WO2018180316A1

WO2018180316A1 - Emulsified cosmetic

Info

Publication number: WO2018180316A1
Application number: PCT/JP2018/008848
Authority: WO
Inventors: 真樹松尾
Original assignee: 株式会社マンダム
Priority date: 2017-03-28
Filing date: 2018-03-07
Publication date: 2018-10-04
Also published as: JPWO2018180316A1; JP6687809B2; CN109414375A; KR20190008302A

Abstract

An emulsified cosmetic containing components A-E, wherein the content of component A is 0.1-1.0 mass%, the content of component B is 0.4 mass% or less, the content of component C is 0.3 mass% or less, the content of component D is 4.0 mass% or less, the mass ratio (component B/component A) of component B to component A is 0.10 or higher, the mass ratio (component C/component A) of component C to component A is 0.02 or higher, and the mass ratio (component D/component A) of component D to component A is 0.4-7.0, inclusive. Component A: (acrylate/beheneth-25 methacrylate) copolymer. Component B: carboxyvinyl polymer and/or alkyl-modified carboxyvinyl polymer. Component C: xanthan gum. Component D: phospholipid. Component E: water.

Description

Emulsified cosmetics

The present invention relates to an emulsified cosmetic.

Conventionally, emulsified cosmetics are known as skin care cosmetics for the purpose of moisturizing skin, and for example, emulsified cosmetics having a viscosity comparable to that of lotion are known (Patent Document 1).

JP 2008-231056 A

Since skin care cosmetics are in direct contact with the skin, tactile sensation during use is also an important characteristic. Conventionally, low-viscosity emulsified cosmetics that are somewhat thicker than the above-mentioned lotions are generally known, but emulsified cosmetics having new properties and feel different from these are new. It can be said that it has value.

The present inventor has studied to impart elasticity to the cosmetic in order to impart a new tactile sensation to the cosmetic. As a method for imparting elasticity to cosmetics, there is a method of crosslinking with a hydrophobic group bond using an alkyl-modified acrylic polymer. However, it has been found that when an appropriate elasticity is imparted only by the polymer, the stability of the emulsified cosmetic is impaired and separation or the like occurs. In addition, although the stability can be improved by blending a large amount of the above-mentioned polymer, in that case, the elasticity becomes too high, causing twisting (coating unevenness) at the time of application, and poor skin familiarity at the time of application. I also found out.

An object of the present invention is to provide an emulsified cosmetic that has moderate elasticity and has a new property and feel different from those of conventional cosmetics. Moreover, it is to provide an emulsified cosmetic excellent in stability and usability.

The present invention contains the following component A, component B, component C, component D, and component E, the content of component A is 0.1 to 1.0% by mass, and the content of component B is 0 .4 mass% or less, the content of component C is 0.3 mass% or less, the content of component D is 4.0 mass% or less, and the mass ratio of component B to component A (component B / Component A) is 0.10 or more, the mass ratio of component C to component A (component C / component A) is 0.02 or more, and the mass ratio of component D to component A (component D / component A) is It is related with emulsified cosmetics which are 0.4 or more and 7.0 or less.
Component A: (Acrylates / Beheneth-25 methacrylate) copolymer Component B: Carboxyvinyl polymer and / or alkyl-modified carboxyvinyl polymer Component C: Xanthan gum Component D: Phospholipid Component E: Water

According to the present invention, it is possible to provide an emulsified cosmetic that has moderate elasticity and has a new property and feel different from conventional cosmetics. Furthermore, according to the present invention, it is possible to provide an emulsified cosmetic excellent in stability and usability.

The emulsified cosmetic of the present invention contains at least an (acrylates / Beheneth-25 methacrylate) copolymer; a carboxyvinyl polymer and / or an alkyl-modified carboxyvinyl polymer; a xanthan gum; a phospholipid; and water. In the present specification, the “(acrylates / behenes-25 methacrylate) copolymer” is referred to as “component A”; the “carboxyvinyl polymer and / or alkyl-modified carboxyvinyl polymer” as “component B”; and the “xanthan gum” as described above. “Component C”; the “phospholipid” may be referred to as “component D”; and the “water” may be referred to as “component E”.

