WO2019130591A1 - 吸収体及び吸収性物品 - Google Patents
吸収体及び吸収性物品 Download PDFInfo
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- WO2019130591A1 WO2019130591A1 PCT/JP2017/047402 JP2017047402W WO2019130591A1 WO 2019130591 A1 WO2019130591 A1 WO 2019130591A1 JP 2017047402 W JP2017047402 W JP 2017047402W WO 2019130591 A1 WO2019130591 A1 WO 2019130591A1
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- layer
- absorbent
- fiber entangled
- fiber
- mass
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
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- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
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Definitions
- the present invention relates to an absorbent used for absorbing a liquid and suitable as a component of an absorbent article such as a sanitary napkin or disposable diaper.
- An absorbent sheet in which a water absorbing polymer is fixed to one surface of a substrate sheet is known as an absorbent of an absorbent article.
- the absorbent sheet having such a configuration is mainly used for a thin absorbent article because it is thin and not bulky as compared with an absorbent containing a pile of fiber materials such as pulp fibers.
- Patent Documents 1 and 2 describe an absorbent sheet having a configuration in which a large number of water-absorbent polymer particles are fixed by a hot melt adhesive between two non-woven fabrics.
- the present invention comprises an absorbent sheet having a base material layer and an absorbent layer comprising a water absorbing polymer fixed to one surface of the base material layer, and a fiber entangled layer, wherein the water absorbent polymer of the absorbent layer and the fiber It is an absorber which adjoins with a confounding layer.
- the present invention is also an absorbent article comprising the above-mentioned absorbent of the present invention.
- FIG. 1 is a perspective view schematically showing an embodiment of the absorber of the present invention.
- FIG. 2 is a cross-sectional view taken along the line II of FIG. 1 and schematically showing a cross section taken along the thickness direction of the absorber shown in FIG. Fig.3 (a) and FIG.3 (b) are sectional drawings (FIG. 2 equivalent view) which shows typically the cross section in alignment with the thickness direction of other embodiment of the absorber of this invention.
- FIG. 4: is sectional drawing (FIG. 2 equivalent view) which shows typically the cross section which follows the thickness direction of other embodiment of the absorber of this invention.
- Patent Documents 1 and 2 meet the needs for thin absorbent bodies, since they are thinner compared to pulp fiber stacks conventionally used as absorbents for absorbent articles. While it is useful for improving the wearing feel and portability of absorbent articles, it is inferior to the fiber stack in terms of absorption capacity, absorption speed, etc. because the content of pulp fibers having liquid absorption capacity is small. There is a tendency and there is room for improvement in terms of absorption performance.
- the accumulated fiber body of pulp fiber is superior to the absorbent sheet in terms of absorption capacity, absorption speed, and the like because it is thicker compared to the absorbent sheet, its thickness is useful for absorbent articles. There is a concern that it may cause a reduction in the wearing feeling of the absorbent article.
- piled fibers of this type of pulp fiber have poor shape stability, especially after liquid absorption, so when applied to an absorbent article, for example, due to the movement of the wearer after body fluid absorption
- the outer shape of the stacked fiber body collapses and is divided into a plurality of pieces, and as a result, inconveniences such as giving a sense of discomfort to the wearer or lowering the absorption performance may occur. I am concerned.
- An absorber which can meet the needs for a thin absorber and is excellent in absorption performance and shape stability after absorption of body fluid has not been provided yet.
- an object of the present invention relates to providing an absorbent body which is thin but is excellent in absorption performance and shape stability, and an absorbent article provided with the same.
- the absorbent body 1 includes an absorbent sheet 2 and a fiber entangled layer 3, and more specifically, includes a laminated structure of the absorbent sheet 2 and the fiber entangled layer 3.
- the absorbent sheet 2 has a base layer 20 and an absorbent layer 21 including a water absorbing polymer P1 fixed to one surface of the base layer 20.
- the fiber entangled layer 3 is a fiber assembly in which a plurality of fibers 3F are entangled without fusion.
- the water absorbent polymer P1 of the absorbent layer 21 in the absorbent sheet 2 is adjacent to the fiber entangled layer 3
- the absorbent layer 21 and the fiber entangled layer 3 are directly and entirely overlapped without interposing other members, and the water absorbent polymer P1 contained in the absorbent layer 21 and the fiber entangled layer Three constituent fibers 3F are in contact with each other.
- the absorbent body consisting only of the fiber entangled layer 3
- the absorbent body that is, the fiber entangled layer 3 absorbs the body fluid such as urine, and then the absorbent article is worn.
- the outer shape of the fiber entangled layer 3 collapses and is divided into a plurality of pieces, resulting in a reduction in absorption performance giving discomfort to the wearer. It is feared that inconveniences such as causing may occur.
- the absorbent body 1 of the present embodiment includes the absorbent sheet 2 laminated on the fiber entangled layer 3, and further, absorption in the fiber entangled layer 3 and the absorbent sheet 2 Since the water absorbing polymer P1 of the layer 21 is adjacent, even if an external force is applied to the fiber entangled layer 3 after liquid absorption and it is likely to be divided, it is fixed to the base layer 20 and the fiber entangled layer 3 Of the fiber entangled layer 3 because the water-absorbent polymer P1 in contact with the water-absorbing polymer P1 is sticky by absorption and gelation, and is bonded to the fiber entangled layer 3 (constituting fibers 3F) by its adhesive power. The shape stability is enhanced so that the fiber entangled layer 3 is unlikely to be divided, and the concern is eliminated.
- the shape stability of the fiber-entangled layer 3 is obtained by the adhesiveness of the water-absorbent polymer P1 itself after liquid absorption. It is possible to increase and suppress division. That is, in order to avoid division of the fiber entangled layer 3 after liquid absorption, it is sufficient if the water absorbing polymer P1 and the fiber entangled layer 3 (constituting fibers 3F) are in contact, and the water absorbing polymer P1 and the fiber entangled layer 3 may not be bonded by an adhesive.
- both surfaces of the base material layer 20 are substantially flat (macroscopically).
- the water absorbing polymer P1 is fixed to one surface of the flat base layer 20, and the water absorbing polymer P1 is not fixed to the other surface of the base layer 20.
- the water absorbing polymer P1 is in the form of particles, and a large number of particulate water absorbing polymers P1 are fixed to one surface of the base layer 20.
- the shape of the particulate water-absorbing polymer P1 is not particularly limited, and examples thereof include spherical, massive, bowl-like, and irregular shapes.
- the average particle size of the particulate water-absorbing polymer P1 is not particularly limited, but is preferably 50 ⁇ m or more, more preferably 200 ⁇ m or more, and preferably 800 ⁇ m or less, more preferably from the viewpoint of the balance between fixability and absorption performance. It is 500 ⁇ m or less.
- the form of the water-absorbing polymer P1 is not particularly limited, and may be, for example, fibrous, sheet-like, etc. It may be a sheet piece obtained by cutting into pieces having a relatively small area.
- water-absorbing polymer P1 those usable in the absorbent sheet of this kind can be used without particular limitation, and examples thereof include sodium polyacrylate, (acrylic acid-vinyl alcohol) copolymer, sodium polyacrylate cross-linked Body, (starch-acrylic acid) graft polymer, (isobutylene-maleic anhydride) copolymer and saponification product thereof, potassium polyacrylate, cesium polyacrylate and the like, and one of these may be used alone or Two or more of them can be used in combination.
- the water absorbing polymer P1 of the absorbent layer 21 has high adhesiveness in a liquid-absorbed state, specifically It is preferable that the adhesion rate measured by the following method is 0.5 or more, particularly 0.7 or more.
