WO2020213109A1 - 電子源、及び荷電粒子線装置 - Google Patents
電子源、及び荷電粒子線装置 Download PDFInfo
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- WO2020213109A1 WO2020213109A1 PCT/JP2019/016563 JP2019016563W WO2020213109A1 WO 2020213109 A1 WO2020213109 A1 WO 2020213109A1 JP 2019016563 W JP2019016563 W JP 2019016563W WO 2020213109 A1 WO2020213109 A1 WO 2020213109A1
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- charged particle
- particle beam
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/02—Details
- H01J37/04—Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement or ion-optical arrangement
- H01J37/06—Electron sources; Electron guns
- H01J37/065—Construction of guns or parts thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/02—Details
- H01J37/04—Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement or ion-optical arrangement
- H01J37/06—Electron sources; Electron guns
- H01J37/073—Electron guns using field emission, photo emission, or secondary emission electron sources
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/02—Details
- H01J37/04—Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement or ion-optical arrangement
- H01J37/06—Electron sources; Electron guns
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
- H01J2237/02—Details
- H01J2237/026—Shields
- H01J2237/0262—Shields electrostatic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
- H01J2237/06—Sources
- H01J2237/063—Electron sources
- H01J2237/06308—Thermionic sources
- H01J2237/06316—Schottky emission
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
- H01J2237/06—Sources
- H01J2237/063—Electron sources
- H01J2237/06375—Arrangement of electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
- H01J2237/18—Vacuum control means
- H01J2237/188—Differential pressure
Definitions
- the present invention relates to an electron source for supplying an electron beam to be irradiated to a sample and a charged particle beam device using the electron source.
- the charged particle beam device generates an observation image of the sample by irradiating the sample with a charged particle beam such as an electron beam and detecting transmitted electrons, secondary electrons, backscattered electrons, X-rays, etc. emitted from the sample. It is a device to do.
- the generated image is required to have high spatial resolution and good reproducibility when repeatedly generated. In order to realize these, it is necessary that the brightness of the irradiated electron beam is high and the amount of current is stable.
- As one of the electron guns that emit such electron beams there is a Schottky electron gun (hereinafter referred to as SE electron gun).
- SE electron gun Schottky electron gun
- Patent Document 1 does not describe a problem at the time of releasing such a large current.
- An object of the present invention is to provide an electron source capable of suppressing minute discharges and stably emitting a large current electron beam, and a charged particle beam device using the electron source.
- the chip, the suppressor arranged behind the tip of the chip, the bottom surface and the cylinder portion, the extraction electrode including the chip and the suppressor, the suppressor and the extraction electrode Provided is a charged particle beam device having a structure in which an electron gun having a conductive metal is provided between a suppressor and a tubular portion of an extraction electrode, and a voltage lower than that of a chip is applied to the conductive metal. To do.
- the chip is composed of a chip, a suppressor arranged behind the tip of the chip, a conductive support portion for holding the suppressor, a bottom surface and a tubular portion. It is equipped with an electron gun having a conductive metal provided between a pull-out electrode containing a suppressor, a porcelain holding a support portion and a pull-out electrode, and a tubular portion of the support portion and the lead-out electrode, and a chip on the conductive metal.
- a charged particle beam apparatus having a configuration in which a lower voltage is applied.
- the chip, the suppressor arranged behind the tip of the chip, the insulator electrically connected to the chip and the insulator holding the suppressor, and the side surface of the suppressor is provided.
- an electron source having a configuration including a conductive metal installed in the insulator.
- an electron source capable of stably emitting a large current electron beam, and a charged particle beam device using the electron source.
- FIG. It is the schematic of the scanning electron microscope which is an example of the charged particle beam apparatus which concerns on Example 1.
- FIG. It is the schematic explaining the structure around the conventional SE electron gun. It is the schematic explaining the structure around the SE electron gun of Example 1.
- FIG. It is a perspective view which shows one configuration example of the electron source of the SE electron gun of Example 1.
- FIG. It is a figure explaining the current change of an electron beam when a minute discharge occurs in an SE electron gun.
- FIG. It is the schematic explaining the mechanism which the minute discharge is generated in the SE electron gun.
- FIG. It is the schematic explaining the mechanism which prevents the minute discharge by the SE electron gun of Example 1.
- FIG. It is the schematic explaining the structure around the SE electron gun of Example 2.
- FIG. It is the schematic explaining the structure around the SE electron gun of Example 3.
- FIG. 4 It is the schematic explaining the structure around the SE electron gun of Example 4.
- FIG. It is the schematic explaining the structure around the SE electron gun of Example 5.
- FIG. It is the schematic explaining the structure around the SE electron gun of Example 6.
- FIG. It is the schematic explaining the structure around the SE electron gun of Example 7.
- FIG. It is the schematic explaining the structure around the SE electron gun of Example 8.
- FIG. It is the schematic explaining the structure around the SE electron gun of Example 9.
- a charged particle beam device there is an electron microscope that generates an observation image of a sample by irradiating the sample with an electron beam and detecting secondary electrons and backscattered electrons emitted from the sample.
- a scanning electron microscope will be described as an example of the charged particle beam device, but the present invention is not limited to this, and can be applied to other charged particle beam devices.
- the first embodiment includes a chip, a suppressor arranged behind the tip of the chip, a bottom surface and a tubular portion, an extraction electrode containing the chip and the suppressor, a porcelain holding the suppressor and the extraction electrode, and a suppressor.
- This is an example of a scanning electron microscope having a structure in which an electron gun having a conductive metal is provided between the lead electrode and a tubular portion and a voltage lower than that of a chip is applied to the conductive metal.
- the scanning electron microscope irradiates the sample 112 with electron beams 115 and detects secondary electrons, backscattered electrons, and the like emitted from the sample to generate an observation image of the sample.
- This observation image is generated by scanning the focused electron beam on the sample and associating the position where the electron beam is irradiated with the detected amount of secondary electrons or the like.
- the scanning electron microscope includes a cylinder body 125 and a sample chamber 113, and the inside of the cylinder body 125 is divided into a first vacuum chamber 119, a second vacuum chamber 126, a third vacuum chamber 127, and a fourth vacuum chamber 128 from the top. .. There is an opening through which the electron beam 115 passes in the center of each vacuum chamber, and the inside of each vacuum chamber is maintained in a vacuum by differential exhaust.
