WO2018092343A1

WO2018092343A1 - Raw water flow path spacer and spiral membrane element provided with same

Info

Publication number: WO2018092343A1
Application number: PCT/JP2017/022819
Authority: WO
Inventors: 友葉岡▲崎▼; 康弘宇田
Original assignee: 日東電工株式会社
Priority date: 2016-11-18
Filing date: 2017-06-21
Publication date: 2018-05-24

Abstract

[Problem] To provide a raw water flow path spacer and a spiral membrane element provided with the same wherein the formation of a concentration polarization layer can be suppressed in a region in the vicinity of a separation membrane in a raw water flow path. [Solution] A raw water flow path spacer 40 is formed by first thread rows M and second thread rows N overlaying each other and is provided alternatingly with a first mesh structure 52 constituted by connecting first square shaped meshes 52a – 52c constituted by the thread rows M, N in the direction of extension of the second thread rows N and a second mesh structure 61 constituted by connecting in the direction of extension of the second thread rows N such that the space between the second thread rows N is smaller than the space between the second thread rows N constituting the first mesh structure 52.

Description

Raw water channel spacer and spiral membrane element provided with the same

The present invention relates to a spiral membrane element that separates components dissolved in a liquid, and more particularly to a raw water channel spacer of a spiral membrane element.

In recent years, attempts have been made to produce ions that are more suitable for beverages by filtering ions, salts, and the like contained in tap water using a separation membrane such as a spiral membrane element.

This spiral membrane element includes a water collecting pipe and a plurality of separation membranes wound around the water collecting pipe. Each separation membrane is formed in a bag shape with the separation membranes overlapped on both sides of a sheet-like permeated water spacer, and in this state, three sides are sealed by means such as adhesion, and the other one side is an open end. . And it is comprised so that the permeated water which flows along a permeated water spacer may flow into a water collection pipe | tube by connecting this open end to a water collection pipe | tube.

Further, a mesh-shaped raw water flow path spacer that forms a flow path of raw water such as tap water is sandwiched between each separation membrane formed in a bag shape. The raw water supplied to the spiral membrane element flows along the raw water flow path spacer, and a part of the raw water permeates the separation membrane to become permeated water and is sent out through the water collecting pipe.

In Patent Document 1, the warp yarn is arranged along the flow direction of the raw water, the weft yarn is arranged in a direction intersecting the flow direction of the raw water, and the weft yarn is formed narrower than the warp yarn, thereby forming a pressure in the raw water flow path. A spiral membrane element having a raw water channel spacer that can reduce loss is disclosed.

JP 2005-305422 A

By the way, as raw water permeates through the separation membrane, ions and salts that cannot permeate the separation membrane remain in the vicinity of the separation membrane on the raw water flow path side. By accumulating the remaining ions and salts in the vicinity of the separation membrane, a concentration layer (hereinafter referred to as a concentration polarization layer as appropriate) having a higher concentration of ions and salts than other regions of the raw water channel is formed. Thereby, since the osmotic pressure in the vicinity of the membrane surface of the separation membrane increases, the amount of permeated water that permeates through the separation membrane decreases, resulting in a problem that permeated water cannot be obtained efficiently from raw water.

Therefore, an object of the present invention is to provide a raw water flow path spacer capable of suppressing the formation of a concentration polarization layer in a region near the separation membrane, and a spiral membrane element provided with the same.

The raw water flow path spacer according to the present invention is sandwiched between a first separation membrane and a second separation membrane wound around a water collection pipe of a spiral type membrane element, and is opposite to a direction parallel to the water collection pipe. A two-layer raw water flow path spacer composed of a first yarn row and a second yarn row that are inclined to each other, and is configured to be continuous in the extending direction of the second yarn row by the first yarn row and the second yarn row. The first mesh structure, the first thread row and the second thread row are connected in the extending direction of the second yarn row, and the second yarn row is larger than the interval between the second yarn rows constituting the first mesh structure. And a second mesh structure configured so that the interval is narrow.

In the raw water flow path spacer according to the present invention, the inclination with respect to the direction parallel to the water collecting pipe of the first yarn row constituting the second mesh structure is parallel to the water collecting pipe of the first yarn row constituting the first mesh structure. It may be configured to be larger than the inclination with respect to.

In the raw water channel spacer according to the present invention, the first mesh structure is configured by alternately arranging the first mesh and the intermediate mesh having a finer mesh than the first mesh, and the second mesh structure includes the intermediate mesh and The second mesh having finer mesh than the intermediate mesh may be alternately arranged.

The spiral element according to the present invention has a water collecting pipe through which permeate flows, a sheet-like permeate spacer, and three sides sealed in a state of being overlapped on both sides of the permeate spacer, and the other side is an open end. A certain bag shape is formed, and includes a first separation membrane and a second separation membrane wound around the water collection pipe in a state where the open end is connected to the water collection pipe, and a raw water flow path spacer according to any of the above inventions. Is.

According to the raw water flow path spacer of the present invention, the first mesh structure and the second mesh structure are alternately arranged and extend in the inclined direction with respect to the direction parallel to the water collecting pipe. Here, the second mesh structure is formed such that the interval between the second yarn rows is narrower than that of the first mesh structure. For this reason, when raw water flows along the parallel direction, the first mesh structure adjacent to the downstream side from the second mesh structure rather than the flow rate of the raw water flowing into the second mesh structure adjacent to the downstream side from the first mesh structure. The flow rate of raw water flowing into the river becomes larger. As a result, the flow rate of the raw water flowing through the first mesh structure increases, and the momentum of the raw water flow flowing downstream while meandering toward the first separation membrane or the second separation membrane around the mesh structure can be increased. On the other hand, since the second mesh structure has a narrower interval between the second yarn rows than the first mesh structure, the same water flow as the first mesh structure can be maintained even if the raw water flow rate is small. As a result, ions and salts remaining in the vicinity of both separation membranes around the first mesh structure and the second mesh structure can be pushed downstream to suppress the formation of the concentration polarization layer.

According to the spiral membrane element of the present invention, in the raw water flow path spacer, the second mesh structure is formed so that the interval between the second yarn rows is narrower than the first mesh structure. The first mesh structure and the second mesh structure extend in a direction inclined with respect to a direction parallel to the water collecting pipe and are alternately arranged. For this reason, when raw water flows along the parallel direction, the first mesh structure adjacent to the downstream side from the second mesh structure rather than the flow rate of the raw water flowing into the second mesh structure adjacent to the downstream side from the first mesh structure. The flow rate of raw water flowing into the river becomes larger. Thereby, the flow rate of the raw water flowing through the first mesh structure increases, and the flow rate of the raw water flow flowing downstream while meandering toward the first separation membrane or the second separation membrane around the mesh structure can be increased. On the other hand, since the second mesh structure has a narrow interval between the second yarn rows, it is possible to maintain the same level of water force as the first mesh structure even if the raw water flow rate is small. As a result, ions and salts remaining in the vicinity of both separation membranes around the first mesh structure and the second mesh structure can be pushed downstream to suppress the formation of the concentration polarization layer.