- the upper limit of the adhesion ratio measured by the following method of the water-absorbing polymer P1 is preferably 0.95 or less, more preferably 0.85, from the viewpoint of suppressing the decrease in absorption performance due to gel blocking of the water-absorbing polymers P1. It is below.
- the central portion ( ⁇ 100) of 4A ( ⁇ 150) can be moistened with physiological saline, and the water-absorbing polymer can be uniformly dispersed over the central portion.
- the filter paper is vertically inclined and supported at a position of 5 mm above the table, the support is released and the filter paper is dropped.
- the adhesion rate of the water-absorbing polymer P1 may be within the above-mentioned preferred range in at least one of the unused state and the used state (the state fixed to the base layer 20).
- the water-absorbing polymer P1 having an adhesion ratio of 0.5 or more reduces the amount of the crosslinking agent added in, for example, a known method for producing a polyacrylic acid-based water-absorbing polymer such as reverse phase suspension polymerization or aqueous solution polymerization. It can be obtained by reducing the degree of crosslinking of the water-absorbing polymer as a product of the production, by changing the conditions such as shortening the reaction time.
- the fixing ratio of the water absorbing polymer P1 to the base layer 20 of the absorbing layer 21 is preferably 10% or more, particularly 30% or more.
- the fixing ratio of the water-absorbing polymer P1 is the ratio of the water-absorbing polymer P1 that does not fall off even when the absorbent sheet 2 is added to physiological saline (0.9 mass% saline solution) being stirred at a predetermined rotation speed. It can be used as an indicator of the fixability of the absorbent / swollen water absorbing polymer P1 to the base material layer 20.
- the upper limit of the fixing rate of the absorbent layer 21 to the base layer 20 is preferably 90% or less, more preferably 80% or less, from the viewpoint of not impairing the flexibility of the absorbent sheet 2 after liquid absorption. It is below. If the fixing rate is too high, the water-absorbent polymer P1 swollen due to liquid absorption will be in close contact with each other, so the rigidity of the absorbent sheet 2 may be increased and the flexibility may be reduced.
- the fixing rate of the water-absorbing polymer P1 is measured according to the following procedures 1 to 5.
- the reason for holding the end of the measurement sample (the absorbent sheet of square shape in plan view of 5 cm square) and temporarily suspending it vertically is that it is not fixedly arranged on the base sheet.
- non-fixed matter such as a water-absorbing polymer (for example, a water-absorbing polymer which is not fixed by an adhesive but simply sprinkled from above the base sheet).
- a water-absorbing polymer for example, a water-absorbing polymer which is not fixed by an adhesive but simply sprinkled from above the base sheet.
- the water absorbing polymer fixing ratio is measured according to the above-described procedures 1 to 5, and the average value of the plurality of water absorbing polymer fixing ratios thus obtained is used as the water absorbing polymer of the absorbent sheet. Fixed rate.
- Magnetic stirrer HI-304N (manufactured by HANNA, reverse stirrer)
- Stirrer Starhead NALGENE (6600-0035) [35 ⁇ ⁇ 12 mm]
- Beaker 300 ml [78 ⁇ ⁇ 103 mm]
- the means for fixing the water-absorbing polymer P1 to the base layer 20 is not particularly limited. The point is that the water-absorbing polymer P1 is not only absorbed in a liquid but also swollen in a liquid absorbed state. It is sufficient if it is a means that can be reliably fixed to the material layer 20 and can effectively prevent the water-absorbing polymer P1 from falling off, and preferably, the fixing ratio of the water-absorbing polymer P1 to the base layer 20 is 10% or more as described above. It is a fixing means to become. Typical of such fastening means is an adhesive.
- the adhesive referred to here has "a narrowly defined adhesive that becomes solid when pasted with a non-adhesive substance in liquid (in a fluid state) before use” and has both “liquid and solid properties". Both of the adhesive which keeps the wet state stable are included.
- the water absorbing polymer P1 does not interpose other members, such as an adhesive agent, and the base material layer 20 Directly attached to the surface of The direct adhesion form of the water absorbing polymer P1 can be obtained by carrying out the production of the water absorbing polymer, specifically, the polymerization reaction of the water absorbing polymer, on the base layer 20.
- the water absorbing polymer P1 of the absorbing layer 21 is fixed to one surface of the base layer 20 by a hot melt adhesive (not shown).
- the hot melt adhesive as the adhesive for fixing the substrate sheet of the water absorbing polymer P1
- the water absorbing polymer P1 is fixed to the substrate layer 20 while securing the flexibility of the substrate layer 20.
- the hot melt adhesive which is an adhesive for fixing a substrate sheet of the water absorbing polymer P1
- one having a flexibility capable of extending following the swelling change accompanying the liquid absorption of the water absorbing polymer P1 is preferable, and specific Are preferably acrylics, silicones, rubbers and olefins.
- the maximum elongation (elongation at cutting) of the adhesive measured in accordance with Japan Adhesive Industry Association Standard JAI7-1999 can be used as an index, and the value of this maximum elongation is The larger the size, the higher the flexibility of the adhesive can be evaluated.
- the maximum elongation of the hot melt adhesive is preferably 200% or more, more preferably 300% or more. It is preferable that the maximum elongation or flexibility of the hot melt adhesive be as high as possible, but the upper limit of the maximum elongation is preferably 3000% or less, more preferably 2500% or less.
- a raw material (base polymer) of the said silicone type adhesive agent a polydimethylsiloxane polymer polymer can be illustrated, for example.
- Examples of the material (base polymer) of the rubber adhesive include natural rubber, polyisoprene, styrene-butadiene copolymer (SBR), styrene-isoprene-styrene block copolymer (SIS), styrene-butadiene-styrene Examples include block copolymers (SBS), styrene-ethylene-butadiene-styrene block copolymers (SEBS), and styrene-ethylene-propylene-styrene block copolymers (SEPS).
- SBR styrene-butadiene copolymer
- SIS styrene-isoprene-styrene block copolymer
- SEPS block copolymers
- SEBS styrene-ethylene-butadiene-styrene block copolymers
- SEPS styrene-ethylene-propylene-s
- the base material layer 20 may be a sheet-like material capable of fixing the water absorbing polymer P1, and may be liquid permeable or liquid impermeable.
- the base material layer 20 include resin films, foams, nets, and the like in addition to fibrous structures such as non-woven fabric, woven fabric, knitted fabric, and paper.
- the base layer 20 is preferably one containing a non-woven fabric or a resin film, that is, the base layer 20 is composed of only one of them.
- Composite sheets comprising either or both are preferred.
- non-woven fabric constituting the base material layer 20 those manufactured by various manufacturing methods can be used without particular limitation, and for example, air-through non-woven fabric, heat roll non-woven fabric, spun lace non-woven fabric, spun bond non-woven fabric, melt blown nonwoven fabric, spun bond-melt blown spun Bond (SMS) nonwoven fabric is mentioned.
- SMS non-woven fabrics may be hydrophilic non-woven fabrics made of fibers subjected to a hydrophilization treatment.
- SMS non-woven fabric is preferably used as the base material layer 20 because it is particularly effective for thinning the absorbent sheet 2 and improving flexibility.
- Examples of the material of the resin film constituting the substrate layer 20 include polyurethane resins, polyester resins such as polyethylene terephthalate (PET), polyolefin resins such as polyethylene (PE) and polypropylene (PP), polyamide resins, Polyvinyl alcohol and modified products and copolymers thereof are mentioned.