The mechanism by which the emulsified cosmetic of the present invention exhibits the above-mentioned excellent effects is unknown, but is considered as follows. In a system containing component A, elasticity is considered to be imparted by the interaction of the alkyl chain. However, if only a small amount of component A is blended, the stability of the system tends to decrease. Conversely, when component A is blended to such an extent that sufficient stability can be obtained, the elasticity becomes too high and the desired tactile sensation is obtained. Not only will it disappear, it will cause kinking during application, and skin familiarity may worsen. Here, it is thought that the gel network is formed by using the component B and the component C together, and the interaction of the alkyl chain is physically weakened, and further, the component D interacts with the alkyl chain. However, it is presumed to further weaken the interaction of the alkyl chain. By reducing the elasticity to some extent by this, the system is adjusted to an appropriate elasticity, and the emulsified cosmetic is considered to have a desirable tactile sensation. Further, by using a plurality of components B to D as components for reducing elasticity, the amount of each of components B to D can be suppressed, so that adverse effects due to these components can be suppressed.

Component A is “(Acrylates / Beheneth-25 Methacrylate) Copolymer”, ie, one or more monomers selected from among esters of methacrylic acid and behenes-25 and acrylic acid, methacrylic acid or simple esters thereof. INCI name (International Cosmetic Ingredient Dictionary and Handbook) “ACRYLATES / BEHENETH-25 METHACRYLATE COPOLYMER (Acrolates / Beheneth-25 Methacrylate Compound)”. Component A functions as a component that increases the elasticity of the emulsified cosmetic. Component A also functions as a component that increases the viscosity of the emulsified cosmetic.

Examples of commercially available components A include, for example, “Aculin 28” manufactured by Dow Chemical Co., Ltd.

Component A is usually used after neutralization with a basic substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine, inorganic bases such as ammonia, sodium hydroxide, and potassium hydroxide, and basic amino acids such as arginine. Moreover, the addition amount of the basic substance is an amount sufficient to neutralize component A, and may be appropriately blended according to the amount of component A used.

The content of component A in 100% by mass of the emulsified cosmetic of the present invention is 0.1% by mass or more, preferably 0.2% by mass from the viewpoint of enhancing the elasticity of the emulsified cosmetic and imparting a characteristic tactile sensation. % Or more, more preferably 0.3% by mass or more, and 1.0% by mass or less from the viewpoint of preventing the elasticity from being excessively high and the accompanying deterioration in skin conformance and coating distortion. It is 9 mass% or less, More preferably, it is 0.8 mass% or less.

Component B is “carboxyvinyl polymer and / or alkyl-modified carboxyvinyl polymer”. By blending component B, an excessive increase in elasticity due to component A can be mitigated. In addition, when it is going to reduce the elasticity of the component A enough only with the component B, a film | membrane feeling and a tension will arise after application | coating of emulsified cosmetics, and a usability | use_condition will fall. For this reason, in addition to the component B, it is necessary to use the component C and the component D together as a component for reducing the elasticity of the component A.

The carboxyvinyl polymer is mainly a polymer of acrylic acid, and the alkyl-modified carboxyvinyl polymer is a copolymer of mainly acrylic acid and alkyl methacrylate (preferably alkyl has 10 to 30 carbon atoms). Examples of the alkyl-modified carboxyvinyl polymer include (acrylates / alkyl acrylate (C10-30)) crosspolymer. Component B may use only 1 type and may use 2 or more types.

Component B can be obtained as a commercial product. Examples of commercially available carboxyvinyl polymers include “Carbopol 934”, “Carbopol 940”, “Carbopol 941”, “Carbopol 980”, “Carbopol 981”, “Carbopol 1342”, “Carbopol”. 2984 ”,“ Carbopol Ultrez 10 ”,“ Carbopol ETD 2050 ”(all Japan Lubrizol Corporation);“ AQUPEC HV-501 ”,“ AQUPEC HV-504 ”,“ AQUPEC HV-505 ”,“ Hibiswako ” 104 ”,“ Hibiswako 105 ”(all of which are Wako Pure Chemical Industries, Ltd.). Examples of commercially available alkyl-modified carboxyvinyl polymers include “PEMULEN TR-1”, “PEMULEN TR-2”, “Carbopol ETD 2020”, “Carbopol ULTREZ 20” (Nippon Lubrizol Corporation), etc. Is mentioned.

The content of Component B in 100% by mass of the emulsified cosmetic of the present invention is 0.4% by mass or less, preferably 0.3% by mass, from the viewpoint of suppressing the film feeling and the tension after application of the emulsified cosmetic. % Or less, and more preferably 0.25% by mass or less. The lower limit of the content of component B may be a value that satisfies a mass ratio with component A described later, but is preferably 0.01% by mass or more, for example. The content of component B is the total amount of all components B contained in the emulsified cosmetic of the present invention.