FIG. 1 is a schematic configuration diagram of a filtration apparatus to which a spiral membrane element according to an embodiment of the present invention is applied. FIG. 2 is a perspective view including a part of the spiral membrane element shown in FIG. 1 in a developed state and a partially enlarged view showing the configuration of the raw water flow path spacer included in the part. FIG. 3 is a perspective view showing the configuration of the raw water flow path spacer sandwiched between the first and second separation membranes shown in FIG. 2 and partially including a cross-sectional view thereof. FIG. 4 is a perspective view showing the raw water flow formed by the raw water flow path spacer sandwiched between the first and second separation membranes shown in FIG. 2 and the target region of the fluid analysis simulation. FIG. 5A is an isoline diagram showing a distribution state of shear stress acting on the first separation membrane shown in FIG. FIG. 5B is an isoline diagram showing a distribution state of shear stress acting on the second separation membrane shown in FIG. Fig.6 (a) is a figure which shows the structure of the raw | natural water flow path spacer which is a comparative example. FIG. 6B is an isoline diagram showing the result of calculating the shear stress that the raw water flowing in the X direction shown in FIG. 6A acts on the first separation membrane by the fluid analysis simulation. FIG. 6C is an isoline diagram showing the result of calculating the shear stress acting on the second separation membrane shown in FIG. 6A by fluid analysis simulation, as in FIG. 6B. FIG. 7 is a diagram showing the results of determining the area ratio of the easily polarized regions in both separation membranes in the raw water flow path spacers of Modifications 1 to 4 by fluid analysis simulation. FIG. 8A is a diagram showing a configuration of the first mesh structure and the second mesh structure in the raw water flow path spacer of the first modification. FIG. 8B is a diagram showing the configuration of the first mesh structure and the second mesh structure in the raw water flow path spacer of the second modification. FIG. 8C is a view showing the configuration of the first mesh structure and the second mesh structure in the raw water flow path spacer of the third modification. FIG. 8D is a view showing the configuration of the first mesh structure and the second mesh structure in the raw water flow path spacer of Modification 4. FIG. 9 is a diagram showing the results of obtaining the area ratio of the easily polarized regions in both separation membranes in the raw water flow path spacers of Modifications 5 to 9 by fluid analysis simulation. FIG. 10A is a diagram showing the configuration of the first mesh structure and the second mesh structure in the raw water flow path spacer of the fifth modification. FIG. 10B is a view showing the configuration of the first mesh structure and the second mesh structure in the raw water flow path spacer of Modification 6. FIG. 10C is a view showing the configuration of the first mesh structure and the second mesh structure in the raw water flow path spacer of Modification 7. FIG. 10 (d) is a diagram showing the configuration of the first mesh structure and the second mesh structure in the raw water flow path spacer of Modification 8. FIG. 10 (e) is a diagram showing the configuration of the first mesh structure and the second mesh structure in the raw water flow path spacer of Modification 9. FIG. 11 is a diagram illustrating a configuration of the raw water flow path spacer according to the tenth modification. FIG. 12 is a perspective view showing a configuration of a raw water flow path spacer sandwiched between the first separation membrane and the second separation membrane shown in FIG. FIG. 13 is a diagram illustrating the configuration of the raw water flow path spacer of the eleventh modification. FIG. 14 is a diagram illustrating a configuration of a raw water flow path spacer according to Modification 12. FIG. 15A is a perspective view showing an internal configuration with a part of the configuration of an evaluation cell used for evaluation of concentration polarization omitted. FIG. 15B is a diagram showing the configuration of the test specimen of the raw water flow path spacer installed inside the evaluation cell. FIG. 15C is a diagram in which the outer shape is indicated by a virtual line and the flow path component is a solid line to show the flow path configuration formed inside the evaluation cell. FIG. 16A is a graph showing a relationship between a concentration ratio in an evaluation test using a specimen of each separation membrane and a measured value of pure water volume flux when the concentration ratio is measured. FIG.16 (b) is a table | surface which shows the measured value of the concentration ratio and the pure water volume flux in the evaluation test using the test body of each separation membrane shown to the same figure (a).

Hereinafter, a filtration apparatus including a spiral membrane element according to an embodiment of the present invention will be described with reference to the drawings. In the following description, the “X” direction indicates a direction parallel to the axial direction of the water collecting pipe, and the “Y” direction and the “Z” direction indicate the radial direction of the water collecting pipe orthogonal to each other.

As shown in FIG. 1, the filtration device 10 includes a raw water tank 12 that stores raw water such as tap water, and a spiral membrane element 20 that performs a filtering process on the raw water. For example, raw water is supplied to the raw water tank 12 via a supply pipe L1. The raw water tank 12 is connected to a water supply pipe L <b> 2 that sends raw water to the spiral membrane element 20. A pump 14 for pumping raw water from the raw water tank 12 and a pretreatment unit 16 for removing turbid components contained in the raw water are installed in the water supply pipe L2. The raw water treated by the pretreatment unit 16 is sent out to the spiral membrane element 20 through the water supply pipe L2. Further, a bypass pipe L2-B is connected to the downstream side of the pump 14 in the water supply pipe L2. The bypass pipe L2-B has a role of adjusting the raw water flow rate sent to the pretreatment unit 16 by returning a part of the raw water flowing through the water supply pipe L2 to the raw water tank 12.

The spiral membrane element 20 has a function of generating permeated water from which ions and salts are removed from raw water and concentrated water containing the removed ions and salts. The permeated water generated by the spiral membrane element 20 is stored in the permeated water tank 18 via the permeated water pipe L3, and the concentrated water is discharged to the outside via the concentrated water pipe L4.

FIG. 2 is a perspective view showing a part of the spiral membrane element 20 in a developed state, and a diagram showing the configuration of the raw water flow path spacer sandwiched between the first separation membrane and the second separation membrane included in the element. .

As shown in FIG. 2, the spiral membrane element 20 includes a water collecting pipe 22 through which permeated water flows, a first separation membrane 24 and a second separation membrane 28 that are wound around the water collecting pipe 22 in a superposed manner. Is provided. The spiral membrane element 20 includes a raw water passage spacer 40 that is sandwiched between the

separation membranes

24 and 28 and forms a raw water passage between the

separation membranes

24 and 28. Since the first separation membrane 24 and the second separation membrane 28 have the same configuration, only the configuration of the first separation membrane 24 will be described below.

The first separation membrane 24 is formed into a bag shape by superposing

separation membranes

24a and 24b made of, for example, a reverse osmosis membrane, an ultrafiltration membrane, or a microfiltration membrane on both sides with a permeated water spacer 26 therebetween. The open end is connected to the water collecting pipe 22. The permeated water spacer 26 forms a flow path communicating with the water collecting pipe 22, and permeated water that has passed through the

separation membranes

24 a and 24 b flows into the water collecting pipe 22 along the flow path.

The water collecting pipe 22 is provided with a plurality of

communication holes

22a, 22b, and 22c at a predetermined pitch along the axial direction, and the permeated water that has permeated through the

separation membranes

24 and 28 passes through the water collecting pipes 22a to 22c. 22 flows in. The other three sides of the first separation membrane 24 except for the open end are sealed with an adhesive or the like to prevent mixing of permeated water and concentrated water.

As shown in FIG. 2, a part of the raw water flowing through the raw water flow path becomes permeated water from which turbid components such as ions and salts have been removed by passing through either one of the

separation membranes

24 and 28, and the permeated water. The water is guided to the water collecting pipe 22 along the water spacer 26. Further, the remaining raw water becomes concentrated water containing a large amount of turbid components removed from the permeated water as it flows along the raw water flow path, and is discharged to the downstream concentrated water pipe L4 (see FIG. 1).

The spiral membrane element 20 may be provided with an upstream cap material 32 and a downstream cap material 34 attached to both end surfaces in the axial direction. The upstream cap member 32 is provided with a gap for the raw water to flow into the spiral membrane element 20. Further, the downstream cap member 34 is provided with two flow paths so that the permeate flowing through the water collecting pipe 22 and the concentrated water discharged from the raw water flow path do not mix.

Subsequently, the configuration of the raw water flow path spacer 40 will be described with reference to FIGS. 2 and 3. FIG. 3 is a perspective view showing the configuration of the raw water flow path spacer 40 sandwiched between the first separation membrane 24 and the second separation membrane 28.

