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WO2021215423A1 - Préparation de produit cosmétique - Google Patents

Préparation de produit cosmétique Download PDF

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Publication number
WO2021215423A1
WO2021215423A1 PCT/JP2021/015976 JP2021015976W WO2021215423A1 WO 2021215423 A1 WO2021215423 A1 WO 2021215423A1 JP 2021015976 W JP2021015976 W JP 2021015976W WO 2021215423 A1 WO2021215423 A1 WO 2021215423A1
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WO
WIPO (PCT)
Prior art keywords
cosmetic
skin
cosmetic according
carbon atoms
acid
Prior art date
Application number
PCT/JP2021/015976
Other languages
English (en)
Japanese (ja)
Inventor
裕介 奥山
Original Assignee
株式会社 資生堂
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Publication of WO2021215423A1 publication Critical patent/WO2021215423A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87—Polyurethanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Definitions

  • the present invention relates to a cosmetic containing nicotinamide and a hydrophobically modified polyether urethane. More specifically, while maintaining the physiological activity based on nicotinamide and the unique film feeling based on the hydrophobically modified polyether urethane, it is excellent in freshness during application and non-stickiness of the back skin, and has a feeling of penetration into the skin. It is related to cosmetics that are high in quality, have no squeaky feeling, and have a good feeling of use.
  • the basic functions of skin care cosmetics include anti-drying, anti-ultraviolet rays, antioxidants, and activation. Some skin care cosmetics having these basic functions are effective for whitening and anti-aging by improving wrinkles and sagging and preventing rough skin. Vitamins are necessary for maintaining normal functioning of the whole body, and at the same time, they are important for maintaining the physiological function of the skin. Among them, vitamin Bs such as nicotinamide are known to be effective against seborrheic dermatitis and eczema, and also have a skin cell activating effect.
  • Patent Documents 1 and 2 disclose cosmetics containing nicotinamide in combination with other active ingredients and exhibiting an antiaging effect on the skin. However, when the cosmetic contains nicotinamide, an undesired feeling of use such as impaired freshness and strong stickiness of the back skin may occur.
  • the hydrophobically modified polyether urethane is known as a viscosity modifier (also called an associative thickener) with less temperature dependence of viscosity, and cosmetics containing the hydrophobically modified polyether urethane are excellent in usability and unique. Since it has a film feeling, many cosmetics containing hydrophobically modified polyether urethane are commercially available.
  • a cosmetic containing a hydrophobically modified polyether urethane, preferably together with a water-soluble polymer such as a carboxyvinyl polymer has excellent stability over time and has a moist and non-greasy feel. Have been described.
  • the present invention has excellent usability such as freshness during application and non-stickiness of the back skin while simultaneously containing a nicotinic acid amide and a hydrophobically modified polyether urethane, and a unique film feeling due to the hydrophobically modified polyether urethane. It is an object of the present invention to provide a cosmetic having a good feel, which has a high penetration into the skin and does not have a squeaky feeling.
  • the present inventor has added an anionic surfactant having a sulfonic acid group in the molecule to a cosmetic containing a nicotinic acid amide and a hydrophobically modified polyether urethane. It has been found that the addition can significantly improve the usability (feel of use) of the cosmetic and solve the above-mentioned problems, and has completed the present invention.
  • the present invention (A) Nicotinamide, (B) Hydrophobic modified polyether urethane and (C) Provided is a cosmetic containing an anionic surfactant having a sulfonic acid group in the molecule.
  • the cosmetic of the present invention has a unique film feeling of the back skin due to the hydrophobically modified polyether urethane while blending nicotinamide, but has a freshness during application, and the back skin has a freshness. Stickiness can also be suppressed. Furthermore, it is possible to realize an unprecedented excellent usability that the feeling of penetration into the skin is high and there is no squeaky feeling.
  • the cosmetic of the present invention is characterized by containing (A) nicotinic acid amide, (B) hydrophobically modified polyether urethane, and (C) an anionic surfactant having a sulfonic acid group in the molecule as essential components. ..
  • A nicotinic acid amide
  • B hydrophobically modified polyether urethane