- the resin film may be provided with a plurality of holes penetrating in the thickness direction from the viewpoint of improvement of liquid permeability and the like.
- a polyolefin resin is particularly preferably used as the base layer 20 because it is excellent in flexibility and processability.
- the absorbent sheet 2 is sprayed with a water absorbing polymer P1 (water absorbing polymer pieces) on the adhesive coated surface.
- the application pattern of the adhesive is not particularly limited, and may be applied to the entire surface of the base layer 20, or may be partially applied, for example, the absorbent sheet 2 is used as an absorbent of the absorbent article.
- partial application that is, application of the adhesive and non-application of the adhesive on one surface of the base layer 20, from the viewpoint of minimizing the decrease in the absorption performance by the adhesive.
- an adhesive is applied.
- the application method of the adhesive is not particularly limited, and known application methods such as slot spray method, curtain spray method, spiral spray method, coater spray method, omega spray method, summit spray method and the like can be used.
- the coating amount of the adhesive is preferably 1 g / m 2 or more, more preferably 5 g / m 2 or more, and preferably 30 g / m 2 or less, more preferably 20 g / m 2 or less, in terms of solid content.
- the thickness and basis weight of the base material layer 20, the basis weight (adhesion amount per unit area) of the water absorbing polymer P1 and the like are not particularly limited, and appropriate values are selected according to the specific use of the absorber 1 and the like. Ru.
- the absorbent body 1 is used as, for example, an absorbent body of the absorbent article, it is also characterized by being thin despite the relatively high basis weight of the water absorbent polymer P1.
- the basis weight of the water-absorbing polymer P1 is preferably from the viewpoint of obtaining a thin and flexible absorbent body having a sufficient absorption capacity.
- the absorbing layer 21 is configured to include only the water absorbing polymer P1, but other components other than the water absorbing polymer, for example, fibers may be included without departing from the scope of the present invention. Good.
- the thickness (substantially thickness) of the base material layer 20 is preferably 0.01 mm or more, more preferably 0.03 mm or more, and preferably 0.8 mm or less, more preferably 0.2 mm or less .
- the basis weight of the base material layer 20 is preferably 5 g / m 2 or more, more preferably 8 g / m 2 or more, and preferably 40 g / m 2 or less, more preferably 25 g / m 2 or less is there.
- a circular plate weighing 2.5 g and having a radius of 12.5 mm is placed on the measurement table, and the position of the upper surface of the circular plate in that state is taken as the reference point A of measurement.
- the circular plate is removed, the measurement object is placed on the measurement table, the circular plate is placed again thereon, and the position of the upper surface of the circular plate in that state is set to position B.
- a laser displacement meter CCD laser displacement sensor LK-080, manufactured by Keyence Corporation
- seat of measurement object from the absorbent article is as follows. Cold spray (manufactured by Nichiban Co., Ltd., trade name) is sprayed from the front sheet side of the absorbent article. Thereafter, the components of the absorbent article other than the measurement object are carefully peeled off from the absorbent article.
- the fiber entangled layer 3 is a fiber assembly in which a plurality of fibers 3F are entangled without being fused to each other, as schematically shown in FIGS. 1 and 2.
- the fiber entangled layer 3 plays a role of compensating for the absorption performance (absorptive capacity, absorption speed, etc.) which tends to run short in the thin absorbent sheet 2.
- the fiber entangled layer according to the present invention is not wet-made. Accordingly, the fiber entangled layer 3 which is an embodiment of the fiber entangled layer according to the present invention does not include paper manufactured by a known wet papermaking method.
- the type of the fibers 3F constituting the fiber entangled layer 3 is not particularly limited, and it is possible to use, as the fibers 3F, fibers commonly used in paper, such as pulp fibers.
- the fiber entangled layer 3 When the fiber entangled layer 3 is wet-papered, such as paper, the smoothness of the surface of the fiber entangled layer 3 is too high, or there are too few voids (interfiber voids) in the fiber interlaced layer 3 Therefore, the contact between the fiber entangled layer 3 and the water absorbent polymer P1 of the absorbent layer 21 is reduced, and the effect of the present invention may not be exhibited. That is, as the fiber entangled layer 3, it is preferable to have a fiber aggregate having low surface smoothness and a large number of inter-fiber voids as compared to a wet-made sheet such as paper.
- the plurality of fibers 3F are entangled with each other but are not fused. That is, in the fiber entangled layer 3, there is no bonding point due to the fusion of the fibers 3F. Therefore, for example, a resin-bonded non-woven fabric in which the constituent fibers are heat-sealed to each other is not included in the fiber entangled layer 3.
- the bonding point of the fibers 3F means the bonding point of the constituent fibers which the fiber entangled layer 3 inherently has, and the fiber entangled layer 3 is subjected to a post-treatment involving melting of the constituent fibers 3F. The attachment points formed by are excluded.
- a fiber entangled layer 3 is manufactured by applying a hot air treatment by an air through method to a non-woven fabric to a web manufactured according to an ordinary method using a card machine as a typical one of bonding points of fibers 3F.
- the bonding point of the fibers 3F formed by the hot air treatment may be mentioned.
- a portion for example, a film-formed portion formed by performing embossing with heat as a post-treatment to the fiber entangled layer 3 (for example, a film-formed portion) is not the bonding point mentioned here.
- the fiber entangled layer 3 having no bonding point due to fusion between constituent fibers 3F is typically a fiber aggregate (sheet) other than a non-woven fabric, and specifically, it was wet-papered as described above On the premise that it is not a thing, it can be exemplified a web manufactured according to a conventional method using a curd method or air laid method, and a laminated fiber body in which pulp sheets are disintegrated and laminated. If the fiber entangled layer 3 does not have the bonding point, the softness of the fiber entangled layer 3 is improved as compared with the case where it is included, and the absorbent 1 having the fiber entangled layer 3 is absorbed.
- the fiber entangled layer 3 contains pulp fiber (cellulose fiber) from a viewpoint of the improvement of the absorption performance of a bodily fluid. That is, it is preferable that at least a part of the constituent fibers 3F of the fiber entangled layer 3 be pulp fibers.
- the pulp fiber since the pulp fiber has a short fiber length, the fiber entangled layer 3 mainly composed of it has poor shape stability in the wet state, and is easily divided when receiving an external force in the wet state.
- the fiber entangled layer 3 is disposed adjacent to the absorbent layer 21 (water absorbing polymer P1) in the absorbent sheet 2, even when the fiber entangled layer 3 is mainly composed of pulp fibers, Division is effectively suppressed.
- pulp fiber those conventionally used in this type of absorbent can be used without particular limitation, and examples thereof include wood pulp such as softwood pulp and hardwood pulp, non-wood pulp such as cotton pulp and hemp pulp, etc. Natural fibers; modified pulps such as cationized pulps and mercerized pulps; and the like. One of these may be used alone, or two or more may be mixed and used.
- the content of pulp fibers in the fiber entangled layer 3 is preferably 30% by mass or more, more preferably 50% by mass or more based on the total mass of the fiber entangled layer 3, and 100% by mass, that is, the fiber entangled layer 3 It may consist only of pulp fibers.
- the fiber entangled layer 3 may have a single layer structure, or may have a laminated structure of a plurality of layers having different compositions, for example, a plurality of layers having different types of constituent fibers 3F.
- the fiber entangled layer 3 has a single layer structure.
- the fiber entangled layer 3 may contain a water absorbing polymer from the viewpoint of improving the absorption performance of the body fluid.