As shown in FIGS. 2 and 3, the raw water passage spacer 40 is a raw water passage spacer having a two-layer structure in which the first yarn row M and the second yarn row N are overlapped with each other. Are fixed in a laminated state. The raw water flow path spacer may be in a state in which the yarn rows M and N are knitted together. The raw water flow path spacer 40 includes

first mesh structures

51, 52, and 53 and

second mesh structures

61, 62, and 63 alternately. Since the first mesh structures 51 to 53 have the same configuration, only the first mesh structure 52 will be described in the following description.

As shown in FIG. 3, the first mesh structure 52 is formed by connecting the first

square meshes

52a, 52b, 52c in the extending direction of the second yarns N2, N3. Since the first quadrangular meshes 52a to 52c have the same configuration, only the first quadrangular mesh 52a will be described below.

The first side part 52a-1 and the second side part 52a-2 in the first square mesh 52a are formed by the first yarns M1 and M2, respectively, and the third side part 52a-3 and the fourth side part 52a-. 4 is formed by the second yarns N2 and N3. As an example, the first quadrangular mesh 52a has a square external shape configured such that the dimensions of the side portions 52a-1 to 52a-4 are 3 mm. Each of the yarn rows M and N is arranged so as to be inclined in the opposite direction, for example, 45 ° with respect to the X direction. Each yarn row M, N is formed of a resin material such as polyester, polyethylene, or polypropylene, for example, in a cylindrical shape having a diameter D of 0.4 mm. And the width E of the raw | natural water flow path formed of the raw | natural water flow path spacer 40 is 0.8 mm as an example. Moreover, the shape of each thread row | line | column M and N is not restricted to a column shape, For example, you may form in flat form.

Since the second mesh structures 61 to 63 have the same configuration, only the second mesh structure 61 will be described, and description of the

second mesh structures

62 and 63 will be omitted as appropriate. The second mesh structure 61 is formed by connecting second

rectangular meshes

61a, 61b, 61c having the same configuration in the extending direction of the second yarns N1, N2.

The first side 61a-1 and the second side 61a-2 of the second quadrangular mesh 61a are formed by the first yarns M1 and M2, respectively, and the third side 61a-3 of the second quadrangular mesh 61a. Is formed by the second thread N1. The fourth side portion of the second quadrangular mesh 61a is constituted by the third side portion 52a-3 in the first quadrangular mesh 52a described above. For example, the second quadrangular mesh 61a may be formed in a parallelogram shape with the dimensions of the side portions 61a-1, 61a-2, 61a-3 being 3 mm.

Here, the inclination angle α1 of the first side portion 61a-1 and the second side portion 61a-2 with respect to the X direction is the first side portion 52a-1 and the second side portion 52a-2 of the first square mesh 52a. The first yarns M1, M2 are bent so as to be larger than the inclination angle α2 with respect to the X direction. As an example, the inclination angle α1 may be 90 ° and the inclination angle α2 may be 45 °. The distance R1 between the two side portions 61a-1 and 61a-2 in the second square mesh 61a is equal to the distance between the two side portions 52a-1 and 52a-2 in the first square mesh 52a (that is, the third side portion). 52a-3)).

Similarly, the interval R2 between both sides 52a-3 and 61a-3 in the second quadrangular mesh 61a is equal to the interval between both sides 52a-3 and 52a-4 in the first quadrilateral mesh 52a (ie, the first side It is formed so as to be narrower than the length of the portion 52a-1.

Thereby, the second quadrangular mesh 61a is configured to have finer eyes than the first quadrangular mesh 52a (i.e., the surrounding area is small), and the resistance that the raw water flowing in the X direction receives from the flow path (hereinafter referred to as the following) (Denoted as channel resistance). Accordingly, the second mesh structure 61 configured by connecting the meshes having the same configuration as the second quadrangular mesh 61a is the first mesh configured by connecting the meshes having the same configuration as the first quadrangular mesh 52a. The channel resistance is larger than that of the structure 52.

Here, the raw water flow in each of the

mesh structures

52, 61, 62 will be described with reference to FIG. FIG. 4 is a view showing the raw water flow formed by the raw water flow path spacer 40 and the simulation region T as in FIG. The simulation region T is a region surrounded by virtual lines T1 to T4, and the virtual line T1 connects the center point of the second quadrangular mesh 61a and the center point of the second quadrangular mesh 61b. This is an intermediate line between the second yarn N1 and the second yarn N2. The imaginary line T3 is an intermediate line between the second thread N3 and the second thread N4 that connects the center point of the second square mesh 62a and the center point of the second square mesh 62b. The virtual line T2 is an intermediate line between the first yarn M2 and the first yarn M3 that connects the center point of the second quadrangular mesh 61b and the center point of the second quadrangular mesh 62b. The virtual line T4 is an intermediate line between the first yarn M1 and the first yarn M2 that connects the center point of the second square mesh 61a and the center point of the second square mesh 62a.

The extending direction of each

mesh structure

52, 61, 62 is inclined with respect to the X direction as shown in FIG. Therefore, the raw water flows downstream while passing through the second mesh structure 61, the first mesh structure 52, and the second mesh structure 62 in this order. This point will be described with reference to an example of raw water flow in each of the quadrilateral meshes 52a, 61a, and 62a constituting a part of each

mesh structure

52, 61, and 62.

The quadrangular meshes 52a, 61a, and 62a are adjacently arranged in the order of the second quadrangular mesh 61a, the first quadrangular mesh 52a, and the second quadrangular mesh 62a from the upstream side in the X direction. In the second quadrangular mesh 61a, part of the raw water flows into the first quadrangular mesh 52a while meandering toward the second separation membrane 28 along the flow C1. Thereby, the flow rate of the raw water in the region close to the second separation membrane 28 can be increased, and residual ions and salts staying in the region close to the second separation membrane 28 can be pushed downstream.

Similarly, in the first square mesh 52a, a part of the raw water flows into the second square mesh 62a while meandering along the flow C2 toward the second separation membrane 28. Thereby, residual ions and salts staying in a region close to the second separation membrane 28 can be pushed downstream.

Further, as described above, the second quadrangular meshes 61a and 62a that respectively constitute part of the

second mesh structures

61 and 62 are the first quadrangular mesh that constitute part of the first mesh structure 52. The channel resistance is larger than 52a. Therefore, as shown in FIG. 4, the flow rate Q1 flowing from the second quadrangular mesh 61a along the flow C1 into the first quadrangular mesh 52a is changed from the first quadrangular mesh 52a to the flow C2. The flow rate Q2 is larger than the flow rate Q2 flowing out to the second quadrangular mesh 62a. Then, the flow rate of the raw water flowing from the first square mesh 52a to the downstream first square mesh 52b is increased by the flow rate Q3 which is the difference between the flow rate Q1 and the flow rate Q2. In this way, the raw water flow rate in the first mesh structure 52 increases, and the raw water flow rate in the

second mesh structures

61 and 62 decreases.

For this reason, the first separation membrane 24 flows along the flow S1, S2, S3 around the sides 52a-2, 61a-2, 62a-2 (see FIG. 3) of the respective

square meshes

52a, 61a, 62a. Of the raw water flow that flows while meandering, the flow rate of the raw water flow S1 in the first mesh structure 52 can be increased. As a result, the flow rate of the raw water in the vicinity region of the first separation membrane 24 surrounded by the first mesh structure 52 can be increased, and residual ions and salts staying in the region can be pushed downstream.

