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WO2021249042A1 - 一种高世代tft-lcd玻璃基板生产线 - Google Patents

一种高世代tft-lcd玻璃基板生产线 Download PDF

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Publication number
WO2021249042A1
WO2021249042A1 PCT/CN2021/089346 CN2021089346W WO2021249042A1 WO 2021249042 A1 WO2021249042 A1 WO 2021249042A1 CN 2021089346 W CN2021089346 W CN 2021089346W WO 2021249042 A1 WO2021249042 A1 WO 2021249042A1
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Prior art keywords
liquid
temperature
production line
glass substrate
glass
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PCT/CN2021/089346
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English (en)
French (fr)
Inventor
彭寿
张冲
金良茂
江龙跃
曹志强
朱明柳
沈玉国
Original Assignee
蚌埠中光电科技有限公司
中建材蚌埠玻璃工业设计研究院有限公司
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Priority to US17/778,255 priority Critical patent/US20230219835A1/en
Priority to KR1020227014863A priority patent/KR20220075408A/ko
Priority to JP2022506648A priority patent/JP7300553B2/ja
Publication of WO2021249042A1 publication Critical patent/WO2021249042A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/18—Stirring devices; Homogenisation
    • C03B5/183—Stirring devices; Homogenisation using thermal means, e.g. for creating convection currents
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/04—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in tank furnaces
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B18/00—Shaping glass in contact with the surface of a liquid
    • C03B18/02—Forming sheets
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B25/00—Annealing glass products
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B25/00—Annealing glass products
    • C03B25/04—Annealing glass products in a continuous way
    • C03B25/06—Annealing glass products in a continuous way with horizontal displacement of the glass products
    • C03B25/08—Annealing glass products in a continuous way with horizontal displacement of the glass products of glass sheets
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B33/00—Severing cooled glass
    • C03B33/02—Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/02—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating
    • C03B5/027—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating by passing an electric current between electrodes immersed in the glass bath, i.e. by direct resistance heating
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/167—Means for preventing damage to equipment, e.g. by molten glass, hot gases, batches
    • C03B5/1672—Use of materials therefor
    • C03B5/1675—Platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/18—Stirring devices; Homogenisation
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/18—Stirring devices; Homogenisation
    • C03B5/182—Stirring devices; Homogenisation by moving the molten glass along fixed elements, e.g. deflectors, weirs, baffle plates
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/18—Stirring devices; Homogenisation
    • C03B5/183—Stirring devices; Homogenisation using thermal means, e.g. for creating convection currents
    • C03B5/185—Electric means
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/18—Stirring devices; Homogenisation
    • C03B5/187—Stirring devices; Homogenisation with moving elements
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/225—Refining
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/235—Heating the glass
    • C03B5/2353—Heating the glass by combustion with pure oxygen or oxygen-enriched air, e.g. using oxy-fuel burners or oxygen lances
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/42—Details of construction of furnace walls, e.g. to prevent corrosion; Use of materials for furnace walls
    • C03B5/43—Use of materials for furnace walls, e.g. fire-bricks
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B7/00—Distributors for the molten glass; Means for taking-off charges of molten glass; Producing the gob, e.g. controlling the gob shape, weight or delivery tact
    • C03B7/02—Forehearths, i.e. feeder channels
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
    • Y02P40/57—Improving the yield, e-g- reduction of reject rates

Definitions

  • the invention relates to the production field of high-generation TFT-LCD glass, and specifically relates to a high-generation TFT-LCD glass substrate production line.
  • TFT-LCD glass substrate is a key strategic material in the electronic information display industry, and represents the highest level in the field of glass manufacturing. At present, my country has become the world's largest information display industry base. In 2018, the demand for glass substrates in mainland China was about 260 million square meters, of which the demand for 8.5-generation glass substrates was 233 million square meters. By 2020, my country's 8.5-generation and above TFT-LCD glass substrate market demand will exceed 300 million square meters, accounting for more than 50% of the world's total demand. The market space and development potential are huge.
  • Chinese invention patent CN 200810054509 describes the automatic processing and production line of TFT-LCD glass substrates, involving the entire process of cutting, grinding, inspection, and packaging. However, this patent does not involve the production process of the original glass substrate;
  • Chinese invention patent CN 201611102225 It relates to a heating system and a cleaning machine for a substrate glass cleaning machine. It mainly explains the automatic heating system used on the glass substrate post-processing cleaning machine and the cleaning machine using the heating system. However, the invention does not involve high-generation TFTs. -Technical content of LCD glass substrate production line.
