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WO2020078795A1 - Mélanges ternaires contenant du fenpropimorphe, des inhibiteurs de succinate déshydrogénase et des azoles - Google Patents

Mélanges ternaires contenant du fenpropimorphe, des inhibiteurs de succinate déshydrogénase et des azoles Download PDF

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Publication number
WO2020078795A1
WO2020078795A1 PCT/EP2019/077351 EP2019077351W WO2020078795A1 WO 2020078795 A1 WO2020078795 A1 WO 2020078795A1 EP 2019077351 W EP2019077351 W EP 2019077351W WO 2020078795 A1 WO2020078795 A1 WO 2020078795A1
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WO
WIPO (PCT)
Prior art keywords
difluoromethyl
carboxamide
pyridine
fenpropimorph
indan
Prior art date
Application number
PCT/EP2019/077351
Other languages
English (en)
Inventor
Felipe ITIHARA DE OLIVEIRA
Andre Vinicius SHINZATO
Maria Angelica QUINTERO PALOMAR
Klaus Daeschner
Markus Gewehr
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Priority to BR112021006011-1A priority Critical patent/BR112021006011A2/pt
Publication of WO2020078795A1 publication Critical patent/WO2020078795A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
    • A01N45/02—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring having three carbocyclic rings

Definitions

  • the present invention relates to fungicidal mixtures comprising as active components, (1 ) fenpropimorph as compound I, and
  • compound II is an inhibitor of succinate dehydrogenase and selected from the group consisting of:
  • compound III from the class of DMI fungicides (inhibitor of C14-demethylase in sterol biosynthesis), wherein compound III is selected from the group consisting of: prothio- conazole, difenoconazole, tetraconazole, cyproconazole, metconazole, 4-[[6-[2-(2,4- difluorophenyl)-1 ,1 -difluoro-2-hydroxy-3-(5-sulfanyl-1 ,2,4-triazol-1-yl)propyl]-3- pyridyl]oxy]benzonitrile, tebuconazole, mefentrifluconazole.
  • the invention relates to an use of the mixture for controlling phytopathogenic harmful fungi and to a method for controlling phytopathogenic pests, wherein the pest, their habitat, breeding grounds, their locus or the plants to be protected against pest attack, the soil or plant propagation material are treated with an effective amount of the mixture.
  • plant propagation material is to be understood to denote all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers (e. g. pota toes), which can be used for the multiplication of the plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, sprouts and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil.
  • propagation material denotes seeds.
  • pests embrace harmful fungi and animal pests.
  • Another problem encountered concerns the need to have available pest control agents which are effective against a broad spectrum of harmful fungi and harmful animal pests.
  • Fenpropimorph is known since many years. However, the compound was just recently introduced in the fungicidal soybean market. It has been surprisingly found, that new ternary mix tures of fenpropimorph with selected other compounds are synergistically highly active. Be- cause of this and the limited number of highly active compounds, it is expected, that fenpropimorph will become a key partner of other active ingredients in ternary mixtures.
  • the mixtures as defined in the outset show markedly en- hanced action against pests compared to the control rates that are possible with the individual compounds and/or is suitable for improving the health of plants when applied to plants, parts of plants, seeds, or at their locus of growth. Especially high activity was shown on soybean. It has been found that the action of the inventive mixtures comprising compound I, compound II and compound III goes far beyond the fungicidal and/or plant health improving action of the ac- tive compounds present in the mixture alone (synergistic action).
  • the ratio by weight of compound I and compound II in ternary mixtures is from 500:1 to 1 :500, preferably from 100:1 to 1 :100 more preferably from 50:1 to 1 :50, most preferably from 20:1 to 1 :20, including also ratios from 10:1 to 1 :10, 1 :5 to 5:1 , or 1 :1.
  • the ratio by weight of compound I and compound III in ternary mixtures is from 500:1 to 1 :500, preferably from 100:1 to 1 :100 more preferably from 50:1 to 1 :50, most preferably from 20:1 to 1 :20, including also ratios from 10:1 to 1 :10, 1 :5 to 5:1 , or 1 :1.
  • the present invention relates to synergistic three way mixtures set forth in the table below, comprising three components, as the case may be:
  • compositions e.g. solutions, emulsions, suspensions, dusts, powders, pastes, granules, pressings, capsules, and mixtures thereof.
  • composition types are suspensions (e.g. SC, OD, FS), emulsifiable concentrates (e.g. EC), emulsions (e.g. EW, EO, ES, ME), capsules (e.g. CS, ZC), pastes, pastilles, wetable powders or dusts (e.g. WP, SP, WS, DP, DS), pressings (e.g. BR, TB, DT), granules (e.g.
  • compositions types are defined in the“Catalogue of pesticide formulation types and international coding system”, Technical Monograph No. 2, 6 th Ed. May 2008, CropLife Interna- tional.
  • compositions are prepared in a known manner, such as described by Mollet and Grube- mann, Formulation technology, Wiley VCH, Weinheim, 2001 ; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.
  • auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protective colloids, adhe- sion agents, thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifiers and binders.
  • Suitable solvents and liquid carriers are water and organic solvents, such as mineral oil fractions of medium to high boiling point, e.g. kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, e. g. toluene, paraffin, tetrahydronaphthalene, al kylated naphthalenes; alcohols, e.g. ethanol, propanol, butanol, benzylalcohol, cyclohexanol; glycols; DMSO; ketones, e.g. cyclohexanone; esters, e.g.
  • mineral oil fractions of medium to high boiling point e.g. kerosene, diesel oil
  • oils of vegetable or animal origin oils of vegetable or animal origin
  • aliphatic, cyclic and aromatic hydrocarbons e. g. toluene, paraffin, tetrahydronaphthalene, al ky
  • lactates carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, e.g. N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.
  • Suitable solid carriers or fillers are mineral earths, e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharides, e.g. cellulose, starch; fertilizers, e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of vegetable origin, e.g. cereal meal, tree bark meal, wood meal, nutshell meal, and mixtures thereof.