On the other hand, the flow rates of the raw water flows S2 and S3 in the second square meshes 61a and 62a are smaller than the flow rate of the flow S1, respectively. However, the interval R1 (see FIG. 3) between the first yarns M1 and M2 in the second quadrilateral meshes 61a and 62a is the interval between the first yarns M1 and M2 in the first quadrilateral mesh 52a, that is, the third side. The portion 52a-3 is configured to be narrower than the length (see FIG. 3). For this reason, as described above, even if the raw water flow rate in the raw water flows S2 and S3 decreases from the raw water flow S1, the same flows S2 and S3 are maintained at a high flow velocity, and the same as the first square mesh 52a. The degree of water is maintained. For this reason, the flow rate of the raw water in the vicinity region of the first separation membrane 24 surrounded by the

second mesh structures

61 and 62 can be increased, and residual ions and salts staying in the region can be pushed downstream.

FIG. 5 (a) is an isoline diagram showing the results of the fluid analysis simulation for the magnitude of the shear stress that the raw water acts on the first separation membrane 24 in the region T shown in FIG. FIG. 5B is an isoline diagram showing the result of obtaining the magnitude of the shear stress acting on the second separation membrane 28 in the region T by the fluid analysis simulation as in FIG. Here, it means that the larger the magnitude of the shear stress acting on each

separation membrane

24, 28, the larger the action of the raw water that pushes residual ions and salts from the region close to each

separation membrane

24, 28. On the other hand, the smaller the shear stress acting on each

separation membrane

24, 28, the smaller the action of the raw water to push residual ions and salts from the area close to each

separation membrane

24, 28. In the fluid analysis simulation, the flow rate of the raw water flowing into the region T along the X direction is 0.162 m / s.

As shown in FIG. 5A, in the region of the first separation membrane 24 surrounded by the first square meshes 52a and 52b, the raw water meandering around the second side 52a-2 (see FIG. 3). It can be seen that a strong shear stress similar to that in the region of the first separation membrane 24 surrounded by the second

quadrangular meshes

61a, 61b, 62a, 62b acts in a wide range.

Further, the flow of raw water in the region where the magnitude of the shear stress acting on each

separation membrane

24, 28 is 0.75 Pa or less, that is, the region adjacent to each

separation membrane

24, 28 is gentle, and the raw water pushes away residual ions and salts. The ratio of the area occupied by the region having a small effect on the surfaces of the

separation membranes

24 and 28 was 16%. In the following description, a region where the above-described shear stress magnitude is 0.75 Pa or less is referred to as an easily polarized region. Furthermore, the average value of the shear stress acting on both

separation membranes

24 and 28 shown in FIGS. 5A and 5B is 3.3 Pa.

FIG. 6A is a diagram showing a configuration of a raw water flow path spacer 300 which is a comparative example. FIG. 6B is an isoline diagram showing the result of obtaining the magnitude of the shear stress acting on the first separation membrane 24 in the region U shown in FIG. FIG. 6C is an isoline diagram showing a distribution state of shear stress acting on the second separation membrane 28 in the region U shown in FIG. In FIG. 6B and FIG. 6C, the flow rate of the raw water flowing into the region U along the X direction is set to 0.162 m / s.

As shown in FIG. 6A, the raw water flow path spacer 300 is formed by laminating a yarn row V including yarns V1, V2, and V3 and a yarn row W including yarns W1, W2, and W3 so as to be orthogonal to each other. The mesh structure 310 is formed. The mesh structure 310 includes

quadrilateral meshes

310a, 310b, 310c, and 310d having the same configuration as the first quadrilateral mesh 52a. Note that the region U is a region surrounded by an imaginary line connecting the center points of the square meshes 310a to 310d.

As shown in FIGS. 6B and 6C, the shear stress acting on the region surrounded by the region U of both

separation membranes

24 and 28 is about 8 Pa at the maximum. Further, the ratio of the area of the easily polarized regions formed in both

separation membranes

24 and 28 to the surfaces of both

separation membranes

24 and 28 is 20%.

Thus, in the raw water flow path spacer 300 of the comparative example, the large shear stress does not act on both

separation membranes

24 and 28 unlike the raw water flow passage spacer 40 of this embodiment, and both separation membranes 24, The area ratio of the easily polarized region formed in the layer 28 is also relatively high at 20%. For this reason, ions and salts remaining in the region adjacent to both

separation membranes

24 and 28 cannot be sufficiently washed away.

Moreover, although it is conceivable to use a raw water flow path spacer composed only of the

second mesh structures

61, 62, 63, in this case, a pressure loss caused by the raw water flow path spacer becomes excessive. For this reason, there is also a problem that the raw water flow path spacer is pushed downstream and a telescope phenomenon occurs.

On the other hand, in the raw water flow path spacer 40 of the present embodiment, the

first mesh structures

51, 52, 53 and the second mesh structure 61, the raw water flowing in the X direction is more difficult to pass than the first mesh structures 51-53. 62 and 63 are alternately arranged. Therefore, for example, the flow rate of raw water flowing from the second quadrangular mesh 61a in the second mesh structure 61 into the first quadrangular mesh 52a in the first mesh structure 52 can be increased. As a result, shear stress equivalent to that of both

separation membranes

24 and 28 in the region surrounded by the second quadrangular mesh 61a is applied to both

separation membranes

24 and 28 in the region surrounded by the first quadrangular mesh 52a. be able to.

As a result, according to the raw water flow path spacer 40, it is possible to suppress the formation of the concentration polarization layer by washing away ions and salts remaining in the vicinity of both

separation membranes

24 and 28 while preventing an increase in pressure loss.

In addition, according to the raw water flow path spacer 40, a large shear stress can be applied to both the

separation membranes

24 and 28, so that both the

separation membranes

24 and 28 are clogged with a substance derived from a bacterial body such as a biofilm. It is also possible to suppress the occurrence of biofouling that becomes a state.

Subsequently, modified examples of the raw water flow path spacer in the present embodiment will be described with reference to FIGS. In the following description, parts that have the same configuration as the raw water flow path spacer 40 in the above embodiment are denoted by the same reference numerals as those in the above embodiment, description thereof is omitted as appropriate, and only parts having different configurations are described. To do.

In Table 1 shown in FIG. 7, in the raw water flow path spacers of Modifications 1 to 4 in which the magnitude of the inclination angle α1 in the first mesh structure is changed, the ratio of the area that the easily polarized region occupies in both

separation membranes

24 and 28 Shows the results obtained by fluid analysis simulation. FIGS. 8A to 8D show the first rectangular mesh in the first mesh structure and the second rectangular shape in the second mesh structure in each of the raw water flow path spacers of Modifications 1 to 4. It is a figure which shows the shape of a mesh typically. In FIGS. 8A to 8D, the flow rate of the raw water flowing into the region T (see FIG. 3) along the X direction is set to 0.162 m / s. Each of the raw water flow path spacers 70, 80, 90, 100 shown in FIGS. 8A to 8D is different from the raw water flow path spacer 40 of the above embodiment in the configuration of the second square mesh. Except for the same configuration.

As shown in FIG. 8A, the raw water flow path spacer 70 of Modification 1 is provided such that the inclination angle α1 of the second quadrangular mesh 71a constituting the second mesh structure 71 is 50 °. This is different from the configuration of the raw water flow path spacer 40 in the above embodiment. As shown in FIG. 7, according to the raw water flow path spacer 70, the area ratio of the easily polarized region to the surfaces of both

separation membranes

24 and 28 is 19%.

As shown in FIG. 8B, the raw water flow path spacer 80 of Modification 2 is provided so that the inclination angle α1 of the second square mesh 81a constituting the second mesh structure 81 is 85 °. This is different from the configuration of the raw water flow path spacer 40 in the above embodiment. Further, as shown in FIG. 7, according to the raw water flow path spacer 80, the area ratio of the easily polarized region to the surfaces of both

separation membranes

24 and 28 is 17%.

