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WO2018159192A1 - Method for transferring image onto balloon and balloon - Google Patents

Method for transferring image onto balloon and balloon Download PDF

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Publication number
WO2018159192A1
WO2018159192A1 PCT/JP2018/002978 JP2018002978W WO2018159192A1 WO 2018159192 A1 WO2018159192 A1 WO 2018159192A1 JP 2018002978 W JP2018002978 W JP 2018002978W WO 2018159192 A1 WO2018159192 A1 WO 2018159192A1
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WO
WIPO (PCT)
Prior art keywords
image
layer
balloon
substrate
toner
Prior art date
Application number
PCT/JP2018/002978
Other languages
French (fr)
Japanese (ja)
Inventor
智子 森井
雅満 相塲
Original Assignee
株式会社アイエヌジー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社アイエヌジー filed Critical 株式会社アイエヌジー
Publication of WO2018159192A1 publication Critical patent/WO2018159192A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63HTOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
    • A63H27/00Toy aircraft; Other flying toys
    • A63H27/10Balloons

Definitions

  • the present invention relates to an image transfer method for transferring and printing an image of any design, photograph, character, etc. on the surface of a balloon generally used for toys, event ornaments, display ornaments, etc. Concerning the transferred balloon.
  • transfer printing for transferring an image to a transfer object.
  • dry transfer in which an adhesive is applied to the back surface of an image layer temporarily attached to a base sheet and then the image layer is transferred to the surface of a transfer object by pressing and adhered, the edges remain on the image during transfer. Therefore, it appears to be printed directly on the transfer object, and there is a feature that no post-processing by a cutting plotter or the like is required.
  • a prior art such as a dry transfer paper described in Patent Document 1 and a method for producing the same is proposed.
  • the adhesive is not applied to the region other than the image layer, there is an advantage that the transfer object is not contaminated.
  • the prior art since the prior art includes a process in which the image layer is converted into a light shielding image and then the photosensitive material is modified and cured by an exposure process, the image layer naturally has to shield light, and the color of the image And the color tone must be constrained.
  • Non-Patent Document 1 The inventor of the present application has been working on simplification of such dry transfer technology, and has developed, manufactured and sold a product “smart paper (trade name)” described in Non-Patent Document 1. This is because a mirror image is printed on a PET (polyethylene terephthalate) base material sheet that has been releasable on the surface by toner printing to form an image layer on the image layer. After applying acrylic glue and drying, the base sheet is brought into close contact with the transfer object and pressed, and when the base sheet is peeled off, only the image layer is adhered to the transfer object as a normal image and transferred. To be completed.
  • the smart paper not only has a very simple process, but also does not use a solvent or the like, and therefore does not cause a problem of environmental load.
  • the present inventor further developed the smart paper, provided an image layer between the upper transfer film and the lower adhesive layer, and the transfer film has releasability from the image layer.
  • a plurality of image transfer sheets characterized by having easy adhesion to the adhesive layer have been developed and patent applications have been filed (Japanese Patent Application Nos. 2016-106167 and 2016-123461: "Invention"). Since the image transfer sheets according to the inventions of the application do not need to form a glue layer by applying glue to a transfer object or remove glue protruding from the image after transfer, unlike smart paper, The work cost and work load can be reduced, and the finish can be homogenized.
  • the conventional technique of transferring an image layer formed by toner printing with a glue layer has a problem to be solved when applied to a transfer object whose surface expands and contracts. .
  • Balloons have been popular as toys and ornaments for many years, but in recent years they have been increasingly used for events such as event ornaments, display ornaments, and promotional novelties. Accordingly, there is an increasing demand for so-called “arrange balloons” that print images of arbitrary designs, photographs, characters, and the like on the surface of the balloons.
  • conventional rubber balloons and balloons made of resin films such as vinyl chloride, polyester, nylon, etc.
  • the edges of sheets coated with these resin films by aluminum deposition are bonded together.
  • Formed so-called “foil material” balloons (generally also called “mylar balloons”) are in widespread use. Since rubber balloons have a certain level of air permeability and are likely to wither over time, balloons that are floated with helium in particular are often made of a resin film with little air permeability. It has become.
  • the balloon is a commodity that is required to be lightweight, helium is often injected and floated in the air. Therefore, when printing an image, the ink to be used must be lightweight. This is because if the weight of the ink is large, the balloon does not easily float, and the balloon in a floating state may be inclined due to the weight of the ink due to printing on one side.
  • balloon materials such as rubber and resin films are extremely thin and vulnerable to heat, and in the case of foil materials, the surface may be damaged by moisture. Therefore, transfer printing such as silk printing, gravure printing, thermal transfer, and water transfer, in which the image layer is heavy, is not suitable for image printing on a balloon.
  • toner printing is a printing method in which an image layer is formed with light toner particles without using a solvent, and thus can be said to be particularly suitable for image printing on a balloon made of vinyl chloride or a foil material.
  • FIG. 1 is a schematic diagram showing a general bonded balloon, and the balloon body B is formed by bonding the edges of two vinyl chloride sheets or aluminum vapor-deposited films cut into an arbitrary shape from a raw material by heat welding.
  • the check valve V is provided, and the pump P is inserted into the check valve V, and air is injected to expand it.
  • Such a balloon is not as elastic as a rubber balloon, and the surface thereof is smoother. Therefore, as shown in FIG. 2, in addition to printing a rich and detailed image by toner printing, it is possible to print a photograph.
  • the bonded balloon has a smaller expansion and contraction of the material itself than the rubber balloon, but the surface expands into a curved surface by injecting air or gas.
  • the image layer composed of toner particles adhered to the surface of the flat original fabric has a problem of causing cracks such as “penetration” generated in the glaze layer of the ceramic. Cracks not only make the printed image look dirty but also make the image layer easy to peel off, reducing the commercial value of the balloon, and particularly when printing a human face photo, there is a problem that the impression becomes worse due to cracks. It was.
  • the present invention has been devised to solve the above-described problems of the prior art, and image transfer for transferring an image of any design, photograph, character, etc. formed by toner printing on a balloon, particularly a bonded balloon.
  • the invention described in claim 1 of the present invention is an image transfer method for transferring an image printed by a toner printer to the surface of a balloon, and applying a paste to the balloon surface.
  • the image transfer method according to claim 1 is the image transfer method in which the above-described smart paper is applied to the balloon balloon before being expanded, and the image layer is crushed by rubbing the surface of the substrate with a vibrator. Three steps are added.
  • an invention described in claim 2 of the present invention is an image transfer method for transferring an image printed by a toner printer to the surface of a balloon, and a substrate having releasability with respect to an image layer; A first step of pressing the adhesive layer side of the image transfer sheet consisting of an adhesive layer made of glue and an image layer provided between the substrate and the adhesive layer to the balloon surface; and rubbing the substrate surface with a vibrator And a second step of crushing the image layer and a third step of peeling the substrate from the image layer.
  • the image transfer method according to claim 2 is the image transfer method to which the image transfer sheet according to the invention of the present application filed by the inventor of the present application is applied. Similarly, the image layer is crushed by rubbing the substrate surface with a vibrator. The process is added.
  • the step of applying the paste on the surface of the balloon in advance to form the glue layer can be omitted.
  • the image layer is formed by toner printing because the image transfer to the balloon requires a reduction in weight. Therefore, the glue layer itself needs to be formed as thin and uniform as possible. In that respect, the thickness of the glue layer is made thinner and more uniform by applying an image transfer sheet with a glue layer formed on the back side of the image layer in advance than smart paper, which requires a manual glue application process. Since it is possible, it is more preferable.
  • the base material provided with the image layer may be pressure-bonded to the balloon through a cold laminator, that is, a laminator without heating.
  • a cold laminator that is, a laminator without heating.
  • the image layer side of the base material is positioned and brought into contact with the surface of the balloon, and then the surface is rubbed from above with a valen for printing, etc., but the balloon covered with the base material is placed on the metal plate.
  • the laminator roller By passing the cold laminator in a state where it is placed on the laminator, the laminator roller can be uniformly pressed. Thereby, the quality of the transferred image can be improved, and the productivity is also improved.
  • the invention described in claim 3 of the present invention is the image transfer method to the balloon according to any one of claims 1 or 2, wherein the image layer is a clear toner layer in order from the substrate side, It has a two-layer structure of a foil layer.
  • Clear toner is literally a transparent toner and is generally used to cause gloss on the printed surface.
  • the image layer By making the image layer into a two-layer structure of a clear toner layer and a foil layer in order from the substrate side, the foil layer under the clear toner layer on the surface appears to be transmitted, so depending on the type of foil, gold, silver, copper, An image of a texture such as aluminum can be transferred to the balloon.
  • a ready-made foil film obtained by vapor-depositing a metal component on a transparent resin film can be used in place of the gold foil used in traditional crafts.
  • the image layer having such a two-layer structure can be formed by the following method.
  • a reverse image is printed on a base material with a clear toner, and a laminator that can be heated at 110 ° C. to 140 ° C. with the base material is attached to the surface on which the foil film is deposited. Pass through. Since the clear toner is generally melted at around 125 ° C. to fuse the foil, when the foil film is peeled off from the substrate after cooling, the foil adheres to the shape of the image. On the other hand, the foil is not adhered to the portion outside the image without the clear toner, and is peeled off while remaining on the foil film. Through the above process, an image layer having a two-layer structure of a clear toner layer and a foil layer is formed.
  • the invention described in claim 4 of the present invention is the image transfer method to the balloon according to any one of claims 1 or 2, wherein the image layer comprises a clear toner layer and a colored toner layer in order from the substrate side. And having a three-layer structure of a foil layer.
  • the image layer has a three-layer structure of a clear toner layer, a colored toner layer, and a foil layer in order from the base material side, so that the color tone of the foil made of a ready-made foil film can be variously changed.