  • mineral earths e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide
  • polysaccharides e.g. cellulose, starch
  • fertilizers
  • Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emulsifier, dispersant, solubilizer, wetter, penetration enhancer, protective colloid, or adjuvant. Examples of surfactants are listed in McCutcheon’s, Vol.1 : Emulsifiers & De tergents, McCutcheon’s Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.).
  • Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof.
  • sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates.
  • Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of fatty acid esters.
  • Examples of phosphates are phosphate esters.
  • Examples of carboxylates are alkyl carboxylates, and carboxylated alcohol or alkylphenol ethoxylates.
  • Suitable nonionic surfactants are alkoxylates, N-subsituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof.
  • alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters which have been alkoxylated with 1 to 50 equivalents.
  • Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide.
  • Exam ples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides.
  • esters are fatty acid esters, glycerol esters or monoglycerides.
  • sugar- based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or al- kylpolyglucosides.
  • polymeric surfactants are home- or copolymers of vinylpyrroli- done, vinylalcohols, or vinylacetate.
  • Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines.
  • Suitable amphoteric surfactants are alkylbetains and imidazolines.
  • Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide.
  • Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or pol- yethyleneamines.
  • Suitable adjuvants are compounds, which have a neglectable or even no pesticidal activity themselves, and which improve the biological performance of the inventive mixtures on the target.
  • examples are surfactants, mineral or vegetable oils, and other auxilaries. Further examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5.
  • Suitable thickeners are polysaccharides (e.g. xanthan gum, carboxymethylcellulose), inorganic clays (organically modified or unmodified), polycarboxylates, and silicates.
  • Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.
  • Suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin.
  • Suitable anti-foaming agents are silicones, long chain alcohols, and salts of fatty acids.
  • Suitable colorants are pigments of low water solubility and water- soluble dyes.
  • examples are inorganic colorants (e.g. iron oxide, titan oxide, iron hexacyanofer- rate) and organic colorants (e.g. alizarin-, azo- and phthalocyanine colorants).
  • Suitable tackifiers or binders are polyvinylpyrrolidons, polyvinylacetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers.
  • composition types and their preparation are:
  • 10-60 wt% of an inventive mixture and 5-15 wt% wetting agent e.g. alcohol alkoxylates
  • a wetting agent e.g. alcohol alkoxylates
  • the active substance dissolves upon dilution with water.
  • an inventive mixture and 1 -10 wt% dispersant e. g. polyvinylpyrrolidone
  • organic solvent e.g. cyclohexanone
  • emulsifiers e.g. calcium dodecylben- zenesulfonate and castor oil ethoxylate
  • water-insoluble organic solvent e.g. aromatic hydrocarbon
  • Emulsions (EW, EO, ES)
  • emulsifiers e.g. calcium dodecylbenzene- sulfonate and castor oil ethoxylate
  • water-insoluble organic solvent e.g. aromatic hydrocarbon
  • an inventive mixture 20-60 wt% are comminuted with addition of 2- 10 wt% dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate), 0.1- 2 wt% thickener (e.g. xanthan gum) and water ad 100 wt% to give a fine active substance suspension. Dilution with water gives a stable suspension of the active substance.
  • dispersants and wetting agents e.g. sodium lignosulfonate and alcohol ethoxylate
  • 0.1- 2 wt% thickener e.g. xanthan gum
  • an inventive mixture 50-80 wt% of an inventive mixture are ground finely with addition of dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate) ad 100 wt% and prepared as water- dispersible or water-soluble granules by means of technical appliances (e. g. extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance.
  • dispersants and wetting agents e.g. sodium lignosulfonate and alcohol ethoxylate
  • 50-80 wt% of an inventive mixture are ground in a rotor-stator mill with addition of 1-5 wt% dispersants (e.g. sodium lignosulfonate), 1 -3 wt% wetting agents (e.g. alcohol ethoxylate) and solid carrier (e.g. silica gel) ad 100 wt%. Dilution with water gives a stable dispersion or solution of the active substance.
  • dispersants e.g. sodium lignosulfonate
  • 1 -3 wt% wetting agents e.g. alcohol ethoxylate
  • solid carrier e.g. silica gel
  • an inventive mixture In an agitated ball mill, 5-25 wt% of an inventive mixture are comminuted with addition of 3- 10 wt% dispersants (e.g. sodium lignosulfonate), 1-5 wt% thickener (e.g. carboxy- methylcellulose) and water ad 100 wt% to give a fine suspension of the active substance. Dilution with water gives a stable suspension of the active substance.
  • dispersants e.g. sodium lignosulfonate
  • 1-5 wt% thickener e.g. carboxy- methylcellulose
  • an inventive mixture 5-20 wt% are added to 5-30 wt% organic solvent blend (e.g. fatty acid dimethylamide and cyclohexanone), 10-25 wt% surfactant blend (e.g. alcohol ethoxylate and arylphenol ethoxylate), and water ad 100 %. This mixture is stirred for 1 h to produce spontaneously a thermodynamicallystable microemulsion.
  • organic solvent blend e.g. fatty acid dimethylamide and cyclohexanone
  • surfactant blend e.g. alcohol ethoxylate and arylphenol ethoxylate
  • An oil phase comprising 5-50 wt% of an inventive mixture, 0-40 wt% water insoluble organic solvent (e.g. aromatic hydrocarbon), 2-15 wt% acrylic monomers (e.g. methylmethacrylate, methacrylic acid and a di- or triacrylate) are dispersed into an aqueous solution of a protective colloid (e.g. polyvinyl alcohol). Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules.
  • an oil phase comprising 5-50 wt% of an inventive mixture according to the invention, 0-40 wt% water insoluble organic solvent (e.g. aromatic hydrocarbon), and an isocyanate monomer (e.g.
  • diphenylmethene-4,4’- diisocyanatae are dispersed into an aqueous solution of a protective colloid (e.g. polyvinyl alcohol).
  • a protective colloid e.g. polyvinyl alcohol.