  • the present invention provides a high-generation TFT-LCD glass substrate production line.
  • a high-generation TFT-LCD glass substrate production line which includes a kiln, a precious metal channel, a tin bath, an annealing kiln, a cutting machine, and a chip unloading machine that are connected in sequence.
  • a set of electrodes are symmetrically arranged on the inner wall, and a set of oxygen burning lances are arranged on the top of the furnace;
  • the precious metal channel includes a glass-liquid mixed flow stirring section, and two glass liquids are connected in parallel at one end of the glass-liquid mixed flow stirring section.
  • Heating, clarifying and cooling section One end of the two glass liquid heating, clarifying and cooling sections is connected to the furnace, and the other end of the glass liquid mixing and stirring section is also connected with a liquid supply tank, and the liquid supply tank is connected with the liquid inlet of the tin tank .
  • the flame injection ports of the set of oxygen burning guns are vertically downward, and the flame can contact the liquid surface of the molten glass in the furnace.
  • the precious metal channel includes a heating, clarifying and cooling section for molten glass, a mixed flow stirring section for molten glass, and a liquid supply tank that are connected in sequence.
  • the heating, clarification and cooling section of molten glass includes a heating channel connected to the furnace at one end, and a clarification tank and a cooling channel are sequentially connected to the other end of the heating channel;
  • the glass liquid mixing and stirring section includes a confluence channel, one end of the confluence channel is connected with the two cooling channels, a set of spoilers are arranged in the confluence channel, and at least one glass liquid stirring tank is connected to the other end of the confluence channel , The liquid outlet of the glass liquid stirring tank is connected to the liquid supply tank.
  • the spoilers in the set of spoilers are distributed in a staggered manner, and a section of serpentine flow passage is divided in the confluence channel by the division of a set of spoilers.
  • At least one glass liquid stirring tank is sequentially connected to the other end of the confluence channel.
  • the temperature of the liquid inlet of the tin bath is 1200-1400°C, and the temperature of the liquid outlet of the tin bath is 650-850°C.
  • a mixed protective gas of nitrogen and hydrogen is passed into the tin bath, wherein the proportion of hydrogen is 3-8%.
  • the temperature zones A, B, C, D, Ret and F are divided from the entrance to the exit, wherein the temperature of the A temperature zone is 600-800°C, the temperature of the B temperature zone is 500-700°C, and the temperature C
  • the temperature of the zone is 400-600°C
  • the temperature of the D temperature zone is 300-500°C
  • the temperature of the Ret temperature zone is 200-400°C
  • the temperature of the F temperature zone is 50-200°C
  • the TFT-LCD glass substrate production line of the present invention can stably produce 8.5-generation, 10.5/11-generation and other large-size TFT-LCD glass substrates, and has the advantages of large product size, excellent product performance, high production efficiency, and large production capacity.
  • Figure 1 is a schematic diagram of the structure of the present invention
  • Figure 2 is a schematic diagram of the structure of the kiln in Figure 1;
  • FIG. 3 is a schematic diagram of the structure of the precious metal channel in FIG. 1;
  • Fig. 4 is a schematic diagram of the structure of the annealing kiln in Fig. 1.
  • a high-generation TFT-LCD glass substrate production line which includes a furnace a, a precious metal channel b, a tin bath c, an annealing furnace d, a cutting machine e, and a sheet unloading machine f which are connected in sequence.
  • a set of electrodes 5 are symmetrically arranged on the inner walls of the kiln a, including both sides of the kiln wall a1, and a set of all-oxygen burning lances 6 are arranged on the top of the kiln a.
  • the all-oxygen burning lances 6 are Distributed vertically, the flame injection port is vertically downward, and the flame can contact the liquid surface of the molten glass in the furnace a. While the heating efficiency of the flame is significantly increased, the flame can also eliminate bubbles floating on the liquid surface.
  • the set of oxygen burning lances 6 are distributed in two rows and the two rows of oxygen burning lances 6 are staggered.
  • the production capacity of the furnace a is 20-100 tons/day, less than 20 tons/day will result in low melting efficiency and high cost, and more than 100 tons/day may cause the molten glass to not be fully and efficiently melted and affect the substrate glass Substrate quality.