In the emulsified cosmetic of the present invention, the mass ratio of component B to component A (component B / component A) is 0.10 or more, preferably 0.21 or more, from the viewpoint of alleviating an excessive increase in elasticity.

Component C is the above “xanthan gum”. Xanthan gum is a chain polysaccharide composed of repeating units of 2 glucose molecules, 2 mannose molecules and glucuronic acid. By blending component C, an excessive increase in elasticity due to component A can be mitigated. In addition, if it is going to reduce the elasticity of the component A enough only by the component C, a null will arise at the time of application | coating of an emulsified cosmetic, and a skin familiarity and fall will fall and a usability | use_condition will fall. For this reason, as a component which reduces the elasticity of the component A, it is necessary to use the component B and the component D together with the component C.

As the component C, a commercially available product can be used. Examples of commercially available components C include “Echo Gum T” (manufactured by DSP Gokyo Food & Chemical Co., Ltd.), “Nom Coat ZZ” (manufactured by Nisshin Oilio Group Co., Ltd.), and the like.

The content of component C in 100% by mass of the emulsified cosmetic of the present invention is 0.3% by mass or less, preferably 0.25% by mass or less, from the viewpoint of suppressing a decrease in skin familiarity and preventing nullification. More preferably, it is 0.2 mass% or less. The lower limit of the content of component C may be a value that satisfies a mass ratio with component A described later, but is preferably 0.01% by mass or more, for example.

In the emulsified cosmetic of the present invention, the mass ratio of component C to component A (component C / component A) is 0.02 or more, preferably 0.03 or more, from the viewpoint of alleviating excessive elasticity increase.

Component D is “phospholipid”. By blending component D, an excessive increase in elasticity due to component A can be mitigated. In addition, when it is going to reduce the elasticity of the component A enough only with the component D, an emulsified cosmetic will change in odor over time, stability will be bad, and a usability | use_condition will fall. For this reason, in addition to the component D, it is necessary to use the component B and the component C together as a component for reducing the elasticity of the component A.

Component D is a complex lipid containing a phosphate residue, and includes natural phospholipids, synthetic phospholipids, hydrogenated phospholipids in which unsaturated carbon chains of naturally derived phospholipids are saturated with hydrogen, and the like. Specific examples of component D include phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylinositol, lysophosphatidylcholine, sphingomyelin, egg yolk lecithin, soybean lecithin, and other natural phospholipids; dilauroylphosphatidylcholine, dimyristoylphosphatidylcholine, dipalmitoylphosphatidylcholine, Examples include synthetic phospholipids such as stearoyl phosphatidylcholine, dioleoylphosphatidylcholine, palmitoyl oleoylphosphatidylcholine; hydrogenated phospholipids such as hydrogenated soybean lecithin, hydrogenated egg yolk lecithin, hydrogenated phosphatidylcholine, and hydrogenated phosphatidylserine. Among these, from the viewpoint of excellent storage stability, hydrogenated phospholipid is preferable, and hydrogenated soybean lecithin is more preferable. Component D may use only 1 type and may use 2 or more types.

The content of component D in 100% by mass of the emulsified cosmetic of the present invention is 4.0% by mass or less, preferably 3.0% by mass or less, from the viewpoint of suppressing odor change over time of the emulsified cosmetic. More preferably, it is 2.0 mass% or less. The lower limit of the content of component D may be a value that satisfies a mass ratio with component A described later, but is preferably 0.3% by mass or more, for example. The content of component D is the total amount of all components D contained in the emulsified cosmetic of the present invention.

In the emulsified cosmetic of the present invention, the mass ratio of the component D to the component A (component D / component A) is 0.4 or more, preferably 0.85 or more, from the viewpoint of alleviating excessive elasticity increase. More preferably, it is 1.0 or more, and is 7.0 or less, preferably 4.5 or less, more preferably 3. from the viewpoint of preventing the elasticity from being excessively lowered and achieving a characteristic feel. 5 or less.

Component E is “water”. Component E has a role as a medium of an emulsified cosmetic for forming an emulsified system. By making cosmetics into an emulsifying system, freshness and emollient effects are exhibited.

The content of component E in 100% by mass of the emulsified cosmetic of the present invention is preferably 55.0% by mass or more, more preferably 65.0% by mass or more, preferably from the viewpoint of containing other components. Is 95.0 mass% or less, more preferably 90.0 mass% or less.