As shown in FIG. 8C, the raw water flow path spacer 90 of Modification 3 is provided such that the inclination angle α1 of the second quadrangular mesh 91a constituting the second mesh structure 91 is 95 °. This is different from the configuration of the raw water flow path spacer 40. Further, as shown in FIG. 7, according to the raw water flow path spacer 90, the area ratio of the easily polarized region to the surfaces of both

separation membranes

24 and 28 is 15%.

As shown in FIG. 8D, the raw water channel spacer 100 of the fourth modification is provided so that the inclination angle α1 of the second quadrangular mesh 101a constituting the second mesh structure 101 is 120 °. It differs from the structure of the said raw | natural water flow path spacer 40 by the point. Further, as shown in FIG. 7, according to the raw water flow path spacer 100, the area ratio of the easily polarized region to the surfaces of both

separation membranes

24 and 28 is 10%.

Further, if the inclination angle is made larger than the inclination angle α1 of the raw water flow path spacer shown in the modified example 4, the first mesh structure and the second mesh structure interfere with each other, making it difficult to manufacture. For this reason, the inclination angle α1 is preferably set to a size of 120 ° or less.

As described above, also in the configurations of the first to fourth modifications, the formation of the concentration polarization layer can be suppressed as in the raw water flow path spacer 40 in the above embodiment.

Table 2 shown in FIG. 9 shows easy polarization that occupies the surfaces of both

separation membranes

24 and 28 in the raw water flow path spacers of Modifications 5 to 9 in which the composition ratios of the first mesh structure 51 and the second mesh structure 61 are changed. The result of having obtained the area ratio of the area | region by the fluid analysis simulation similarly to the raw | natural water flow path spacer 40 of the said embodiment is shown. In the fluid analysis simulation shown in the figure, the flow rate of the raw water flowing along the X direction is set to 0.162 m / s. FIGS. 10 (a) to 10 (e) are diagrams schematically showing the configuration of the raw water flow path spacer in the case of modifications 5 to 9. FIG.

The raw water flow path spacer 110 of Modification 5 includes first mesh structures 112 and second mesh structures 114 shown in FIG. The first mesh structure 112 is configured by arranging two first

quadrangular meshes

112a and 112b in the extending direction of the first yarns M11 and M12 constituting the first yarn row M10. The first

quadrangular meshes

112a and 112b have the same configuration as the first quadrangular mesh 52a. The second mesh structure 114 has the same configuration as the second mesh structure 61. As shown in FIG. 9, in the raw water flow path spacer 110, the area ratio of the easily polarized region occupying the surfaces of both

separation membranes

24 and 28 is 18%.

The raw water flow path spacer 120 of the modified example 6 includes first mesh structures 122 and second mesh structures 124 shown in FIG. The first mesh structure 122 is configured by arranging three first

rectangular meshes

122a, 122b, 122c in the extending direction of the first yarns M21, M22 constituting the first yarn row M20. The first quadrangular meshes 122a to 122c have the same configuration as the first quadrangular mesh 52a. The second mesh structure 124 has the same configuration as the second mesh structure 61. As shown in FIG. 9, in the raw water channel spacer 120, the area ratio of the easily polarized region occupying the surfaces of both

separation membranes

24 and 28 is 19%.

The raw water flow path spacer 130 of the modified example 7 is alternately provided with the first mesh structure 132 and the second mesh structure 134 shown in FIG. The first mesh structure 132 is configured by arranging two first square meshes 132a and 132b in the extending direction of the yarns M31 and M32 constituting the first yarn row M30. The first

quadrangular meshes

132a and 132b have the same configuration as the first quadrangular mesh 52a. The second mesh structure 134 is configured by arranging two second

rectangular meshes

134a and 134b in the extending direction of the first yarns M31 and M32 constituting the first yarn row M30. As shown in FIG. 9, in the raw water channel spacer 130, the area ratio of the easily polarized region in the surfaces of both

separation membranes

24 and 28 is 16%.

The raw water flow path spacer 140 of the modified example 8 is alternately provided with the first mesh structure 142 and the second mesh structure 144 shown in FIG. The first mesh structure 142 has the same configuration as the first mesh structure 51. The second mesh structure 144 is configured by arranging two second square meshes 144a and 144b in the extending direction of the first yarns M41 and M42 constituting the first yarn row M40. The configuration of the second quadrangular meshes 144a and 144b is the same as that of the second quadrangular mesh 61a. As shown in FIG. 9, in the raw water flow path spacer 140, the area ratio of the easily polarized region occupying the surfaces of both

separation membranes

24 and 28 is 15%.

The raw water flow path spacer 150 of the modification 9 is alternately provided with a first mesh structure 152 and a second mesh structure 154 shown in FIG. The first mesh structure 152 has the same configuration as the first mesh structure 51. The second mesh structure 154 is configured by arranging three second

square meshes

154a, 154b, and 154c in the extending direction of the first yarns M51 and M52 constituting the first yarn row M50. In this raw water flow path spacer 150, the area ratio of the easily polarized region occupying the surfaces of both

separation membranes

24 and 28 is 14%.

As described above, also in the configurations of the modified examples 5 to 9, the formation of the concentration polarization layer can be suppressed similarly to the raw water flow path spacer 40 in the above embodiment.

FIG. 11 is a diagram showing a configuration of the raw water flow path spacer 160 of the tenth modification. FIG. 12 is an enlarged view showing the configuration of the first mesh structure and the second mesh structure included in the raw water flow path spacer 160 shown in FIG.

As shown in FIGS. 11 and 12, the raw water passage spacer 160 is a two-layer raw water passage spacer in which the first yarn row A and the second yarn row B are overlapped with each other. Are fixed in a laminated state. Each of the yarn rows A and B is inclined by 45 °, for example, in opposite directions with respect to the X direction, like the yarn rows M and N in the above embodiment. The interval between the first yarns A1 and A2 constituting the first yarn row A and the interval between the first yarns A2 and A3 are provided to be the same size, and is set to 4 mm as an example. The interval between the first yarns A3 and A4 and the interval between the first yarns A4 and A5 are set to be half the interval between the first yarns A1 and A2. Similarly, the interval between the second yarns B1 and B2 and the interval between the second yarns B2 and B3 constituting the second yarn row B are set to be the same size, and is set to 4 mm as an example. The interval between the second yarns B3 and B4 and the interval between the second yarns B4 and B5 are each set to be half the size of the interval between the second yarns B1 and B2. Each of the yarns A1 to A5 and B1 to B5 is formed in a columnar shape, for example, and has a diameter of 0.4 mm.

As shown in FIG. 11, the raw water flow path spacer 160 includes

first mesh structures

171 and 172 configured to be connected in the extending direction of the second yarn row B by the first yarn row A and the second yarn row B described above. , 173 and

second mesh structures

181, 182 and 183 are alternately provided. Since the first mesh structures 171 to 173 have the same configuration and the second mesh structures 181 to 183 also have the same configuration, in the following description, the first mesh structure 172 and the second mesh structure 182 are taken as an example. Give an explanation.

The first mesh structure 172 is formed of the first mesh 172a-1 formed by the first yarns A1 to A3 and the second yarns B1 to B3, and the first yarns A3 to A5 and the second yarns B3 to B5. Intermediate meshes 172a-2 are alternately arranged along the extending direction of the second yarn row B. The first mesh 172a-1 has, for example, a square appearance. On the other hand, the intermediate mesh 172a-2 has, for example, a rectangular appearance, and is configured to have finer eyes than the first mesh 172a-1. For this reason, when the first mesh 172a-1 and the intermediate mesh 172a-2 are compared, the flow resistance of the first mesh 172a-1 is smaller than that of the intermediate mesh 172a-2.

