal type 29 one resin 29a is polypropylene PP, the other resin 29b is high density polyethylene HDPE, and the polypropylene PP and high density polyethylene HDPE are
  • the melting point difference is more than 20 °C) (as shown in Figure 5B) or two-component side-by-side type 30 (one resin 30a is polypropylene PP, the other resin 30b is high-density polyethylene HDPE, and polypropylene PP and high-density polyethylene are used.
  • the melting points of ethylene HDPE differ by more than 20°C) (as shown in Figure 5C).
  • the spunbond long fiber web 25 and the meltblown fiber webs 23 and 24 are bicomponent fiber structures, the melting points of the two resins differ by more than 20°C, and the surface layer contains low-melting resins.
  • the low melting point resin on the surface of the bicomponent spunbond long fibers and the bicomponent meltblown short fibers begins to melt, so that the fibers are adhered to each other, and the meltblown short fibers in the meltblown fiber webs 23 and 24 are melted.
  • the present invention discloses a method for manufacturing a composite wiper and a composite wiper 37 produced by the method, comprising the following steps: (1) The wood pulp 31 is loosened and scattered by the opening roller A3 , under the action of the auxiliary airflow, the wood pulp fiber web 32 is formed through the nozzle B3.
  • thermoplastic resin polypropylene PP and high-density polyethylene HDPE are heated respectively, and after melting, they enter the melt-blown spinning devices C3 and C3', and the heat is used in the melt-blown spinning devices C3 and C3'.
  • the air flow will blow the melt stream of thermoplastic resin sprayed from the two-component melt-blown spinneret of the melt-blown spinneret into a fiber bundle with a fiber diameter of ⁇ 10 ⁇ m, so as to form a high-density polypropylene PP and high-density fiber bundle with the hot air flow.
  • the melt-blown fiber webs 33 and 34 are composed of polyethylene HDPE, and the surface contains two-component melt-blown fibers of high-density polyethylene HDPE.
  • thermoplastic resin polypropylene PP is heated, melted, and then enters the spunbond spinning device D3, where the heated thermoplastic resin melt is turned into a melt stream in the spunbond spinning device D3 , and then sprayed out through the spinneret holes of the spunbond spinneret, cooled by side-blown cold air E3, and the spunbond long fibers are drawn by the drafting device F3 to form a spunbond long fiber web 35.
  • thermoplastic resin polypropylene PP is heated, melted and then enters the spunbond spinning device D3', where the heated thermoplastic resin melt is turned into a melt in the spunbond spinning device D3'.
  • the thin stream is then sprayed out through the spinneret holes of the spunbond spinneret, cooled by side-blown cold air E3', and the spunbond long fibers are drawn by the drafting device F3' to form a spunbond long fiber web 35'.
  • the formed melt-blown fiber webs 33 and 34 intersect with the side surfaces of the wood pulp fiber web 32 and the spunbond long fiber webs 35 and 35' respectively, forming the sides of the melt-blown fiber webs 33 and 34.
  • the layers are a multi-layer structured web 36 with spunbond filament webs 35, 35' on both sides and a wood pulp web 32 in the middle.
  • the multi-layer fiber web 36 consolidates the fiber web together through the hot air oven H3 and the hot roller G3 to form the upper and lower layers as melt-blown fiber webs 33 and 34, and the middle layer is the spunbond fiber webs 33 and 34 on both sides.
  • Webs 35, 35' and composite wiper 37 (shown in Figure 7) with a wood pulp web 32 in between. Wherein, the weight of the wood pulp fiber web 32 accounts for 80% of the total weight of the composite wiper 37; the grammage distribution of the spunbond long fiber webs 35 and 35' is 20 g/m 2 .
  • the melting points of the two resins differ by more than 20°C, and the surface layer contains low-melting resins.
  • the low melting point resin of the surface layer of the component meltblown short fibers begins to melt, making the fibers adhere to each other, and the existence of the spunbond long fiber webs 35, 35' will interact with the meltblown fiber webs 33, 34 and the wood pulp fiber web 32.