  • the addition of a polyamine results in the formation of polyurea microcapsules.
  • the monomers amount to 1-10 wt%.
  • the wt% relate to the total CS composition.
  • Dustable powders (DP, DS)
  • an inventive mixture are ground finely and mixed intimately with solid carrier (e.g. finely divided kaolin) ad 100 wt%.
  • solid carrier e.g. finely divided kaolin
  • an inventive mixture is ground finely and associated with solid carrier (e.g. silicate) ad 100 wt%.
  • solid carrier e.g. silicate
  • organic solvent e.g. aromatic hydrocarbon
  • compositions types i) to xiii) may optionally comprise further auxiliaries, such as 0.1 -1 wt% bactericides, 5-15 wt% anti-freezing agents, 0.1-1 wt% anti-foaming agents, and 0.1 -1 wt% colorants.
  • the resulting agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75%, by weight of active substance.
  • the active substances are employed in a purity of from 90% to 100%, preferably from 95% to 100% (according to NMR spectrum).
  • Solutions for seed treatment (LS), Suspoemulsions (SE), flowable concentrates (FS), powders for dry treatment (DS), water-dispersible powders for slurry treatment (WS), water-soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are usually employed for the purposes of treatment of plant propagation materials, particularly seeds.
  • the compositions in question give, after two-to-tenfold dilution, active substance concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40%, in the ready-to-use preparations. Application can be carried out before or during sowing.
  • Methods for applying the inventive mixtures and compositions thereof, respectively, on to plant propagation material, especially seeds include dressing, coating, pelleting, dusting, soaking and in-furrow application methods of the propagation mate rial.
  • the inventive mixtures or the compositions thereof, respectively are applied on to the plant propagation material by a method such that germination is not induced, e. g. by seed dressing, pelleting, coating and dusting.
  • the amounts of active substances applied are, depending on the kind of effect desired, from 0.001 to 2 kg per ha, preferably from 0.005 to 2 kg per ha, more preferably from 0.01 to 1 .0 kg per ha, and in particular from 0.05 to 0.75 kg per ha.
  • amounts of active substance of from 0.01-10kg, preferably from 0.1-1000 g, more preferably from 1-100 g per 100 kilogram of plant propagation material (preferably seeds) are general ly required.
  • the amount of active substance applied depends on the kind of application area and on the desired effect. Amounts customarily applied in the protection of materials are 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of active substance per cubic meter of treated material.
  • oils, wetters, adjuvants, fertilizer, or micronutrients, and further pesticides may be added to the active substances or the compositions comprising them as premix or, if appropriate not until immedi- ately prior to use (tank mix).
  • pesticides e.g. herbicides, insecticides, fungicides, growth regulators, safeners
  • These agents can be admixed with the compositions according to the invention in a weight ratio of 1 :100 to 100:1 , preferably 1 :10 to 10:1.
  • the user applies the composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank, a spray plane, or an irrigation system.
  • the agrochemical composition is made up with water, buffer, and/or further auxiliaries to the desired application concentration and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained.
  • 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of agricultural useful area.
  • individual components of the composition according to the in vention such as parts of a kit or parts of a binary mixture may be mixed by the user himself in a spray tank or any other kind of vessel used for applications (e. g. seed treater drums, seed pelleting machinery, knapsack sprayer) and further auxiliaries may be added, if appropriate.
  • a spray tank or any other kind of vessel used for applications (e. g. seed treater drums, seed pelleting machinery, knapsack sprayer) and further auxiliaries may be added, if appropriate.
  • one embodiment of the invention is a kit for preparing a usable pesticidal composition, the kit comprising a) a composition comprising component 1 ) as defined herein and at least one auxiliary; and b) a composition comprising component 2) as defined herein and at least one auxiliary; and optionally c) a composition comprising at least one auxiliary and option ally a further active component 3) as defined herein.
  • the present invention comprises an use of the mixture for controlling phytopath- ogenic harmful fungi and to a method for controlling phytopathogenic pests, wherein the pest, their habitat, breeding grounds, their locus or the plants to be protected against pest attack, the soil or plant propagation material are treated with an effective amount of the mixture.
  • inventive mixtures are suitable for controlling the following fungal plant diseases:
  • Albugo spp. white rust on ornamentals, vegetables (e. g. A. Candida) and sunflowers (e. g. A. tragopogonis) ⁇ , Alternaria spp. (Alternaria leaf spot) on vegetables (e.g. A. dauci or A. porri), oilseed rape (A brassicico!a or brassicae ), sugar beets (A tenuis), fruits (e.g. A. grandis), rice, soybeans, potatoes and tomatoes (e. g. A. soiani, A. grandis ox A. alternate!), tomatoes (e. g. A. so iani or A. aiternata) and wheat (e.g. A.
  • sorokiniana on cereals and e. g. B. oryzae on rice and turfs; Biumeria (formerly Erysiphe) graminis (powdery mildew) on cereals (e. g. on wheat or barley); Botrytis cinerea (teleomorph: Botryotinia fuckeiianar. grey mold) on fruits and berries (e. g. strawberries), vegetables (e. g. lettuce, carrots, celery and cabbages); B. squamosa or B. aiiii on onion family), oilseed rape, ornamentals (e.g. B eiiptica), vines, forestry plants and wheat; Bremia iactucae (downy mildew) on lettuce; Ceratocystis ⁇ syn. Ophiostoma) spp.
  • Botrytis cinerea teleomorph: Botryotinia fuckeiianar. grey mold
  • fruits and berries e. g.
  • iirio- dendri teleomorph: Neonectria iiriodendri. Black Foot Disease) and ornamentals; Dematophora (teleomorph: RoseHinia) necatrix (root and stem rot) on soybeans; Diaporthe spp., e. g. D.
  • phaseolorum (damping off) on soybeans; Drechs!era (syn. Helminthosporium, teleomorph: Pyr- enophora) spp. on corn, cereals, such as barley (e. g. D. teres, net blotch) and wheat (e. g. D. tritici-repentis. tan spot), rice and turf; Esca (dieback, apoplexy) on vines, caused by Formiti- poria (syn. Phel/inus) punctata, F.