  • the precious metal channel is a high-flow precious metal channel.
  • the precious metal channel includes a glass-liquid mixed-flow stirring section 1.
  • Two glass-liquid heating, clarification and cooling sections 2 are connected in parallel at one end of the glass-liquid mixed flow stirring section 1. Connected.
  • the glass liquid heating, clarifying and cooling section 2 includes a heating channel 2a connected at one end to the furnace a, and a clarification tank 2b and a cooling channel 2c are sequentially connected to the other end of the heating channel 2a.
  • the diameter of the heating channel 2a is 150mm-300mm, and the length is 500mm-1500mm; the diameter of the clarification tank 2b is 250mm-400mm, and the length is 3000mm-8000mm; the diameter of the cooling channel 2c is 220mm-360mm, and the length is 2000mm-6000mm.
  • the maximum temperature of the heating channel 2a during operation is 1650°C
  • the maximum temperature of the clarification tank 2b during operation is 1670°C
  • the temperature of the cooling channel 2c during operation is 1500°C-1550°C.
  • the glass liquid mixed flow stirring section 1 includes a confluence channel 1a, one end of the confluence channel 1a is connected to the two cooling channels 2c, a set of spoilers 1c is provided in the confluence channel 1a, and the other end of the confluence channel 1a is connected
  • the spoilers 1c of the set of spoilers 1c are arranged in a staggered distribution, and a section of serpentine flow passage 4 is divided in the confluence channel 1a by the division of a set of spoilers 1c.
  • the diameter of the confluence channel 1a is 300mm-500mm; the diameter of the glass liquid stirring tank 1b is 350mm-550mm, and the stirring speed is 2 to 20 revolutions per minute.
  • the heating channel 2a, clarification tank 2b, cooling channel 2c, confluence channel 1a, glass liquid stirring tank 1b, spoiler 1c and liquid supply tank 3 are made of platinum rhodium alloy or platinum iridium alloy or platinum.
  • the liquid outlet of the last molten glass stirring tank 1b is in communication with the liquid supply tank 3, and the liquid end of the liquid supply tank 3 is in communication with the liquid inlet of the tin tank c.
  • the diameter of the liquid supply tank 3 is 300mm-500mm, and the working temperature is 1200°C to 1400°C.
  • the temperature of the liquid inlet of the tin bath c is 1200-1400°C, and the temperature of the liquid outlet of the tin bath c is 650-850°C.
  • a mixed protective gas of nitrogen and hydrogen is introduced into the tin bath c, in which the proportion of hydrogen is 3-8%.
  • a corresponding drawing machine is also provided in the tin bath c.
  • the tin bath c and the edge-drawing machine are the prior art, so the structure and the matching relationship between the tin bath c and the edge-drawing machine will not be repeated here.
  • the liquid outlet of the tin bath c is connected to the annealing kiln d through a transition roller table, and the annealing kiln d is divided into temperature zones A, B, C, D, Ret, and F along the inlet to the outlet, wherein the temperature of A Zone temperature is 600-800°C, B temperature zone temperature is 500-700°C, C temperature zone temperature is 400-600°C, D temperature zone temperature is 300-500°C, Ret temperature zone temperature is 200-400°C, F temperature The temperature of the zone is 50-200°C, and there is a free cooling zone E with open kiln wall between the Ret temperature zone and the F temperature zone.
  • the surface temperature is ⁇ 70°C
  • the internal stress is less than 50Psi
  • the overall plate warpage is less than 0.1mm.
  • the glass sheet enters the cutting machine e through the conveying roller table, and is cut, edged, and broken into qualified glass sheets, and then the sheet is taken, stacked and boxed under the action of the unloader f.
  • the cutting machine e and the unloading machine f are mature products in the prior art, so the structure of the cutting machine e and the unloading machine f will not be repeated here.