  • Adhered to each other, when passing through the hot roller G2, the multi-layer structure fiber web 36 will form an intertwined network structure, so that the wood pulp short fibers in the upper and lower surface layers of the melt-blown fiber webs 33, 34 and the middle layer.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nonwoven Fabrics (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)

Abstract

一种复合擦拭巾(17、27、37)及其制造方法,复合擦拭巾(17、27、37)的上表面层与下表面层为熔喷纤维网(13、14、23、24、33、34),复合擦拭巾(17、27、37)的中间层为木浆纤维网(12、22、32),在上表面层或/和下表面层的熔喷纤维网(13、14、23、24、33、34)和木浆纤维网(12、22、32)之间具有由纺粘长纤维构成的纺粘长纤维网(15、25、35、35'),上表面层与下表面层的熔喷纤维网(13、14、23、24、33、34)中的熔喷短纤维交织于邻接的纺粘长纤维网(15、25、35、35')或木浆纤维网(12、22、32)之中。

Description

一种复合擦拭巾及其制造方法 技术领域
本发明涉及擦拭巾技术领域,尤其涉及应用于个人护理、婴幼儿护理用的一种防掉毛、增加力学强度的复合擦拭巾及其制造方法。
背景技术
目前,擦拭巾由于携带及收纳相当的方便,且使用便利,因此受到广大消费者的喜爱。在日常生活中常常需要用到擦拭巾,例如当父母替婴儿更换尿布时,或是餐厅用餐时,或是化妆护理皮肤时。可见,擦拭巾在个人护理、婴幼儿护理方面应用越来越广泛。擦拭巾可以是水刺无纺布制品,也可以是熔喷复合无纺布制品。较传统的布类擦拭巾,其生产方法方便,价格低廉,并且干湿均可使用。
技术问题
但是现有的熔喷复合无纺布是由熔喷纤维层作为表面层,木浆纤维层作为中间层,经复合后而形成的,由于木浆纤维长度较短,容易从熔喷纤维层掉出,即出现所谓的“掉毛”现象,并且熔喷纤维层由熔喷纤维铺网而成,熔喷纤维为短纤维,纤维之间固结后,形成的熔喷纤维层力学性能较低,从而影响熔喷复合擦拭巾的力学性能。
技术解决方案
本发明的目的在于提供一种可有效防止掉毛、增加力学性能的复合擦拭巾及其制造方法,克服现有产品及生产方法的缺陷。
为实现上述目的,本发明的解决技术方案是:一种复合擦拭巾,所述擦拭巾的上表面层与下表面层为熔喷纤维网,所述擦拭巾的中间层为木浆纤维网,在所述上表面层或/和下表面层的熔喷纤维网和木浆纤维网之间具有由纺粘长纤维构成的纺粘长纤维网,所述上表面层与下表面层的熔喷纤维网中的熔喷短纤维交织于邻接的纺粘长纤维网或木浆纤维网之中。
所述纺粘长纤维为单组分纺粘长纤维、双组份纺粘长纤维或两者共混纺粘长纤维。
所述纺粘长纤维网的克重为2~20g/m 2