The emulsified cosmetic of the present invention can further contain an “oil agent” as component F from the viewpoint of making the dosage form an emulsifying system.

Examples of component F include higher aliphatic alcohols, higher fatty acids, fats and oils, hydrocarbon oils, ester oils, silicone oils, waxes, and the like.

Specific examples of component F include monovalent branched aliphatic alcohols having 12 to 24 carbon atoms such as octyldodecanol, decyltetradecanol, and isostearyl alcohol; monovalent branched alcohols having 12 to 22 carbon atoms such as oleyl alcohol. Linear unsaturated aliphatic alcohols; monovalent linear saturated aliphatic alcohols having 12 to 22 carbon atoms such as cetyl alcohol, stearyl alcohol, behenyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid , Higher fatty acids such as undecylenic acid, lanolinic acid, isostearic acid; coconut oil, palm oil, hydrogenated palm oil, avocado oil, sesame oil, olive oil, kukui nut oil, grape particle oil, safflower oil, almond oil, corn oil, cottonseed oil , Sunflower seed oil, grape seed oil, hazelnut , Oils such as macadamia nut oil, meadow foam oil, rosehip oil; hydrocarbon oils such as olefin oligomer, light liquid isoparaffin, squalane, liquid paraffin, liquid isoparaffin, petrolatum; ethyl oleate, isopropyl myristate, isopropyl palmitate, myristine Myristyl acid, cetyl palmitate, oleyl oleate, octyldodecyl myristate, octyldodecyl oleate, ethyl isostearate, isopropyl isostearate, cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, tri-2-ethylhexanoic acid Glyceryl (trioctanoin), tri (capryl / capric acid) glyceryl, glyceryl triisopalmitate, pentaerythritol tetra-2-ethylhexanoate , Ester oils such as isocetyl octoate, isostearyl octoate, isocetyl isostearate, octyldodecyl isostearate, octyldodecyl dimethyloctanoate, propylene glycol isostearate, hydrogenated castor oil hydroxystearate; dimethicone, methylpolysiloxane, high polymerization Methylpolysiloxane, methylphenylpolysiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, methylcyclopolysiloxane, alcohol-modified silicone, alkyl-modified silicone, Silicone oil such as amino-modified silicone and epoxy-modified silicone; wax such as jojoba oil and beeswax It is. Component F may be used alone or in combination of two or more.

The content of component F in 100% by mass of the emulsified cosmetic of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, from the viewpoint of functionality such as an emollient effect. More preferably, it is 1.0% by mass or more, and from the viewpoint of use feeling such as stickiness suppression, it is preferably 50.0% by mass or less, more preferably 40.0% by mass or less, and further preferably 30%. 0.0 mass% or less. The content of component F is the total amount of all components F contained in the emulsified cosmetic of the present invention when a plurality of components F are used.

The emulsified cosmetic of the present invention may further optionally contain other components other than those described above. Examples of other components include surfactants (cationic surfactants, anionic surfactants, nonionic surfactants, amphoteric surfactants, etc.), lower alcohols, polyhydric alcohols, ultraviolet absorbers, powders, antioxidants Agents, preservatives, fragrances, coloring agents, chelating agents, refreshing agents, vitamins, neutralizing agents, amino acids, pH adjusters, whitening agents, anti-inflammatory agents, deodorants, animal and plant extracts, sequestering agents An additive etc. are mentioned. Only 1 type may be used for said other component, and 2 or more types may be used for it.

The pH of the emulsified cosmetic of the present invention is, for example, preferably 4.5 to 7.5 at 25 ° C., more preferably 5.0 to 7.0.

The emulsified cosmetic of the present invention has a consistency at 25 ° C. of preferably 5.0 to 100.0 gf, more preferably 10.0 to 80.0 gf, from the viewpoint of having the characteristic properties of the present invention. More preferably, it is 25.0 to 70.0 gf. The “consistency at 25 ° C.” is a value measured using a consistency meter equipped with a 17φ flat adapter at 25 ° C., a speed of 60 mm / min, and a stroke of 20 mm. An example of such a consistency meter is “RHEO METER” manufactured by Sun Kagaku Co., Ltd.