  • E. pisl such as cucurbits (e. g. E. cichoracearum), cabbages, oilseed rape (e. g. E. cruciferarum) ; Eu- typa lata (Eutypa canker or dieback, anamorph: Cytosporina lata, syn. Libertella blepharis ) on fruit trees, vines and ornamental woods; Exseroh/lum (syn. Helminthosporium) spp. on corn (e. g. E. turcicum) ⁇ , Fusarium (teleomorph: Gibberella ) spp. (wilt, root or stem rot) on various plants, such as F. graminearum or F.
  • cucurbits e. g. E. cichoracearum
  • cabbages oilseed rape
  • oilseed rape e. g. E. cruciferarum
  • Eu- typa lata Eutypa canker or die
  • Monilia spp. bloom and twig blight, brown rot) on stone fruits and other rosaceous plants; Mycosphaerella s ⁇ . on cereals, bananas, soft fruits and ground nuts, such as e. g. M. gra minicola (anamorph: Zymoseptoria tritici formerly Septoria triticr. Septoria blotch) on wheat or M. f/j/ensis (syn. Pseudocercospora fijiensis. black Sigatoka disease) and M. musico!a on bananas, M. arachidico!a (syn. M. a ra chid is or Cercospora arachidis), M.
  • Peronospora spp. downy mildew on cabbage (e. g. P. brassicae), oilseed rape (e. g. P. parasitica), onions (e. g. P. destructor), tobacco (P. tabacina) and soybeans (e. g. P. manshurica), Phakopsora pachyrhizi and P. meibo- miae (soybean rust) on soybeans; Phia!ophora spp. e. g. on vines (e. g. P. tracheiphi/a and P.
  • soybeans e. g. P. gregata. stem rot
  • Phoma Hngam syn. Leptosphaeria bi- globosa and L. maculans. root and stem rot
  • P. betae root rot, leaf spot and damping-off
  • sugar beets and P. zeae-maydis (syn. Phyllostica zeae) on corn
  • Phomopsis spp. on sunflowers, vines e. g. P. viticola. can and leaf spot
  • soybeans e. g. stem rot: P.
  • phaseoli, teleomorph Diaporthe phaseolorum
  • Physoderma maydis brown spots
  • Phytophthora spp. wilt, root, leaf, fruit and stem root
  • various plants such as papri ka and cucurbits (e. g. P. capsid), soybeans (e. g. P. megasperma, syn. P. sojae), potatoes and tomatoes (e. g. P. infestans. late blight) and broad-leaved trees (e. g. P. ramorum.
  • Pseudo- pezicuia tracheiphila red fire disease or .rotbrenner’, anamorph: Phia!ophora
  • Puccin- ia spp. rusts on various plants, e. g. P. triticina (brown or leaf rust), P. striiformis (stripe or yel low rust), P. hordei (dwarf rust), P. graminis (stem or black rust) or P. recondita (brown or leaf rust) on cereals, such as e. g. wheat, barley or rye, P.
  • kuehnii range rust on sugar cane and P. as pa rag ion asparagus
  • Pyrenopeziza spp. e.g. P. brassicae on oilseed rape
  • Pyrenophora anamorph: Drechsiera ) tritici-repentis (tan spot) on wheat or P. teres (net blotch) on barley
  • Pyricuiaria spp. e. g. P. oryzae (teleomorph: Magnaporthe grisea. rice blast) on rice and P. grisea on turf and cereals
  • so/ani(root and stem rot) on soybeans R. soiani (sheath blight) on rice or R. cereaiis (Rhizoctonia spring blight) on wheat or barley; Rhizopus stoionifer (black mold, soft rot) on strawberries, carrots, cabbage, vines and tomatoes; Rhynchosporium secalis and R. ses (scald) on barley, rye and triticale; Sarociadium oryzae and S. attenua- tum (sheath rot) on rice; Sderotinia spp. (stem rot or white mold) on vegetables ( S . minor and S.
  • Erysiphe necator prowdery mildew, anamorph: Oidium tuckerf
  • Setosphaeria spp. leaf blight
  • corn e. g. S. turcicum, syn. Heiminthosporium turcicum
  • turf e. g. S. reiiiana, syn. Ustiiago reiiiana. head smut
  • Sphaerotheca fuiiginea syn. Podo sphaera xanthir.
  • occulta stem smut
  • Uromyces spp. rust
  • vegetables such as beans (e. g. U. appendicuiatus, syn. U. phaseoh ), sugar beets (e. g. U. betae ox U. beticoia) and on pulses (e.g. U. vignae, U. pisi, U. viciae-fabae and U. fabae), Usti!ago spp. (loose smut) on cereals (e. g. U. nuda and U. avaenae), corn (e. g. U. maydis. corn smut) and sugar cane; Venturia spp.
  • the inventive mixtures are suitable for controlling the following fungal diseases on soybeans: A /tern aria spp. (Alternaria leaf spot); Cercospora spp. (Cercospora leaf spots), e. g. C. sojina or C. kikuchii) ; Coiietotrichum (teleomorph: Giomereiia) spp. (anthracnose), e. g. C. truncatum or C. gioeosporioides), Corynespora cassiicoia (leaf spots); Dematophora ⁇ teleo morph: Roseiiinia) necatrix (root and stem rot); Diaporthe spp., e.
  • D. phaseoiorum ⁇ damping off Fusarium (teleomorph: Gibbereiia ) spp. (wilt, root or stem rot), e.g. F. tucumaniae and F. brasiiiense each causing sudden death syndrome on soybeans; Macrophomina phaseoiina (syn. phaseoii) (root and stem rot); Microsphaera diffusa (powdery mildew); Peronospora spp. (downy mildew), e. g. P. manshurica, Phakopsora pachyrhizi and P.