  • the colored toner layer can be provided by printing an image with a light-colored colored toner so that the colored toner layer overlaps the image formed by the clear toner layer, and the method of providing the foil layer is the same as that of the invention described in claim 3.
  • Ready-made foil films are limited to single color such as gold, silver, copper, and aluminum, but it is possible to add gradations and patterns to metallic images by printing a colored toner layer. It becomes.
  • an invention described in claim 5 of the present invention is the image transfer method to the balloon according to any one of claims 1 to 4, wherein the composition of the paste is made of vinyl acetate / acrylate. It is characterized by adding 10 to 35% of an aqueous acrylic emulsion to a polymer emulsion. The addition of the aqueous acrylic emulsion has the effect of improving the elasticity of the glue layer during curing without greatly reducing the adhesive strength of the glue.
  • the adhesive layer be as thin and uniform as possible.
  • the adhesive used has an adhesive force that prevents the image layer from being easily peeled off by fixing the image layer to the surface of the balloon.
  • the balloon When the balloon is inflated after it has solidified over time, it is required to retain elasticity corresponding to the expansion of the surface. This is because even if the image layer has been finely crushed in advance by vibration of the vibrator, if the glue layer itself is cracked or unevenly stretched, the image layer may still be cracked at a density that is easily visible.
  • the elasticity of the glue layer can be realized by modifying the glue with additives, but the toner particles are made by mixing a plastic resin with a pigment, wax, a charge control material, etc. Oil-based additives cannot be used because they are soluble.
  • the paste according to the present invention has appropriate elasticity, it can be repaired afterwards even when a cracked portion of the image layer is noticed when the balloon is inflated. That is, the balloon is once evacuated and deflated, and the image layer is crushed by applying vibration with a vibrator again from above on a place where the crack of the image is conspicuous. Thereby, a crack can be made inconspicuous and an image layer does not peel easily.
  • the invention described in claim 6 of the present invention is a balloon in which an image is transferred by the image transfer method of any one of claims 1 to 5.
  • the image transfer method according to the present invention has the following effects. That is, (1) Since the image is adhered to the balloon surface by the glue layer, the durability of the image is higher than the method of printing the image directly on the balloon or the original fabric of the balloon with a toner printer, and the color is fine and clear. Image transfer is possible. Further, even when the balloon is deflated, the image is not easily peeled off. (2) Since the image can be transferred so as to straddle the bonding line of the material peculiar to the bonded balloon, a white line that divides the image is not generated when the balloon is inflated. Therefore, large images can be transferred with high quality, and image transfer to a large balloon can be performed at low cost.
  • the image layer has a two-layer structure of a clear toner layer and a foil layer in order from the substrate side, a high-quality metallic tone image can be transferred at a low cost. Furthermore, if the image layer has a three-layer structure of a clear toner layer, a colored toner layer, and a foil layer, gradation and a pattern can be easily added to a metallic tone image, and the expressiveness of the image transferred to the balloon can be improved.
  • FIG. 3 is a schematic cross-sectional view showing the steps of an image transfer method to a balloon according to the first embodiment of the present invention using the smart paper described in claim 1.
  • the glue layer 13 is formed at a position where the image on the surface of the balloon B is transferred, in a range slightly larger than the image.
  • the glue used for the glue layer 13 is obtained by adding 10 to 35% of an acrylic emulsion aqueous paint to a glue of vinyl acetate / acrylate copolymer emulsion. Also, the paste should be applied as thin and as uniform as possible.
  • the smart paper 10 is adhered to the glue layer 13 and the image layer 12 is adhered by rubbing and pressing from the surface with valen or the like for printing, or through a cold laminator as described above. To do.
  • the smart paper 10 is obtained by printing a mirror image on the back surface of the substrate 11 with a toner printer to form an image layer 12.
  • the image layer 12 is crushed by applying vibration while uniformly rubbing the portion of the image layer 12 using the vibrator V.
  • the base material 11 of the smart paper 10 is slowly peeled off.
  • the paste layer 13 in a portion protruding from the image layer 12 is removed from the surface of the balloon B while adhering to the base material 11. No. 12 remains and image transfer is completed.
  • FIG. 4 is a schematic cross-sectional view showing steps of an image transfer method to a balloon according to a second embodiment of the present invention using the image transfer sheet according to claim 2.
  • the image transfer sheet 20 is affixed at a position where the image on the surface of the balloon B is transferred.
  • the image transfer sheet 20 includes a base material 21 having releasability with respect to an image layer, a paste layer 23 made of a paste, and an image layer 22 provided between the base material and the paste layer.
  • the glue used for the glue layer 23 is obtained by adding 10 to 35% by weight of an acrylic emulsion aqueous paint to the glue of the vinyl acetate / acrylate copolymer emulsion.
  • the image layer 22 is adhered to the surface of the balloon B by rubbing and pressing from the surface with valen for printing, or by passing through a cold laminator as described above, as in the first embodiment.
  • the image transfer sheet 20 is a sheet with a paste (on which a reverse image is printed on a surface of a base material 21 by a toner printer and a paste layer is provided on the surface of a sheet-like separator (not shown)).
  • the adhesive layer surface (not shown) can be applied, and then the separator can be peeled off to prepare in advance.
  • the image layer 22 is crushed by applying vibrations while equally rubbing the portion of the image layer 22 using the vibrator V.
  • the base material 21 of the smart paper 10 is slowly peeled off. At this time, the base material 21 has releasability with respect to the image layer 22, while it has easy adhesiveness with respect to the paste, so that the portion of the paste layer 23 that protrudes from the image layer 22 adheres to the base material 21. While being removed from the surface of the balloon B, the image layer 22 remains and the image transfer is completed.
  • the photographs 5A and 6A show the state of the image in which the second step of crushing the image layer 22 with a vibrator is omitted in image transfer using the image transfer sheet 20 and the balloon B after transfer is inflated.
  • the photographs 5B and 6B show the state of the image when the second step is performed.
  • the image when the second step is omitted is cracked with a coarse density in the shape of a ceramic intrusion on one side, and in particular, the crack can be easily seen from a distance of 1 m or more in the dark portion. It becomes a conspicuous state.
  • the image when the second step is carried out has a very small crack density, and the quality is clearly improved.
  • FIG. 7 is a continuous view showing a manufacturing process of an image layer according to the fourth aspect of the present invention.
  • a desired image is printed as a reverse image on the surface of the base material by the toner printer P on the base material S with the clear toner to provide the clear toner layer c1.
  • the color toner layer c2 is provided by printing the image with the color toner so as to overlap the clear toner layer c1.
  • the color of the colored toner is not limited, but it is preferable to use a light color toner, and it may be printed as an image having a gradation or a pattern.
  • a foil film M is placed on the image.
  • the foil film M is formed by depositing a metal component on the back surface of the transparent resin film f to form a foil layer m, and various commercial products such as a gold foil tone, a silver foil tone, a copper foil tone, and an aluminum tone depending on the type of the metal component. Can be used.
  • the printed substrate S covered with the foil film M is passed through a laminator L and heated by pressure.
  • the temperature of the laminator L is preferably 110 ° C to 140 ° C.
  • the foil film M is pressure-bonded onto the substrate S, and the clear toner layer c1 and the colored toner layer c2 are melted by heat so that the foil layer m is adhered only to the image portion. .
  • FIG. 8 is a cross-sectional view showing a second step of the first embodiment in which an image transfer sheet having an image layer formed by the above step is pressure-bonded to a glue layer on the balloon surface.
  • FIG. 9 is a cross-sectional view showing a second step of the second embodiment in which a glued image transfer sheet having an image layer formed by the above-described step is pressure-bonded to the balloon surface.
  • any transfer method an image having a three-layer structure is adhered and transferred onto the balloon surface in the order of the foil layer m, the colored toner layer c2, and the clear toner layer c1 from the bottom.
  • an image that can be printed by a toner printer can be transferred to a balloon, particularly a balloon made of foil material, which has recently become popular, with high quality.
  • a balloon particularly a balloon made of foil material, which has recently become popular, with high quality.
  • an image layer having a two-layer structure or a three-layer structure including a foil layer it is possible to transfer an image having a rich metallic tone.
  • balloons for printing arbitrary original images in small lots such as promotional novelties, event decorations, display decorations, party goods, souvenirs, etc.
  • the image transfer method according to the present invention is more suitable when the surface of the transfer object is softer than when the surface of the transfer object is hard. Therefore, a soft resin, to which image transfer by toner printing could not be applied conventionally due to the problem of image cracking The applicability is great in that it can be applied to products and the like.
  • 1 is a schematic diagram showing a general bonded balloon. It is the example photograph of the balloon which transferred the image which carried out toner printing. It is process drawing of the image transfer method which concerns on 1st Embodiment of this invention. It is process drawing of the image transfer method which concerns on 2nd Embodiment of this invention. It is a comparative photograph which shows the effect of the image transfer method which concerns on 2nd Embodiment of this invention. It is a comparative photograph which shows the effect of the image transfer method which concerns on 2nd Embodiment of this invention. It is a continuation figure showing a manufacturing process of an image layer of a three-layer structure.

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Abstract

[Problem] To provide: an image transfer method which is designed to transfer an image (any design, photograph, characters, etc.) formed by toner printing onto a balloon, in particular, a laminated balloon, suppresses a reduction in the quality of the transferred image due to cracks in an image layer which may occur when the balloon is expanded, and prevents formation of a white line in the image due to a joining line of a balloon material dividing the image; and a balloon on which an image is transferred. [Solution] This method for transferring an image onto a balloon is designed to transfer an image printed by a toner printer onto a balloon surface and comprises: a first step of pressing onto the balloon surface a glue layer side of an image transfer sheet which comprises a substrate, a glue layer and an image layer disposed between the substrate and the glue layer, the substrate having releasability with respect to the image layer, the glue layer being made of a glue material prepared by adding 10-35% by weight of an aqueous acrylic emulsion to a vinyl acetate-acrylic acid ester copolymer emulsion glue material; a second step of scraping the substrate surface with a vibrator and thereby fracturing the image layer; and a third step of removing the substrate from the image layer. This balloon has an image transferred thereon by said method for transferring an image onto a balloon.