- the fiber entangled layer 3 further contains a water absorbing polymer P2 in addition to the fibers 3F. If the fiber entangled layer 3 contains the water absorbing polymer P2, the entanglement of the fibers 3F is inhibited by the water absorbing polymer P2, and thus the aforementioned fiber entangled layer 3 is likely to be divided.
- the content of the water-absorbing polymer P2 in the fiber entangled layer 3 is preferably 20% by mass or more, more preferably 50% by mass or more, and preferably 80% by mass or less, based on the total mass of the fiber entangled layer 3 Preferably it is 70 mass% or less.
- water absorbent polymer P2 of the fiber entangled layer 3 one usable as the water absorbent polymer P1 of the absorbent layer 21 can be used.
- the type, shape, and average particle diameter of the water-absorbing polymer may be the same or different for the water-absorbing polymer P1 and the water-absorbing polymer P2.
- the fiber entangled layer 3 contains the water absorbing polymer P2
- the content of the water absorbing polymer P2 in the fiber entangled layer 3 (hereinafter also referred to as “water absorbing polymer content R3P” Is preferably higher than the content of fibers 3F in the fiber entangled layer 3 (hereinafter also referred to as “fiber content R3F").
- the water absorbing polymer content R3P is calculated by dividing the total weight of the water absorbing polymer P2 contained in the fiber entangled layer 3 by the weight of the fiber entangled layer 3, and the fiber content R3F is a constituent fiber of the fiber entangled layer 3 It is calculated by dividing the total weight of 3F by the weight of the fiber entangled layer 3.
- the ratio of the water-absorbing polymer content R3P to the fiber content R3F is preferably 1.1 or more, more preferably 1.3 as R3P / R3F, assuming that R3P> R3F as described above.
- the water-absorbent polymer content R3P in the fiber entangled layer 3 is preferably 55% by mass or more, more preferably 60% by mass or more, and preferably 80% by mass or less, more preferably 70% by mass or less.
- the fiber content R3F in the fiber entangled layer 3 is preferably 20% by mass or more, more preferably 30% by mass or more, and preferably 45% by mass or less, more preferably 40% by mass or less.
- the fiber entangled layer 3 contains the water absorbing polymer P2 as in the present embodiment, it is preferable that the water absorbent polymer P2 of the fiber entangled layer 3 intrudes into the absorbing layer 21.
- the bond between the water-absorbent polymer P1 (the absorbent layer 21) and the fiber entangled layer 3 is further strengthened, and the effect of suppressing the division of the fiber entangled layer 3 described above can be further improved.
- Whether or not the water absorbing polymer P2 is in the absorbing layer 21 is determined by the following method. That is, the cross section along the thickness direction of the absorber 1 as shown in FIG. 2 is observed with an electron microscope, and in the observation image, the number of the water absorbing polymer P2 entering the absorbing layer 21 is counted, and the number is the predetermined standard. When it is more than the value, it is assumed that the water absorbing polymer P2 is in the absorbing layer 21.
- the lower end of the water absorbent polymer P2 of the fiber entangled layer 3 (the end on the side adjacent to the absorbing layer 21) is the upper end of the water absorbent polymer P1 of the absorbent layer 21 (fiber entangled)
- the water absorbing polymer P2 penetrates into the absorbing layer 21 when at least 20 pieces are counted out below the layer 3 side end portion and the number is present at a ratio of 1 or more per 5 mm width. I assume.
- the fiber entangled layer 3 contains the water absorbing polymer P2 as in the present embodiment
- the absorbing layer 21 water absorbing polymer It is preferable that the content of the fibers 3F is higher on the side adjacent to P1) than on the side opposite to the adjacent side. More specifically, as shown in FIG. 2, the fiber entangled layer 3 containing the fibers 3F and the water absorbing polymer P2 is bisected in the thickness direction (vertical direction in FIG. 2) and relatively closer to the absorbing layer 21.
- the side is the absorbent layer side 30 and the opposite side is the non-absorbent layer side 31
- the magnitude relationship of "absorbent layer side 30> non-absorbent layer side 31" is established for the content of fibers 3F.
- the constituent fibers 3F be localized on the absorbent layer side 30 and that the water absorbent polymer P2 be localized on the nonabsorbent layer side 31.
- the absorption layer side 30 (adjacent surface side to the absorption layer 21) of the fiber entangled layer 3 is a “constituting fiber rich layer” that contains more fibers 3F than the non-absorbing layer side 31;
- the bond between the constituent fiber 3F on the layer side 30 and the absorbent layer 21 (water absorbing polymer P1) is further strengthened, and the effect of suppressing the division of the fiber entangled layer 3 described above can be further improved.
- the content rate of fibers 3F of each part is as follows, assuming that the magnitude relationship of “absorbent layer side 30> non-absorbent layer side 31” is satisfied. It is preferable to set as follows.
- the content of fibers 3F on the absorbent layer side 30 is preferably 30% by mass or more, more preferably 40% by mass or more, based on the total mass of the absorbent layer side 30. Preferably it is 100 mass% or less, More preferably, it is 90 mass% or less.
- the content of fibers 3F on the non-absorbing layer side 31 is preferably 10% by mass or more, more preferably 20% by mass or more, and preferably 80% by mass or less, based on the total mass of the non-absorbing layer side 31 Preferably it is 70 mass% or less.
- the fiber content is 1) the absorbent layer side 30 of the fiber entangled layer 3 (adjacent surface side with the absorbent layer 21), 2) the non-absorbent layer side of the fiber interlaced layer 3 31, 3) It is preferable to be higher in the order of the absorption layer 21. That is, the absorbent layer side 30 of the fiber entangled layer 3 has the highest fiber content, the absorbent layer 21 has the lowest fiber content, and the fiber content of the non-absorbent layer side 31 of the fiber entangled layer 3 is the two. It is preferable to be intermediate.
- “fiber” in “content of fiber” includes not only constituent fiber 3F of fiber entangled layer 3 but also all fibers contained in absorbent body 1.
- the constituent fiber 3F of the fiber entangled layer 3 that usually constitutes the main component of this "fiber”.
- the fiber content of the absorbent body 1 partially differs, it is possible to further improve the division suppressing effect of the fiber entangled layer 3.
- the fiber entangled layer 3 is usually disposed closer to the skin of the wearer than the absorbent sheet 2, so in the fiber entangled layer 3, Where the non-absorbent layer side 31 is relatively close from the wearer's skin and the absorbent layer side 30 is relatively far from the wearer's skin, the non-absorbent layer side 31 relatively closer to the wearer's skin is worn Because the fiber content is lower than that of the absorbent layer side 30 relatively distant from the skin of the person, the liquid once absorbed in the absorbent layer 21 (water absorbent polymer P1) returns to the wearer's skin again. Is effectively suppressed.
- the fiber content of each part of the absorbent body 1 it is premised that the magnitude relationship of "the absorbent layer side 30 of the fiber entangled layer 3> the non-absorbent layer side 31 of the fiber entangled layer 3> the absorbent layer 21" holds.
- the content rate of the fiber of each of the absorption layer side 30 and the non-absorption layer side 31 can be set to the said range.
- the content of fibers in the absorbent layer 21 is preferably 30% by mass or less, more preferably 10% by mass or less based on the total mass of the absorbent layer 21. Zero, that is, the absorbent layer 21 contains all fibers. It does not have to be.