- each vacuum chamber will be described.
- the first vacuum chamber 119 is evacuated by an ion pump 120 and a non-evaporable getter (NEG) pump 118, and the pressure is ultra-high vacuum of 10-8 Pa, more preferably 10-9 Pa or less. Make the vacuum extremely high.
- the NEG pump 118 has a high exhaust speed in an extremely high vacuum and can obtain 10-9 Pa or less.
- the SE electron gun 101 is placed inside the first vacuum chamber 119.
- the SE electron gun 101 is held by the insulator 116 and is electrically insulated from the cylinder 125.
- a control electrode 102 is arranged below the SE electron gun 101.
- An observation image is obtained by emitting an electron beam 115 from the SE electron gun 101 and finally irradiating the sample 112. Details of the configuration of the SE electron gun 101 will be described later.
- the second vacuum chamber 126 is exhausted by the ion pump 121.
- An acceleration electrode 103 is arranged in the second vacuum chamber 126.
- the third vacuum chamber 127 is exhausted by the ion pump 122.
- a condenser lens 110 is arranged in the third vacuum chamber 127.
- the fourth vacuum chamber 128 and the sample chamber 113 are exhausted by the turbo molecular pump 109.
- a detector 114 is arranged in the fourth vacuum chamber 128.
- An objective lens 111 and a sample 112 are arranged in the sample chamber 113.
- a control voltage is applied to the control electrode 102 to form an electrostatic lens between the SE electron gun 101 and the control electrode 102.
- the electron beam 115 is focused by this electrostatic lens and adjusted to a desired optical magnification.
- An acceleration voltage of about 0.5 kV to 60 kV is applied to the acceleration electrode 103 to the SE electron gun 101 to accelerate the electron beam 115.
- the condenser lens 110 focuses the electron beam 115 and adjusts the amount of current and the opening angle.
- a plurality of condenser lenses may be provided, or may be arranged in another vacuum chamber.
- the objective lens 111 reduces the electron beam 115 into minute spots and irradiates the sample 112 while scanning. At this time, secondary electrons, backscattered electrons, and X-rays reflecting the surface shape and material are emitted from the sample. By detecting these with the detector 114, an observation image of the sample is obtained.
- a plurality of detectors may be provided, or may be arranged in another vacuum chamber such as a sample chamber 113.
- the configuration around the conventional SE electron gun 201 will be described with reference to FIG.
- the conventional SE electron gun 201 is mainly composed of an SE chip 202, a suppressor 203, and a drawer electrode 204.
- the SE chip 202 is a single crystal with a tungsten ⁇ 100> orientation, and its tip is sharpened to a radius of curvature of less than 0.5 ⁇ m. Zirconium oxide 205 is applied to the middle of the single crystal.
- the SE chip 202 is welded to the filament 206. Both ends of the filament 206 are connected to terminals 207, respectively.
- the two terminals 207 are held by the insulator 208 and are electrically insulated from each other.
- the two terminals 207 extend coaxially with the SE chip 202 and are connected to a current source via a feedthrough (not shown).
- the SE chip 202 is heated from 1500K to 1900K by constantly passing an electric current through the terminal 207 and energizing and heating the filament 206.
- the zirconium oxide 205 diffuses and moves on the surface of the SE chip 202 and covers the (100) crystal plane at the center of the tip of the electron source.
- the (100) plane is characterized in that the work function is reduced when it is covered with zirconium oxide.
- thermions are emitted from the heated (100) plane, and an electron beam 115 is obtained.
- the total amount of emitted electron beams is called the emission current, which is typically about 50 ⁇ A.
- the suppressor 203 is a cylindrical metal and is arranged so as to cover other than the tip of the SE chip 202.
- the cylinder of the suppressor 203 extends in parallel with the SE chip 202 in the axial direction and is held by the insulator 208 by fitting.
- the suppressor 203 and the terminal 207 are electrically insulated by the insulator 208.
- a suppressor voltage of ⁇ 0.1 kV to ⁇ 0.9 kV is applied to the suppressor 203 with respect to the SE chip 202.
- the SE chip 202 is also characterized by emitting thermoelectrons from its side surface. However, by applying such a negative voltage to the suppressor 203, the emission of unnecessary thermoelectrons emitted from the side surface is prevented.
- the tip of the SE chip 202 is typically arranged so as to protrude about 0.25 mm from the suppressor 203.
- the tip of the SE chip 202 By performing precise positioning of 1 mm or less and projecting only a short distance in this way, only the tip of the SE chip 202 contributes to the emission of electron beams, and the amount of unnecessary electrons emitted from the side surface is reduced as much as possible. To do. Further, if the protrusion length is about 0.25 mm, there is an advantage that a sufficient electric field can be applied to the tip of the electron source depending on the configuration of the extraction voltage described later.
- the drawer electrode 204 is a cup-shaped metal cylinder in which the bottom surface and the cylinder are integrally formed, and the bottom surface is arranged so as to face the SE chip 202.
- the drawer electrode 204 is held in contact with the insulator 210 and is electrically insulated from the suppressor 203.
- An extraction voltage of about + 2 kV is applied to the extraction electrode 204 with respect to the SE chip 202. Since the tip of the SE chip 202 is sharpened, a high electric field is concentrated on the tip. The higher the electric field applied, the lower the effective work function of the surface due to the Schottky effect, and more electron beams can be emitted.
- the distance between the SE chip 202 and the bottom surface of the extraction electrode 204 is typically about 0.5 mm. By assembling at such a narrow distance, a sufficiently high electric field can be applied to the tip of the electron source even with a low extraction voltage.
- a diaphragm 209 is provided on the bottom surface of the extraction electrode 204, and the electrons passing through the diaphragm 209 are finally used to generate an image.
- a thin plate of molybdenum or the like is used for the drawing 209, and the diameter of the opening of the drawing 209 is typically about 0.1 mm to 0.5 mm. By making the aperture smaller, it is possible to prevent unnecessary electrons from passing through the diaphragm and prevent the observed image from being deteriorated.
- the SE chip 202 is positioned and welded on the central axis of the insulator 208 using a high-precision jig.