Description

バルーンへの画像転写方法、バルーンImage transfer method to balloon, balloon
 本発明は、一般に玩具、イベント用装飾品、ディスプレイ用装飾品などに使用されるバルーン(風船)の表面に、任意の意匠、写真、文字等の画像を転写印刷する画像転写方法、及び画像が転写されたバルーンに関する。 The present invention relates to an image transfer method for transferring and printing an image of any design, photograph, character, etc. on the surface of a balloon generally used for toys, event ornaments, display ornaments, etc. Concerning the transferred balloon.
 画像を転写対象物に転写する転写印刷としては、水転写、熱転写、昇華転写、乾式転写等の技術が知られている。中でも、基材シート上に仮着した画像層の裏面に接着剤を塗布した上で、押圧によって画像層を転写対象物の表面に移行させて接着する乾式転写は、転写時に画像に縁が残らないため、転写対象物に直接印刷したように見え、カッティングプロッター等による後処理も不要といった特徴を有する。 Techniques such as water transfer, thermal transfer, sublimation transfer, and dry transfer are known as transfer printing for transferring an image to a transfer object. In particular, dry transfer, in which an adhesive is applied to the back surface of an image layer temporarily attached to a base sheet and then the image layer is transferred to the surface of a transfer object by pressing and adhered, the edges remain on the image during transfer. Therefore, it appears to be printed directly on the transfer object, and there is a feature that no post-processing by a cutting plotter or the like is required.
 かかる乾式転写のための転写シートおよびその製造方法として、たとえば特許文献1に記載の乾式転写紙およびその製造法のような先行技術(以下「先行技術」という。)が提案されている。かかる先行技術によれば、画像層以外の領域に接着剤を塗布しないので、転写対象物が汚染されないという利点を有する。しかし、先行技術では、画像層を光遮蔽像とした上で露光処理により感光性材料を変性させて硬化させる工程を含むため、画像層は当然に光を遮蔽しなければならず、画像の色彩や色調は制約を受けざるを得ない。また、感光性材料への光照射の工程、光照射後に未硬化の感光性材料を溶媒によって除去する工程等が必要とされ、製造工程が複雑かつ高コストとなるだけでなく、溶媒等を使用することによる環境負荷の問題を有するものであった。
特開平6-210963号公開公報
As such a transfer sheet for dry transfer and a method for producing the same, a prior art (hereinafter referred to as “prior art”) such as a dry transfer paper described in Patent Document 1 and a method for producing the same is proposed. According to such a prior art, since the adhesive is not applied to the region other than the image layer, there is an advantage that the transfer object is not contaminated. However, since the prior art includes a process in which the image layer is converted into a light shielding image and then the photosensitive material is modified and cured by an exposure process, the image layer naturally has to shield light, and the color of the image And the color tone must be constrained. In addition, the process of light irradiation to the photosensitive material, the process of removing the uncured photosensitive material with a solvent after the light irradiation, etc. are required, which not only makes the manufacturing process complicated and expensive, but also uses a solvent etc. It has the problem of the environmental load by doing.
Japanese Laid-Open Patent Publication No. 6-210963
 本願発明者は、従前よりかかる乾式転写技術の簡便化に取り組み、非特許文献1に記載の製品「スマートペーパー(商品名)」を開発して製造販売してきた。これは、表面に離型可能処理を施したPET(ポリエチレンテレフタラート)製の基材シート上にレーザープリンター等のトナー印刷によって鏡像の画像を印刷して画像層を形成し、該画像層上にアクリル系の糊を塗布して乾燥させた後、基材シートを転写対象物に密着させて押圧を加え、基材シートを剥離すると画像層のみが正像にて転写対象物に接着され転写が完了するものである。該スマートペーパーは、工程が極めて簡易であるだけでなく、溶剤等を使用しないため環境負荷の問題も生じない。また、転写に際して水を使用せず熱も加えないため、金属、ガラス、合成樹脂はもとより紙、木、皮革、繊維(布)、陶器まで適用可能な転写対象物の素材が幅広い。さらに、画像層を柔軟な基材シート上に仮着させた上で転写するため、直接プリンターを通せない立体物や曲面にも転写可能であるなど、乾式転写のコスト低減、適用範囲の拡大、作業の簡易化・効率化の効果を奏するものである。
「スマートペーパー」の説明(出願人ウェブサイトのページ)URL:http://ing-global.net/smartpaper/index.html?id=movie
The inventor of the present application has been working on simplification of such dry transfer technology, and has developed, manufactured and sold a product “smart paper (trade name)” described in Non-Patent Document 1. This is because a mirror image is printed on a PET (polyethylene terephthalate) base material sheet that has been releasable on the surface by toner printing to form an image layer on the image layer. After applying acrylic glue and drying, the base sheet is brought into close contact with the transfer object and pressed, and when the base sheet is peeled off, only the image layer is adhered to the transfer object as a normal image and transferred. To be completed. The smart paper not only has a very simple process, but also does not use a solvent or the like, and therefore does not cause a problem of environmental load. In addition, since no water is used and no heat is applied during transfer, there are a wide range of materials that can be applied to metal, glass, synthetic resin, paper, wood, leather, fiber (cloth), and ceramics. Furthermore, since the image layer is transferred after being temporarily attached to a flexible substrate sheet, it can also be transferred to solid objects and curved surfaces that cannot be passed directly through the printer, reducing the cost of dry transfer, expanding the application range, This has the effect of simplifying and improving work efficiency.
Explanation of "smart paper" (applicant website page) URL: http://ing-global.net/smartpaper/index.html?id=movie
 また、本願発明者は、前記スマートペーパーをさらに発展させ、上層の転写フィルムと下層の糊層との間に画像層を設け、該転写フィルムを、画像層に対しては離型性を有するとともに糊層に対しては易接着性を有するものとしたことを特徴とする複数の画像転写シートを開発し、特許出願も行っている(特願2016-106167、特願2016-123461:以下「出願発明」と記す)。これら出願発明に係る画像転写シートは、スマートペーパーのように、転写対象物に糊を塗布して糊層を形成したり、転写後に画像からはみ出した糊を除去したりする必要がないため、転写作業のコストや作業負担を低減でき、仕上りも均質化できる。しかし、前記の本願発明者の発明を含め、トナー印刷で形成した画像層を糊層により転写する方式の従来技術は、表面が伸縮する転写対象物への適用には解決すべき課題が存在した。 The present inventor further developed the smart paper, provided an image layer between the upper transfer film and the lower adhesive layer, and the transfer film has releasability from the image layer. A plurality of image transfer sheets characterized by having easy adhesion to the adhesive layer have been developed and patent applications have been filed (Japanese Patent Application Nos. 2016-106167 and 2016-123461: "Invention"). Since the image transfer sheets according to the inventions of the application do not need to form a glue layer by applying glue to a transfer object or remove glue protruding from the image after transfer, unlike smart paper, The work cost and work load can be reduced, and the finish can be homogenized. However, including the above-described invention of the present inventor, the conventional technique of transferring an image layer formed by toner printing with a glue layer has a problem to be solved when applied to a transfer object whose surface expands and contracts. .
 バルーン(風船)は、長年に渡り玩具や装飾品として普及してきたものであるが、近年ではイベント用装飾品、ディスプレイ用装飾品、販促用ノベルティ等の用途での活用が進んでおり、用途に応じてバルーンの表面に任意の意匠、写真、文字等の画像を印刷する、いわゆる「アレンジバルーン」の需要が増加している。特に、販促用ノベルティやギフト等の用途では、従来のゴム風船や、塩化ビニル・ポリエステル・ナイロン等の樹脂フィルム製のバルーンとともに、これらの樹脂フィルムをアルミ蒸着でコーティングしたシートの縁を貼り合わせて形成したいわゆる「ホイル素材」のバルーン(一般に「マイラーバルーン」とも呼ばれている。)が普及している。なお、ゴム風船は素材が一定の通気性を有しており時間経過により萎み易いため、特にヘリウムを入れて浮遊させるバルーンでは殆ど通気性のない樹脂フィルム製のものが使用されることが多くなっている。 Balloons have been popular as toys and ornaments for many years, but in recent years they have been increasingly used for events such as event ornaments, display ornaments, and promotional novelties. Accordingly, there is an increasing demand for so-called “arrange balloons” that print images of arbitrary designs, photographs, characters, and the like on the surface of the balloons. In particular, for applications such as promotional novelties and gifts, together with conventional rubber balloons and balloons made of resin films such as vinyl chloride, polyester, nylon, etc., the edges of sheets coated with these resin films by aluminum deposition are bonded together. Formed so-called “foil material” balloons (generally also called “mylar balloons”) are in widespread use. Since rubber balloons have a certain level of air permeability and are likely to wither over time, balloons that are floated with helium in particular are often made of a resin film with little air permeability. It has become.
ゴム風船は、膨張の前後での素材の展張率が極めて大きいため、画像の印刷には一般的には弾力性の高いインクによるシルク印刷が用いられる。シルク印刷は明瞭でバルーンの膨張に追従できる画像を印刷可能であるが、製版コストが掛かるため小ロット印刷の場合には経済性の問題があり、多色刷りや写真の印刷にも適していない。また、画像転写シートを用いた乾式転写印刷を行う場合は、ゴム風船を少なくともある程度は膨らませた状態で転写作業を行わなければならず、作業の手間や仕上りの点での問題があった。一方、樹脂フィルムを貼り合わせたバルーン(以下、「貼り合わせバルーン」と記す。)は、原反状態あるいは膨張前の状態で各種の印刷方法が適用可能であるが、製版を要する印刷方法の経済性の問題は同様である。なお、樹脂フィルム製のバルーンには、素材を貼り合わせずに一体成形したものも存在するが、本発明の説明に関しては、便宜上それも含めて「貼り合わせバルーン」と称するものとする。 Since rubber balloons have a very large material expansion ratio before and after expansion, silk printing using highly elastic ink is generally used for image printing. Silk printing is clear and can print an image that can follow the expansion of the balloon. However, since plate-making costs are required, there is an economic problem in the case of small lot printing, and it is not suitable for multicolor printing or photo printing. Also, when performing dry transfer printing using an image transfer sheet, the transfer operation must be performed with the rubber balloon inflated at least to some extent, which has problems in terms of labor and finishing. On the other hand, various printing methods can be applied to a balloon in which a resin film is bonded (hereinafter referred to as “bonded balloon”) in an original fabric state or a state before expansion. The sex issue is similar. In addition, some balloons made of resin film are integrally formed without bonding materials, but for the description of the present invention, they will be referred to as “bonded balloons” for the sake of convenience.
小ロットでのアレンジバルーンの製造には、このほかに、カッティングフィルムで製作した画像をバルーンに貼り付ける方法もある。しかし、カッティングフィルムでの貼付け画像の製作・貼付作業は手間やコストが掛かるだけでなく、基本的に膨張状態のバルーンにしか適用できないため、完成品の輸送において嵩張るだけでなく、バルーンが少しでも萎むとバルーン自体が変形したり、貼り付けたカッティングフィルムがはがれ易くなるという問題点があった。 In addition to this, there is another method for manufacturing an arrangement balloon in a small lot, in which an image made of a cutting film is pasted on the balloon. However, the production and pasting of pasted images with a cutting film is not only labor-intensive and costly, but is basically applicable only to inflated balloons. When deflated, the balloon itself is deformed and the attached cutting film is easily peeled off.