所述熔喷短纤维为单组分熔喷短纤维、双组份熔喷短纤维或两者共混的熔喷短纤维。
所述熔喷短纤维的直径≤10um。
所述的双组份纺粘长纤维和所述的双组份熔喷短纤维分别由熔点相差20℃以上,且表面含有低熔点树脂的纤维构成,纤维结构为双组份皮芯型、双组份橘瓣型或双组份并列型。
所述木浆纤维网的重量占所述擦拭巾总重量的百分比大于50%。
所述木浆纤维网的重量占所述擦拭巾总重量的百分比为65%~80%。
一种复合擦拭巾的制造方法,包括下列步骤:(1)木浆通过开松辊开松打散,在辅助气流的作用下通过喷管形成木浆纤维网;(2)采用熔喷法工艺,将热塑性树脂加热,熔融后进入熔喷纺丝装置,在熔喷纺丝装置中利用热气流将从熔喷喷丝板的熔喷喷丝孔中喷出的热塑性树脂的熔体细流吹散成纤维直径≤10μm的纤维束,从而伴随热气流形成熔喷纤维网;(3)采用纺粘法工艺,将热塑性树脂加热,熔融后进入纺粘纺丝装置,在纺粘纺丝装置中将加热后的热塑性树脂的熔体变为熔体细流,然后通过纺粘喷丝板的纺粘喷丝孔中喷出,侧吹冷风冷却,并通过牵伸装置对纺粘长纤维进行牵伸后形成纺粘长纤维网;(4)所形成的熔喷纤维网分别与邻接的木浆纤维网或纺粘长纤维网的侧面处相交汇,形成两侧是熔喷纤维网,中间为木浆纤维网和纺粘长纤维网的多层结构纤维网;(5)所述多层纤维网通过加热装置将纤维网固结在一起,形成上、下两层为熔喷纤维网,中间层为木浆纤维网和纺粘长纤维网的复合擦拭巾。
所述熔喷喷丝孔和所述的纺粘喷丝孔的结构类型为单组分喷丝孔、双组份喷丝孔或两者相互混合排列。
所述的双组份喷丝孔为为皮芯型、橘瓣型或并列型。
所述加热装置为热风烘箱、热轧辊或两者相结合。
有益效果
采用上述技术方案后,由于本发明的复合擦拭巾在表面层熔喷纤维网和中间层木浆纤维网之间还具有纺粘长纤维网,在制造过程中,熔喷纤维网中的熔喷短纤维部分交织于纺粘长纤维网和木浆纤维网之中,形成的多层结构纤维网通过加热装置处理时,纺粘长纤维网会与熔喷纤维网和木浆纤维网相互粘连在一起,构成交织的网状结构,使得木浆短纤难以移动,进而所形成的擦拭巾在使用时不会出现“掉毛”的现象,有效防止擦拭巾配合液体使用时木浆短纤维在吸水后团聚的现象发生,同时纺粘长纤维网由纺粘长纤维组成,由于纤维本身力学强度相较于熔喷短纤维会大大提高,在纤维网固结后所形成的复合擦拭巾的力学强度也大大提高,解决了擦拭巾在使用时容易断裂,力学强度低的问题。
附图说明
图1 为本发明实施例1中复合擦拭巾的制造示意图。
图2 为本发明实施例1中擦拭巾的剖面图。
图3为本发明实施例2中复合擦拭巾的制造示意图。
图4为本发明实施例2中复合擦拭巾的剖面图。
图5A为本发明的皮芯型熔喷纤维的截面图。
图5B为本发明的双组份并列型熔喷纤维的截面图。
图5C为本发明的双组份橘瓣型熔喷纤维的截面图。
图6为本发明实施例3的复合擦拭巾的制造示意图。
图7为本发明实施例3的复合擦拭巾的剖面图。
符号说明。
【实施例1】木浆11,木浆纤维网12,熔喷纤维网13、14,纺粘纤维网15,多层结构纤维网16,擦拭巾17,开松辊A1,喷管B1,熔喷纺丝装置C1、C1’ ,纺粘纺丝装置D1,侧吹冷风E1,牵伸装置F1,热轧辊G1。