- the basis weight of the fiber entangled layer 3 is not particularly limited, but it is necessary and sufficient from the viewpoint of improving the feeling of wearing and portability when the absorber 1 is applied to an absorbent article by making the absorber 1 thin and thin. It is preferable to reduce as much as possible while securing good absorption performance. From such a viewpoint, the basis weight of the fibers in the fiber entangled layer 3 is preferably 50 g / m 2 or more, more preferably 90 g / m 2 or more, and preferably 200 g / m 2 or less, more preferably 170 g / m 2 It is below.
- the basic weight in the fiber of the fiber entangled layer 3 mentioned here means the basic weight of the fiber of the whole laminated structure, when the fiber entangled layer 3 has a laminated structure formed by laminating a plurality of layers. Do.
- Absorbent body 1 can be used alone to absorb liquid.
- it can be used as a drip sheet, a sheet placed under food, a sheet for pets, and the like.
- it is used also as an absorber in various hygiene products, such as a medical pad and a breast milk sheet.
- it is used as an absorber in absorbent articles, such as a sanitary napkin and a disposable diaper.
- the present invention includes an absorbent article comprising the above-described absorbent of the present invention.
- Such an absorbent article of the present invention typically comprises a top sheet located closer to the skin of the wearer and a back sheet located farther from the skin of the wearer, and the absorbent of the present invention, specifically For example, the above-described absorber 1 is disposed between the two sheets.
- the absorbent body 1 may be disposed so that the fiber entangled layer 3 is closer to the wearer's skin (the above-mentioned surface sheet) than the absorbent sheet 2; conversely, the absorbent sheet 2 is a fiber entangled layer It may be arranged closer to the wearer's skin (the above-mentioned surface sheet) than 3 but the arrangement of the former, that is, the fiber entangled layer 3 is a skin from the viewpoint of improving the wearing feeling and cushioning feeling of the absorbent article. It is preferable that the side (front sheet side) and the absorbent sheet 2 be the non-skin side (back sheet side).
- the fiber entangled layer 3 When the fiber entangled layer 3 is on the skin side and the absorbent body 1 is disposed in the absorbent article, the fiber entangled layer 3 is an external force caused by the movement of the wearer as compared with the case where the fiber entangled layer 3 is on the non-skin side. There is a concern that it is likely to be divided as a result of this, but such concerns are wiped out by the characteristic configuration of the absorber 1 described above. Since the absorbent article of the present invention comprises the absorbent body of the present invention such as the absorbent body 1, it is thin but excellent in absorption performance and shape stability, and the problem of separation of the absorbent during wear is less likely to occur. .
- FIG. 3 and 4 show another embodiment of the absorber of the present invention.
- aborber 1 a component different from the above-mentioned embodiment (absorber 1) is mainly explained, the same component attaches the same numerals, and omits explanation.
- the description about the said embodiment is suitably applied to the component part which is not demonstrated in particular.
- Each of the absorbents 1A and 1B shown in FIG. 3 includes the covering sheet 4 that integrally covers the absorbent sheet 2 and the fiber entangled layer 3.
- the adhesion between the absorbent sheet 2 and the fiber entangled layer 3 is enhanced by the presence of the covering sheet 4 that covers the outer surface of the absorbent sheet 2 and the fiber entangled layer 3 as described above.
- a water-permeable sheet material can be used as the covering sheet 4 and, for example, paper, non-woven fabric and the like can be used.
- the basis weight of the covering sheet 4 is preferably 8 g / m 2 or more, more preferably 12 g / m 2 or more, and preferably 30 g / m 2 or less, more preferably 20 g / m 2 or less.
- the covering sheet 4 in the absorbent 1A is a single continuous sheet having a size capable of covering the entire outer surface of the laminated structure of the absorbing sheet 2 and the fiber entangled layer 3.
- a surface of the fiber entangled layer 3 (for example, a surface facing the skin when the absorbent 1A is applied to the absorbent article) and a surface of the absorbent sheet 2 (for example, when the absorbent 1A is applied to the absorbent article) Non-skin facing surface) covers the whole area of each.
- the absorbent sheet 2 and the fiber entangled layer 3 and the covering sheet 4 may be bonded by an adhesive.
- the covering sheet 4 in the absorbent 1A may not be a single sheet as shown in the figure, and for example, a skin covering sheet covering the surface of the fiber entangled layer 3 and another covering sheet
- the body may be configured to include two sheets of one non-skin side covering sheet that covers the surface of the absorbent sheet 2.
- the "skin-facing surface” is a surface of an absorbent article or a component thereof (for example, an absorbent body) that is directed toward the skin of the wearer when wearing the absorbent article, ie, the wearer relatively
- the “non-skin facing surface” is the surface of the absorbent article or component thereof that is directed to the side (dressing side) opposite to the skin side when the absorbent article is worn, ie, relative It is the side far from the wearer's skin.
- "at the time of wearing” here means the state by which the usual appropriate wearing position was maintained.
- the covering sheet 4 in the absorbent body 1 B is a portion other than the base layer 20 in the laminated structure of the absorbent sheet 2 and the fiber entangled layer 3 (absorbent layer 21 and fiber entangled layer 3)
- the entire surface of the substrate is covered, and the substrate layer 20 is not covered.
- the covering sheet 4 and the base material layer 20 are bonded with an adhesive or the like at their peripheral portions, whereby a space defined by the covering sheet 4 and the base material layer 20 is formed.
- the absorbent layer 21 and the fiber entangled layer 3 are accommodated in the space.
- the base material layer 20 is configured to include a plurality of (7 in FIG. 4) strip-like base material layers 20S long in one direction.
- the plurality of strip-shaped base layers 20S are arranged so that the longitudinal directions thereof coincide with each other in the width direction orthogonal to the longitudinal direction, and the plurality of strip-shaped base layers 20S adjacent in the width direction As shown in FIG. 4, the gaps are divided by the slits 22 penetrating the base material layer 20 in the thickness direction.
- the plurality of strip-shaped base layers 20S can move independently, and for example, as shown in FIG. 4, in the plurality of strip-shaped base layers 20S, in the thickness direction of the absorber 1C. The positions may be different from one another.
- the absorbent layer 21 water absorbent polymer P1
- the adhesion between the fiber entangled layer 3 and the fiber entangled layer 3 may be reduced, and the effect of suppressing the division of the fiber entangled layer 3 described above may be reduced.
- the base material layer 20 is configured to include the plurality of (7 in FIG. 4) band-like base material layers 20S that can move independently, fiber entanglement is caused.
- the plurality of strip-like base layers 20 S constituting the base material layer 20 can be closely attached following the irregularities of the fiber entangled layer 3 As a result, the effect of suppressing the division of the predetermined fiber entangled layer 3 is stably exerted.
- the extending direction of the cuts 22 of the base material layer 20 is not particularly limited, but the absorber 1C is applied from the viewpoint of more reliably achieving the function and effect by the cuts 22 (strip-like base material layer 20S). It is preferable to match the longitudinal direction of the absorbent article to be made.
- the longitudinal direction of the absorbent article is the longitudinal direction of the wearer of the absorbent article, that is, the direction extending from the ventral side of the wearer to the dorsal side via the crotch.
- a plurality of the band-like base layers 20S be integrated without part of them being divided, for example, not shown.
- the longitudinal direction both ends of each of the plurality of strip-shaped base layers 20S are connected without being divided.
- a plurality of cuts 22 extending in the longitudinal direction are intermittently arranged in the width direction of the substrate layer 20 in a portion of the substrate layer 20 which is sandwiched between the longitudinal direction end portions thereof As a result, the portion sandwiched between the longitudinal ends is divided into the plurality of strip-shaped base layers 20S.
- the plurality of strip-shaped base layers 20S are integrated at the longitudinal ends of the base layer 20. Because of this, the absorber 1C is a single object as a whole.