さらに、バルーンは軽量であることが要求される商品であり、ヘリウムを注入して空中に浮遊させることも多いため、画像を印刷する場合、使用するインクは軽量でなければならない。インクの重量が大きいとバルーンが浮遊しにくくなるだけでなく、片面への印刷により浮遊状態のバルーンがインクの重量により傾いてしまうことがあるからである。また、ゴムや樹脂フィルム等のバルーンの素材は極めて薄くて熱に弱く、特にホイル素材の場合は水分によっても表面を傷めてしまうおそれがある。そのため、画像層の重量が大きなシルク印刷やグラビア印刷、熱転写や水転写等の転写印刷はバルーンへの画像印刷に適当ではない。一方、トナー印刷は、溶剤を使用せず、軽量なトナー粒子により画像層を形成する印刷方法であるため、特に塩化ビニル製やホイル素材のバルーンへの画像印刷に好適といえる。 Furthermore, since the balloon is a commodity that is required to be lightweight, helium is often injected and floated in the air. Therefore, when printing an image, the ink to be used must be lightweight. This is because if the weight of the ink is large, the balloon does not easily float, and the balloon in a floating state may be inclined due to the weight of the ink due to printing on one side. In addition, balloon materials such as rubber and resin films are extremely thin and vulnerable to heat, and in the case of foil materials, the surface may be damaged by moisture. Therefore, transfer printing such as silk printing, gravure printing, thermal transfer, and water transfer, in which the image layer is heavy, is not suitable for image printing on a balloon. On the other hand, toner printing is a printing method in which an image layer is formed with light toner particles without using a solvent, and thus can be said to be particularly suitable for image printing on a balloon made of vinyl chloride or a foil material.
図1は、一般的な貼り合わせバルーンを示す略図であり、バルーン本体Bは原反素材から任意の形状にカッティングした2枚の塩化ビニルシートあるいはアルミ蒸着フィルムの縁を熱溶着で貼り合わせて形成して逆止弁Vを設けたものであり、ポンプPを逆止弁Vに挿入し、空気を注入して膨張させる。かかるバルーンはゴム風船ほど素材が伸縮せず表面も円滑であるため、図2のようにトナー印刷によって色彩豊かで精細な画像を印刷できるほか、写真の印刷も可能である。 FIG. 1 is a schematic diagram showing a general bonded balloon, and the balloon body B is formed by bonding the edges of two vinyl chloride sheets or aluminum vapor-deposited films cut into an arbitrary shape from a raw material by heat welding. Thus, the check valve V is provided, and the pump P is inserted into the check valve V, and air is injected to expand it. Such a balloon is not as elastic as a rubber balloon, and the surface thereof is smoother. Therefore, as shown in FIG. 2, in addition to printing a rich and detailed image by toner printing, it is possible to print a photograph.
 従来、貼り合わせバルーンにトナー印刷で画像を付加してアレンジバルーンを製作するためには、原反状態の素材に印刷機でトナー印刷を行った上でこれをカッティングし、熱溶着で貼り合わせていた。このため、一度に印刷できる画像の大きさには制約があるだけでなく、大きなアレンジバルーンを製作する場合には、バルーン表面の広範囲に渡る画像を表裏の素材に分割して印刷する場合があるが、完成時には熱溶着での貼り合わせによって生じた接合線が画像を分断し、画像中に白線を生じるという問題があった。 Conventionally, in order to produce an arrangement balloon by adding an image to a bonding balloon by toner printing, the toner is printed on a raw material with a printing machine and then cut and bonded by thermal welding. It was. For this reason, not only is there a restriction on the size of an image that can be printed at once, but when a large arrangement balloon is manufactured, an image covering a wide area of the balloon surface may be divided into front and back materials and printed. However, at the time of completion, there is a problem in that a joining line generated by bonding by heat welding divides the image and a white line is generated in the image.
また、貼り合わせバルーンはゴム風船に比べれば素材自体の伸縮は小さいものの、空気やガスを注入することで表面が曲面状態に膨張する。この際、平面状態の原反の表面に付着したトナー粒子から成る画像層は、陶磁器の釉薬層に生じる「貫入」の如きひび割れを生じるという問題があった。ひび割れは印刷画像の外観を汚く見せるだけでなく画像層が剥離し易くなってバルーンの商品価値を低下させ、特に人物の顔写真を印刷した場合には、ひび割れにより印象が悪くなるという問題があった。 In addition, the bonded balloon has a smaller expansion and contraction of the material itself than the rubber balloon, but the surface expands into a curved surface by injecting air or gas. At this time, the image layer composed of toner particles adhered to the surface of the flat original fabric has a problem of causing cracks such as “penetration” generated in the glaze layer of the ceramic. Cracks not only make the printed image look dirty but also make the image layer easy to peel off, reducing the commercial value of the balloon, and particularly when printing a human face photo, there is a problem that the impression becomes worse due to cracks. It was.
かかるひび割れは、画像層の伸縮率がバルーンの膨張による素材表面の展張に追従し切れないために生じるものである以上、トナー印刷によって画像層を形成する限り不可避であり、本願発明者の開発したスマートペーパーや前記出願発明のように糊層によって画像層を転写対象物に接着する技術をもってしても、画像層のひび割れを防ぐことは困難であった。 Such cracks are unavoidable as long as the image layer is formed by toner printing as long as the expansion rate of the image layer cannot follow the expansion of the surface of the material due to the expansion of the balloon. Even with a technique for adhering an image layer to an object to be transferred with a glue layer as in the case of smart paper or the invention of the application, it was difficult to prevent cracking of the image layer.
 本発明は、以上のような従来技術の問題を解決するべく考案されたものであり、バルーン、特に貼り合わせバルーンにトナー印刷によって形成した任意の意匠、写真、文字等の画像を転写する画像転写方法であって、バルーンの膨張時に画像層のひび割れによって生じる転写画像の品質の低下を抑制するとともに、バルーン素材の接合線が画像を分断し、画像中に白線を生じることを防ぐことのできる画像転写方法を提供することを課題とする。 The present invention has been devised to solve the above-described problems of the prior art, and image transfer for transferring an image of any design, photograph, character, etc. formed by toner printing on a balloon, particularly a bonded balloon. A method that suppresses deterioration in the quality of a transferred image caused by cracking of an image layer when a balloon is inflated, and prevents a bonding line of a balloon material from dividing the image and generating a white line in the image. It is an object to provide a transfer method.
 上記課題を解決するために、本発明の請求項1に記載した発明は、トナープリンタで印刷した画像をバルーンの表面に転写するための画像転写方法であって、バルーン表面に糊料を塗布して糊層を形成する第1工程と、画像層に対して離型性を有する基材に画像層をトナー印刷して成る画像転写シートの画像層側を糊層に圧着する第2工程と、基材表面をバイブレーターで擦過して画像層を破砕する第3工程と、基材を画像層から剥離する第4工程とから成ることを特徴とする。すなわち、請求項1に係る画像転写方法は、膨張前のホイル素材のバルーンに対して、前述のスマートペーパーを適用した画像転写方法において、基材表面をバイブレーターで擦過して画像層を破砕する第3工程を加えたものである。 In order to solve the above-mentioned problems, the invention described in claim 1 of the present invention is an image transfer method for transferring an image printed by a toner printer to the surface of a balloon, and applying a paste to the balloon surface. A first step of forming an adhesive layer, and a second step of pressing the image layer side of an image transfer sheet formed by toner printing on a substrate having releasability with respect to the image layer to the adhesive layer; It comprises a third step of crushing the surface of the substrate with a vibrator to crush the image layer and a fourth step of peeling the substrate from the image layer. That is, the image transfer method according to claim 1 is the image transfer method in which the above-described smart paper is applied to the balloon balloon before being expanded, and the image layer is crushed by rubbing the surface of the substrate with a vibrator. Three steps are added.
 本願発明者は、バルーンの膨張時に画像層にひび割れが生じることが不可避である点に鑑み、ひび割れを防ぐのではなく、ひび割れが生じても目立たせない、という逆転の発想に至った。すなわち、ひび割れが目立つのは陶磁器の釉薬層の貫入の如くひびの密度が粗いからであり、ひびの密度が目視で判別しにくい程度に細かければ、視覚的な画像層の品位が向上する点に着目したのである。そこで、バルーン表面に圧着転写した画像層にバイブレーターにより振動を加えてトナー粒子同士の結合を破砕しておく工程を追加することで、膨張時に生じるひび割れの密度が細かくなるようにした。 In view of the fact that cracks are inevitably generated in the image layer when the balloon is inflated, the inventor of the present application has come up with the idea of reversal not to prevent cracks but to make them inconspicuous even if cracks occur. In other words, cracks are conspicuous because the crack density is coarse, such as the penetration of a glaze layer in ceramics, and if the crack density is so small that it is difficult to distinguish visually, the quality of the visual image layer is improved. We focused on. Therefore, by adding a step of crushing the bond between the toner particles by applying vibration to the image layer pressure-transferred on the balloon surface by a vibrator, the density of cracks generated during expansion is reduced.
 次に、本発明の請求項2に記載した発明は、トナープリンタで印刷した画像をバルーンの表面に転写するための画像転写方法であって、画像層に対して離型性を有する基材と、糊料から成る糊層と、基材と糊層との間に設けた画像層とから成る画像転写シートの糊層側をバルーン表面に圧着する第1工程と、基材表面をバイブレーターで擦過して画像層を破砕する第2工程と、基材を画像層から剥離する第3工程とから成ることを特徴とする。 Next, an invention described in claim 2 of the present invention is an image transfer method for transferring an image printed by a toner printer to the surface of a balloon, and a substrate having releasability with respect to an image layer; A first step of pressing the adhesive layer side of the image transfer sheet consisting of an adhesive layer made of glue and an image layer provided between the substrate and the adhesive layer to the balloon surface; and rubbing the substrate surface with a vibrator And a second step of crushing the image layer and a third step of peeling the substrate from the image layer.
 請求項2に係る画像転写方法は、本願発明者が出願した前記出願発明に係る画像転写シートを適用した画像転写方法において、同様に基材表面をバイブレーターで擦過して画像層を破砕する第2工程を加えたものである。最終的に転写対象物へ画像転写を行う際に請求項2に記載の構成を有する画像転写シートを用いれば、予めバルーンの表面に糊料を塗布して糊層を形成する工程が省略できる。また、前述のとおり、画像層をトナー印刷で形成するのは、バルーンへの画像転写では軽量化が求められるためであるから、糊層自体も可能な限り薄くかつ均一に形成する必要がある。その点、手作業での糊料の塗布工程が必要なスマートペーパーよりも、予め画像層の裏面に糊層が形成された画像転写シートを適用する方が、糊層の厚みを薄くかつ均一にできるため、より好適である。 The image transfer method according to claim 2 is the image transfer method to which the image transfer sheet according to the invention of the present application filed by the inventor of the present application is applied. Similarly, the image layer is crushed by rubbing the substrate surface with a vibrator. The process is added. When the image transfer sheet having the configuration according to claim 2 is used when finally transferring the image to the transfer object, the step of applying the paste on the surface of the balloon in advance to form the glue layer can be omitted. In addition, as described above, the image layer is formed by toner printing because the image transfer to the balloon requires a reduction in weight. Therefore, the glue layer itself needs to be formed as thin and uniform as possible. In that respect, the thickness of the glue layer is made thinner and more uniform by applying an image transfer sheet with a glue layer formed on the back side of the image layer in advance than smart paper, which requires a manual glue application process. Since it is possible, it is more preferable.