  • C an anionic surfactant having a sulfonic acid group in the molecule
  • the (A) nicotinamide (hereinafter, may be simply referred to as "component (A)") contained in the cosmetic of the present invention is an amide compound of nicotinic acid (also referred to as vitamin B3 or niacin). Nicotinamide is a water-soluble vitamin, which is a substance widely known as one of the B vitamins, and can be obtained by extracting from a natural product such as rice bran or synthesizing it by a known method.
  • the content of nicotinamide (component (A)) in the cosmetic of the present invention is not particularly limited, but is preferably 0.5 to 10% by mass, more preferably 1 to 10% by mass, based on the total amount of the cosmetic. %, More preferably 3 to 8% by mass.
  • nicotinamide (component (A)) in the cosmetic of the present invention is not particularly limited, but is preferably 0.5 to 10% by mass, more preferably 1 to 10% by mass, based on the total amount of the cosmetic. %, More preferably 3 to 8% by mass.
  • it is effective in terms of rough skin improving effect, whitening effect, and skin aging prevention effect based on the skin cell activating effect and epidermal cell ceramide synthesis promoting effect of nicotinamide (see Patent Document 2). You can get a feeling.
  • the (B) hydrophobically modified polyether urethane (hereinafter, may be simply referred to as “component (B)”) blended in the cosmetic of the present invention is a compound also called an associative thickener or an associative polymer. .. Specifically, those represented by the following formula (I) are preferable, but the present invention is not limited thereto.
  • R 1 represents an alkyl group having 2 to 4 carbon atoms.
  • R 2 and R 4 each independently represent an alkylene group or a phenylethylene group having 2 to 4 carbon atoms. It is preferably an alkylene group having 2 to 4 carbon atoms.
  • R 3 represents an alkylene group having 1 to 10 carbon atoms which may have a urethane bond.
  • R 5 represents a linear, branched or secondary alkyl group having 8 to 36 carbon atoms, preferably 12 to 24 carbon atoms.
  • m is a number of 2 or more, preferably 2.
  • h is a number of 1 or more, preferably 1.
  • k is a number from 1 to 500, preferably a number from 100 to 300.
  • n is a number from 1 to 200, preferably a number from 10 to 100.
  • the (PEG-240 / decyltetradeceth-20 / HDI) copolymer (INCI name: PEG-240 / HDI COPOLYMER BIS-DECYLTETRADECHETH-20 ETHE) Is preferably used.
  • Examples of commercially available products of the (PEG-240 / decyltetradeceth-20 / HDI) copolymer include "ADEKA NOL GT-700" (manufactured by ADEKA Corporation).
  • the content of the hydrophobically modified polyether urethane (component (B)) in the present invention is not particularly limited, but is usually preferably 0.3 to 3% by mass, more preferably 0.5 to 3% by mass, based on the total amount of cosmetics. It is 2.5% by mass, more preferably 0.5 to 2% by mass. Within this range, the unique film feeling of the hydrophobically modified polyether urethane can be obtained, and the cosmetic as a whole has freshness during application and can suppress stickiness of the back skin.
  • the "film feeling” in the present specification means a feeling that a soft film gently covers and protects the skin when applied to the skin.
  • the (C) sulfonic acid group-containing anionic surfactant (hereinafter, may be simply referred to as “component (C)”) blended in the cosmetic of the present invention has a hydrophobic portion and a hydrophilic portion. It is a surfactant having and, and is an anionic surfactant having a sulfonic acid group in the hydrophilic portion thereof.
  • R 1 CO-a- (CH 2 ) n SO 3 M 1 (II)
  • R 1 CO- represents a saturated or unsaturated fatty acid residue (acyl group) having an average number of carbon atoms of 10 to 22
  • a is -O- or -NR 2-
  • R 2 indicates a hydrogen atom or an alkyl group having 1 to 3 carbon atoms
  • M 1 indicates a hydrogen atom, alkali metals, alkaline earth metals, ammonium or organic amines
  • n indicates 1 to 1 to It is preferable to use the one represented by (indicating an integer of 3).
  • anionic surfactant having the (C) sulfonic acid group represented by the above formula (II) in the molecule include stearoyl methyl taurine salt, cocoyl methyl taurine salt, and lauroyl methyl taurine salt. Particularly preferred examples include sodium stearoylmethyltaurine (INCI name).
  • Commercially available products can be used as the component (C) in the present invention, such as NIKKOL SMT (sodium stearoylmethyl taurine, manufactured by Nikko Chemicals Co., Ltd.), NIKKOL LMT (sodium lauroylmethyl taurine, manufactured by Nikko Chemicals Co., Ltd.), NIKKOL CMT-30. (Sodium cocoyl methyl taurine, manufactured by Nikko Chemicals Co., Ltd.) and the like can be exemplified.