- the absorbent layer 21 is formed only on one side of the base layer 20, but may be formed on both sides of the base layer 20, that is, on both sides of the base layer 20 P1 may be fixed.
- the absorbent 1C shown in FIG. 4 when the absorbing layer 21 is formed on both sides of the base layer 20, the water absorbing polymer P1 and the fiber entangled layer 3 are obtained even if the strip base layer 20S is twisted and reversed. The effect is maintained that the contact with is maintained.
- the absorbent article to which the absorbent of the present invention is applied and the absorbent article of the present invention can be widely used for the absorption of body fluid (urine, soft stool, menstrual blood, sweat, etc.) discharged from the human body. It includes, for example, unfolded disposable diapers, pants-type disposable diapers, sanitary napkins, sanitary shorts and the like. Further, the following appendices will be disclosed regarding the embodiment of the present invention described above.
- ⁇ 5> The absorbent according to any one of ⁇ 1> to ⁇ 4>, wherein the fiber entangled layer contains a water absorbing polymer.
- the content of the water-absorbing polymer in the fiber entangled layer is preferably 20% by mass or more, more preferably 50% by mass or more, and preferably 80% by mass, based on the total mass of the fiber entangled layer
- the absorber as described in said ⁇ 5> which is 70 mass% or less still more preferably.
- ⁇ 7> The absorbent body according to ⁇ 5> or ⁇ 6>, wherein the content of the water absorbing polymer in the fiber entangled layer is higher than the content of fibers in the fiber entangled layer.
- the ratio of the content ratio of the water-absorbing polymer in the fiber entangled layer to the content ratio of fibers in the fiber entangled layer is preferably> 1.1 or more as the former / latter on the premise of the former> the latter
- the absorbent according to the above ⁇ 7> which is preferably 1.3 or more, and preferably 3.5 or less, more preferably 2.5 or less.
- the content of the water-absorbent polymer in the fiber entangled layer is preferably 55% by mass or more, more preferably 60% by mass or more, and preferably 80% by mass or less, more preferably 70% by mass or less
- the fiber content in the fiber entangled layer is preferably 20% by mass or more, more preferably 30% by mass or more, and preferably 45% by mass or less, more preferably 40% by mass or less.
- ⁇ 11> The absorbent according to any one of ⁇ 5> to ⁇ 10>, wherein the water absorbing polymer of the fiber entangled layer penetrates the absorption layer.
- ⁇ 12> In the fiber entangled layer, the fiber content ratio of the side adjacent to the absorption layer (the absorption layer side) is higher than the side opposite to the adjacent surface (the non-absorption layer side).
- the fibers are unevenly distributed on the side adjacent to the absorption layer (the absorption layer side), and the water-absorbent polymer is unevenly distributed on the opposite side (non-absorbent layer side) to the absorption layer
- the fiber content of the fiber entangled layer on the side adjacent to the absorption layer (side of the absorption layer) is preferably 30% by mass or more, more preferably 30% by mass, based on the total mass on the side adjacent to the absorption layer.
- the fiber content of the fiber entangled layer on the side opposite to the absorbent layer side (non-absorbent layer side) is preferably 10% by mass or more, more preferably 20% by mass with respect to the total mass on the opposite side.
- the absorbent according to any one of the above ⁇ 1> to ⁇ 14> which has a mass% or more, preferably 80 mass% or less, more preferably 70 mass% or less.
- the basis weight of the fibers in the fiber entangled layer is preferably 50 g / m 2 or more, more preferably 90 g / m 2 or more, and preferably 200 g / m 2 or less, more preferably 170 g / m 2 or less.
- the fiber entangled layer does not have a bonding point due to fusion between fibers, and is a web of a web manufactured by a card method or an air laid method, or a laminated body of fibrillated products of pulp sheets.
- the absorber according to any one of 1> to ⁇ 16>.
- the fixation ratio of the water-absorbent polymer of the absorbent layer to the base material layer is preferably 10% or more, more preferably 30% or more, and preferably 90% or less, more preferably 80% or less.
- the adhesion ratio of the water-absorbent polymer of the absorption layer is preferably 0.5 or more, more preferably 0.7 or more, and preferably 0.95 or less, more preferably 0.85 or less.
- the content of fibers in the absorption layer is preferably 30% by mass or less, more preferably 10% by mass or less, based on the total mass of the absorption layer, more preferably zero, that is, fibers in the absorption layer.
- the absorbent according to any one of the above ⁇ 1> to ⁇ 19> which does not contain ⁇ 21> The absorbent according to any one of ⁇ 1> to ⁇ 20>, wherein the absorption layer is formed on both sides of the base material layer.
- the ⁇ 22> fiber content ratio of the ⁇ 1> to ⁇ 21 higher in the order of the surface side of the fiber entangled layer adjacent to the absorbent layer, the side opposite to the adjacent surface of the fiber interlaced layer, and the absorbent layer.
- the base material layer is configured to include a plurality of band-like base layers long in one direction, and the plurality of band-like base materials have a width orthogonal to the longitudinal direction such that their longitudinal directions coincide.
- ⁇ 25> The absorber according to ⁇ 24>, in which a part of the plurality of strip-shaped base layers are integrated without being divided.
- An absorbent article comprising the absorbent according to any one of ⁇ 1> to ⁇ 25>.
- ⁇ 27> The absorbent article according to ⁇ 26>, wherein the absorbent body is disposed such that the fiber entangled layer is closer to the skin of the wearer than the absorbent sheet.