【实施例2】木浆21,木浆纤维网22,熔喷纤维网23、24,纺粘纤维网 25,多层结构纤维网26,擦拭巾27,开松辊A2,喷管B2,熔喷纺丝装置C2、C2’ ,纺粘纺丝装置D2,侧吹冷风E2,牵伸装置F2,热风烘箱H2,皮芯型熔喷纤维28,双组份并列型熔喷纤维29,双组份橘瓣型熔喷纤维30,芯层树脂28a,皮层树脂28b,其中一种树脂29b、30b,另一种树脂29a、30a。
【实施例3】木浆31,木浆纤维网32,熔喷纤维网33、34 ,纺粘纤维网 35、 35’,多层结构纤维网36 ,擦拭巾37,开松辊A3 ,喷管B3,熔喷纺丝装置C3、C3’ ,纺粘纺丝装置D3、D3’,侧吹冷风E3、 E3’  ,牵伸装置F3、E3’ ,热轧辊G3,热风烘箱H3。
本发明的实施方式
为了进一步解释本发明的技术方案,下面通过具体实施例来对本发明进行详细阐述。
实施例1。
如图1所示,本发明揭示了一种复合擦拭巾的制造方法,包括下列步骤:(1)木浆11通过开松辊A1开松打散,在辅助气流的作用下通过喷管B1形成木浆纤维网12。
(2)采用熔喷法工艺,将热塑性树脂聚丙烯PP加热,熔融后进入熔喷纺丝装置C1、C1’,在熔喷纺丝装置C1、C1’中利用热气流将从熔喷喷丝板的熔喷喷丝孔中喷出的热塑性树脂的熔体细流吹散成纤维直径≤10μm的纤维束,伴随热气流形成熔喷纤维网13、14。
(3)采用纺粘法工艺,将热塑性树脂聚丙烯PP加热,熔融后进入纺粘纺丝装置D1,在纺粘纺丝装置D1中将加热后的热塑性树脂的熔体变为熔体细流,然后通过纺粘喷丝板的纺粘喷丝孔中喷出,侧吹冷风E1冷却,并通过牵伸装置F1对纺粘长纤维进行牵伸后形成纺粘长纤维网15。
(4)所形成的熔喷纤维网13、14分别与木浆纤维网12和纺粘长纤维网15的侧面处相交汇,形成两侧是熔喷纤维网13、14,中间为木浆纤维网12和纺粘长纤维网15的多层结构纤维网16。
(5)所述多层纤维网16通过热轧辊G1将纤维网固结在一起,形成上、下两层为熔喷纤维网13、14,中间层为木浆纤维网12和纺粘长纤维网15的复合擦拭巾17。
如图2所示,本发明还揭示了一种可应用上述复合擦拭巾的制造方法制成的复合擦拭巾17,所述擦拭巾的上、下两表面层为熔喷纤维网13、14,中间层为木浆纤维网12,在所述的上表面层或下表面层熔喷纤维网13/14和木浆纤维网12之间具有由纺粘长纤维构成的纺粘长纤维网15。当然,亦可同时在上表面层与下表面层的熔喷纤维13、14与木浆纤维网12之间同时设置由纺粘长纤维构成的纺粘长纤维网15。所述的上表面层或下表面层的熔喷纤维网13/14中的熔喷短纤维部分交织于邻接于熔喷纤维网的纺粘长纤维网15或木浆纤维网12之中。
其中,纺粘长纤维网15的克重为2~20g/m 2,此实施例中纺粘长纤维网15的克重为10g/m 2。木浆纤维网12的重量占所述复合擦拭巾17总重量的百分比大于50%,最佳为65%~80%;此实施例中木浆纤维网12的重量占所述复合擦拭巾17总重量的百分比为70%。
采用上述技术方案后,由于纺粘长纤维网15的存在,熔喷纤维网13、14中的熔喷短纤维部分交织于熔喷纤维网13、14邻接的纺粘长纤维网15或木浆纤维网12之中,通过热轧辊G1后形成交织的网状结构,令木浆短纤难以移动,以防止所形成的复合擦拭巾17在使用时出现的“掉毛”现象,也有效防止擦拭巾配合液体使用时木浆短纤维在吸水后团聚的现象发生,同时纺粘长纤维网15由纺粘长纤维组成,由于纤维本身力学强度相较于熔喷短纤维会大大提高,从而解决了擦拭巾在使用时容易断裂,力学强度低的问题。