The second mesh structure 182 includes an intermediate mesh 182a-1 formed by the first yarns A1 to A3 and the second yarns B3 to B5, and a second mesh formed by the first yarns A3 to A5 and the second yarns B3 to B5. The meshes 182a-2 are alternately arranged along the extending direction of the second yarn row B. Similar to the intermediate mesh 172a-2, the intermediate mesh 182a-1 has, for example, a rectangular external shape, and is configured to have the same roughness as the mesh 172a-2. Further, the second mesh 182a-2 has, for example, a square-shaped appearance shape, and has finer eyes than the intermediate mesh 182a-1. For this reason, when the second mesh 182a-2 and the intermediate mesh 182a-1 are compared, the flow resistance of the second mesh 182a-2 is larger than that of the intermediate mesh 182a-1.

As shown in FIG. 12, in the second mesh structure 182, part of the raw water flows along the flows C11 and C12 from the intermediate mesh 182a-1 to the first mesh 172a-1 in the first mesh structure 172 on the downstream side. To do. In the first mesh 172a-1, a part of the raw water flows from the first mesh 172a-1 to the intermediate mesh 183a-1 of the second mesh structure 183 on the downstream side along the flows C21 and C22.

Here, the second mesh 182a-2 and the first mesh 172a-1 are adjacent to the downstream side in the raw water flow of the intermediate mesh 182a-1. Since the second mesh 182a-2 has higher flow resistance than the first mesh 172a-1, the raw water flowing from the intermediate mesh 182a-1 along the flows C11 and C12 into the first mesh 172a-1 The flow rate Q11 is larger than the flow rate Q12 of raw water flowing into the second mesh 182a-2.

On the other hand, intermediate meshes 172a-2 and 183a-1 are adjacent to the downstream side of the first mesh 172a-1. Since both meshes 172a-2 and 183a-1 have the same coarseness of the eyes, the magnitude of the channel resistance is also comparable. For this reason, the flow rate Q12 of raw water flowing out to the intermediate mesh 183a-1 along the flows C21 and C22 and the flow rate Q13 of raw water flowing out to the intermediate mesh 172a-2 along the flows S11, 12 are comparable. Become.

Accordingly, the flow rate Q11 flowing from the second mesh structure 182 along the flows C11 and C12 into the first mesh 172a-1 in the first mesh structure 172, and the second flow along the flows C21 and 22 from the mesh 172a-1. Raw water flowing from the first mesh 172a-1 in the first mesh structure 172 into the downstream intermediate mesh 172a-2 along the flows S11 and S12 by a difference flow rate ΔQ _{11-12 from the} flow rate Q12 flowing out to the mesh structure 183 The flow rate Q13 increases. As described above, also in the raw water flow path spacer 160, the water flow of the raw water flowing through the first mesh structure 172 can be increased, and the same effect as the raw water flow path spacer 40 in the above embodiment can be obtained.

In addition, when the fluid analysis simulation is performed on the raw water flow path spacer 160 under the same conditions as the above-described raw water flow path spacer 40, the area ratio of the easily polarized region in the surfaces of both

separation membranes

24 and 28 is 17%.

In the fluid analysis simulation, when the raw water channel spacer 160 is used, the average value of the shear stress that the raw water flow acts on both

separation membranes

24 and 28 is 2.6 Pa, whereas the above-described raw water channel is used. The average value of the shear stress of the spacer 40 was 3.3 Pa.

Therefore, when the raw water channel spacer 160 is used, the average shear stress acting on both

separation membranes

24 and 28 is about 20% lower than that of the raw water channel spacer 40 described above. For this reason, the effect that a pressure loss can be suppressed compared with the raw | natural water flow path spacer 40 can also be acquired.

FIG. 13 is a view showing a configuration of the raw water flow path spacer 200 of the eleventh modification. As shown in FIG. 13, the raw water flow path spacer 200 is a modification of the raw water flow path spacer 160 described above. In the following description, only portions different in configuration from the raw water flow path spacer 160 will be described, and description of portions common in configuration will be omitted as appropriate.

As shown in FIG. 13, the raw water passage spacer 200 is a two-layer raw water passage spacer in which the first yarn row A10 and the second yarn row B10 are overlapped with each other, and each yarn row A10, B10 is laminated. It is formed by fixing with. The configuration differs from the configuration of the raw water flow path spacer 160 in that the yarns A11, A12, A13 constituting the first yarn row A10 are arranged at equal intervals. On the other hand, the configurations of the second yarns B11 to B15 constituting the second yarn row B10 are the same as the second yarns B1 to B5 in the raw water flow path spacer 160 described above.

As shown in FIG. 13, the raw water channel spacer 200 includes

first mesh structures

201, 202, and 203 configured along the second yarn row B10 by the first yarn row A10 and the second yarn row B10 described above. The

second mesh structures

211, 212, and 213 are alternately provided. The first mesh structures 201 to 203 have the same configuration, and the second mesh structures 211 to 213 also have the same configuration. For this reason, in the following description, the first mesh structure 202 and the second mesh structure 212 will be described as an example.

The first mesh structure 202 includes a first mesh 202a formed by the first yarns A11 and A12 and the second yarns B11 to B13, and a number of meshes having the same configuration as the first mesh 202a are the second yarns. A large number are arranged in the extending direction of the row B10.

The second mesh structure 212 includes a second mesh 212a formed by the first yarns A11, A12 and the second yarns B13 to B15, and a number of meshes having the same configuration as the second mesh 212a are the second yarns. A large number are arranged in the extending direction of the row B10. The second mesh 212a is formed with finer eyes than the first mesh 202a. For this reason, channel resistance becomes larger than the 1st mesh 202a.

When the fluid analysis simulation was performed on the raw water flow path spacer 200 under the same conditions as the raw water flow path spacer 40 in the above embodiment, the area ratio of the easily polarized regions occupying the surfaces of the

separation membranes

24 and 28 was 17%. Also in the raw water flow path spacer 200 of this modified example 11, the same effect as the raw water flow path spacer 160 described above can be obtained.

FIG. 14 is a view showing the configuration of the raw water flow path spacer 230 of the twelfth modification. The raw water flow path spacer 230 includes

first mesh structures

231, 232, 233 and

second mesh structures

241, 242, 243 that are formed by superimposing the yarn rows M, N alternately. Here, since the

first mesh structures

231, 232, and 233 have the same configuration, and the

second mesh structures

241, 242, and 243 also have the same configuration, in the following description, the first mesh structure 232 and the second mesh structure 232 The raw water flow path spacer 230 will be described by taking the mesh structure 241 as an example.

The raw water flow path spacer 230 is different from the configuration of the raw water flow path spacer 40 described above in that the intervals of the yarn rows N are equal. On the other hand, the interval R4 between the yarns M1 and M2 constituting the second mesh structure 241 is narrower than the interval R3 between the yarns M1 and M2 constituting the first mesh structure 232. In this way, the yarn mesh M may be configured such that the interval in the second mesh structure 241 is narrower than that in the first mesh structure 231. However, in this case, the yarn row M corresponds to the second yarn row, and the yarn row N corresponds to the first yarn row.

Subsequently, the method of using the evaluation cell 400 used for the evaluation test of the concentration polarization suppression effect by the raw water flow path spacer 40 and the evaluation test using the cell 400 will be described with reference to FIGS. A description will be given using. FIG. 15A is a perspective view showing the evaluation cell 400 with a part of the cell omitted, and a partial cross-sectional view. FIG. 15B is a diagram illustrating a configuration of a test body of the raw water flow path spacer 40 installed in the evaluation cell 400. FIG. 15C is a diagram showing the outline of the flow path in the evaluation cell 400 and the solid line of the flow path component. In FIG. 15A, the cross section of the test body 40-T in the raw water channel spacer 40 is indicated by hatching with “x” mark for convenience.