  • Phiaiophora spp. e. g. P. gregata. stem rot
  • Phomopsis spp. e. g. stem rot: P. phaseoii (teleo morph: Diaporthe phaseoiorum) ⁇ , Pythium spp. (damping-off); Phytophthora spp. (wilt, root, leaf, fruit and stem root), e. g. P. megasperma, syn. P. sojae), Rhizoctonia spp., e. g. R. soiani (root and stem rot); Scierotinia spp.
  • the inventive mixtures are suitable for controlling the following fungal diseases on soybeans: Alternaria spp. (Alternaria leaf spot); Cercospora spp. (Cercospora leaf spots), e. g. C. sojina or C. kikuchii), Coiietotrichum (teleomorph: Giomereiia) spp. (anthracnose), e. g.
  • D. phaseoiorum (damping off); Fusarium (teleomorph: Gibbereiia) spp. (wilt, root or stem rot), e.g. F. tucumaniae and F. brasiiiense each causing sudden death syndrome on soybeans; Mac rophomina phaseoiina ⁇ syn. phaseoii) (root and stem rot); Peronospora spp. (downy mildew), e. g. P. manshurica, Phakopsora pachyrhizi and P. meibomiae (soybean rust); Phomopsis spp., e. g. stem rot: P.
  • phaseoii (teleomorph: Diaporthe phaseoiorum) ⁇ , Phytophthora spp. (wilt, root, leaf, fruit and stem root), e. g. P. megasperma, syn. P. sojae), Rhizoctonia spp., e. g. R. soiani (root and stem rot); Septoria spp., e. g. S. glycines (brown spot).
  • the inventive mixtures are suitable for controlling Phakopsora pachyrhizi and P. meibomiae (soybean rust) on soybeans.
  • the mixtures according to the present invention are also suitable for controlling harmful fungi in the protection of stored products or harvest and in the protection of materials.
  • protection of materials is to be understood to denote the protection of technical and non-living materials, such as adhesives, glues, wood, paper and paperboard, textiles, leather, paint dispersions, plastics, cooling lubricants, fiber or fabrics, against the infestation and de struction by harmful microorganisms, such as fungi and bacteria.
  • harmful microorganisms such as fungi and bacteria.
  • Ascomycetes such as Ophiostoma spp., Ceratocystis spp., Aureobasidium pullulans, Sderophoma s p p . , Chaetomium spp.
  • Humicola spp. Petriella spp., Trichurus spp.; Basidiomycetes such as Coni- ophora spp., Coriotus spp., Gloeophyllum spp., Lentinus spp., P/eurotus spp., Poria spp., Ser- pu!a spp. and Tyromyces spp., Deuteromycetes such as A spergiHus spp., dadosporium spp., PeniciHium spp., Trichoderma spp., A!ternaria spp., Paecilomyces spp. and Zygomycetes such as Mucorspp., and in addition in the protection of stored products and harvest the following yeast fungi are worthy of note: Candida spp. and Saccharomyces cerevisae.
  • soya soybean
  • cereals for example cucumbers, beans and cucurbits
  • cereals such as wheat, rye, barley, rice, oats
  • soya soybean
  • cereals and corn are used in soya (soybean), cereals and corn.
  • pesticidally effective amount means the amount of the inventive mixtures or of compositions comprising the mixtures needed to achieve an observable effect on growth, including the effects of necrosis, death, retardation, prevention, and removal, destruction, or oth erwise diminishing the occurrence and activity of the target organism.
  • the pesticidally effective amount can vary for the various mixtures / compositions used in the invention.
  • a pesticidally effective amount of the mixtures / compositions will also vary according to the prevailing conditions such as desired pesticidal effect and duration, weather, target species, locus, mode of application, and the like.
  • the present invention comprises a method for improving the health of plants, wherein the plant, the locus where the plant is growing or is expected to grow or plant propagation material, from which the plant grows, is treated with a plant health effective amount of an inventive mixture.
  • plant effective amount denotes an amount of the inventive mixtures, which is sufficient for achieving plant health effects as defined herein below. More exemplary information about amounts, ways of application and suitable ratios to be used is given below. Again, the skilled artisan is well aware of the fact that such an amount can vary in a broad range and is dependent on various factors, e.g. the treated cultivated plant or material and the climatic conditions.
  • inventive mixtures are employed by treating the fungi or the plants, plant propagation materials (preferably seeds), materials or soil to be protected from fungal attack with a pesticidally effective amount of the active compounds.
  • the application can be carried out both before and after the infection of the materials, plants or plant propagation materials (preferably seeds) by the pests.
  • the term plant refers to an entire plant, a part of the plant or the propagation material of the plant.
  • inventive mixtures and compositions thereof are particularly important in the control of a multitude of phytopathogenic fungi on various cultivated plants, such as cereals, e. g. wheat, rye, barley, triticale, oats or rice; beet, e. g. sugar beet or fodder beet; fruits, such as pomes, stone fruits or soft fruits, e. g.
  • cereals e. g. wheat, rye, barley, triticale, oats or rice
  • beet e. g. sugar beet or fodder beet
  • fruits such as pomes, stone fruits or soft fruits, e. g.
  • the inventive mixtures and compositions thereof are used for controlling a multitude of fungi on field crops, such as potatoes, sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rape, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamentals; or vegetables, such as cucumbers, tomatoes, beans or squashes.
  • field crops such as potatoes, sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rape, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamentals; or vegetables, such as cucumbers, tomatoes, beans or squashes.
  • treatment of plant propagation materials with the inventive mixtures and compo sitions thereof, respectively is used for controlling a multitude of fungi on cereals, such as wheat, rye, barley and oats; potatoes, tomatoes, vines, rice, corn, cotton and soybeans.
  • cultiva plants is to be understood as including plants which have been modified by breeding, mutagenesis or genetic engineering including but not limiting to agricultural biotech products on the market or in development (cf. http://cera-gmc.org/, see GM crop database therein).
  • Genetically modified plants are plants, which genetic material has been so modified by the use of recombinant DNA techniques that under natural circumstances cannot readily be obtained by cross breeding, mutations or natural recombination.