实施例2。
如图3所示,本发明揭示了一种复合擦拭巾的制造方法,包括下列步骤:(1)木浆21通过开松辊A2开松打散,在辅助气流的作用下通过喷管B2形成木浆纤维网22。
(2)采用熔喷法工艺,将热塑性树脂聚丙烯PP和高密度聚乙烯HDPE分别加热,熔融后进入熔喷纺丝装置C2、C2’,在熔喷纺丝装置C2、C2’中利用热气流将从熔喷喷丝板的双组份熔喷喷丝孔中喷出的热塑性树脂的溶体细流吹散成纤维直径≤10μm的纤维束,伴随热气流形成由聚丙烯PP和高密度聚乙烯HDPE组成且表面含有高密度聚乙烯HDPE的双组份熔喷纤维构成的熔喷纤维网23、24。
(3)采用纺粘法工艺,将热塑性树脂聚丙烯PP和高密度聚乙烯HDPE分别加热,熔融后进入纺粘纺丝装置D2,在纺粘纺丝装置D2中将加热后的热塑性树脂的熔体变为熔体细流,然后通过纺粘喷丝板的双组份纺粘喷丝孔中喷出,侧吹冷风E2冷却,并通过牵伸装置F2对纺粘长纤维进行牵伸后形成纺粘长纤维网25,其中纺粘长纤维是由聚丙烯PP和高密度聚乙烯HDPE组成的,且表面含有高密度聚乙烯HDPE的双组份纺粘长纤维。
(4)所形成的熔喷纤维网23、24分别与木浆纤维网22和纺粘长纤维网25的侧面处相交汇,形成两侧是熔喷纤维网23、24,中间为木浆纤维网22和纺粘长纤维网25的多层结构纤维网26。
(5)所述多层纤维网26通过热风烘箱H2将纤维网固结在一起,形成上、下两层为熔喷纤维网23、24,中间层为木浆纤维网22和纺粘长纤维网25的复合擦拭巾27。
如图4所示,本发明还揭示了一种可应用上述复合擦拭巾的制造方法制成的复合擦拭巾27,所述擦拭巾的上、下两表面层为熔喷纤维网23、24,中间层为木浆纤维网22,在所述的上表面层或下表面层熔喷纤维网23/24和木浆纤维网22之间具有由纺粘长纤维构成的纺粘长纤维网25。当然,亦可同时在上表面层与下表面层的熔喷纤维23、24与木浆纤维网22之间同时设置由纺粘长纤维构成的纺粘长纤维网25。所述的上表面层或下表面层的熔喷纤维网23/24中的熔喷短纤维部分交织于邻接于熔喷纤维网的纺粘长纤维网25或木浆纤维网22之中。
其中,木浆纤维网22的重量占所述复合擦拭巾27总重量的百分比大于50%,最佳为65%~80%;此实施例中木浆纤维网12的重量占所述复合擦拭巾17总重量的百分比为70%。纺粘长纤维网25的克重为2~20g/m 2,此实施例中纺粘长纤维网15的克重为15g/m 2;双组份纺粘长纤维和所述的双组份熔喷短纤维的纤维结构为双组份皮芯型28(芯层树脂28a为聚丙烯PP,皮层树脂28b为高密度聚乙烯HDPE,且聚丙烯PP和高密度聚乙烯HDPE的熔点相差20℃以上)(见图5A所示)、双组份橘瓣型29(一种树脂29a为聚丙烯PP,另一种树脂29b为高密度聚乙烯HDPE,且聚丙烯PP和高密度聚乙烯HDPE的熔点相差20℃以上)(见图5B所示)或双组份并列型30(一种树脂30a为聚丙烯PP,另一种树脂30b为高密度聚乙烯HDPE,且聚丙烯PP和高密度聚乙烯HDPE的熔点相差20℃以上)(见图5C所示)。