- the outer circumference of the insulator 208 and the inner circumference of the suppressor 203, the outer circumference of the suppressor 203 and the inner circumference of the insulator 210, and the outer circumference of the insulator 210 and the inner circumference of the drawer electrode 204 are each assembled by fitting on the order of 10 ⁇ m. Therefore, the SE chip 202, the suppressor 203, and the extraction electrode 204 have a highly accurate coaxial structure, and precise positioning between the electrodes is possible.
- the SE chip 202 and the suppressor 203 have a coaxial structure, the potential distribution created by the suppressor 203 in the vicinity of the SE chip 202 becomes uniform. As a result, unnecessary electrons that are about to be emitted from the side surface of the SE chip 202 can be uniformly suppressed in all directions. In addition, the electrons emitted from the SE chip 202 are not bent at a non-uniform potential in space, and electron beams can be emitted on the axis.
- the diaphragm 209 can also be arranged coaxially. As a result, the displacement of the diaphragm 209 prevents the emitted electrons from passing through, and there is no possibility that the electron beam cannot be obtained. In addition, the electric field distribution given to the tip of the SE chip 202 by the diaphragm 209 becomes uniform, and electron beams can be emitted on the axis.
- the SE electron gun is used to efficiently emit an electron beam from the tip of the electron source, suppress unnecessary electron emission from the side surface of the electron source, and realize a uniform potential distribution in the electron gun space. It is necessary to assemble with high precision with a small size of 1 mm or less. Therefore, the inside of the SE electron gun has a very narrow space, and has a feature of maintaining a voltage difference on the order of kV in this space.
- the configuration around the SE electron gun 101 of this embodiment and the configuration of the electron source thereof will be described with reference to FIGS. 3A and 3B.
- the electron gun of this embodiment includes an electron source including an SE chip 202, a filament 206, an insulator 208, and a suppressor 303 having a shielding electrode 301 newly made of a conductive metal, and further uses an insulator 310 having a step. A gap 311 is provided between the lower surface of the 310 and the inner peripheral surface of the cylinder of the extraction electrode 204.
- the electron sources of this embodiment are installed on the SE chip 202, the suppressor 303 arranged behind the tip of the chip, the terminal 207 electrically connected to the chip, the insulator 208 holding the suppressor, and the side surface of the suppressor.
- the electron source is provided with a shielding electrode 301 made of a conductive metal to which a voltage lower than that of the chip is applied.
- the configuration of the same symbol means the same configuration as described above, and the description thereof will be
- a step is provided at the bottom of the insulator 310, and the surface arranged below (the traveling direction of the electron beam 115) is referred to as a lower surface 312 and the upper surface is conveniently referred to as an upper surface 313.
- the lower surface 312 is arranged on the suppressor 301 side, and the upper surface 313 is provided on the extraction electrode 204 side.
- a gap 311 is provided between the lower surface 312 of the insulator 310 and the inner peripheral surface of the extraction electrode 204.
- a shielding electrode 301 made of a conductive metal integrally formed is provided on the side surface of the suppressor 303.
- the cylindrical portion on the side surface of the suppressor 303 extends in the axial direction of the SE chip 202 and is held by fitting with the insulator 310.
- the shielding electrode 301 is provided on the side surface of the cylindrical portion of the suppressor 303 and projects laterally.
- the shielding electrode 301 has a structure extending in the direction perpendicular to the axial direction of the SE chip 202.
- the shielding electrode 301 is arranged between the suppressor 303 and the cylindrical portion of the extraction electrode 204. The voltage difference between the shielding electrode 301 and the extraction electrode 204 is maintained by the vacuum between them and is electrically insulated.
- the shielding electrode 301 further has a cylindrical portion 302 extending toward the insulator 310 side.
- the upper end of the cylindrical portion 302 extends to the gap 311.
- the cylindrical portion 302 of the shielding electrode 301 has the same axis as the cylinder of the drawing electrode 204 and extends in the parallel direction.
- the cylinder of the extraction electrode 204 extends in the axial direction of the SE chip 202, so that the cylindrical portion 302 also extends in the axial direction of the SE chip 202.
- the lower surface 312 of the insulator 310 is covered with the shielding electrode 301 and the cylindrical portion 302, and the drawer electrode 204 is not expected.
- the shielding electrode 301 including the cylindrical portion 302 does not come into contact with the insulator 310, and prevents unnecessary electric fields from concentrating on the surface of the shielding electrode 301.
- a differential pressure between the suppressor voltage and the extraction voltage is applied to the outer peripheral side surface of the shielding electrode 301. Therefore, the side surface of the shielding electrode is formed of a curved surface or a flat surface to prevent unnecessary electric field concentration. The action of preventing minute discharge by this configuration will be described later.
- the insulator 208 and the insulator 310 may be other electrically insulating materials such as glass.
- the radius of curvature of the tip of the SE chip 202 is set to 0.5 ⁇ m or more, more preferably 1.0 ⁇ m or more.
- the emission current is set to 300 ⁇ A or more, so that high brightness that cannot be obtained with the conventional radius of curvature can be obtained.
- the extraction voltage is typically used above 3 kV.
- the tip radius of curvature of 1 ⁇ m the brightness higher than the conventional one can be obtained by setting the emission current to 600 ⁇ A or more.
- the extraction voltage is typically 5 kV or higher.
- the electron shock desorption gas When a metal material such as the extraction electrode 204 or the diaphragm 209 is irradiated with electrons, the electron shock desorption gas is released.
- the amount of electron shock desorbed gas released increases in proportion to the amount of irradiated current and the applied extraction voltage. Therefore, when an emission current of 300 ⁇ A or 500 ⁇ A or more is emitted from the SE chip 202 at a high extraction voltage, an electron shock desorption gas that is an order of magnitude more than the conventional one is generated, and the vacuum chamber 119 shown in FIG. 1 Exacerbate pressure. When the pressure reaches the 10-7 Pa level, the surface of the SE chip 202 is damaged and the shape is deformed, which may impair the stability of the current.
- the vacuum chamber 119 is exhausted by the NEG pump 118 and the ion pump 120 having a large exhaust speed. Therefore, even if a large current is discharged, the deterioration of the pressure is suppressed, and the pressure in the vacuum chamber 119 can be maintained in the 10-8 Pa range or less. Therefore, the surface of the SE chip 202 is not damaged, and there is an effect that a stable electron beam can be obtained even with a large current.