  • the content of the component (C) in the present invention is not particularly limited, but is usually preferably 0.1 to 3% by mass, more preferably 0.1 to 2% by mass, and further, based on the total amount of the cosmetics. It is preferably 0.3 to 1.5% by mass. If the component (C) is blended in this range, it is possible to effectively suppress the decrease in freshness during application and the stickiness of the back skin due to the coexistence of nicotinamide and the hydrophobically modified polyether urethane. In addition, "stickiness of the back skin” in this specification means that the skin becomes sticky after being applied to the skin.
  • the anionic surfactant which is the component (C)
  • stickiness and the like caused by (A) nicotinic acid amide and (B) hydrophobically modified polyether urethane are suppressed.
  • another surfactant may be contained.
  • Other surfactants are ionic surfactants and nonionic surfactants containing anionic (however, those having no sulfonic acid group in the molecule), cationic and amphoteric, and cosmetics and the like. It is selected from those that can be blended in.
  • the types and amounts of other surfactants are limited to the range that does not impair the effects of the present invention.
  • the cosmetics of the present invention also include aspects that do not contain nonionic surfactants.
  • Amino acids or derivatives thereof can be contained alone or in combination of two or more. Particularly preferred examples include arginine and trimethylglycine.
  • the amount of the component (D) blended in the cosmetic of the present invention is not particularly limited, but is 0 from the viewpoint of improving the non-stickiness, penetration and squeaky feeling of the back skin of the cosmetic. It is preferably 0.01 to 3% by mass, more preferably 0.05 to 2% by mass, still more preferably 0.1 to 1.5% by mass.
  • the essential ingredients (A), (B) and (C) are all water-soluble, there is no stickiness on the back skin, the feeling of penetration into the skin is excellent, and there is no squeaky feeling.
  • the cosmetic of the present invention may contain other optional ingredients as long as the effects of the present invention are not impaired.
  • Other optional components include, for example, aqueous media, water-soluble polymers (excluding component (B)), oils, UV absorbers, moisturizers, chemicals, chelating agents, preservatives, antioxidants, powders. , Perfume, colorant, pigment and the like, and can be appropriately blended depending on the form and use of the cosmetic.
  • Moisturizers include, for example, polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, martitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-hydroxystearate. , Sodium lactate, bile acid salt, dl-pyrrolidone carboxylate, alkylene oxide derivative, short chain soluble collagen, diglycerin (EO) PO adduct and the like.
  • EO represents ethylene oxide
  • PO] represents propylene oxide.
  • the oil content is not particularly limited, and various oil components widely used in cosmetics can be blended, regardless of whether it is a solid oil content or a liquid oil content.
  • the solid oil content is a solid or semi-solid oil content at room temperature that is generally used for cosmetics.
  • oils include, for example, cacao butter, coconut oil, horse oil, hardened coconut oil, palm oil, beef fat, sheep oil, hardened beef fat, palm kernel oil, pig oil, beef bone oil, wax kernel oil, hardened oil, etc.
  • Solid fats and oils such as beef leg fat, mokuro, and hardened castor oil; Waxes such as hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, cellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, POE hydrogenated lanolin alcohol ether; polyethylene wax, paraffin wax, ceresin, vaseline, micro Hydrocarbon waxes such as crystallin wax and lunacera; fatty acid glyceryl ethers such as monostearyl glycerin ether (bacyl alcohol); fatty acid glycerides such as acetoglyceride and tri-2-heptyl undecanoic acid glyceride, and one of them or Two or more types can be used in combination.
  • Waxes such as hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, cellac wax, POE lanolin alcohol ether, POE
  • the liquid oil content is a liquid oil content at room temperature that is generally used for cosmetics.
  • oils include, for example, avocado oil, evening primrose oil, camellia oil, turtle oil, macadamia nut oil, sunflower oil, almond oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, palmitic acid, wheat germ.
  • Oil Southernca oil, Himashima oil, Amani oil, Saflower oil, Cotton seed oil, Eno oil, Soybean oil, Palmitic acid, Tea seed oil, Kaya oil, Rice bran oil, Glycerol oil, Japanese millet oil, Johoba oil, germ oil, etc.