An example of the dosage form of the emulsified cosmetic of the present invention is gel cream. The emulsified cosmetic of the present invention has no fluidity and has elasticity. Moreover, it has the property of flowing when a shearing force is applied. For this reason, even if it takes out in the shape of a sphere or a cylinder from a container, for example, the shape can be maintained, and if vibration is added, it will shake like a jelly. In addition, it has a soft jelly-like appearance. In addition, when applying to a skin or the like by applying a shearing force, it can be applied without resistance. Furthermore, the emulsified cosmetic of the present invention can be a reversible structure that can easily return to the original structure even if the structure is broken by a physical action. For this reason, even if the emulsified cosmetic filled in the container or the like is scraped off with a finger or the like, the scratched marks are automatically repaired, and the surface of the filled cosmetic becomes a flat surface. Thus, the emulsified cosmetic composition of the present invention exhibits new properties and a feeling of use (feel of skin) that are different from those of conventional cosmetic compositions.

Examples of the emulsified cosmetic of the present invention include skin care cosmetics such as cleansing cosmetics, moisturizing cosmetics, whitening cosmetics, acne care cosmetics, and anti-aging cosmetics (for example, for the purpose of suppressing wrinkles and sagging). Fees: sunscreen cosmetics and the like. The emulsified cosmetic of the present invention is preferably used as a skin cosmetic. The emulsified cosmetic of the present invention may be any of cosmetics, quasi drugs, pharmaceuticals, and miscellaneous goods, for example.

The parts to which the emulsified cosmetic of the present invention is applied include the face (for example, forehead, eyes, eyes, cheeks, mouth), arms, elbows, back of hands, fingertips, feet, knees, heels, neck, armpits, and back. Can be mentioned.

Examples of the method for preparing the emulsified cosmetic of the present invention include a method in which the above-described components are mixed and a known method, for example, a method using a homomixer, and the like.

Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited only to these examples. In addition, a compounding quantity and content are the quantity converted into the pure part, and represent "mass%" unless it mentions specially.

Examples 1 to 15 and Comparative Examples 1 to 7 (Preparation of emulsified cosmetics)
According to the compositions described in Tables 1 to 3, emulsified cosmetics of Examples and Comparative Examples were prepared as follows.

As the aqueous phase, Component A, Component B, Component C, Component E, BG, glycerin, methyl paraben, and potassium hydroxide were mixed and heated to 85 ° C. Further, as the oil phase, Component D, Component F, glyceryl behenate, polyglyceryl octastearate-6, and glyceryl stearate were mixed and heated to 85 ° C. Next, the water phase and the oil phase were mixed, emulsified by stirring with a homomixer at a rotational speed of 6000 rpm for 5 minutes, and cooled to 35 ° C. to prepare a gel cream emulsified cosmetic.

The pH of the emulsified cosmetic of Example 1 at 25 ° C. was about 6.4, and the consistency at 25 ° C. was 40 gf.

Details of main raw materials in Examples, Comparative Examples and Formulation Examples are as follows. The amounts listed in Tables 1 to 3 are not the amount of the product but the amount of each component (the amount of the active ingredient).

(Acrylates / Beheneth-25 Methacrylate) Copolymer: Trade name “Aculin 28”, manufactured by Dow Chemical Co. (Acrylates / alkyl acrylate (C10-30)) Crosspolymer: Trade name “PEMULEN TR-1,” Xanthan gum manufactured by LUBRIZOL : Trade name “Echo Gum T”, Hydrogenated lecithin (hydrogenated soybean lecithin) manufactured by DSP Gokyo Food & Chemical Co., Ltd .: Trade name “Resinol S-10”, Trioctanoin manufactured by Nikko Chemicals Co., Ltd .: Trade name “Exepearl TGO”, Kao's squalane: Trade name “NIKKOL Sugar Squalane”, Nippon Surfactant's hydroxy stearic acid hydrogenated castor oil: Trade name “Technol MH”, Yokozeki Yushi Co., Ltd. dimethicone: Trade name “SH200C 10CS-JASU”, Toray Dow Made by Corning Glyceryl tea tearate (glyceryl monostearate): trade name “CUTINA GMS-V”, glyceryl behenate and polyglyceryl octastearate-6 manufactured by BASF Corporation: trade name “TAISET SC50”, Taiyo Kagaku BG (1,3- Butylene glycol): Trade name “1,3-butylene glycol”, Daicel carbomer: Trade name “Carbopol 981”, LUBRIZOL shea fat: Trade name “Star Shear butter refined”, IMCD Group BV. Made