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  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
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  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
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Abstract

本发明涉及一种高世代TFT-LCD玻璃基板生产线，它包括依次连通的窑炉、大流量贵金属通道、锡槽、退火窑、裁切机以及下片机。本发明将TFT-LCD玻璃的高效熔化、玻璃液澄清均化、超薄浮法成形以及退火工艺技术相结合能够生产8.5代、10.5/11代等大尺寸TFT-LCD玻璃基板，具有产品尺寸大、产品性能优、工艺程序连贯、生产效率高、产能大等优点。

Description

一种高世代TFT-LCD玻璃基板生产线
本申请要求于2020年06月08日提交中国专利局、申请号为202010510899.7、发明名称为“一种高世代TFT-LCD玻璃基板生产线”的中国专利申请的优先权，其全部内容通过引用结合在本申请中。
技术领域
本发明涉及高世代TFT-LCD玻璃生产领域，具体地说就是一种高世代TFT-LCD玻璃基板生产线。
背景技术
TFT-LCD玻璃基板是电子信息显示产业的关键战略材料，代表着玻璃制造领域的最高水平。当前我国已成为全球最大的信息显示产业基地，2018年，中国大陆地区对玻璃基板的需求量约为2.6亿平方米，其中8.5代玻璃基板的需求量为2.33亿平方米。到2020年我国8.5代及以上TFT-LCD玻璃基板市场需求将超3亿平方米，占全球总需求量的50％以上，市场空间和发展潜力巨大。
中国发明专利CN 200810054509阐述了TFT-LCD玻璃基板自动加工生产线，涉及切割、研磨、检验、包装的后加工处理全过程，但该专利未涉及玻璃基板原片的生产工艺过程；中国发明专利CN 201611102225涉及一种用于基板玻璃清洗机的加热系统及清洗机，主要阐释的是玻璃基板后加工清洗机上使用的自动加热系统，以及应用该加热系统的清洗机，但该发明并没有涉及高世代TFT-LCD玻璃基板生产线的技术内容。
发明内容
本发明就是为了克服现有技术中的不足，提供一种高世代TFT-LCD玻璃基板生产线。本申请提供以下技术方案：
一种高世代TFT-LCD玻璃基板生产线，它包括依次连通的窑炉、贵金属通道、锡槽、退火窑、裁切机以及下片机，在所述的窑炉包括在窑炉壁两侧的内壁上对称设有一组电极，在窑炉的煊顶上设有一组全氧烧枪；所述的贵金属通道，它包括玻璃液混流搅拌段，在玻璃液混流搅拌段一端并联有两个玻璃液加热澄清冷却段，所述两个玻璃液加热澄清冷却段一端均与窑炉连通， 在玻璃液混流搅拌段另一端还连通有供液槽，所述的供液槽与锡槽进液口连通。
在上述方案的基础上，还可以有以下进一步的技术方案：
所述的一组全氧烧枪的火焰喷射口竖直向下，且火焰能接触到窑炉内玻璃液的液面。
所述的贵金属通道包括依次连通的玻璃液加热澄清冷却段、玻璃液混流搅拌段以及供液槽。
所述的玻璃液加热澄清冷却段包括一端与窑炉连通的加热通道，在加热通道另一端依次连通有澄清槽和冷却通道；
所述的玻璃液混流搅拌段包括汇流通道，汇流通道的一端与所述的两条冷却通道连通，在汇流通道内设有一组扰流板，在汇流通道另一端连通有至少一个玻璃液搅拌槽，在玻璃液搅拌槽的出液口与供液槽连通。
所述的一组扰流板中的各扰流板为错位分布，通过一组扰流板的分割在汇流通道内分割出一段蛇形流道。
在汇流通道另一端依次连通有至少一个玻璃液搅拌槽。
当包括多个玻璃液搅拌槽(1b)时，相邻的两个玻璃液搅拌槽的搅拌方向不同。
所述锡槽进液口的温度为1200-1400℃，锡槽出液口的温度650-850℃。
在所述的锡槽内通入有氮氢混合保护气体，其中氢气比例为3-8％。