- FIG. 4 will be used to explain the change in the current of the electron beam when a minute discharge occurs.
- the micro discharge occurs instantaneously and, as is clear from the figure, ends in a short time of 1 second or less. At that time, the current amount of the electron beam decreases momentarily and then returns to the original current amount.
- the pressure in the first vacuum chamber may rise momentarily at the same time as the minute discharge, but this also returns to the original pressure within a few seconds.
- the discharge that is a problem with electron guns is generally called flashover or breakdown, and once it occurs, it causes melting of the electron source, damage to the high-voltage power supply, dielectric breakdown of the porcelain, etc. It is a large discharge that cannot obtain an electron beam again unless it is replaced.
- the minute discharge is a relatively mild discharge because the current is temporarily reduced, but then the electron beam is continuously obtained.
- the conventional discharge occurs, for example, when a high extraction voltage of about +10 kV is applied to the extraction electrode.
- this minute discharge does not occur even when the same high extraction voltage is applied, but occurs only when a large current electron beam is emitted in addition to the application of the extraction voltage, and the frequency of occurrence increases as the amount of current increases. Become.
- the micro discharge has a generation mechanism different from that of the conventional discharge, and can be said to be a different phenomenon.
- a discharge that has been a problem in the past is referred to as a large discharge.
- FIG. 5 the mechanism by which minute electric discharge is generated in the conventional SE electron gun 201 shown in FIG. 2 will be described. Since the electron gun has an axisymmetric structure, only one side surface is shown. Further, the potential distribution 510 in the space formed by the voltage applied to each of the chip 202, the suppressor 203, and the extraction electrode 204 is schematically shown by a broken line.
- the tip of the SE chip 202 protrudes from the suppressor 203, and the side beam 501 is emitted from the ⁇ 100 ⁇ equivalent crystal plane existing on the side surface thereof.
- the side beam 501 emits in an oblique direction and collides with the extraction electrode 204. Further, a part of the electron beam 115 emitted from the (100) plane at the center of the tip of the electron source also collides with the aperture 209.
- the amount of current that collides with the extraction electrode 204 and the diaphragm 209 is 90% or more of the emission current.
- the SE electron gun is characterized in that most of the current emitted from the electron source is applied to a narrow space inside the gun.
- each reflected electron When an electron collides with a metal material such as the extraction electrode 204 or the aperture 209, a part of the electron is emitted to the vacuum side as a reflected electron.
- the emission angle of the reflected electrons is wide, and generally has a distribution based on the cosine law with the specular reflection component as the peak.
- the energy of reflected electrons also has a distribution, and has electrons that store energy at the time of incident by elastic scattering and electrons that lose energy by inelastic scattering. Therefore, each reflected electron has a different orbit.
- the outline of the orbit will be described using the backscattered electron 502.
- the reflected electrons 502 emitted from the extraction electrode 204 travel in the direction of the suppressor 203, but the energy of the reflected electrons 502 is the same as the extraction voltage at the maximum, and cannot reach the suppressor 203. Therefore, it is pushed back by the repulsive force acting in the vertical direction of the potential distribution and collides with the extraction electrode 502 again.
- a part of the reflected electrons 502 is emitted as reflected electrons 503 and collides with the inner surface of the cylinder of the extraction electrode 204.
- a part of the backscattered electrons 503 is re-emitted as backscattered electrons 504, pushed back to the potential distribution of the suppressor 203, and collides with the extraction electrode 204 again.
- a part of the reflected electrons 504 becomes reflected electrons 505 and finally collides with the insulator 210.
- the secondary electron emission rate of the insulator 210 is larger than 1, and when one electron collides with the insulator 210, more than one secondary electron is emitted.
- the energy of the emitted secondary electrons 506 is as small as several volts, and reaches the extraction electrode 204 by the repulsive force of the potential distribution and is absorbed. As a result, the number of electrons on the surface 507 of the insulator 210 with which the reflected electrons 505 collided decreases, and the surface 507 is positively charged.
- a higher potential difference is formed along the surface between the contact point 511 of the suppressor 203 and the insulator 210 and the positively charged surface 507, and the closer the distance between the two, the higher the electric field is applied to the contact point 511. Will be done.
- field emission occurs at the contact point 511, and a large amount of electrons are emitted.
- these electrons While receiving the repulsive force of the potential distribution, these electrons move along the surface of the insulator 210 and in the space, and reach the extraction electrode 204.
- a minute discharge is generated by the current transfer between the electrodes, and the voltage difference between the electrodes changes, so that the current amount of the electron beam fluctuates.
- the SE electron gun 101 of this embodiment prevents minute discharge will be described with reference to FIG. Similar to the conventional SE electron gun, in the SE electron gun 101 of the present embodiment, the side beam 501 emitted from the SE chip 202 collides with the extraction electrode 204 and emits reflected electrons 502. The reflected electrons 502 are pushed back by receiving a repulsive force due to the potential distribution created between the suppressor 303 and the extraction electrode 204, and re-collide with the extraction electrode 204. After that, the reflected electron 502 repeatedly emits and collides with the extraction electrode.
- the shielding electrode 301 on the suppressor 303, the negative potential distribution created by the suppressor voltage spreads, and it becomes difficult for the reflected electrons to reach the insulator 310.
- the lower surface 312 of the insulator 310 is surrounded by the shielding electrode 301 and its cylindrical portion 302, so that backscattered electrons cannot collide with each other.
- the reflected electrons finally collide with the upper surface 313 of the insulator 310 after repeating more collisions than before, and positively charge the surface 517 thereof.
- the insulator 310 is provided with a step at the bottom, and the upper surface 313 and the lower surface 312 are separated from each other.
- the creepage distance between the contact point 511 between the insulator 310 and the suppressor 303 and the positively charged surface 517 is sufficiently long, and a high electric field is not applied to the contact point 511. As a result, field emission does not occur and the generation of minute discharges is prevented.
- the cylindrical portion 302 of the shielding electrode 301 has the same axis as the cylinder of the extraction electrode 204 and is extended in parallel by a certain distance, so that the cylindrical portion 302 and the inner peripheral surface of the extraction electrode 204 are aligned.