As shown in FIGS. 15 (a) to 15 (c), the evaluation cell 400 is a substantially rectangular parallelepiped concentration measuring unit formed by fitting a male die 410 and a female die 420 together. The evaluation cell 400 is used by replacing the spiral membrane element 20 included in the filtration device 10 shown in FIG. As shown in FIG. 15A, the male mold 410 is a metal or resin member having a convex portion 412 provided at the center. As for this convex part 412, the protrusion surface 412a is formed in a rounded rectangle shape. A rounded rectangle means a shape that forms an outer shape of a short side and a long side constituting a rectangle, the outer side being replaced with a curve that protrudes outward in a semicircular shape. Moreover, the chamfering process is given to the peripheral part of the protrusion surface 412a, and the inclined surface 412b is formed.

The female mold 420 is a metal or resin member in which a concave portion 422 that fits into the convex portion 412 of the male die 410 is provided in the central portion. In the evaluation cell 400, the evaluation flow path 430 is formed between the convex portion 412 and the concave portion 422 by fitting both the

molds

410 and 420 together. As shown in FIG. 15C, the evaluation channel 430 has a rounded rectangular outer shape. As an example, the total length D1 is 167 mm, and the diameter of the semicircular portion formed at both ends, that is, the width D2 is 35 mm, and the thickness of the flow path is about 1 mm.

Further, as shown in FIGS. 15A and 15C, the male mold 410 is provided with a pipe end 414 constituting the raw water inlet and a pipe end 416 constituting the concentrated water outlet. The pipe end 414 constituting the raw water inlet is connected to a water supply pipe L2 (see FIG. 1) for supplying raw water, and the pipe end 416 constituting the concentrated water outlet is connected to a concentrated water pipe L4 (see FIG. 1). The Both pipe ends 414 and 416 communicate with the evaluation flow path 430 through connecting

flow paths

414a and 416a provided inside the male mold 410, respectively. The female mold 420 is also provided with pipe ends 424 and 426 that respectively constitute permeate outlets at positions facing the pipe ends 414 and 416 of the male mold 410. The pipe ends 424 and 426 and the evaluation flow path 430 are communicated with each other through connecting

flow paths

424a and 426a formed in the female mold 420. Moreover, the pipe ends 424 and 426 constituting the permeate outlet are each connected to the permeate pipe L3 (see FIG. 1).

Next, a method for using the evaluation cell 400 will be described. The evaluation channel 430 formed inside the evaluation cell 400 includes a test body 26-T of the permeated water spacer 26, a test body 24-T of the separation membrane 24a, and a test body 40 of the raw water channel spacer 40. -T is stored in a stacked state. Each test body 26-T, 24-T, 40-T is processed in advance into a rounded rectangular shape so as to fit in the recess 422 of the female mold 420 without a gap. At this time, as shown in FIG. 15 (a), the permeated water spacer test body 26-T, the separation membrane test body 24-T, and the raw water channel spacer test body 40- viewed from the female mold 420 side. It installs in the recessed part 422 in order of T. By installing each of the test bodies 26-T, 24-T, and 40-T in this way, the permeated water that has passed through the test body 24-T, which is a separation membrane, passes through the inside of the test body 26-T and communicates therewith. It will flow out of either of the

flow paths

424a and 426a to the permeate pipe L3 (see FIG. 1). On the other hand, the raw water that has not permeated through the specimen 24-T as the separation membrane is discharged as concentrated water to the concentrated water pipe L4 (see FIG. 1) via the communication channel 416a.

And as shown to Fig.15 (a), after installing the test body 40-T in the recessed part 422, the O-ring 432 is attached so that the side wall 422a of the recessed part 422 may be followed. The O-ring 432 is an annular member whose outer periphery has a rounded rectangular shape, and is a rubber packing having a circular cross section. The O-ring 432 is pressed against an inclined surface 412 b formed on the convex portion 412 of the male die 410, thereby closing the gap between the convex portion 412 of the male die 410 and the concave portion 422 of the female die 420. It has a function as a sealing material that prevents water leakage. Further, the raw water flow channel spacer 160 of the modified example and the raw water flow channel spacer 300 of the comparative example are also tested in the same manner as the test sample 40-T of the raw water flow channel spacer 40. T is made and evaluated.

As described above, after each test body 24-T, 26-T, 40-T and the O-ring 432 are installed in the concave portion 422 of the female mold 420, the convex portion 412 of the male mold 410 is fitted into the concave portion 422. Both

molds

410 and 420 are fixed by a plurality of bolts BL1 to BL4 (see FIG. 15A). At this time, if a gap remains between the convex portion 412 of the male mold 410 and the O-ring 432, a plurality of permeated water spacers 26-T are stacked so that the O-ring 432 and the inclined surface 412b of the convex portion 412 are overlapped. It adjusts so that it may press-contact between the side walls of the recessed part 422. FIG. Thereby, the attachment operation | work to the cell 400 for evaluation of the test body 40-T of the raw | natural water flow path spacer 40 is completed.

In this evaluation test, the specimen 300-T was manufactured such that the interval between the yarn rows V (see FIG. 6A) and the interval between the yarn rows W (see FIG. 6B) were 2 mm. The diameters of the yarns V1 to V3 and W1 to W3 constituting the yarn rows V and W are 0.2 mm.

Further, the test body 40-T was manufactured such that the interval between the first yarn rows M (see FIG. 3) and the interval between the second yarn rows N (see FIG. 3) were 2 mm. (Accordingly, in the test body 40-T, the first square mesh 52a described above has a square appearance with a side of 2 mm, and the second square mesh 61a has a rhombus with a side of 2 mm. The diameter D of each of the yarns M1 to M3 and N1 to N4 constituting each yarn row M and N (which has a shape) is 0.2 mm.

In the test body 160-T, the interval between the first yarns A1 and A2 and the interval between the first yarns A2 and A3 constituting the first yarn row A (see FIG. 11) is 3 mm, respectively. The distance between the first yarns A4 and A5 was 1.5 mm. In the second yarn row B (see FIG. 11), the interval between the second yarns B1 and B2 and the interval between the second yarns B2 and B3 are each 3 mm, and the interval between the second yarns B3 and B4 and the second yarn B4 , B5 were each made to be 1.5 mm apart. The diameters of the yarns A1 to A5 and B1 to B5 constituting the yarn rows A and B are 0.2 mm.

Subsequently, an evaluation test of the raw water flow path spacer using the evaluation cell 400 will be described. In addition, this evaluation test is implemented on the conditions of 25 degreeC temperature.

First, the pure water permeability coefficient A is calculated. This “pure water” permeability coefficient is a permeability coefficient obtained from the relationship of the following formula (1) when the raw water supplied from the pipe end 414 to the evaluation cell 400 is pure water not containing impurities such as salt. is there.

J _W = A × P _out (1)
In the above formula (1), J _W is a pure water volume flux [m ³ / (m ² s)], and P _out is a measured value of a water pressure gauge (not shown) installed in the concentrated water pipe L4. . The pure water permeability coefficient A is calculated by adjusting the flow rate adjustment valve (not shown) of the concentrated water pipe L4 and the flow rate control valve of the bypass pipe L2-B, so that P _out = 0.5 MPa, the concentrated water pipe L4. The permeate flow rate Q _L3 [m ³ / s] of the permeate pipe L3 when the concentrated water flow rate Q _L4 at 14.5 cc / min. Is measured. Then, the pure water volume flux J _W1 is obtained by dividing the permeated water flow rate Q _L3 by the area of the test body 24-T of the separation membrane 24a.

Similarly, when P _out = 2.0 MPa and the concentrated water flow rate Q _L4 is 14.5 cc / min., The permeated water flow rate Q _L3 [m ³ / s] is measured, and the measured value is used as the test body 24. Measure the pure water volume flux J _W2 by dividing by the area of T.