在所述的退火窑内沿入口向出口划分出A、B、C、D、Ret以及F温度区，其中A温度区温度为600-800℃，B温度区温度为500-700℃，C温度区温度为400-600℃，D温度区温度为300-500℃，Ret温度区温度为200-400℃，F温度区温度为50-200℃，在Ret温度区与F温度区之间设有敞开窑壁的自由降温区E。
发明优点:
本发明的TFT-LCD玻璃玻璃基板生产线能够稳定生产8.5代、10.5/11代等大尺寸TFT-LCD玻璃基板，具有产品尺寸大、产品性能优、生产效率高、产能大等优点。
附图说明
为了更清楚地说明本发明实施例和现有技术的技术方案，下面对实施例和现有技术中所需要使用的附图作简单地介绍，显而易见地，下面描述中的附图仅仅是本发明的一些实施例，对于本领域普通技术人员来讲，在不付出创造性劳动的前提下，还可以根据这些附图获得其他的附图。
图1为本发明的结构示意图；
图2是图1中的窑炉的结构示意图；
图3是图1中的贵金属通道的结构示意图；
图4是图1中退火窑的结构示意图。
具体实施方式
为使本发明的目的、技术方案、及优点更加清楚明白，以下参照附图并举实施例，对本发明进一步详细说明。显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。本领域普通技术人员基于本申请中的实施例所获得的所有其他实施例，都属于本申请保护的范围。
如图1-4所示，一种高世代TFT-LCD玻璃基板生产线，它包括依次连通的窑炉a、贵金属通道b、锡槽c、退火窑d、裁切机e以及下片机f，在所述的窑炉a包括窑炉壁a1两侧的内壁上对称设有一组电极5，在窑炉a的煊顶上设有一组全氧烧枪6，所述的全氧烧枪6为竖直分布，所述火焰喷射口竖直向下，且火焰能接触到窑炉a内玻璃液的液面，在显著增加火焰加热效率的同时，火焰还能消除漂浮在液面上的泡沫。所述的一组全氧烧枪6成两排分布且两排的全氧烧枪6成交错分布。
所述窑炉a的生产能力为20～100吨/天，小于20吨/天会造成熔化效率低，成本较高，大于100吨/天可能会造成玻璃液不能充分高效熔制，影响基板玻璃基板质量。
在本申请的一些实施方式中，所述贵金属通道为大流量贵金属通道。
所述的贵金属通道包括玻璃液混流搅拌段1，在玻璃液混流搅拌段1一端并联有两个玻璃液加热澄清冷却段2，所述两个玻璃液加热澄清冷却段2一端均与窑炉a连通。
所述的玻璃液加热澄清冷却段2包括一端与窑炉a连通的加热通道2a， 在加热通道2a另一端依次连通有澄清槽2b和冷却通道2c。所述加热通道2a的直径为150mm-300mm，长度为500mm-1500mm；所述澄清槽2b的直径为250mm-400mm，长度为3000mm-8000mm；所述冷却通道2c的直径为220mm-360mm，长度为2000mm-6000mm。所述加热通道2a工作时的最高温度为1650℃，所述澄清槽2b工作时的最高温度为1670℃，所述冷却通道2c的工作时的温度为1500℃～1550℃。
所述的玻璃液混流搅拌段1包括汇流通道1a，汇流通道1a的一端与所述的两条冷却通道2c连通，在汇流通道1a内设有一组扰流板1c，在汇流通道1a另一端连通有至少一个玻璃液搅拌槽1b，例如可以是三个玻璃液搅拌槽1b，且相邻的两个玻璃液搅拌槽1b的搅拌方向不同。
所述的一组扰流板1c中的各扰流板1c为错位分布，通过一组扰流板1c的分割在汇流通道1a内分割出一段蛇形流道4。所述汇流通道1a的直径为300mm-500mm；所述玻璃液搅拌槽1b的直径为350mm-550mm，搅拌转速为2圈-20圈每分钟。所述的加热通道2a、澄清槽2b、冷却通道2c、汇流通道1a、玻璃液搅拌槽1b、扰流板1c以及供液槽3由铂铑合金或铂铱合金或铂制成。
最后一个玻璃液搅拌槽1b的出液口与供液槽3连通，所述的供液槽3出液端与锡槽c进液口连通。所述供液槽3的直径为300mm-500mm，工作时的温度为1200℃～1400℃。
所述锡槽c进液口的温度为1200-1400℃，锡槽c出液口的温度650-850℃。在所述的锡槽c内通入有氮氢混合保护气体，其中氢气比例为3-8％。在锡槽c内还设有对应配合的拉边机。所述的锡槽c和拉边机均为现有技术，因此这里不再赘叙其结构以及锡槽c和拉边机的配合关系。