- a narrow path 601 may be formed between them.
- the potential distribution becomes narrow and the flight distance of the reflected electrons becomes short, so that a large number of re-collisions occur.
- the number of reflected electrons decreases by several percent each time they collide. As the number of re-collisions increases, the absolute number of reflected electrons reaching the insulator 310 decreases, and the amount of charge decreases to prevent minute discharges.
- the contact point 511 is surrounded by the shielding electrode 301, so that the potential distribution inside the contact point 511 becomes uniform and the electric field becomes small. Even if an electron is emitted from the contact point 511, the force applied to the electron becomes small, the probability that the electron reaches the extraction electrode 204 is small, and a minute discharge is less likely to occur.
- an SE chip 202 having a tip curvature radius of 0.5 ⁇ m or 1.0 ⁇ m or more is used, and an extraction voltage of 3 kV or 5 kV or more is applied to the extraction electrode 204. Further, when an SE electron source having a larger tip curvature is used, the extraction voltage increases to 10 kV or more. Even in this case, by extending the creepage distance of the insulator 310, the electric field in the creepage direction is reduced, and the risk of large discharge is also reduced.
- the suppressor 303 and the shielding electrode 301 As another effect, by integrally configuring the suppressor 303 and the shielding electrode 301, it is possible to maintain a simple structure without adding the number of parts. This has the advantage of cost reduction. Further, similarly to the conventional SE electron gun, the insulator 208, the suppressor 303, the insulator 310, and the drawer electrode 204 can be assembled by fitting each of them, and a highly accurate coaxial structure and positioning between the electrodes are possible. .. As a result, also in the electron gun 101 of the present embodiment, efficient emission of electron beams from the electron source, suppression of unnecessary electron emission from the side surface of the electron source, and uniform potential distribution in the electron gun space can be realized. ..
- ions are generated from the metal irradiated with the electron beam by electron shock desorption.
- the collision of the ions also causes the insulator 210 to be positively charged, and a minute discharge can occur by the same mechanism.
- the SE electron gun 101 of this embodiment can also prevent minute discharges caused by these ions.
- a shielding electrode 301 integrally formed with the suppressor 303 and an insulator 310 provided with a step are used, and the collision position of reflected electrons on the surface of the insulator 310 is separated from the suppressor 303 to prevent minute discharge.
- the configuration of the SE electron gun in which the suppressor and the shielding electrode have different structures will be described. Since the configuration other than the shielding electrode is the same as that of the first embodiment, the description thereof will be omitted.
- the SE electron gun of the second embodiment will be described with reference to FIG. 7.
- the shielding electrode 701 has a structure different from that of the suppressor 203, and is made of a conductive metal.
- the inner peripheral surface of the shielding electrode 701 and the outer peripheral surface of the suppressor 203 are assembled and held by fitting. Further, the outer peripheral surface of the shielding electrode 701 and the inner peripheral surface of the insulator 310 are assembled by fitting.
- the chip 202, the suppressor 203, the shielding electrode 701, and the extraction electrode 204 have a coaxial structure, and precise positioning is possible.
- the shielding electrode 701 and the suppressor 203 come into contact with each other, they have the same potential and the suppressor voltage is applied.
- the end surface of the cylindrical portion 722 of the shielding electrode 701 reaches the gap 311 provided by the insulator 310 with a step, similarly to the SE electron gun 101 of the first embodiment. Therefore, the action described with reference to FIG. 6 works, and minute discharge can be prevented.
- the electron gun of this embodiment has more fitting points due to the increase in the number of parts, which may deteriorate the shaft accuracy and increase the cost.
- the shielding electrode 701 a different structure from the suppressor 203, the suppressor 203 used in the conventional SE electron gun 201 can be diverted.
- a standardized suppressor structure there are advantages that the manufacturing cost of the suppressor can be reduced and that a commercially available SE electron source with a suppressor can be used as it is.
- Example 2 a configuration in which the suppressor and the shielding electrode have different structures has been described.
- Example 3 a configuration in which the fitting position of the insulator 310 to the suppressor is changed and the shielding electrode is miniaturized will be described. Since the configuration other than the shielding electrode is the same as that of the first embodiment, the description thereof will be omitted.
- the SE electron gun of Example 3 will be described with reference to FIG.
- the suppressor 702 of the present embodiment has a shielding electrode 703 at the upper end of the side surface thereof, and the suppressor 702 and the shielding electrode 703 are integrally formed as in the first embodiment.
- the outer peripheral surface of the cylindrical portion having the lower surface 312 of the insulator 310 and the inner peripheral surface of the suppressor 702 are held and assembled by fitting. As a result, each electrode has a coaxial structure and is precisely positioned.
- the position of the contact point 511 between the suppressor 702 and the insulator 310 which is the starting point of field emission, changes.
- the end face of the cylindrical portion 723 of the shielding electrode 703 reaches the gap 311 provided by the insulator 310 having a step.
- the contact point 511 is covered with the potential of the shielding electrode 703, and the action described with reference to FIG. 6 prevents minute discharge.
- the shielding electrode 703 can be miniaturized. As a result, there is an advantage that the diameter of the extraction electrode 204 can be reduced and the SE electron gun can be miniaturized. In addition, since the shape of the shielding electrode 703 can be relatively simplified, there is an advantage that the suppressor 702 having an integrated configuration can be easily manufactured and the cost can be reduced.
- the configuration in which the fitting position of the insulator 310 is changed and the shielding electrode is miniaturized has been described.
- an example of an electron source in which the structure of the shielding electrode is changed so that the electron source can be mounted on the conventional SE electron gun 201 of FIG. 2 and the suppressor 704 and the shielding electrode 705 are integrated is described. To do. Since the configurations other than the shielding electrode 705 are the same as those in the first embodiment, the description thereof will be omitted.
- the SE electron gun of this embodiment will be described with reference to FIG.
- the suppressor 704 of this embodiment has a shielding electrode 705 integrally formed with the suppressor 704 on its side surface.
- the shielding electrode 705 has a feature that it does not have a cylindrical portion.