  • Liquid fats and oils Liquid fats and oils; cetyl octanate, 2-ethylhexanoate cetyl, hexyldecyl dimethyloctanoate, ethyllaurate, hexyl laurate, isopropyl myristate, 2-hexyldecyl myristate, myristyl myristate, octyldodecyl myristate, palmitic acid Isopropyl acid, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, 2-heptylundecyl palmitate, butyl stearate, isocetyl stearate, isosetyl isostearate, decyl oleate, dodecyloleate, oleyl oleate, myristyl lactate , Cetyl lactate, diisostearyl malate,
  • the ultraviolet absorber examples include benzoic acid-based ultraviolet absorbers such as paraaminobenzoic acid; anthranilic acid-based ultraviolet absorbers such as methyl anthranilate; salicylic acid-based ultraviolet absorbers such as octyl salicylate; isopropyl paramethoxysilicate and paramethoxykei.
  • a silicic acid-based ultraviolet absorber such as octyl dermatate; a pyridazine derivative such as dimorpholinopyridadinone; a benzoylmethane derivative such as 4-methoxy-4'-t-butyldibenzoylmethane; 3- (4'-methylbenzylidene) ) -D, l-Phenyl, 3-Bendylidene-d, l-Phenyl and other phenyl derivatives; 2,2'-hydroxy-5-methylphenylbenzotriazole, 2- (2'-hydroxy-5'-t-octyl) Phenyl) benzotriazole, benzotriazole derivatives such as 2- (2'-hydroxy-5'-methylphenylbenzotriazole; others; 2-phenyl-5-methylbenzoxazole; dibenzalazine; dianisoilmethane; 5- (3,3) 3-Dimethyl-2-norbornylidene) -3-pentan
  • Drugs include, for example, ascorbic acid (vitamin C), tranexamic acid, codic acid, ellagic acid, arbutin, alkoxysalicylic acid, glycyrrhizic acid, tocopherol, retinol and salts or derivatives thereof (eg, sodium L-ascorbic acid, L- Ascorbic acid ester magnesium salt, L-ascorbic acid glucoside, 2-O-ethyl-L-ascorbic acid, 3-O-ethyl-L-ascorbic acid, 4-methoxysalicylic acid sodium salt, 4-methoxysalicylic acid potassium salt, glycyrrhizic acid Dipotassium, stearyl glycyrrhizinate, tocophenol acetate, retinol acetate, retinol palmitate, etc.) can be exemplified. Further, various extracts and the like can be blended, but the cosmetic of the present invention also
  • Chelating agents include citramaric acid, agaric acid, glyceric acid, shikimic acid, hinokithiol, gallic acid, tannic acid, coffee acid, ethylenediamine tetraacetic acid, ethylene glycol diamine tetraacetic acid, diethylenetriamine pentaacetic acid, phytic acid, polyphosphate, metaphosphate. , And their analogs, alkali metal salts, carboxylic acid esters, and the like.
  • Preservatives include paraoxybenzoic acid esters such as methylparaben, ethylparaben, and butylparaben, benzoic acid, salicylic acid, sorbic acid, parachlormethacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, and photosensitive agents. Element, phenoxyethanol and the like can be mentioned.
  • antioxidant examples include ⁇ -tocopherol, carotenoid and the like.
  • the cosmetics according to the present invention include pharmaceuticals, non-pharmaceutical products (ointments, etc.) and basic cosmetics such as washing pigments, lotions, milky lotions, creams, gels, essences (beauty essences), packs, masks, etc .; foundations, lipsticks, etc. Makeup cosmetics; sun care products such as sunscreens; aromatic cosmetics; body cosmetics and the like.
  • basic cosmetics such as washing pigments, lotions, milky lotions, creams, gels, essences (beauty essences), packs, masks, etc .
  • Makeup cosmetics such as sunscreens
  • aromatic cosmetics such as aromatic cosmetics
  • body cosmetics and the like it is suitable for providing as a skin cosmetic in view of the feeling of use when applied to the skin and the effect based on nicotinamide.
  • the present invention will be described in more detail with reference to specific examples below, but the present invention is not limited to the following examples.
  • the blending amount in the following examples indicates mass% with respect to the total amount of cosmetics.
  • Oil-in-water cosmetics having the compositions listed in Tables 1 and 2 below were prepared by a conventional method, and the above items (1) to (5) were evaluated.
  • Comparative Example 1 in Table 1 is a cosmetic containing (A) nicotinamide and containing PEG-60 glyceryl isostearate, which is a nonionic surfactant.
  • the cosmetic of Comparative Example 1 had good penetration and no squeaky feeling, and was slightly inferior in freshness and non-stickiness of the back skin, but at a level where there was no practical problem.
  • (B) hydrophobically modified polyether urethane is not blended, it is not possible to obtain a skin film feeling after application as a matter of course.
  • Comparative Example 2 was a cosmetic containing (A) nicotinamide and (B) hydrophobically modified polyether urethane, and the film feeling after application was good.
  • the surfactant to be blended is nonionic
  • the freshness, the non-stickiness of the back skin, the permeation feeling and the lack of squeaky feeling are remarkably reduced.
  • This tendency was not improved by replacing the nonionic surfactant with sodium stearoyl glutamate, which is an anionic surfactant having no sulfonic acid group (Comparative Example 3).