  • one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant.
  • Such genetic modifications also include but are not limited to targeted post-translational modification of protein(s), oligo- or polypeptides e. g. by glycosylation or polymer additions such as prenylated, acetylated or farnesylated moieties or PEG moieties.
  • auxin herbicides such as
  • herbicides e. bromoxynil or ioxynil herbicides as a result of conventional methods of breeding or genetic engineering. Furthermore, plants have been made resistant to multiple classes of herbicides through multiple genetic modifications, such as resistance to both glyphosate and glufosinate or to both glyphosate and a herbicide from another class such as ALS inhibitors, HPPD inhibitors, auxin herbicides, or ACCase inhibitors.
  • These herbicide resistance technologies are e. g. described in Pest Management Sci. 61 , 2005, 246; 61 , 2005, 258; 61 , 2005, 277; 61 , 2005, 269; 61 , 2005, 286; 64, 2008, 326; 64, 2008, 332;
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more insecticidal proteins, especially those known from the bacterial genus Bacillus , particularly from Bacillus thuringiensis, such as d-endotoxins, e. g. CrylA(b), CrylA(c), CrylF, CrylF(a2), CryllA(b), CrylllA, CrylllB(bl) or Cry9c; vegetative insecticidal proteins (VIP), e. g. VIP1 , VIP2, VIP3 or VIP3A; insecticidal proteins of bacteria colonizing nematodes, e. g. Photorhabdus spp.
  • VIP1 , VIP2, VIP3 or VIP3A vegetative insecticidal proteins
  • toxins produced by animals such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins; toxins pro prised by fungi, such Streptomycetes toxins, plant lectins, such as pea or barley lectins; agglutinins; proteinase inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors; ribosome-inactivating proteins (RIP), such as ricin, maize-RIP, abrin, luffin, saporin or bryodin; steroid metabolism enzymes, such as 3-hydroxysteroid oxidase, ecdyster- oid-IDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors or HMG-CoA-reductase; ion channel blockers, such as blockers
  • insecticidal proteins or toxins are to be understood expressly also as pre-toxins, hybrid proteins, truncated or otherwise modified proteins.
  • Hybrid proteins are characterized by a new combination of protein domains, (see, e. g. WO 02/015701 ).
  • Further examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, e. g., in EP-A 374 753, WO 93/007278,
  • WO 95/34656 EP-A 427 529, EP-A 451 878, WO 03/18810 und WO 03/52073.
  • the methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, e. g. in the publications mentioned above.
  • These insecticidal proteins contained in the genetically modified plants impart to the plants producing these proteins tolerance to harmful pests from all taxonomic groups of athropods, especially to beetles (Coelop- tera), two-winged insects (Diptera), and moths (Lepidoptera) and to nematodes (Nematoda).
  • Genetically modified plants capable to synthesize one or more insecticidal proteins are, e.
  • Agrisure ® CB and Bt176 from Syngenta Seeds SAS, France, (corn cultivars producing the CrylAb toxin and PAT enzyme), MIR604 from Syngenta Seeds SAS, France (corn cultivars producing a modified version of the Cry3A toxin, c.f. WO 03/018810), MON 863 from Monsanto Europe S.A., Belgium (corn cultivars producing the Cry3Bb1 toxin), IPC 531 from Monsanto Europe S.A., Belgium (cotton cultivars producing a modified version of the CrylAc toxin) and 1507 from Pioneer Overseas Corporation, Belgium (corn cultivars producing the Cry1 F toxin and PAT enzyme).
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the resistance or tolerance of those plants to bacterial, viral or fungal pathogens.
  • proteins are the so-called“pathogenesis- related proteins” (PR proteins, see, e. g. EP-A 392 225), plant disease resistance genes (e. g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solarium bu!bocastanum) or T4-lysozym (e. g. potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Er- winia amylvora).
  • PR proteins so-called“pathogenesis- related proteins”
  • plant disease resistance genes e. g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solarium bu!bocastanum
  • T4-lysozym e.
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the productivity (e. g. bio mass production, grain yield, starch content, oil content or protein content), tolerance to drought, salinity or other growth-limiting environmental factors or tolerance to pests and fungal, bacterial or viral pathogens of those plants.
  • productivity e. g. bio mass production, grain yield, starch content, oil content or protein content
  • plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve human or animal nutrition, e. g. oil crops that produce health-promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (e. g. Nexera ® rape, DOW Agro Sciences, Canada).
  • plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve raw material production, e. g. potatoes that produce increased amounts of amylopectin (e. g. Amflora ® potato, BASF SE, Germany).
  • a modified amount of substances of content or new substances of content specifically to improve raw material production, e. g. potatoes that produce increased amounts of amylopectin (e. g. Amflora ® potato, BASF SE, Germany).
  • the separate or joint application of the compounds of the inventive mixtures is carried out by spraying or dusting the seeds, the seedlings, the plants or the soils before or after sowing of the plants or before or after emergence of the plants.
  • inventive mixtures and the compositions comprising them can be used for protecting wooden materials such as trees, board fences, sleepers, etc. and buildings such as houses, out- houses, factories, but also construction materials, furniture, leathers, fibers, vinyl articles, electric wires and cables etc. from ants and/or termites, and for controlling ants and termites from doing harm to crops or human being (e.g. when the pests invade into houses and public facilities).
  • Customary application rates in the protection of materials are, for example, from 0.01 g to 1000 g of active compound per m 2 treated material, desirably from 0.1 g to 50 g per m 2 .
  • the content of the mixture of the active ingredients is from 0.001 to 80 weight %, preferably from 0.01 to 50 weight % and most preferably from 0.01 to 15 weight.
  • the spray solutions were prepared in several steps:
  • the stock solution was prepared: a mixture of acetone and/or dimethylsulfoxide and the wetting agent/emulsifier Wettol, which is based on ethoxylated alkylphenoles, in a relation (volume) solvent-emulsifier of 99 to 1 was added to the initial weight of the compound to give a total of 5 ml. Water was then added to total volume of 100 ml.