- the shielding electrode 705 projects in the outer peripheral direction and covers only the downward direction of the contact point 511 between the suppressor 704 and the insulator 210. Therefore, the positively charged portion on the surface of the insulator 210 is separated from the contact point 511 by the amount of the shielding electrode 705 protruding. As a result, the frequency of minute discharges can be reduced as compared with the conventional SE electron gun 201.
- the SE electron gun of this embodiment does not have the insulator 310 with the step described in the first embodiment, the creepage distance cannot be sufficiently extended. Further, since the structure is not such that the cylindrical portion 302 of the shielding electrode covers the contact point 511, the structure is such that an electric field is easily applied to the contact point 511. Therefore, as compared with Example 1, the effect of preventing minute discharge is limited, and the frequency is reduced. However, by changing only the suppressor 705 of this embodiment, it can be mounted on the conventional SE electron gun 201, and there is an advantage that the frequency of minute discharge can be reduced while suppressing the development cost.
- Example 4 the structure of the shielding electrode was changed so that it could be mounted on a conventional SE electron gun.
- the extraction electrode is provided with an opening to reduce the absolute number of reflected electrons reaching the insulator to enhance the effect of preventing minute discharge.
- the openings of the diaphragm 209 including the openings of the diaphragm 209, at least two or more openings are provided in the extraction electrode. Since the configuration other than the extraction electrode is the same as that of the first embodiment, the description thereof will be omitted.
- the SE electron gun of Example 5 will be described with reference to FIG.
- the extraction electrode 801 of this embodiment has an opening 802 on the bottom surface thereof, which is different from the opening of the aperture 209. Further, the opening 803 is provided on the cylindrical surface of the extraction electrode 801 at a position facing the cylindrical portion 302 of the shielding electrode 301.
- the side beam 501 emitted from the chip 202 irradiates the extraction electrode 801 to emit backscattered electrons. Among these reflected electrons, some of the reflected electrons 804 having low energy pass through the opening 802 on the bottom surface and pass out of the SE electron gun. As a result, the absolute number of reflected electrons that finally reach the insulator 310 is reduced.
- Example 5 an opening was provided in the extraction electrode to reduce the absolute number of reflected electrons reaching the insulator to enhance the effect of preventing minute discharges.
- Example 6 the extraction electrode protrudes inward. A configuration will be described in which a portion is provided to reduce the absolute number of reflected electrons reaching the insulator to enhance the effect of preventing minute discharges. Since the configuration other than the extraction electrode is the same as that of the first embodiment, the description thereof will be omitted.
- the extraction electrode 809 of this embodiment has a protrusion 813 on the bottom surface. Further, it has a protruding portion 814 on the cylindrical surface.
- the protrusion 813 on the bottom surface is integrally formed with the extraction electrode 809, and the diaphragm 209 is arranged below the extraction electrode 809. Further, the protruding portion 813 has a taper, and the diameter of the opening thereof is larger on the throttle 209 side than on the SE chip 202 side. A withdrawal voltage is applied to the protrusion 813.
- the upper surface of the protrusion 813 facing the suppressor 303 is made flat in order to prevent unnecessary electric field concentration.
- the protrusion 814 on the cylindrical surface is integrally formed with the extraction electrode 809, and an extraction voltage is applied.
- the end face of the protrusion 814 on the suppressor 303 side has a taper, and the diameter of the opening is larger on the lower surface than on the upper surface.
- the surface of the end surface of the protrusion 814 facing the suppressor 303 side is made flat to prevent unnecessary electric field concentration.
- the side beam 812 having a large emission angle emits reflected electrons 816 after colliding with the diaphragm 209. Since the reflected electrons 816 are emitted with a peak in the mirror surface direction, most of them collide with the lower surface of the taper of the protrusion 813. From here, the emitted reflected electrons 817 collide with the diaphragm 209.
- the side beam 812 having a large emission angle repeatedly re-collides a large number of reflected electrons in the bag portion generated between the taper of the protrusion 813 and the diaphragm 209, and the side beam 812 repeatedly collides with the bag portion. Reduce the number. As a result, the insulator 310 cannot be reached.
- the side beam 812 with a small emission angle emitted from the SE chip 202 emits reflected electrons 811 after colliding with the diaphragm 209.
- the reflected electrons 811 pass through the opening of the protrusion 813, collide with the extraction electrode 809, and emit the reflected electrons 818.
- the reflected electrons 818 collide with the lower surface of the protrusion 814 and emit the reflected electrons 819.
- a narrow path 815 is formed between the protrusion 814 and the suppressor 303.
- the solid angle through which the reflected electrons can pass is small, which makes it difficult for the reflected electrons to pass through.
- the potential distribution becomes narrow, forcing the reflected electrons to collide with the protrusion 814 in large numbers. As a result, the number of reflected electrons reaching the insulator 310 is effectively reduced.
- Example 6 a configuration was described in which a protrusion was provided inside the extraction electrode to reduce the absolute number of reflected electrons reaching the insulator, thereby enhancing the effect of preventing minute discharge.
- the inner diameter of the contact portion between the extraction electrode and the insulator is made smaller than the inner diameter of the tubular portion of the extraction electrode.
- the extraction electrode is provided with a neck portion, and the neck portion and the insulator are held by fitting.
- the configuration in which the effect of preventing minute discharge is enhanced by reducing the absolute number of reflected electrons will be described. Since the configuration other than the extraction electrode is the same as that of the first embodiment, the description thereof will be omitted.
- the SE electron gun of Example 7 will be described with reference to FIG.
- the extraction electrode of this embodiment is divided into an extraction electrode bottom portion 821 and an extraction electrode cylindrical portion 824 for assembly. Further, a neck portion 822 is provided above the drawer electrode cylindrical portion 824. The neck portion 822 and the insulator 820 are held by fitting. Further, the insulator 820 and the suppressor 303 are held by fitting. Further, the length of the cylindrical portion 302 of the suppressor 303 is extended to bring it closer to the vicinity of the neck portion 822.
- the distance of the narrow path 601 formed between the cylindrical portion 302 of the shielding electrode 301 and the drawer electrode cylindrical portion 824 is extended. Further, a narrow path 823 is added between the neck portion 822 and the cylindrical portion 302. By extending the distance of these narrow paths, the number of times the reflected electrons collide with the extraction electrode bottom 821 increases, and the number of reflected electrons reaching the insulator 820 decreases. As a result, the amount of charge of the insulator 820 is reduced, and minute discharge is prevented.