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Abstract
Description
また本発明は、前記の本発明の吸収体を具備する吸収性物品である。
乾燥した濾紙の中央部に生理食塩水1gを付与して該中央部を湿らし、水平な台の上に載置された該濾紙の該中央部に、測定対象の吸水性ポリマー0.1gを均一に散布する。例えば、アドバンテック東洋製濾紙No.4A(φ150)の中央部(φ100)を生理食塩水で湿らし、該中央部に吸水性ポリマーを均一散布することができる。吸水性ポリマーを散布してから1分経過後、濾紙を垂直に傾けた状態で台の上方5mmの位置で支持し、該支持を解除して該濾紙を落下させる。この濾紙の落下操作を100回繰り返し、その間に濾紙から脱落した吸水性ポリマーの総重量aと、濾紙上に残留した吸水性ポリマーの総重量bとから、次式により吸水性ポリマーの粘着率を算出する。粘着率=b/(a+b)
(手順2)測定サンプルの全体を生理食塩水に浸漬し、浸漬開始から30分後に該測定サンプルを該生理食塩水から取り出す。
(手順3)容量300mlのビーカーに直径35mm、軸方向長さ12mmの円柱形撹拌子及び生理食塩水300mlを入れ、マグネティックスターラーを用いて回転数600±5rpmで該攪拌子を回転させて該生理食塩水を攪拌する。この攪拌中の生理食塩水に前記手順2を経た測定サンプルを投入し、その投入から30秒後に該測定サンプルを該生理食塩水から取り出す。
(手順4)前記手順3を経た湿潤状態の測定サンプルを、槽内の温度が105℃に設定された恒温槽の該槽内に12時間静置した後、その乾燥状態の測定サンプルの重量(攪拌処理後サンプル重量)を測定する。
(手順5)前記初期サンプル重量及び前記攪拌処理後サンプル重量それぞれから吸水性ポリマー以外の部材の総重量を減算し、初期吸水性ポリマー重量(W0)及び攪拌処理後吸水性ポリマー重量(W1)をそれぞれ算出する。そして次式により、測定サンプル(吸収性シート)の吸水性ポリマー固定率を算出する。
吸水性ポリマーの固定率(%)=(W1/W0)×100
また、前記手順1において、測定サンプルとして、5cm四方の吸収性シートを用意できない場合(例えば、吸収性シートのサイズが小さいために、測定サンプルのサイズが5cm四方に満たない場合)は、評価対象のシートからサイズが5cm四方に満たない小サイズの測定サンプルを複数採取し、それら複数の測定サンプルの片面の面積の合計が25cm2となるようにする。そして、複数の測定サンプルそれぞれについて、前記手順1~5に従って吸水性ポリマー固定率を測定し、そうして得られた複数の吸水性ポリマー固定率の平均値を、当該吸収性シートの吸水性ポリマー固定率とする。
・マグネティックスターラー:HI-304N(HANNA社製、反転スターラー)
・攪拌子:スターヘッド NALGENE(6600-0035)〔35φ×12mm〕
・ビーカー:300ml〔78φ×103mm〕
前記シリコーン系接着剤の素材(ベースポリマー)としては、例えば、ポリジメチルシロキサンポリマー重合体を例示できる。
前記ゴム系接着剤の素材(ベースポリマー)としては、例えば、天然ゴム、ポリイソプレン、スチレン-ブタジエン共重合体(SBR)、スチレン-イソプレン-スチレンブロック共重合体(SIS)、スチレン-ブタジエン-スチレンブロック共重合体(SBS)、スチレン-エチレン-ブタジエン-スチレンブロック共重合体(SEBS)、スチレン-エチレン-プロピレン-スチレンブロック共重合体(SEPS)を例示できる。
同様の観点から、基材層20の坪量は、好ましくは5g/m2以上、さらに好ましくは8g/m2以上、そして、好ましくは40g/m2以下、さらに好ましくは25g/m2以下である。
測定台に重さ2.5g、半径12.5mmの円形プレートを載置し、その状態での円形プレートの上面の位置を測定の基準点Aとする。次に円形プレートを取り除き、測定台に測定対象を置き、その上に円形プレートを再び載置し、その状態での円形プレートの上面の位置を位置Bとする。測定機器にはレーザ変位計(株式会社キーエンス製、CCDレーザ変位センサーLK-080)を用いる。前記基準点Aと前記位置Bとの差を、測定対象の厚み、即ち、測定対象の0.5cN/cm2(=0.05kPa)圧力下での厚みとする。
繊維交絡層3における吸水性ポリマー含有率R3Pは、好ましくは55質量%以上、さらに好ましくは60質量%以上、そして、好ましくは80質量%以下、さらに好ましくは70質量%以下である。
繊維交絡層3における繊維含有率R3Fは、好ましくは20質量%以上、さらに好ましくは30質量%以上、そして、好ましくは45質量%以下、さらに好ましくは40質量%以下である。
吸収層側30(吸収層21との隣接面側)における繊維3Fの含有率は、該吸収層側30の全質量に対して、好ましくは30質量%以上、さらに好ましくは40質量%以上、そして、好ましくは100質量%以下、さらに好ましくは90質量%以下である。
非吸収層側31における繊維3Fの含有率は、該非吸収層側31の全質量に対して、好ましくは10質量%以上、さらに好ましくは20質量%以上、そして、好ましくは80質量%以下、さらに好ましくは70質量%以下である。
例えば前記実施形態では、吸収層21は基材層20の片面のみに形成されていたが、基材層20の両面に形成されていてもよく、即ち、基材層20の両面に吸水性ポリマーP1が固定されていてもよい。特に、図4に示す吸収体1Cにおいて、基材層20の両面に吸収層21が形成されていると、帯状基材層20Sがヨレて反転しても、吸水性ポリマーP1と繊維交絡層3との接触が維持されるという効果が奏される。
<2> 前記吸収層の吸水性ポリマーが、ホットメルト接着剤によって前記基材層の一面に固定されている前記<1>に記載の吸収体。
<3> 前記基材層が不織布又は樹脂フィルムを含む前記<1>又は<2>に記載の吸収体。
<4> 前記繊維交絡層がパルプ繊維を含む前記<1>~<3>のいずれか1項に記載の吸収体。
<6> 前記繊維交絡層における前記吸水性ポリマーの含有率が、該繊維交絡層の全質量に対して、好ましくは20質量%以上、さらに好ましくは50質量%以上、そして、好ましくは80質量%以下、さらに好ましくは70質量%以下である前記<5>に記載の吸収体。
<7> 前記繊維交絡層における前記吸水性ポリマーの含有率の方が、該繊維交絡層における繊維の含有率よりも高い前記<5>又は<6>に記載の吸収体。
<8> 前記繊維交絡層における前記吸水性ポリマーの含有率と該繊維交絡層における繊維の含有率との比が、前者>後者を前提として、前者/後者として、好ましくは1.1以上、さらに好ましくは1.3以上、そして、好ましくは3.5以下、さらに好ましくは2.5以下である前記<7>に記載の吸収体。
<9> 前記繊維交絡層における前記吸水性ポリマーの含有率が、好ましくは55質量%以上、さらに好ましくは60質量%以上、そして、好ましくは80質量%以下、さらに好ましくは70質量%以下である前記<7>又は<8>に記載の吸収体。
<10> 前記繊維交絡層における繊維の含有率が、好ましくは20質量%以上、さらに好ましくは30質量%以上、そして、好ましくは45質量%以下、さらに好ましくは40質量%以下である前記<7>~<9>のいずれか1項に記載の吸収体。
<11> 前記繊維交絡層の前記吸水性ポリマーが、前記吸収層に入り込んでいる前記<5>~<10>のいずれか1項に記載の吸収体。
<12> 前記繊維交絡層において、前記吸収層との隣接面側(前記吸収層側)の方が、該隣接面とは反対側(非吸収層側)よりも繊維の含有率が高い前記<5>~<11>のいずれか1項に記載の吸収体。
<13> 前記繊維交絡層において、繊維が前記吸収層との隣接面側(前記吸収層側)に偏在し、前記吸水性ポリマーが該吸収層側とは反対側(非吸収層側)に偏在している前記<5>~<12>のいずれか1項に記載の吸収体。
<15> 前記繊維交絡層の前記吸収層側とは反対側(非吸収層側)における繊維の含有率が、該反対側の全質量に対して、好ましくは10質量%以上、さらに好ましくは20質量%以上、そして、好ましくは80質量%以下、さらに好ましくは70質量%以下である前記<1>~<14>のいずれか1項に記載の吸収体。
<16> 前記繊維交絡層における繊維の坪量が、好ましくは50g/m2以上、さらに好ましくは90g/m2以上、そして、好ましくは200g/m2以下、さらに好ましくは170g/m2以下である前記<1>~<15>のいずれか1項に記載の吸収体。
<17> 前記繊維交絡層は、繊維どうしの融着による結合点を有しておらず、カード法若しくはエアレイド法によって製造されたウエブ、又はパルプシートの解繊物の積繊体である前記<1>~<16>のいずれか1項に記載の吸収体。