  • Wettol which is based on ethoxylated alkylphenoles
  • This stock solution was diluted with the described solvent-emulsifier-water mixture to the given concentration.
  • Example 1 Curative control of soy bean rust on soy beans caused by Phakopsora pachyrhizi
  • Leaves of pot-grown soy bean seedlings were inoculated with spores of Phakopsora pachyrhizi.
  • the plants were transferred to a humid chamber with a relative humidity of about 95% and 20 to 24 ⁇ C for 24 h.
  • the next day the plants were cultivated for 2 days in a greenhouse chamber at 23-27°C and a relative humidity between 60 and 80 %.
  • the plants were sprayed to run-off with an aqueous suspension, containing the concentration of active ingredient or their mixture as described below. The plants could air-dry.
  • the trial plants were cultivated for 14 days in a greenhouse chamber at 23-27°C and a relative humidity between 60 and 80 %.
  • the extent of fungal attack on the leaves was visually assessed as % diseased leaf area.
  • Leaves of pot-grown soy bean seedlings were sprayed to run-off with an aqueous suspension, containing the concentration of active ingredient or their mixture as described below.
  • the plants could air-dry.
  • the trial plants were cultivated for 2 days in a greenhouse chamber at 23-27°C and a relative humidity between 60 and 80 %. Then the plants were inoculated with spores of Phakopsora pachyrhizi. To ensure the success the artificial inoculation, the plants were transferred to a humid chamber with a relative humidity of about 95 % and 20 to 24 ⁇ C for 24 h.
  • the trial plants were cultivated for fourteen days in a greenhouse chamber at 23-27°C and a relative humidity between 60 and 80 %. The extent of fungal attack on the leaves was visually assessed as % diseased leaf area.
  • the diseases were converted into efficacies.
  • An efficacy of 0 means that the infection level of the treated plants corresponds to that of the untreated control plants; an efficacy of 100 means that the treated plants were not infected.

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  • Agronomy & Crop Science (AREA)
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  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • Wood Science & Technology (AREA)
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Abstract

La présente invention concerne des mélanges fongicides comprenant, en tant que composants actifs, (1) du fenpropimorphe en tant que composé I, et (2) un composé fongicide II, le composé II étant un inhibiteur de succinate déshydrogénase et choisi dans le groupe constitué par : le 2-(difluorométhyle)-N-[(3R)-1,1-diméthyl-3-propyl-indan-4-yl]pyridine-3-carboxamide, le 2-(difluorométhyl)-N-(1,1,3-triméthylindan-4-yl)) pyridine-3-carboxamide, le 2-(difluorométhyl)-N- [(3R)-1,1,3-triméthylindan-4-yl]pyridine-3-carboxamide, le 2-(difluorométhyl)-N-(3-éthyl -1,1-diméthyl-indan-4-yl))pyridine-3-carboxamide, le 2- (difluorométhyl)-N-[(3R)-3-éthyl-1,1-diméthyl-indan-4-yl]pyridine-3-carboxamide, le 2-(difluorométhyle)-N-(1,1-diméthyl-3-propyl-indan-4-yl) pyridine-3-carboxamide, le 2-(difluorométhyl)-N-(3-isobutyl -1,1-diméthyl-indan-4-yl))pyridine-3-carboxamide, le 2-(difluorométhyl)-N-[(3R)-3-isobutyl-1,1-diméthyl-indan-4-yl]pyridine-3-carboxamide, l'inpyrfluxame, le bixafènen, le pydiflumétofène, le benzovindiflupyr, le fluxapyroxad, le fluindapyr, l'isoflucypram, le sédaxane, et (3) un composé fongicide III de la classe des fongicides DMI (inhibiteur de la C14-déméthylase dans la biosynthèse des stérols), le composé III étant choisi dans le groupe constitué par le prothio-conazole, le difénoconazole, le tétraconazole, le cyproconazole, le metconazole, le 4-[[6-[2-(2,4-difluorophényl))-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy] benzonitrile, le tébuconazole, le méfentrifluconazole.
PCT/EP2019/077351 2018-10-19 2019-10-09 Mélanges ternaires contenant du fenpropimorphe, des inhibiteurs de succinate déshydrogénase et des azoles WO2020078795A1 (fr)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022089969A1 (fr) * 2020-10-27 2022-05-05 BASF Agro B.V. Compositions comprenant du méfentrifluconazole

Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0374753A2 (fr) 1988-12-19 1990-06-27 American Cyanamid Company Toxines insecticides, gènes les codant, anticorps les liant, ainsi que cellules végétales et plantes transgéniques exprimant ces toxines
EP0392225A2 (fr) 1989-03-24 1990-10-17 Ciba-Geigy Ag Plantes transgéniques résistantes aux maladies
EP0427529A1 (fr) 1989-11-07 1991-05-15 Pioneer Hi-Bred International, Inc. Lectines larvicides, et résistance induite des plantes aux insectes
EP0451878A1 (fr) 1985-01-18 1991-10-16 Plant Genetic Systems, N.V. Modification de plantes par techniques de génie génétique pour combattre ou contrôler les insectes
WO1993007278A1 (fr) 1991-10-04 1993-04-15 Ciba-Geigy Ag Sequence d'adn synthetique ayant une action insecticide accrue dans le mais
WO1995034656A1 (fr) 1994-06-10 1995-12-21 Ciba-Geigy Ag Nouveaux genes du bacillus thuringiensis codant pour des toxines actives contre les lepidopteres