在所述锡槽c出液口通过过渡辊台与退火窑d连通，在所述的退火窑d内沿入口向出口划分出A、B、C、D、Ret以及F温度区，其中A温度区温度为600-800℃，B温度区温度为500-700℃，C温度区温度为400-600℃，D温度区温度为300-500℃，Ret温度区温度为200-400℃，F温度区温度为50-200℃，在Ret温度区与F温度区之间设有敞开窑壁的自由降温区E。玻璃板在经过退火窑d的退火后，表面温度≤70℃，内应力小于50Psi，整板翘曲 度小于0.1mm。
而后玻璃板通过输送辊道进入裁切机e经过切裁、掰边、掰断成合格的玻璃片，而后在下片机f的作用下进行取片、堆垛和装箱。所述的裁切机e和下片机f均为现有技术中的成熟产品，所以这里不再赘叙裁切机e和下片机f的结构。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内，所做的任何修改、等同替换、改进等，均应包含在本发明保护的范围之内。

Claims (10)

  1. 一种高世代TFT-LCD玻璃基板生产线，它包括依次连通的窑炉(a)、贵金属通道(b)、锡槽(c)、退火窑(d)、裁切机(e)以及下片机(f)，在所述的窑炉(a)包括在窑炉壁(a1)两侧的内壁上对称设有一组电极(5)，其特征在于：在窑炉(a)的煊顶上设有一组全氧烧枪(6)；所述的贵金属通道，包括玻璃液混流搅拌段(1)，在玻璃液混流搅拌段(1)一端并联有两个玻璃液加热澄清冷却段(2)，所述两个玻璃液加热澄清冷却段(2)一端均与窑炉(a)连通，在玻璃液混流搅拌段(1)另一端还连通有供液槽(3)，所述的供液槽(3)与锡槽(c)进液口连通。
  2. 根据权利要求1中所述的高世代TFT-LCD玻璃基板生产线，其特征在于：所述的一组全氧烧枪(6)的火焰喷射口竖直向下，且火焰能接触到窑炉(a)内玻璃液的液面。
  3. 根据权利要求1中所述的高世代TFT-LCD玻璃基板生产线，其特征在于：所述的玻璃液加热澄清冷却段(2)包括一端与窑炉(a)连通的加热通道(2a)，在加热通道(2a)另一端依次连通有澄清槽(2b)和冷却通道(2c)。
  4. 根据权利要求3中所述的高世代TFT-LCD玻璃基板生产线，其特征在于：所述的玻璃液混流搅拌段(1)包括汇流通道(1a)，汇流通道(1a)的一端与所述的两条冷却通道(2c)连通，在汇流通道(1a)内设有一组扰流板(1c)，在汇流通道(1a)另一端连通有至少一个玻璃液搅拌槽(1b)，玻璃液搅拌槽(1b)的出液口与供液槽(3)连通。
  5. 根据权利要求4中所述的高世代TFT-LCD玻璃基板生产线，其特征在于：所述的一组扰流板(1c)中的各扰流板(1c)为错位分布，通过一组扰流板(1c)的分割在汇流通道(1a)内分割出一段蛇形流道(4)。
  6. 根据权利要求4中所述的高世代TFT-LCD玻璃基板生产线，其特征在于：在汇流通道(1a)另一端依次连通有至少一个玻璃液搅拌槽(1b)。
  7. 根据权利要求6中所述的高世代TFT-LCD玻璃基板生产线，其特征在于：当包括多个玻璃液搅拌槽(1b)时，相邻的两个玻璃液搅拌槽(1b)的搅拌方向不同。
  8. 根据权利要求1中所述的高世代TFT-LCD玻璃基板生产线，其特征 在于：所述锡槽(c)进液口的温度为1200-1400℃，锡槽(c)出液口的温度650-850℃。
  9. 根据权利要求1中所述的高世代TFT-LCD玻璃基板生产线，其特征在于：在所述的锡槽(c)内通入有氮氢混合保护气体，其中氢气比例为3-8％。
  10. 根据权利要求1中所述的高世代TFT-LCD玻璃基板生产线，其特征在于：在所述的退火窑(d)内沿入口向出口划分出A、B、C、D、Ret以及F温度区，其中A温度区温度为600-800℃，B温度区温度为500-700℃，C温度区温度为400-600℃，D温度区温度为300-500℃，Ret温度区温度为200-400℃，F温度区温度为50-200℃，在Ret温度区与F温度区之间设有敞开窑壁的自由降温区E。
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