 なお、請求項1、請求項2のいずれの画像転写方法においても、画像層を設けた基材のバルーンへの圧着をコールドラミネーター、すなわち加熱無しのラミネーターを通すことで行っても良い。従来は、バルーン表面に基材の画像層側を位置決めして当接させた後、版画用のバレン等で上から擦過して圧着を行っていたが、基材を被せたバルーンを金属板上に載せた状態でコールドラミネーターを通過させることで、ラミネーターのローラーにより圧着が均一に行えるようになる。これにより、転写画像の品質が向上でき、生産性も向上する。 In any of the image transfer methods according to claims 1 and 2, the base material provided with the image layer may be pressure-bonded to the balloon through a cold laminator, that is, a laminator without heating. Conventionally, the image layer side of the base material is positioned and brought into contact with the surface of the balloon, and then the surface is rubbed from above with a valen for printing, etc., but the balloon covered with the base material is placed on the metal plate. By passing the cold laminator in a state where it is placed on the laminator, the laminator roller can be uniformly pressed. Thereby, the quality of the transferred image can be improved, and the productivity is also improved.
 次に、本発明の請求項3に記載した発明は、請求項1又は2のいずれかに記載のバルーンへの画像転写方法であって、前記画像層が、基材側から順にクリアトナー層、箔層の二層構造を有することを特徴とする。 Next, the invention described in claim 3 of the present invention is the image transfer method to the balloon according to any one of claims 1 or 2, wherein the image layer is a clear toner layer in order from the substrate side, It has a two-layer structure of a foil layer.
 クリアトナーは文字通り透明なトナーであり、一般的に印刷面に光沢を生じさせるために使用される。画像層を基材側から順にクリアトナー層、箔層の二層構造とすることにより、表面のクリアトナー層の下の箔層が透過して見えるため、箔の種類により金、銀、銅、アルミ等の風合いの画像をバルーンに転写することが可能となる。箔は、伝統工芸に用いられる金箔等の代わりに、透明樹脂フィルムに金属成分を蒸着させた既製の箔フィルムを使用することができる。かかる二層構造の画像層の形成は、次の方法で行うことができる。すなわち、まず、基材上に逆像画像をクリアトナーで印刷し、その上に箔フィルムの箔が蒸着された面を貼り付けた状態で基材ごと110℃乃至140℃で加熱可能なラミネーターに通す。クリアトナーは一般的に125℃前後で溶融して箔を融着させるため、冷却後に箔フィルムを基材から剥がすと画像の形状に箔が接着される。一方、クリアトナーのない画像外の部分については箔は接着されず、箔フィルムに残留したまま剥離される。以上の過程により、クリアトナー層、箔層の二層構造から成る画像層が形成されるのである。 Clear toner is literally a transparent toner and is generally used to cause gloss on the printed surface. By making the image layer into a two-layer structure of a clear toner layer and a foil layer in order from the substrate side, the foil layer under the clear toner layer on the surface appears to be transmitted, so depending on the type of foil, gold, silver, copper, An image of a texture such as aluminum can be transferred to the balloon. As the foil, a ready-made foil film obtained by vapor-depositing a metal component on a transparent resin film can be used in place of the gold foil used in traditional crafts. The image layer having such a two-layer structure can be formed by the following method. That is, first, a reverse image is printed on a base material with a clear toner, and a laminator that can be heated at 110 ° C. to 140 ° C. with the base material is attached to the surface on which the foil film is deposited. Pass through. Since the clear toner is generally melted at around 125 ° C. to fuse the foil, when the foil film is peeled off from the substrate after cooling, the foil adheres to the shape of the image. On the other hand, the foil is not adhered to the portion outside the image without the clear toner, and is peeled off while remaining on the foil film. Through the above process, an image layer having a two-layer structure of a clear toner layer and a foil layer is formed.
 ちなみに、箔フィルムを用いずとも、基材上にメタリックトナーで直接画像をトナー印刷することも可能であるが、メタリックトナーを使用できるトナー印刷機は限定される上にメタリックトナー自体も高価であり、また、箔フィルムの方がメタリックトナーよりも画像の仕上りがはるかに高質である。 By the way, it is possible to directly print an image with a metallic toner on a substrate without using a foil film, but the toner printer that can use the metallic toner is limited and the metallic toner itself is expensive. Also, the finish of the image of the foil film is much higher than that of the metallic toner.
 本発明の請求項4に記載した発明は、請求項1又は2のいずれかに記載のバルーンへの画像転写方法であって、前記画像層が、基材側から順にクリアトナー層、有色トナー層、箔層の三層構造を有することを特徴とする。 The invention described in claim 4 of the present invention is the image transfer method to the balloon according to any one of claims 1 or 2, wherein the image layer comprises a clear toner layer and a colored toner layer in order from the substrate side. And having a three-layer structure of a foil layer.
 画像層を基材側から順にクリアトナー層、有色トナー層、箔層の三層構造とすることにより、既製の箔フィルムによる箔の色調を様々に変化させることができる。有色トナー層はクリアトナー層による画像に重なるよう、淡い色調の有色トナーで画像を印刷して設けることができ、箔層を設ける方法は請求項3に記載した発明と同様である。既製の箔フィルムは金箔調、銀箔調、銅箔調、アルミ調など単色のものに限られるが、有色トナー層を印刷して設けることでメタリック調の画像にグラデーションや模様を付加することが可能となる。 The image layer has a three-layer structure of a clear toner layer, a colored toner layer, and a foil layer in order from the base material side, so that the color tone of the foil made of a ready-made foil film can be variously changed. The colored toner layer can be provided by printing an image with a light-colored colored toner so that the colored toner layer overlaps the image formed by the clear toner layer, and the method of providing the foil layer is the same as that of the invention described in claim 3. Ready-made foil films are limited to single color such as gold, silver, copper, and aluminum, but it is possible to add gradations and patterns to metallic images by printing a colored toner layer. It becomes.
 次に、本発明の請求項5に記載した発明は、請求項1乃至4のいずれかに記載のバルーンへの画像転写方法であって、前記糊料の組成を、酢酸ビニル・アクリル酸エステル共重合体エマルジョンに、水性アクリルエマルジョンを10乃至35%添加して成ることを特徴とする。水性アクリルエマルジョンの添加は、糊料の接着力を大きく低下させることなく、硬化時の糊層の弾力性を向上させる効果を奏する。 Next, an invention described in claim 5 of the present invention is the image transfer method to the balloon according to any one of claims 1 to 4, wherein the composition of the paste is made of vinyl acetate / acrylate. It is characterized by adding 10 to 35% of an aqueous acrylic emulsion to a polymer emulsion. The addition of the aqueous acrylic emulsion has the effect of improving the elasticity of the glue layer during curing without greatly reducing the adhesive strength of the glue.
 前述の通り、糊層は可能な限り薄くかつ均一とすることが望ましく、また、使用する糊料は画像層をバルーンの表面に固定して容易には剥離させない接着力を有するととともに、画像転写後の時間経過により固化した後、バルーンを膨張させた際に、その表面の伸張に対応する弾力性を保持することが求められる。バイブレーターの振動によって予め画像層を細かく破砕してあっても、糊層自体がひび割れたり不均等に伸張した場合、やはり画像層のひび割れが容易に目視可能な密度で生じるおそれがあるからである。ここで、糊層の弾力性は添加剤による糊料の改質で実現可能であるが、トナー粒子は、プラスティック樹脂に顔料及びワックス、帯電制御材等を混合したものであり、一般的に油溶性を呈するため、油性の添加剤は使用できない。 As described above, it is desirable that the adhesive layer be as thin and uniform as possible. Further, the adhesive used has an adhesive force that prevents the image layer from being easily peeled off by fixing the image layer to the surface of the balloon. When the balloon is inflated after it has solidified over time, it is required to retain elasticity corresponding to the expansion of the surface. This is because even if the image layer has been finely crushed in advance by vibration of the vibrator, if the glue layer itself is cracked or unevenly stretched, the image layer may still be cracked at a density that is easily visible. Here, the elasticity of the glue layer can be realized by modifying the glue with additives, but the toner particles are made by mixing a plastic resin with a pigment, wax, a charge control material, etc. Oil-based additives cannot be used because they are soluble.
 本願発明者がかかる糊料の組成について試行錯誤を重ねた結果、酢酸ビニル・アクリル酸エステル共重合体エマルジョンに水性アクリルエマルジョンを重量比10乃至35%添加することで好適な結果を得られることが判明した。酢酸ビニル・アクリル酸エステル共重合体エマルジョンは、糊付壁紙等に用いられるいわゆる「エマルジョン糊」の一般的な成分である。一方、アクリルエマルジョンは、アクリル樹脂を分散質、水を分散媒として乳化させたもので、建築用壁材の下地調整に用いられる水性下塗用塗料の一般的な成分である。本願発明者の試行では、水性アクリルエマルジョンの重量比が概ね10%未満では糊層の柔軟性が不足し、概ね35%超では糊層の接着力が不足することを確認している。 As a result of repeated trial and error on the composition of the paste by the present inventor, it is possible to obtain a suitable result by adding an aqueous acrylic emulsion to the vinyl acetate / acrylic acid ester copolymer emulsion at a weight ratio of 10 to 35%. found. Vinyl acetate / acrylic acid ester copolymer emulsion is a common component of so-called “emulsion glue” used for wallpaper with glue. On the other hand, the acrylic emulsion is emulsified using an acrylic resin as a dispersoid and water as a dispersion medium, and is a general component of a water-based undercoating paint used for adjusting the foundation of a building wall material. In the trial of the present inventor, it has been confirmed that when the weight ratio of the aqueous acrylic emulsion is less than about 10%, the adhesive layer has insufficient flexibility, and when it exceeds approximately 35%, the adhesive force of the adhesive layer is insufficient.
また、本発明に係る糊料は適度な弾力性を有するため、バルーン膨張時に画像層のひび割れが目立つ箇所が生じた場合にも、事後的に修復可能である。すなわち、一旦バルーンを排気して萎ませ、画像のひび割れの目立つ箇所に当て布等をした上で、その上から再度バイブレーターで振動を加えて画像層を破砕する。これにより、ひび割れを目立たなくすることができ、画像層が容易に剥離することもない。 In addition, since the paste according to the present invention has appropriate elasticity, it can be repaired afterwards even when a cracked portion of the image layer is noticed when the balloon is inflated. That is, the balloon is once evacuated and deflated, and the image layer is crushed by applying vibration with a vibrator again from above on a place where the crack of the image is conspicuous. Thereby, a crack can be made inconspicuous and an image layer does not peel easily.
 最後に、本発明の請求項6に記載した発明は、請求項1乃至5のいずれかの画像転写方法により画像を転写したことを特徴とするバルーンである。 Finally, the invention described in claim 6 of the present invention is a balloon in which an image is transferred by the image transfer method of any one of claims 1 to 5.
 本発明に係る画像転写方法は、以下のような効果を奏する。すなわち、
(1)糊層により画像をバルーン表面に接着するため、膨張前のバルーンあるいはバルーンの原反にトナー印刷機で直接画像を印刷する方法に比べ画像の耐久性がより高く、精細で発色も鮮明な画像転写が可能となる。また、バルーンを萎ませた場合にも画像が容易には剥落しない。
(2)貼り合わせバルーンに特有の素材の接合線を跨ぐ形で画像を転写できるため、バルーンの膨張時に画像を分断する白線を生じさせない。そのため、大きな画像も高品位で転写可能であり、大型のバルーンへの画像転写も低コストで可能となる。
(3)バルーンの膨張時に画像層に生じるひび割れの密度を細かくできるため転写画像の品位を向上でき、写真の転写には特に好適である。
(4)画像層を基材側から順にクリアトナー層、箔層の二層構造とすることで、メタリック調の高質な画像を低コストで転写可能となる。さらに、画像層をクリアトナー層、有色トナー層、箔層の三層構造とすれば、メタリック調の画像にグラデーションや模様を容易に付加でき、バルーンへの転写画像の表現力を向上できる。