WO2002015701A2 (fr) 2000-08-25 2002-02-28 Syngenta Participations Ag Nouvelles toxines insecticides derivees de proteines cristallines insecticides de $i(bacillus thuringiensis)
WO2003018810A2 (fr) 2001-08-31 2003-03-06 Syngenta Participations Ag Toxines cry3a modifiees et sequences d'acides nucleiques les codant
WO2003052073A2 (fr) 2001-12-17 2003-06-26 Syngenta Participations Ag Nouvel evenement du mais
WO2015197530A2 (fr) 2014-06-25 2015-12-30 Bayer Cropscience Ag Carboxamides difluorométhyl-nicotinique-indanyle
WO2016096944A1 (fr) * 2014-12-19 2016-06-23 Bayer Cropscience Aktiengesellschaft Combinaisons de composés actifs
WO2016097003A1 (fr) * 2014-12-19 2016-06-23 Bayer Cropscience Aktiengesellschaft Combinaisons de composés actifs
WO2016096849A1 (fr) * 2014-12-19 2016-06-23 Bayer Cropscience Aktiengesellschaft Combinaisons de composés actifs
WO2016187201A2 (fr) 2015-05-18 2016-11-24 Viamet Pharmaceuticals, Inc. Composés antifongiques
EP3162208A1 (fr) 2015-10-29 2017-05-03 Helm AG Composition fongicide pour contrôler les infections fongiques chez la plante de soja
WO2017220491A1 (fr) * 2016-06-22 2017-12-28 Bayer Cropscience Aktiengesellschaft Combinaisons de composés actifs
WO2018011112A1 (fr) * 2016-07-15 2018-01-18 Basf Se Mélanges fongicides contenant un carboxamide
WO2018162999A1 (fr) 2017-03-07 2018-09-13 Upl Ltd Combinaisons fongicides

Patent Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0451878A1 (fr) 1985-01-18 1991-10-16 Plant Genetic Systems, N.V. Modification de plantes par techniques de génie génétique pour combattre ou contrôler les insectes
EP0374753A2 (fr) 1988-12-19 1990-06-27 American Cyanamid Company Toxines insecticides, gènes les codant, anticorps les liant, ainsi que cellules végétales et plantes transgéniques exprimant ces toxines
EP0392225A2 (fr) 1989-03-24 1990-10-17 Ciba-Geigy Ag Plantes transgéniques résistantes aux maladies
EP0427529A1 (fr) 1989-11-07 1991-05-15 Pioneer Hi-Bred International, Inc. Lectines larvicides, et résistance induite des plantes aux insectes
WO1993007278A1 (fr) 1991-10-04 1993-04-15 Ciba-Geigy Ag Sequence d'adn synthetique ayant une action insecticide accrue dans le mais
WO1995034656A1 (fr) 1994-06-10 1995-12-21 Ciba-Geigy Ag Nouveaux genes du bacillus thuringiensis codant pour des toxines actives contre les lepidopteres
WO2002015701A2 (fr) 2000-08-25 2002-02-28 Syngenta Participations Ag Nouvelles toxines insecticides derivees de proteines cristallines insecticides de $i(bacillus thuringiensis)
WO2003018810A2 (fr) 2001-08-31 2003-03-06 Syngenta Participations Ag Toxines cry3a modifiees et sequences d'acides nucleiques les codant
WO2003052073A2 (fr) 2001-12-17 2003-06-26 Syngenta Participations Ag Nouvel evenement du mais
WO2015197530A2 (fr) 2014-06-25 2015-12-30 Bayer Cropscience Ag Carboxamides difluorométhyl-nicotinique-indanyle
WO2016096944A1 (fr) * 2014-12-19 2016-06-23 Bayer Cropscience Aktiengesellschaft Combinaisons de composés actifs
WO2016097003A1 (fr) * 2014-12-19 2016-06-23 Bayer Cropscience Aktiengesellschaft Combinaisons de composés actifs
WO2016096849A1 (fr) * 2014-12-19 2016-06-23 Bayer Cropscience Aktiengesellschaft Combinaisons de composés actifs
WO2016187201A2 (fr) 2015-05-18 2016-11-24 Viamet Pharmaceuticals, Inc. Composés antifongiques
EP3162208A1 (fr) 2015-10-29 2017-05-03 Helm AG Composition fongicide pour contrôler les infections fongiques chez la plante de soja
WO2017220491A1 (fr) * 2016-06-22 2017-12-28 Bayer Cropscience Aktiengesellschaft Combinaisons de composés actifs
WO2018011112A1 (fr) * 2016-07-15 2018-01-18 Basf Se Mélanges fongicides contenant un carboxamide
WO2018162999A1 (fr) 2017-03-07 2018-09-13 Upl Ltd Combinaisons fongicides

Non-Patent Citations (12)

* Cited by examiner, † Cited by third party
Title
AUSTRAL. J., AGRICULT. RES., vol. 58, 2007, pages 708
KNOWLES: "Adjuvants and additives, Agrow Reports DS256", 2006, T&F INFORMA
KNOWLES: "Agrow Reports DS243", 2005, T&F INFORMA, article "New developments in crop protection product formulation"
MOLLETGRUBE-MANN: "Formulation technology", 2001, WILEY VCH
PEST MANAGEMENT SCI, vol. 61, 2005, pages 286
PEST MANAGEMENT SCI, vol. 64, 2008, pages 332
PEST MANAGEMENT SCI., vol. 61, 2005, pages 246
PEST MANAGEMENT SCI., vol. 61, 2005, pages 258
R.S. COLBY: "Calculating synergistic and antagonistic responses of herbicide combinations", WEEDS, vol. 15, 1967, pages 20 - 22, XP001112961
SCIENCE, vol. 316, 2007, pages 1185
STEFANIA KUPFER ET AL: "Effective control of brown rost (Puccinia recondita f. sp. secalis Rob. ex Desm.) in winter rye with fungicides of different groups of fungicid mixtures. Evaluation of the tets of the German federal states Brandenburg, Sachsen-Anhalt, Sachsen und Thüringen", GESUNDE PFLANZEN, vol. 64, no. 3, 19 June 2012 (2012-06-19), DE, pages 117 - 127, XP055535727, ISSN: 0367-4223, DOI: 10.1007/s10343-012-0280-3 *
WEED SCI., vol. 57, 2009, pages 108

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WO2022089969A1 (fr) * 2020-10-27 2022-05-05 BASF Agro B.V. Compositions comprenant du méfentrifluconazole

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