<19> 前記吸収層の前記吸水性ポリマーの粘着率が、好ましくは0.5以上、さらに好ましくは0.7以上、そして、好ましくは0.95以下、さらに好ましくは0.85以下である前記<1>~<18>のいずれか1項に記載の吸収体。
<20> 前記吸収層における繊維の含有率が、該吸収層の全質量に対して、好ましくは30質量%以下、さらに好ましくは10質量%以下であり、より好ましくはゼロ即ち該吸収層に繊維が全く含まれていない前記<1>~<19>のいずれか1項に記載の吸収体。
<21> 前記吸収層が前記基材層の両面に形成されている前記<1>~<20>のいずれか1項に記載の吸収体。
<22> 繊維の含有率が、前記繊維交絡層の前記吸収層との隣接面側、該繊維交絡層の該隣接面とは反対側、前記吸収層の順で高い前記<1>~<21>のいずれか1項に記載の吸収体。
<24> 前記基材層は、一方向に長い複数の帯状基材層を含んで構成され、該複数の帯状基材層は、それらの長手方向を一致させて、該長手方向と直交する幅方向に隣り合うように配されている前記<1>~<23>のいずれか1項に記載の吸収体。
<25> 前記複数の帯状基材層どうしは、それらの一部が分断されずに一体となっている前記<24>に記載の吸収体。
<26> 前記<1>~<25>のいずれか1項に記載の吸収体を具備する吸収性物品。
<27> 前記吸収体は、前記繊維交絡層が前記吸収性シートよりも着用者の肌から近くなるように配されている前記<26>に記載の吸収性物品。
Claims (27)
- 基材層、及び該基材層の一面に固定された吸水性ポリマーを含む吸収層を有する吸収性シートと、繊維交絡層とを備え、該吸収層の吸水性ポリマーと該繊維交絡層とが隣接している吸収体。
- 前記吸収層の吸水性ポリマーが、ホットメルト接着剤によって前記基材層の一面に固定されている請求項1に記載の吸収体。
- 前記基材層が不織布又は樹脂フィルムを含む請求項1又は2に記載の吸収体。
- 前記繊維交絡層がパルプ繊維を含む請求項1~3のいずれか1項に記載の吸収体。
- 前記繊維交絡層が吸水性ポリマーを含む請求項1~4のいずれか1項に記載の吸収体。
- 前記繊維交絡層における前記吸水性ポリマーの含有率が、該繊維交絡層の全質量に対して、20質量%以上80質量%以下である請求項5に記載の吸収体。
- 前記繊維交絡層における前記吸水性ポリマーの含有率の方が、該繊維交絡層における繊維の含有率よりも高い請求項5又は6に記載の吸収体。
- 前記繊維交絡層における前記吸水性ポリマーの含有率と該繊維交絡層における繊維の含有率との比が、前者>後者を前提として、前者/後者として、1.1以上3.5以下である請求項7に記載の吸収体。
- 前記繊維交絡層における前記吸水性ポリマーの含有率が、55質量%以上80質量%以下である請求項7又は8に記載の吸収体。
- 前記繊維交絡層における繊維の含有率が、20質量%以上45質量%以下である請求項7~9のいずれか1項に記載の吸収体。
- 前記繊維交絡層の前記吸水性ポリマーが、前記吸収層に入り込んでいる請求項5~10のいずれか1項に記載の吸収体。
- 前記繊維交絡層において、前記吸収層との隣接面側の方が、該隣接面とは反対側よりも繊維の含有率が高い請求項5~11のいずれか1項に記載の吸収体。
- 前記繊維交絡層において、繊維が前記吸収層との隣接面側に偏在し、前記吸水性ポリマーが該吸収層側とは反対側に偏在している請求項5~12のいずれか1項に記載の吸収体。
- 前記繊維交絡層の前記吸収層との隣接面側における繊維の含有率が、該隣接面側の全質量に対して、30質量%以上100質量%以下である請求項1~13のいずれか1項に記載の吸収体。
- 前記繊維交絡層の前記吸収層側とは反対側における繊維の含有率が、該反対側の全質量に対して、10質量%以上80質量%以下である請求項1~14のいずれか1項に記載の吸収体。
- 前記繊維交絡層における繊維の坪量が、50g/m2以上200g/m2以下である請求項1~15のいずれか1項に記載の吸収体。
- 前記繊維交絡層は、繊維どうしの融着による結合点を有しておらず、カード法若しくはエアレイド法によって製造されたウエブ、又はパルプシートの解繊物の積繊体である請求項1~16のいずれか1項に記載の吸収体。
- 前記吸収層の前記吸水性ポリマーの前記基材層に対する固定率が、10%以上90%以下である請求項1~17のいずれか1項に記載の吸収体。
- 前記吸収層の前記吸水性ポリマーの粘着率が、0.5以上0.95以下である請求項1~18のいずれか1項に記載の吸収体。
- 前記吸収層における繊維の含有率が、該吸収層の全質量に対して、30質量%以下である請求項1~19のいずれか1項に記載の吸収体。
- 前記吸収層が前記基材層の両面に形成されている請求項1~20のいずれか1項に記載の吸収体。
- 繊維の含有率が、前記繊維交絡層の前記吸収層との隣接面側、該繊維交絡層の該隣接面とは反対側、前記吸収層の順で高い請求項1~21のいずれか1項に記載の吸収体。
- さらに、前記吸収性シート及び前記繊維交絡層を一体的に被覆する被覆シートを備える請求項1~22のいずれか1項に記載の吸収体。
- 前記基材層は、一方向に長い複数の帯状基材層を含んで構成され、該複数の帯状基材層は、それらの長手方向を一致させて、該長手方向と直交する幅方向に隣り合うように配されている請求項1~23のいずれか1項に記載の吸収体。
- 前記複数の帯状基材層どうしは、それらの一部が分断されずに一体となっている請求項24に記載の吸収体。
- 前記請求項1~25のいずれか1項に記載の吸収体を具備する吸収性物品。
- 前記吸収体は、前記繊維交絡層が前記吸収性シートよりも着用者の肌から近くなるように配されている請求項26に記載の吸収性物品。
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GB2008108.9A GB2582103B (en) | 2017-12-29 | 2017-12-29 | Absorber and absorbent article |
US16/954,685 US20200315869A1 (en) | 2017-12-29 | 2017-12-29 | Absorber and absorbent article |
CN201780097755.XA CN111565690B (zh) | 2017-12-29 | 2017-12-29 | 吸收体和吸收性物品 |
DE112017008310.9T DE112017008310T5 (de) | 2017-12-29 | 2017-12-29 | Absorbiereinrichtung und absorptionsartikel |
RU2020123918A RU2748668C1 (ru) | 2017-12-29 | 2017-12-29 | Поглотитель и впитывающее изделие |
PCT/JP2017/047402 WO2019130591A1 (ja) | 2017-12-29 | 2017-12-29 | 吸収体及び吸収性物品 |
JP2019562711A JP7022152B2 (ja) | 2017-12-29 | 2017-12-29 | 吸収体及び吸収性物品 |
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WO2022224955A1 (ja) * | 2021-04-19 | 2022-10-27 | 花王株式会社 | 吸収性シート及び吸収性物品 |
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CN114948450A (zh) * | 2022-05-24 | 2022-08-30 | 山东爸爸的选择健康科技有限公司 | 一种扩散快、防堆积的吸收芯体 |
CN116262089A (zh) * | 2022-10-20 | 2023-06-16 | 杭州诺邦无纺股份有限公司 | 一种高透气性可冲散防漏层的制备方法及在吸收性卫生用品中的应用 |
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CN111565690A (zh) | 2020-08-21 |
GB2582103A (en) | 2020-09-09 |
GB2582103B (en) | 2022-05-11 |
RU2748668C1 (ru) | 2021-05-28 |
US20200315869A1 (en) | 2020-10-08 |
CN111565690B (zh) | 2022-04-12 |
JP7022152B2 (ja) | 2022-02-17 |
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