 
The image transfer method according to the present invention has the following effects. That is,
(1) Since the image is adhered to the balloon surface by the glue layer, the durability of the image is higher than the method of printing the image directly on the balloon or the original fabric of the balloon with a toner printer, and the color is fine and clear. Image transfer is possible. Further, even when the balloon is deflated, the image is not easily peeled off.
(2) Since the image can be transferred so as to straddle the bonding line of the material peculiar to the bonded balloon, a white line that divides the image is not generated when the balloon is inflated. Therefore, large images can be transferred with high quality, and image transfer to a large balloon can be performed at low cost.
(3) Since the density of cracks generated in the image layer when the balloon is inflated can be reduced, the quality of the transferred image can be improved, and it is particularly suitable for transfer of photographs.
(4) Since the image layer has a two-layer structure of a clear toner layer and a foil layer in order from the substrate side, a high-quality metallic tone image can be transferred at a low cost. Furthermore, if the image layer has a three-layer structure of a clear toner layer, a colored toner layer, and a foil layer, gradation and a pattern can be easily added to a metallic tone image, and the expressiveness of the image transferred to the balloon can be improved.

(第1実施形態)
 以下、本発明の実施形態について図面に基づいて説明する。図3は、請求項1に記載したスマートペーパーを用いた本発明の第1実施形態に係るバルーンへの画像転写方法の工程を示す断面略図である。第1工程(1)では、バルーンBの表面の画像を転写する位置に、画像よりもやや広い範囲で糊料を塗布し、糊層13を形成する。糊層13に用いる糊料は、酢酸ビニル・アクリル酸エステル共重合体エマルジョンの糊料に、アクリルエマルジョン水性塗料を10乃至35%添加して成るものを用いる。また、糊料は可能な限り薄くかつ均一に塗布する必要がある。次に、第2工程(2)では、スマートペーパー10を糊層13に貼付け、表面から版画用のバレン等で擦過押圧するか、あるいは、前述の通りコールドラミネーターを通すことにより画像層12を接着する。スマートペーパー10は、基材11の裏面にトナー印刷機で鏡像の画像を印刷して画像層12を形成したものである。次に、第3工程(3)では、バイブレーターVを用いて画像層12の部分を均等に擦過しつつ振動を加え、画像層12を破砕する。最後に、第4工程(4)では、スマートペーパー10の基材11をゆっくりと剥離する。この際、基材11は画像層12に対して離型性を有するため、画像層12からはみ出した部分の糊層13は基材11に付着したままバルーンB表面から除去されるが、画像層12は残存して画像転写が完了する。
(First embodiment)
Hereinafter, embodiments of the present invention will be described with reference to the drawings. FIG. 3 is a schematic cross-sectional view showing the steps of an image transfer method to a balloon according to the first embodiment of the present invention using the smart paper described in claim 1. In the first step (1), the glue layer 13 is formed at a position where the image on the surface of the balloon B is transferred, in a range slightly larger than the image. The glue used for the glue layer 13 is obtained by adding 10 to 35% of an acrylic emulsion aqueous paint to a glue of vinyl acetate / acrylate copolymer emulsion. Also, the paste should be applied as thin and as uniform as possible. Next, in the second step (2), the smart paper 10 is adhered to the glue layer 13 and the image layer 12 is adhered by rubbing and pressing from the surface with valen or the like for printing, or through a cold laminator as described above. To do. The smart paper 10 is obtained by printing a mirror image on the back surface of the substrate 11 with a toner printer to form an image layer 12. Next, in the third step (3), the image layer 12 is crushed by applying vibration while uniformly rubbing the portion of the image layer 12 using the vibrator V. Finally, in the fourth step (4), the base material 11 of the smart paper 10 is slowly peeled off. At this time, since the base material 11 has releasability with respect to the image layer 12, the paste layer 13 in a portion protruding from the image layer 12 is removed from the surface of the balloon B while adhering to the base material 11. No. 12 remains and image transfer is completed.
 (第2実施形態)
 図4は、請求項2に記載した画像転写シートを用いた本発明の第2実施形態に係るバルーンへの画像転写方法の工程を示す断面略図である。第1工程(1)では、バルーンBの表面の画像を転写する位置に、画像転写シート20を貼り付ける。画像転写シート20は画像層に対して離型性を有する基材21と、糊料から成る糊層23と、基材と糊層との間に設けた画像層22とから構成されている。糊層23に用いる糊料は、第1実施形態と同様に、酢酸ビニル・アクリル酸エステル共重合体エマルジョンの糊料に、アクリルエマルジョン水性塗料を10乃至35重量%添加して成るものを用いる。貼付け後、表面から版画用のバレン等で擦過押圧するか、あるいは、前述の通りコールドラミネーターを通すことにより画像層22をバルーンB表面に接着する点は、第1実施形態と同様である。なお、画像転写シート20は、基材21の表面にトナー印刷機で逆像の画像を印刷した上で、シート状のセパレータ(図示せず)の表面に糊層を設けて成る糊付きシート(図示せず)の糊層面を貼り付け、その後、セパレータを剥離することにより事前に製作しておくことができる。次に、第2工程(2)では、第1実施形態と同様に、バイブレーターVを用いて画像層22の部分を均等に擦過しつつ振動を加えて画像層22を破砕する。最後に第3工程(3)では、やはり第1実施形態と同様に、スマートペーパー10の基材21をゆっくりと剥離する。この際、基材21は画像層22に対しては離型性を有する一方糊料に対しては易接着性を有するため、画像層22からはみ出した部分の糊層23は基材21に付着したままバルーンB表面から除去されるが、画像層22は残存して画像転写が完了する。
(Second Embodiment)
FIG. 4 is a schematic cross-sectional view showing steps of an image transfer method to a balloon according to a second embodiment of the present invention using the image transfer sheet according to claim 2. In the first step (1), the image transfer sheet 20 is affixed at a position where the image on the surface of the balloon B is transferred. The image transfer sheet 20 includes a base material 21 having releasability with respect to an image layer, a paste layer 23 made of a paste, and an image layer 22 provided between the base material and the paste layer. As in the first embodiment, the glue used for the glue layer 23 is obtained by adding 10 to 35% by weight of an acrylic emulsion aqueous paint to the glue of the vinyl acetate / acrylate copolymer emulsion. After pasting, the image layer 22 is adhered to the surface of the balloon B by rubbing and pressing from the surface with valen for printing, or by passing through a cold laminator as described above, as in the first embodiment. In addition, the image transfer sheet 20 is a sheet with a paste (on which a reverse image is printed on a surface of a base material 21 by a toner printer and a paste layer is provided on the surface of a sheet-like separator (not shown)). The adhesive layer surface (not shown) can be applied, and then the separator can be peeled off to prepare in advance. Next, in the second step (2), as in the first embodiment, the image layer 22 is crushed by applying vibrations while equally rubbing the portion of the image layer 22 using the vibrator V. Finally, in the third step (3), similarly to the first embodiment, the base material 21 of the smart paper 10 is slowly peeled off. At this time, the base material 21 has releasability with respect to the image layer 22, while it has easy adhesiveness with respect to the paste, so that the portion of the paste layer 23 that protrudes from the image layer 22 adheres to the base material 21. While being removed from the surface of the balloon B, the image layer 22 remains and the image transfer is completed.
図5及び図6は、第2実施形態に係る画像転写方法によるバルーンBへの転写画像の品位向上効果を示す比較写真である。写真5A、6Aは、画像転写シート20を用いた画像転写に当りバイブレーターにより画像層22を破砕する第2工程を省略し、転写後のバルーンBを膨張させた状態の画像の状態を示す。一方、写真5B、6Bは、第2工程を実施した場合の画像の状態を示す。比較写真から明らかなとおり、第2工程を省略した場合の画像は一面に陶磁器の貫入状に粗い密度でひび割れが入り、特に濃色の部分では1m以上離れた所からでも容易にひび割れが目視できるほど目立つ状態となる。一方、第2工程を実施した場合の画像は、ひび割れの密度は極めて小さく、明らかに品位が向上している。 5 and 6 are comparative photographs showing the effect of improving the quality of the transferred image onto the balloon B by the image transfer method according to the second embodiment. The photographs 5A and 6A show the state of the image in which the second step of crushing the image layer 22 with a vibrator is omitted in image transfer using the image transfer sheet 20 and the balloon B after transfer is inflated. On the other hand, the photographs 5B and 6B show the state of the image when the second step is performed. As can be seen from the comparative photograph, the image when the second step is omitted is cracked with a coarse density in the shape of a ceramic intrusion on one side, and in particular, the crack can be easily seen from a distance of 1 m or more in the dark portion. It becomes a conspicuous state. On the other hand, the image when the second step is carried out has a very small crack density, and the quality is clearly improved.