采用上述技术方案后,由于纺粘长纤维网25和熔喷纤维网23、24 为双组份纤维结构,两种树脂的熔点相差20℃以上,并且表层含有低熔点树脂,在通过加热装置热风烘箱H2时,双组份纺粘长纤维和双组份熔喷短纤维的表层的低熔点树脂开始熔融,使得纤维之间互相粘连,并且在熔喷纤维网23、24中的熔喷短纤维部分交织于熔喷纤维网23、24邻接的纺粘长纤维网25或木浆纤维网22之中,使得木浆短纤维在由熔喷纤维网23、24 和纺粘长纤维网形成的交织网中难以移动,所形成的复合擦拭巾27在使用时不会出现“掉毛”的现象,也有效防止复合擦拭巾配合液体使用时木浆短纤维在吸水后团聚的现象发生,同时纺粘长纤维网25由纺粘长纤维组成,由于纤维本身力学强度相较于熔喷短纤维会大大提高,从而解决了擦拭巾在使用时容易断裂,力学强度低的问题。
实施例3。
如图6、7所示,本发明揭示了一种复合擦拭巾的制造方法以及用该方法制造的复合擦拭巾37,包括下列步骤:(1)木浆31通过开松辊A3开松打散,在辅助气流的作用下通过喷管B3形成木浆纤维网32。
(2)采用熔喷法工艺,将热塑性树脂聚丙烯PP和高密度聚乙烯HDPE分别加热,熔融后进入熔喷纺丝装置C3、C3’,在熔喷纺丝装置C3、C3’中利用热气流将从熔喷喷丝板的双组份熔喷喷丝孔中喷出的热塑性树脂的溶体细流吹散成纤维直径≤10μm的纤维束,从而伴随热气流形成由聚丙烯PP和高密度聚乙烯HDPE组成的,且表面含有高密度聚乙烯HDPE的双组份熔喷纤维构成的熔喷纤维网33、34。
(3)采用纺粘法工艺,将热塑性树脂聚丙烯PP加热,熔融后进入纺粘纺丝装置D3,在纺粘纺丝装置D3中将加热后的热塑性树脂的熔体变为熔体细流,然后通过纺粘喷丝板的喷丝孔中喷出,侧吹冷风E3冷却,并通过牵伸装置F3对纺粘长纤维进行牵伸后形成纺粘长纤维网35。
(4)采用纺粘法工艺,将热塑性树脂聚丙烯PP加热,熔融后进入纺粘纺丝装置D3’,在纺粘纺丝装置D3’中将加热后的热塑性树脂的熔体变为熔体细流,然后通过纺粘喷丝板的喷丝孔中喷出,侧吹冷风E3’冷却,并通过牵伸装置F3’对纺粘长纤维进行牵伸后形成纺粘长纤维网35’。
(5)所形成的熔喷纤维网33、34分别与木浆纤维网32和纺粘长纤维网35、35’的侧面处相交汇,形成两侧表面是熔喷纤维网33、34,中间层为两侧为纺粘长纤维网35、35’和中间为木浆纤维网32的多层结构纤维网36。
(6)所述多层纤维网36通过热风烘箱H3和热轧辊G3将纤维网固结在一起,形成上、下两层为熔喷纤维网33、34,中间层为两侧为纺粘长纤维网35、35’和中间为木浆纤维网32的复合擦拭巾37(见图7所示)。其中,木浆纤维网32的重量占所述复合擦拭巾37总重量的百分比为80%;纺粘长纤维网35、35’的克重分布为20g/m 2
采用上述技术方案后,由于熔喷纤维网33、34为双组份纤维结构,两种树脂的熔点相差20℃以上,并且表层含有低熔点树脂,因此,在通过加热装置热风烘箱H2时,双组份熔喷短纤维的表层的低熔点树脂开始熔融,使得纤维之间互相粘连,并且纺粘长纤维网35,35’的存在,会与熔喷纤维网33、34和木浆纤维网32相互粘连在一起,在通过热轧辊G2时,多层结构纤维网36会形成交织的网状结构,使得木浆短纤维在由上、下表面层熔喷纤维网33、34 和中间层中两侧纺粘长纤维网35、35’形成的交织网中难以移动,使得所形成的复合擦拭巾37在使用时更不会出现“掉毛”的现象,同时也有效防止复合擦拭巾配合液体使用时木浆短纤维在吸水后团聚的现象发生。