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Le but de la présente invention est de fournir une préparation cosmétique qui contient du nicotinamide et qui donne, après application, une sensation de film de revêtement sur la peau qui est due à un polyéther uréthane modifié hydrophobisé et qui est néanmoins excellente en matière de fraîcheur pendant l'application et de peau non collante après l'application. La présente invention concerne une préparation de produit cosmétique caractérisée en ce qu'elle comprend (A) du nicotinamide, (B) un polyéther uréthane hydrophobisé, et (C) un agent tensioactif anionique possédant un groupe acide sulfonique dans la molécule.
PCT/JP2021/015976 2020-04-24 2021-04-20 Préparation de produit cosmétique WO2021215423A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2020-077012 2020-04-24
JP2020077012A JP2021172610A (ja) 2020-04-24 2020-04-24 化粧料

Publications (1)

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WO2021215423A1 true WO2021215423A1 (fr) 2021-10-28

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118201590A (zh) * 2021-12-03 2024-06-14 株式会社资生堂 化妆品

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06293625A (ja) * 1993-04-08 1994-10-21 Asahi Chem Ind Co Ltd 化粧水
JPH09505822A (ja) * 1993-12-02 1997-06-10 バイヤースドルフ・アクチエンゲゼルシヤフト Ｌ−アルギニン、ｌ−オルニチン又はｌ−シトルリン及びこれらの物質の局所用調製物類の使用
JP2009227646A (ja) * 2008-03-25 2009-10-08 Shiseido Co Ltd 皮膚外用剤
JP2014122199A (ja) * 2012-12-21 2014-07-03 L'oreal Sa 化粧品組成物
WO2019098352A1 (fr) * 2017-11-17 2019-05-23 ロート製薬株式会社 Composition cosmétique, méthode de criblage, et méthode cosmétique
JP2019131547A (ja) * 2018-01-31 2019-08-08 株式会社コーセー 水性組成物
JP2020132631A (ja) * 2019-02-15 2020-08-31 ロート製薬株式会社 皮膚外用組成物

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06293625A (ja) * 1993-04-08 1994-10-21 Asahi Chem Ind Co Ltd 化粧水
JPH09505822A (ja) * 1993-12-02 1997-06-10 バイヤースドルフ・アクチエンゲゼルシヤフト Ｌ−アルギニン、ｌ−オルニチン又はｌ−シトルリン及びこれらの物質の局所用調製物類の使用
JP2009227646A (ja) * 2008-03-25 2009-10-08 Shiseido Co Ltd 皮膚外用剤
JP2014122199A (ja) * 2012-12-21 2014-07-03 L'oreal Sa 化粧品組成物
WO2019098352A1 (fr) * 2017-11-17 2019-05-23 ロート製薬株式会社 Composition cosmétique, méthode de criblage, et méthode cosmétique
JP2019131547A (ja) * 2018-01-31 2019-08-08 株式会社コーセー 水性組成物
JP2020132631A (ja) * 2019-02-15 2020-08-31 ロート製薬株式会社 皮膚外用組成物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE MINTEL July 2018 (2018-07-01), ANONYMOUS: "Ampoule Serum", XP055860870, retrieved from MINTEL Database accession no. 5853595 *

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