(Evaluation test 1: Evaluation of elasticity)
About 30 g of the emulsified cosmetic of each Example and Comparative Example was filled in a jar container and stored in a thermostatic bath at 25 ° C. for 1 week in a sealed state. The properties of each emulsified cosmetic after storage were evaluated according to the following criteria based on the appearance observation and the feel when the emulsified cosmetic was scraped with a finger. The results are shown in Tables 1 to 3.
A (excellent): It is a property having no fluidity and elasticity, and can be easily scraped with a finger.
○ (good): It is a property having no fluidity and elasticity, but it is difficult to scrape with a finger (high elasticity). Or the elasticity felt when scraping with a finger is weak (elasticity is low).
X (defect): The material has no fluidity and elasticity, but cannot be scraped with a finger (elasticity is too high). Alternatively, no elasticity is observed during appearance observation and scraping with a finger (elasticity is too low).

(Evaluation Test 2: Stability)
About 100 g of the emulsified cosmetic of each Example and Comparative Example was filled in a wide-mouthed glass bottle (so-called mayonnaise bottle) and stored in a thermostatic bath at 40 ° C. for 4 weeks in a sealed state. After each emulsion cosmetic after storage was returned to room temperature (25 ° C.), the presence or absence of separation and the presence or absence of odors of each emulsion cosmetic were evaluated according to the following criteria. The results are shown in Tables 1 to 3.
○ (Good): Separation and unpleasant odor are not recognized.
X (defect): Separation or unpleasant odor is recognized.

(Evaluation test 3: with null)
The emulsified cosmetics obtained in each Example and each Comparative Example were applied to the inner side of the forearm and applied by hand. “With null” at the time of applying each cosmetic was evaluated according to the following criteria. The results are shown in Tables 1 to 3.
◎ (Excellent): Skin conformity is good and no slickness is felt during application.
○ (good): The familiarity with the skin is a little slow, and a slight null is felt, but it is acceptable in practical use.
X (defect): The familiarity with the skin is clearly slow, and an uncomfortable null feeling is felt.

From Tables 1 to 3, it was found that the emulsified cosmetics of Examples 1 to 15 having the composition of the present invention had an excellent effect of evaluation of ～ to ◎ in terms of elasticity, stability and nulliness.
On the other hand, from Comparative Examples 1 to 7, it was found that if all of component B, component C and component D were not included in a specific amount and a specific ratio, any evaluation could only exert an inferior effect of x.

Formulation Example 1 (Gel Cream)
(Acrylates / Beheneth-25 methacrylate) copolymer 0.6% by mass
Carbomer 0.15% by mass
Xanthan gum 0.05% by mass
Hydrogenated phospholipid 1.0% by mass
Water balance Polyglyceryl-6 octastearate 0.5% by mass
Glyceryl monobehenate 0.5% by mass
Glyceryl monostearate 0.5% by mass
Potassium hydroxide 0.18% by mass
Squalane 5.0% by mass
Glyceryl tri-2-ethylhexanoate 5.0% by mass
Shea fat 0.5% by mass
Isononyl isononanoate 0.5% by mass
Dimethicone 0.5% by mass
Glycerin 5.0% by mass
1,3-butylene glycol 5.0% by mass
Dipropylene glycol 3.0% by mass
Methylparaben 0.2% by mass
Phenoxyethanol 0.2% by mass
Octoxyglycerin 0.2% by mass
l-Menthol 0.05% by mass
Perfume 0.02% by mass
Ethanol 5.0% by mass
Total 100% by mass

The emulsified cosmetic of the present invention has moderate elasticity, and can be used as a cosmetic having new properties and feel different from conventional cosmetics.

Claims

It contains the following component A, component B, component C, component D, and component E, the content of component A is 0.1 to 1.0% by mass, and the content of component B is 0.4% by mass The content of component C is 0.3% by mass or less, the content of component D is 4.0% by mass or less, and the mass ratio of component B to component A (component B / component A) is 0.10 or more, the mass ratio of component C to component A (component C / component A) is 0.02 or more, and the mass ratio of component D to component A (component D / component A) is 0.4 or more. An emulsified cosmetic that is 7.0 or less.
Component A: (Acrylates / Beheneth-25 methacrylate) copolymer Component B: Carboxyvinyl polymer and / or alkyl-modified carboxyvinyl polymer Component C: Xanthan gum Component D: Phospholipid Component E: Water
Furthermore, the emulsified cosmetics of Claim 1 containing the following component F.
Component F: Oil agent