- Example 7 a configuration was described in which a neck portion was provided on the extraction electrode and the absolute number of reflected electrons was reduced to enhance the effect of preventing minute discharges.
- the insulator is made of a semi-conductive material, or a semi-conductive or conductive thin film is provided on the surface of the insulator to prevent electrification and enhance the effect of preventing minute discharges. To do. Since the configuration other than the insulator is the same as that of the first embodiment, the description thereof will be omitted.
- the SE electron gun of the eighth embodiment will be described with reference to FIG.
- the semi-conductive insulator 830 is used instead of the insulator 310 of the first embodiment.
- the semi-conductive insulator 830 is an insulator having an electric conductivity intermediate between that of a metal and an insulator, and has a volume resistivity of about 10 10 ⁇ cm to 10 12 ⁇ cm.
- this semi-conductive insulator 830 it is possible to maintain the voltage difference between the extraction electrode 204 and the suppressor 303, although the dark current increases.
- the reflected electrons collide with the semi-conductive insulator 830 the electrons are immediately supplied from the nearby semi-conductive insulator 830 even if the surface is charged, and the charging is relaxed. As a result, no field emission occurs from the contact point 511, and minute discharge can be prevented.
- a similar effect can be achieved by providing a semi-conductive coating 831 on the surface of the insulating insulator.
- the semi-conductive coating 831 is a thin film having a volume resistivity of about 10 10 ⁇ cm to 10 12 ⁇ cm, and has a thickness of about several ⁇ m. Even if reflected electrons collide with the semi-conductive coating 831, the charge is immediately relaxed and minute discharge can be prevented.
- the semi-conductive coating 831 is effective not only on the entire surface of the insulating insulator but also on a part of the surface. When provided on a part of the surface, the conductivity of the semi-conductive coating 831 may be increased, and the volume resistivity may be 10 10 ⁇ cm or less. If the area to be covered is limited to a very small part of the surface, a conductive metal thin film may be formed, or a metallize may be used to form a film. Further, by putting a semi-conductive or metal covering in the vicinity of the contact point 511, the effect of relaxing the electric field concentration at the contact point 511 is added.
- Example 8 a configuration was described in which the insulator is made into a semi-conductive insulator, or the insulator is coated with a semi-conductive coating to prevent charging and enhance the effect of preventing minute discharge.
- the suppressor is held by the conductive support portion and the absolute number of reflected electrons is reduced to enhance the effect of preventing minute discharges. That is, it consists of a chip, a suppressor arranged behind the tip of the chip, a conductive support portion that holds the suppressor, a bottom surface and a tubular portion, and an extraction electrode that includes the chip and the suppressor, and a support portion and a drawer.
- a charged particle beam device that includes a conductor that holds an electrode and an electron gun that has a conductive metal provided between the support and the cylinder of the extraction electrode, and applies a voltage lower than that of the chip to the conductive metal. Is an example of.
- the SE electron gun of the ninth embodiment will be described with reference to FIG. Since the configuration other than the support portion is the same as that of the first embodiment, the description thereof will be omitted.
- the suppressor 303 of this embodiment is held by the support portion 840.
- the support portion 840 is a conductive metal cylinder and has a coaxial structure with the suppressor 303. When the support portion 840 comes into contact with the suppressor 303, the potential becomes the same as that of the suppressor 303.
- the support portion 840 is held by fitting with the insulator 310.
- the insulator 310 and the cylinder of the drawer electrode 204 are held by fitting. As a result, precise positioning and coaxial structure between the SE chip 202 and the extraction electrode 204 are maintained.
- a feedthrough 841 is connected to the pin 207 to supply power to the filament 206.
- a shielding electrode 301 is provided on the side surface of the support portion 840 so as to cover the lower surface 312 of the insulator 310 together with the cylindrical portion 3
- the trajectory of the reflected electrons is controlled by the shielding electrode 310 which is an integral structure with the support portion 840 of the suppressor 303, and the position where the reflected electrons collide with the insulator 310 is separated from the contact point 511.
- the increase in the electric field at the contact point 511 due to charging can be suppressed, and minute discharge can be prevented.
- the support portion 840 of the suppressor 303 the distance between the SE chip 202 and the insulator 310 is increased. As a result, the number of collisions until the reflected electrons reach the insulator 310 increases, and the absolute number of electrons decreases, so that minute discharge can be effectively prevented.
- the shielding electrode 310 may be attached to other than the suppressor itself. Further, even when other conductive parts are added to the suppressor 303 or the support portion 840 and brought into contact with each other, the same effect can be realized by providing the shielding electrode 310 in the additional parts.
- the SE chip 202 of the present invention may be a cold cathode field emission electron source, a thermionic source, or a photoexcited electron source.
- the material of the SE chip 202 is not limited to tungsten, and other materials such as LaB6, CeB6, and carbon-based materials may be used.
- the above-described embodiment has been described in detail in order to explain the present invention in an easy-to-understand manner, and is not necessarily limited to the one including all the described configurations. It is possible to replace a part of the configuration of one embodiment with the configuration of another embodiment, and it is also possible to add the configuration of another embodiment to the configuration of one embodiment. Further, it is possible to add / delete / replace a part of the configuration of each embodiment with another configuration.
- extraction electrode 205 ... zirconium oxide, 206 ... filament, 207 ... terminal, 208 ... ⁇ ⁇ , 209 ... aperture, 210 ... ⁇ ⁇ , 301 ... shielding Electrode, 302 ... Cylindrical part, 303 ... Suppressor, 310 ... ⁇ , 311 ... Void, 312 ... Bottom surface, 313 ... Top surface, 501 ... Side beam, 502 ... Reflected electron, 503 ... Reflected electron, 504 ... Reflected electron, 505 ... Reflection Electron, 506 ... Secondary electron, 507 ... Surface, 510 ... Potential distribution, 511 ... Contact point, 517 ... Surface, 601 ...