図7は、請求項4に記載した発明による画像層の製作工程を示す連続図である。(1)まず、基材表面にトナー印刷機Pにより所望の画像を逆像で基材S上にクリアトナーで印刷してクリアトナー層c1を設ける。(2)次に、クリアトナー層c1に重なる形で画像を有色トナーで印刷して有色トナー層c2を設ける。この際、有色トナーの色は限定されないが淡い色調のトナーを使用することが好適であり、グラデーションや模様を有する画像として印刷しても良い。(3)次に、画像の上に箔フィルムMを被せる。箔フィルムMは、透明樹脂フィルムfの裏面に金属成分を蒸着させて箔層mを形成したものであり、金属成分の種類により金箔調、銀箔調、銅箔調、アルミ調など様々な市販製品を使用できる。(5)次に、箔フィルムMを被せた印刷済の基材SをラミネーターLに通し圧着加熱する。ラミネーターLの温度は110℃乃至140℃が好適である。(6)ラミネーターLを通すことで、箔フィルムMは基材S上に圧着されるとともに、クリアトナー層c1、有色トナー層c2が熱により溶融して画像部分にのみ箔層mが接着される。(7)最後に、箔フィルムMを基材Sから剥がすと、箔層mが画像部分にのみ転写され、画像外の部分は透明樹脂フィルムfに残留したまま除去される。以上の工程により、基材S上にはクリアトナー層c1、有色トナー層c2、箔層mの三層構造の画像層が形成される。なお、上記工程のうち、有色トナー層c2を省略することにより、請求項3に記載の二層構造の画像層が形成される。 FIG. 7 is a continuous view showing a manufacturing process of an image layer according to the fourth aspect of the present invention. (1) First, a desired image is printed as a reverse image on the surface of the base material by the toner printer P on the base material S with the clear toner to provide the clear toner layer c1. (2) Next, the color toner layer c2 is provided by printing the image with the color toner so as to overlap the clear toner layer c1. At this time, the color of the colored toner is not limited, but it is preferable to use a light color toner, and it may be printed as an image having a gradation or a pattern. (3) Next, a foil film M is placed on the image. The foil film M is formed by depositing a metal component on the back surface of the transparent resin film f to form a foil layer m, and various commercial products such as a gold foil tone, a silver foil tone, a copper foil tone, and an aluminum tone depending on the type of the metal component. Can be used. (5) Next, the printed substrate S covered with the foil film M is passed through a laminator L and heated by pressure. The temperature of the laminator L is preferably 110 ° C to 140 ° C. (6) By passing the laminator L, the foil film M is pressure-bonded onto the substrate S, and the clear toner layer c1 and the colored toner layer c2 are melted by heat so that the foil layer m is adhered only to the image portion. . (7) Finally, when the foil film M is peeled off from the substrate S, the foil layer m is transferred only to the image portion, and the portion outside the image is removed while remaining on the transparent resin film f. Through the above steps, an image layer having a three-layer structure of the clear toner layer c1, the colored toner layer c2, and the foil layer m is formed on the substrate S. Note that, by omitting the colored toner layer c <b> 2 in the above steps, an image layer having a two-layer structure according to claim 3 is formed.
図8は、前記工程により形成した画像層を有する画像転写シートをバルーン表面の糊層に圧着する第一実施形態の第2工程を示す断面図である。図9は、同じく前記工程により形成した画像層を有する糊付き画像転写シートをバルーン表面に圧着する第二実施形態の第2工程を示す断面図である。いずれの転写方法によっても、バルーン表面には下から箔層m、有色トナー層c2、クリアトナー層c1の順に三層構造の画像が糊層により接着されて転写される。これにより、箔によるメタリックな風合いの画像を有色トナーの色により色調を自由に変化させたりグラデーションや模様を付加したりすることが可能となり、転写画像の表現力を大幅に拡大できる。また、転写画像の表面はクリアトナー層c1により保護されるため、その耐久性を高めることができる。 FIG. 8 is a cross-sectional view showing a second step of the first embodiment in which an image transfer sheet having an image layer formed by the above step is pressure-bonded to a glue layer on the balloon surface. FIG. 9 is a cross-sectional view showing a second step of the second embodiment in which a glued image transfer sheet having an image layer formed by the above-described step is pressure-bonded to the balloon surface. In any transfer method, an image having a three-layer structure is adhered and transferred onto the balloon surface in the order of the foil layer m, the colored toner layer c2, and the clear toner layer c1 from the bottom. As a result, it is possible to freely change the color tone of the image of the metallic texture by the foil and add a gradation or a pattern depending on the color of the colored toner, thereby greatly expanding the expressive power of the transferred image. Further, since the surface of the transferred image is protected by the clear toner layer c1, the durability can be enhanced.
 以上、本発明に係る画像転写方法の具体的な構成について説明したが、本発明は上記実施形態に限定されるものではなく、本発明の技術的思想の範囲内において改良または改変が可能であり、それらは本発明の技術的範囲に属するものである。 The specific configuration of the image transfer method according to the present invention has been described above. However, the present invention is not limited to the above embodiment, and can be improved or modified within the scope of the technical idea of the present invention. They belong to the technical scope of the present invention.
 本発明によれば、トナー印刷機で印刷可能な画像を、バルーン、特に近年普及が進むホイル素材のバルーンに高品位で転写可能である。また、箔層を含む二層構造、三層構造の画像層を適用すれば、メタリック調の表現力豊かな画像を転写することも可能となる。販促用ノベルティ、イベント用装飾品はもとより、ディスプレイ用装飾品、パーティグッズ、記念品等など、任意のオリジナル画像を小ロットで印刷するアレンジバルーンの需要は増加しており、本発明はかかるアレンジバルーンを低コストかつ高品質で実現可能という点で大きな利用可能性を有するものである。また、本発明に係る画像転写方法は、転写対象物の表面が硬い場合よりも柔らかい場合により好適であるため、画像のひび割れの問題から従来はトナー印刷による画像転写が適用できなかった軟質の樹脂製品等への適用も可能となる点で、利用可能性は大きいものである。 According to the present invention, an image that can be printed by a toner printer can be transferred to a balloon, particularly a balloon made of foil material, which has recently become popular, with high quality. In addition, by applying an image layer having a two-layer structure or a three-layer structure including a foil layer, it is possible to transfer an image having a rich metallic tone. There is an increasing demand for arrangement balloons for printing arbitrary original images in small lots, such as promotional novelties, event decorations, display decorations, party goods, souvenirs, etc. Has great applicability in that it can be realized at low cost and with high quality. In addition, the image transfer method according to the present invention is more suitable when the surface of the transfer object is softer than when the surface of the transfer object is hard. Therefore, a soft resin, to which image transfer by toner printing could not be applied conventionally due to the problem of image cracking The applicability is great in that it can be applied to products and the like.
一般的な貼り合わせバルーンを示す略図である。1 is a schematic diagram showing a general bonded balloon. トナー印刷した画像を転写したバルーンの事例写真である。It is the example photograph of the balloon which transferred the image which carried out toner printing. 本発明の第1実施形態に係る画像転写方法の工程図である。It is process drawing of the image transfer method which concerns on 1st Embodiment of this invention. 本発明の第2実施形態に係る画像転写方法の工程図である。It is process drawing of the image transfer method which concerns on 2nd Embodiment of this invention. 本発明の第2実施形態に係る画像転写方法の効果を示す比較写真である。It is a comparative photograph which shows the effect of the image transfer method which concerns on 2nd Embodiment of this invention. 本発明の第2実施形態に係る画像転写方法の効果を示す比較写真である。It is a comparative photograph which shows the effect of the image transfer method which concerns on 2nd Embodiment of this invention. 三層構造の画像層の製作工程を示す連続図である。It is a continuation figure showing a manufacturing process of an image layer of a three-layer structure. 三層構造の画像層を有する画像転写シートによる第1実施形態の第2工程を示す図である。It is a figure which shows the 2nd process of 1st Embodiment by the image transfer sheet which has an image layer of a three-layer structure. 三層構造の画像層を有する画像転写シートによる第2実施形態の第2工程を示す図である。It is a figure which shows the 2nd process of 2nd Embodiment by the image transfer sheet which has an image layer of a three-layer structure.
   B  バルーン
   V  バイブレーター
   S  基材
   c1 クリアトナー層
   c2 有色トナー層
   M  箔フィルム
   f  透明樹脂フィルム
   m  箔層
   L  ラミネーター
   10 スマートペーパー(第1実施形態) 
   11 基材(第1実施形態)
   12 画像層(第1実施形態)
   13 糊層(第1実施形態)
   20 画像転写シート(第2実施形態)
  21 基材(第2実施形態)
   22 画像層(第2実施形態)
   23 糊層(第2実施形態)
B Balloon V Vibrator S Substrate c1 Clear Toner Layer c2 Colored Toner Layer M Foil Film f Transparent Resin Film m Foil Layer L Laminator 10 Smart Paper (First Embodiment)
11 Substrate (first embodiment)
12 Image layer (first embodiment)
13 Glue layer (first embodiment)
20 Image transfer sheet (second embodiment)
21 Substrate (second embodiment)
22 Image layer (second embodiment)
23 glue layer (second embodiment)