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  1. 一种复合擦拭巾,其特征在于:所述擦拭巾的上表面层与下表面层为熔喷纤维网,所述擦拭巾的中间层为木浆纤维网,在所述上表面层或/和下表面层的熔喷纤维网和木浆纤维网之间具有由纺粘长纤维构成的纺粘长纤维网,所述上表面层与下表面层的熔喷纤维网中的熔喷短纤维交织于邻接的纺粘长纤维网或木浆纤维网之中。
  2. 如权利要求1所述的一种复合擦拭巾,其特征在于:所述纺粘长纤维为单组分纺粘长纤维、双组份纺粘长纤维或两者共混纺粘长纤维。
  3. 如权利要求2所述的一种复合擦拭巾,其特征在于:所述双组份纺粘长纤维是由熔点相差20℃以上,且表面含有低熔点树脂的纤维构成,纤维结构为双组份皮芯型、双组份橘瓣型或双组份并列型。
  4. 如权利要求1所述的一种复合擦拭巾,其特征在于:所述纺粘长纤维网的克重为2~20g/m 2
  5. 如权利要求1所述的一种复合擦拭巾,其特征在于:所述熔喷短纤维为单组分熔喷短纤维、双组份熔喷短纤维或两者共混的熔喷短纤维。
  6. 如权利要求5所述的一种复合擦拭巾,其特征在于:所述双组份熔喷短纤维是由熔点相差20℃以上,且表面含有低熔点树脂的纤维构成,纤维结构为双组份皮芯型、双组份橘瓣型或双组份并列型。
  7. 如权利要求1所述的一种复合擦拭巾,其特征在于:所述熔喷短纤维的直径≤10um。
  8. 如权利要求1所述的一种复合擦拭巾,其特征在于:所述木浆纤维网的重量占所述擦拭巾总重量的百分比大于50%。
  9. 如权利要求8所述的一种复合擦拭巾,其特征在于:所述木浆纤维网的重量占所述擦拭巾总重量的百分比为65%~80%。
  10. 一种复合擦拭巾的制造方法,其特征在于,包括下列步骤:
    (1)木浆通过开松辊开松打散,在辅助气流的作用下通过喷管形成木浆纤维网;
    (2)采用熔喷法工艺,将热塑性树脂加热,熔融后进入熔喷纺丝装置,在熔喷纺丝装置中利用热气流将从熔喷喷丝板的熔喷喷丝孔中喷出的热塑性树脂的熔体细流吹散成纤维直径≤10μm的纤维束,从而伴随热气流形成熔喷纤维网;
    (3)采用纺粘法工艺,将热塑性树脂加热,熔融后进入纺粘纺丝装置,在纺粘纺丝装置中将加热后的热塑性树脂的熔体变为熔体细流,然后通过纺粘喷丝板的纺粘喷丝孔中喷出,侧吹冷风冷却,并通过牵伸装置对纺粘长纤维进行牵伸后形成纺粘长纤维网;
    (4)所形成的熔喷纤维网分别与邻接的木浆纤维网或纺粘长纤维网的侧面处相交汇,形成两侧是熔喷纤维网,中间为木浆纤维网和纺粘长纤维网的多层结构纤维网;
    (5)所述多层纤维网通过加热装置将纤维网固结在一起,形成上、下两层为熔喷纤维网,中间层为木浆纤维网和纺粘长纤维网的复合擦拭巾。
  11. 如权利要求10所述的一种复合擦拭的制造方法,其特征在于:所述熔喷喷丝孔和所述的纺粘喷丝孔的结构类型为单组分喷丝孔、双组份喷丝孔或两者相互混合排列。
  12. 如权利要11所述的复合擦拭巾的制造方法,其特征在于:所述的双组份喷丝孔为皮芯型、橘瓣型或并列型。
  13. 如权利要求10所述一种复合擦拭巾的制造方法,其特征在于:所述加热装置为热风烘箱、热轧辊或两者相结合。
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