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Abstract
Description
201…従来のSE電子銃、202…SEチップ、203…サプレッサ、204…引出電極、205…酸化ジルコニウム、206…フィラメント、207…端子、208…碍子、209…絞り、210…碍子、301…遮蔽電極、302…円筒部、303…サプレッサ、310…碍子、311…空隙、312…下面、313…上面、501…サイドビーム、502…反射電子、503…反射電子、504…反射電子、505…反射電子、506…二次電子、507…表面、510…電位分布、511…接触点、517…表面、601…狭い経路、701…遮蔽電極、702…サプレッサ、703…遮蔽電極、704…サプレッサ、705…遮蔽電極、722…円筒部、723…円筒部、801…引出電極、802…開口、803…開口、804…反射電子、805…反射電子、810…サイドビーム、811…反射電子、812…サイドビーム、813…突出部、814…突出部、815…狭い経路、816…反射電子、817…反射電子、818…反射電子、819…反射電子、820…碍子、821…引出電極底部、822…ネック部、823…狭い経路、824…引出電極円筒部、830…半導電性碍子、831…半導電性被覆、840…支持部、841…フィードスルー。
Claims (15)
- チップと、前記チップの先端よりも後方に配置されたサプレッサと、底面と筒部から成り、前記チップと前記サプレッサを内包する引出電極と、前記サプレッサと前記引出電極を保持する碍子と、前記サプレッサと前記引出電極の筒部との間に設けられた導電性金属を持つ電子銃を備え、
前記導電性金属に前記チップよりも低い電圧を印加する、
ことを特徴とする荷電粒子線装置。 - 請求項1に記載の荷電粒子線装置であって、
前記碍子の端面に段差をもたせ、前記碍子と前記引出電極の筒部との間に空隙を設けた、
ことを特徴とする荷電粒子線装置。 - 請求項2に記載の荷電粒子線装置であって、
前記導電性金属の一部を、前記空隙まで伸ばす、
ことを特徴とする荷電粒子線装置。 - 請求項3に記載の荷電粒子線装置であって、
前記導電性金属と前記サプレッサとを一体で構成する、
ことを特徴とする荷電粒子線装置。 - 請求項4に記載の荷電粒子線装置であって、
前記導電性金属は筒構造をもち、前記筒構造は前記引出電極の筒部と同軸方向に伸びている、
ことを特徴とする荷電粒子線装置。 - 請求項4に記載の荷電粒子線装置であって、
前記引出電極に少なくとも二つ以上の開口を設ける、
ことを特徴とする荷電粒子線装置。
- 請求項4に記載の荷電粒子線装置であって、
前記引出電極の内側に少なくとも一つの突出部を設ける、
ことを特徴とする荷電粒子線装置。 - 請求項4に記載の荷電粒子線装置であって、
前記引出電極と前記碍子の接触箇所の内径は、前記引出電極の筒部の内径よりも小さい、
ことを特徴とする荷電粒子線装置。 - 請求項4に記載の荷電粒子線装置であって、
前記碍子を半導電性の材料で構成する、又は前記碍子の表面に半導電性、ないしは導電性の薄膜を設ける、
ことを特徴とする荷電粒子線装置。 - 請求項4に記載の荷電粒子線装置であって、
前記チップの先端の曲率半径を0.5μmよりも大きくする、
ことを特徴とする荷電粒子線装置。 - 請求項4に記載の荷電粒子線装置であって、
前記チップが配置された真空室を、非蒸発ゲッターポンプで排気する、
ことを特徴とする荷電粒子線装置。 - チップと、前記チップの先端よりも後方に配置されたサプレッサと、前記サプレッサを保持する導電性の支持部と、底面と筒部から成り、前記チップと前記サプレッサを内包する引出電極と、前記支持部と前記引出電極を保持する碍子と、前記支持部と前記引出電極の筒部との間に設けられた導電性金属を持つ電子銃を備え、
前記導電性金属に前記チップよりも低い電圧を印加する、
ことを特徴とする荷電粒子線装置。 - 請求項12に記載の荷電粒子線装置であって、
前記碍子の端面に段差をもたせ、前記碍子と前記引出電極の筒部との間に空隙を設けた、
ことを特徴とする荷電粒子線装置。 - 請求項13に記載の荷電粒子線装置であって、
前記導電性金属の一部を、前記空隙まで伸ばす、
ことを特徴とする荷電粒子線装置。 - チップと、
前記チップの先端より後方に配置されたサプレッサと、
前記チップに電気的に接続された端子と前記サプレッサを保持する碍子と、
前記サプレッサの側面に設置された導電性金属と、を備える、
ことを特徴とする電子源。
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KR1020217030924A KR102640728B1 (ko) | 2019-04-18 | 2019-04-18 | 전자원 및 하전 입자선 장치 |
US17/601,421 US20220199349A1 (en) | 2019-04-18 | 2019-04-18 | Electron source and charged particle beam device |
JP2021514730A JP7137002B2 (ja) | 2019-04-18 | 2019-04-18 | 電子源、及び荷電粒子線装置 |
CN201980094952.5A CN113646864B (zh) | 2019-04-18 | 2019-04-18 | 电子源以及带电粒子线装置 |
DE112019006988.8T DE112019006988T5 (de) | 2019-04-18 | 2019-04-18 | Elektronenquelle und mit einem Strahl geladener Teilchen arbeitende Vorrichtung |
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2019
- 2019-04-18 JP JP2021514730A patent/JP7137002B2/ja active Active
- 2019-04-18 KR KR1020217030924A patent/KR102640728B1/ko active IP Right Grant
- 2019-04-18 WO PCT/JP2019/016563 patent/WO2020213109A1/ja active Application Filing
- 2019-04-18 US US17/601,421 patent/US20220199349A1/en active Granted
- 2019-04-18 CN CN201980094952.5A patent/CN113646864B/zh active Active
- 2019-04-18 DE DE112019006988.8T patent/DE112019006988T5/de active Pending
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KR102640728B1 (ko) | 2024-02-27 |
KR20210129191A (ko) | 2021-10-27 |
JP7137002B2 (ja) | 2022-09-13 |
CN113646864B (zh) | 2024-05-28 |
CN113646864A (zh) | 2021-11-12 |
TWI724803B (zh) | 2021-04-11 |
TW202040591A (zh) | 2020-11-01 |
JPWO2020213109A1 (ja) | 2020-10-22 |
US20220199349A1 (en) | 2022-06-23 |
DE112019006988T5 (de) | 2021-11-18 |
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