Claims (6)

  1.  トナー印刷機で印刷した画像をバルーンの表面に転写するための画像転写方法であって、バルーン表面に糊料を塗布して糊層を形成する第1工程と、画像層に対して離型性を有する基材に画像層をトナー印刷して成る画像転写シートの画像層側を糊層に圧着する第2工程と、基材表面をバイブレーターで擦過して画像層を破砕する第3工程と、基材を画像層から剥離する第4工程とから成ることを特徴とする、バルーンへの画像転写方法。 An image transfer method for transferring an image printed by a toner printer to the surface of a balloon, the first step of forming a glue layer by applying a paste to the balloon surface, and releasability with respect to the image layer A second step of pressure-bonding the image layer side of the image transfer sheet formed by toner-printing the image layer on a substrate having a paste layer, a third step of rubbing the surface of the substrate with a vibrator and crushing the image layer, A method for transferring an image to a balloon, comprising a fourth step of peeling the substrate from the image layer.
  2.  トナー印刷機で印刷した画像をバルーンの表面に転写するための画像転写方法であって、画像層に対して離型性を有する基材と、糊料から成る糊層と、基材と糊層との間に設けた画像層とから成る画像転写シートの糊層側をバルーン表面に圧着する第1工程と、基材表面をバイブレーターで擦過して画像層を破砕する第2工程と、基材を画像層から剥離する第3工程とから成ることを特徴とする、バルーンへの画像転写方法。 An image transfer method for transferring an image printed by a toner printer to the surface of a balloon, the substrate having releasability with respect to the image layer, a paste layer made of a paste, and the substrate and the paste layer A first step of pressure-bonding the adhesive layer side of the image transfer sheet comprising the image layer provided between and a balloon surface; a second step of rubbing the substrate surface with a vibrator to crush the image layer; and And a third step of peeling off the image layer from the image layer.
  3.  前記画像層は、基材側から順にクリアトナー層、箔層の二層構造を有することを特徴とする、請求項1又は2のいずれかに記載のバルーンへの画像転写方法。 3. The image transfer method to a balloon according to claim 1, wherein the image layer has a two-layer structure of a clear toner layer and a foil layer in order from the substrate side.
  4.  前記画像層は、基材側から順にクリアトナー層、有色トナー層、箔層の三層構造を有することを特徴とする、請求項1又は2のいずれかに記載のバルーンへの画像転写方法。 3. The image transfer method to a balloon according to claim 1, wherein the image layer has a three-layer structure of a clear toner layer, a colored toner layer, and a foil layer in order from the substrate side.
  5.  前記糊料の組成は、酢酸ビニル・アクリル酸エステル共重合体エマルジョンに、水性アクリルエマルジョンを10乃至35重量%添加して成ることを特徴とする、請求項1乃至4のいずれかに記載のバルーンへの画像転写方法。 The balloon according to any one of claims 1 to 4, wherein the composition of the paste is obtained by adding 10 to 35% by weight of an aqueous acrylic emulsion to a vinyl acetate / acrylic ester copolymer emulsion. Image transfer method.
  6.  請求項1乃至5のいずれかの画像転写方法により画像を転写したことを特徴とする、バルーン。 A balloon obtained by transferring an image by the image transfer method according to any one of claims 1 to 5.
PCT/JP2018/002978 2017-03-02 2018-01-30 Method for transferring image onto balloon and balloon WO2018159192A1 (en)

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JP7041785B1 (en) * 2021-10-18 2022-03-24 株式会社アイエヌジー Image foil transfer sheet, image foil transfer sheet manufacturing method, image foil transfer method

Citations (5)

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Publication number Priority date Publication date Assignee Title
JPH02122998A (en) * 1988-11-01 1990-05-10 Dainippon Printing Co Ltd Transfer foil
JP2004042378A (en) * 2002-07-10 2004-02-12 Teicho Ryo Material for manufacturing balloon suitable for ink jet print and printing method thereof
JP2005504650A (en) * 2001-04-20 2005-02-17 スリーエム イノベイティブ プロパティズ カンパニー Inkjet transfer printing method
US20080226761A1 (en) * 2007-03-13 2008-09-18 Teng-Hui Wu Foil balloon for enabling customized design to print on either side and method of manufacturing same
JP3187548U (en) * 2013-09-05 2013-12-05 一郎 末松 Balloon surface transfer sheet

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02122998A (en) * 1988-11-01 1990-05-10 Dainippon Printing Co Ltd Transfer foil
JP2005504650A (en) * 2001-04-20 2005-02-17 スリーエム イノベイティブ プロパティズ カンパニー Inkjet transfer printing method
JP2004042378A (en) * 2002-07-10 2004-02-12 Teicho Ryo Material for manufacturing balloon suitable for ink jet print and printing method thereof
US20080226761A1 (en) * 2007-03-13 2008-09-18 Teng-Hui Wu Foil balloon for enabling customized design to print on either side and method of manufacturing same
JP3187548U (en) * 2013-09-05 2013-12-05 一郎 末松 Balloon surface transfer sheet

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