Then, using P _out = 0.5 MPa, pure water volume flux J _W1 and P _out = 2.0 MPa, pure water volume flux J _W2 , the above equation (1) is obtained by linear approximation using the least square method. The pure water permeability coefficient A is obtained.

Next, the raw water supplied from the pipe end 414 to the evaluation cell 400 is changed to, for example, a sodium chloride (NaCl) solution adjusted to have a salt concentration of about 250 ppm, and P _out = 0.5 MPa, concentrated. The water flow rate Q _{L4 is set} to 14.5 ± 0.5 [cc / min], and the flow rate Q _L3 [m ³ / s] of the permeated water in this case is measured. Then, the solution volume flux J _V is calculated by dividing the permeated water flow rate Q _L3 by the area of the specimen 24-T, and the calculated solution volume flux J _V is substituted into the following equation (2). Then, the osmotic pressure P _f on the membrane surface of the test body 24-T is calculated. In the following formula (2), P _out = 0.5 MPa.

P _f = P _out- (J _V / A) (2)
Then, the membrane surface concentration C _m which means the salt concentration of the raw water in the vicinity of the membrane surface of the specimen 24-T as a separation membrane is calculated by the following equation (3).

C _m = B × P _f (3)
In the above formula (3), the conversion coefficient B is a constant determined by the relationship between the salt concentration of NaCl, MgSO ₄ , CaCl _{2 and the} like contained in the raw water and the osmotic pressure, and the salt contained in the raw water as in this embodiment. In the case of sodium chloride, the conversion coefficient B = 1.2294.

Next, the bulk concentration Cb is calculated from the relationship of the equation (4).

C _b = (C _in + C _out ) / 2 (4)
In the above formula (4), C _in is the salt concentration of the raw water flowing through the water supply pipe L2, and C _out is the salt concentration of the concentrated water flowing through the concentrated water pipe L4. In the present embodiment, since the salt concentration of sodium chloride contained in the raw water is adjusted in advance to around 250 ppm as described above, only the salt concentration C _{out of the} concentrated water flowing through the concentrated water pipe L4 may be measured. Moreover, what is necessary is just to perform the measurement of the salt concentration in concentrated water or raw | natural water by measuring an electrical conductivity (rate) as an example.

Then, it calculates the C _b calculated by the equation (4), the concentration ratio C _r shown in equation (5) is the ratio of C _m calculated by the equation (3).

C _r = C _m / C _b (5)
Here, FIG. 16A is a graph showing the measurement results of each separation membrane with the concentration ratio Cr described above on the vertical axis and the measured value of the pure water volume flux J _{W on} the horizontal axis. In FIG. 6A, the “Δ” mark indicates the measured value of the test specimen 300-T of the raw water flow path spacer 300 as a comparative example, and “◇” indicates the measurement of the test specimen 40-T of the raw water flow path spacer 40. “10” indicates the measured value of the test body 160 -T of the raw water flow path spacer 160 of the tenth modification. FIG. 16 (b), the table shown with pure water volume flux _{J w} at the time of measurement the measured value of the concentration ratio _{C r} of each specimen 40-T, 160-T, 300-T shown in the diagram (a) It is.

Moreover, as shown in FIG. 3, the 1st thread line M and the 2nd thread line N of the raw | natural water flow path spacer 40 are comprised asymmetrically. For this reason, the raw water flows in the vicinity of the membrane surface of the separation membrane 24a and the separation membrane 28a facing each other with the raw water flow path spacer 40 interposed therebetween are greatly different. For this reason, the distribution state of the salt concentration in the vicinity of both

separation membranes

24a and 28a is also greatly different. Therefore, in the evaluation test using the test body 40-T of the raw water flow path spacer 40, the case where the first thread row M is placed in contact with the test body 24-T of the separation membrane 24, and the test body 24-T It is necessary to measure the concentration ratio _Cr in the case where the second yarn row N is placed in contact with each other and to evaluate the magnitude of the concentration polarization based on the average value.

Therefore, in FIG. 16B, the case where the first yarn row M is in contact with the test body 24-T is “B”, and the second yarn row N is in contact with the test body 24-T. Each case is indicated as “A”.

In the following description, the test body 40-T of the raw water channel spacer 40 in the installation state “A” is referred to as a test body 40-TA, and the test body 40 in the case where the installation state “B” is shown. -T is appropriately described as test body 40-TB.

As shown in FIG. 16 (a), in the evaluation test using the specimen 40-TA, the concentration of pure water volume flux J _w = 0.91 × 10 ⁻⁵ [m ³ / (m ² s)] The ratio C _r = 2.1. Further, in the evaluation test using the specimen 40-TB, the concentration ratio C _r = 3.1 in the pure water volume flux J _w = 1.13 × 10 ⁻⁵ [m ³ / (m ² s)]. is there. Therefore, the average value of the concentration ratio Cr in the test bodies 40-TA and 40-TB is 2.6, which is lower than the minimum value 2.7 of the concentration ratio Cr of the test body 300-T which is a comparative example. Therefore, according to the raw | natural water flow path spacer 40, it has confirmed that concentration polarization could be reduced rather than the conventional raw | natural water flow path spacer 300. FIG.

As shown in FIG. 16 (a), in the evaluation test using the test body 160-T of the raw water flow path spacer 160, the pure water volume flux J _w = 1.03 × 10 ⁻⁵ [m ³ / (m ² concentration ratio _{C r} in the case of s)] is 1.6, pure volumetric flux _{^{J w = 1.51 × 10 -5 [}} m 3 / (m 2 s)] concentration ratio _{C r} in the case of the 2.4. In the evaluation test using thus specimen 160-T, it can be seen that far below 2.7 is the minimum value of the concentration ratio C _r in specimen 300-T is a comparative example in either case . Therefore, according to the raw water flow path spacer 160, it was confirmed that the concentration polarization could be reduced as compared with the conventional raw water flow path spacer 300.

In the above evaluation test using a specimen 160-T, it was 6.4kPa The measured pressure loss P _L at which the concentrated water flow rate Q _L4 in concentrated water pipe L4 was 14.5cc / min.. The pressure loss P _L is hydraulically P _in the water supplied to the evaluation channel 430 of the evaluation cell 400 from the tube end 414, a differential pressure between P _out as described above.

Similarly, in the above evaluation test using the specimen 300-T, when the pressure loss P _L was measured when the concentrated water flow rate Q _L4 was 14.5 cc / min., The measured value was 8.6 kPa. .

As described above, it was confirmed that when the specimen 160-T was used, the pressure loss could be reduced as compared with the conventional specimen 300-T. For this reason, according to the raw | natural water flow path spacer 160, it is possible to aim at reduction of both concentration polarization and pressure loss.

The present invention can be carried out in a mode in which various improvements, modifications, or variations are added based on the knowledge of those skilled in the art without departing from the spirit of the present invention. Moreover, you may implement with the form which substituted any invention specific matter to the other technique within the range which the same effect | action or effect produces.

Claims

A first yarn array sandwiched between a first separation membrane and a second separation membrane wound around a water collecting pipe of a spiral membrane element, and inclined in opposite directions with respect to a direction parallel to the water collecting pipe; A raw water flow path spacer having a two-layer structure composed of two yarn rows,
A first mesh structure configured by the first yarn row and the second yarn row being connected in the extending direction of the second yarn row;
The first yarn row and the second yarn row are configured to be continuous in the extending direction of the second yarn row, and the second yarn row is more than the interval between the second yarn rows constituting the first mesh structure. A second mesh structure configured to have a narrow spacing;
Characterized by comprising alternately,
Raw water channel spacer.
The inclination of the first yarn row constituting the second mesh structure with respect to the direction parallel to the water collecting pipe is greater than the inclination of the first yarn row constituting the first mesh structure with respect to the direction parallel to the water collecting pipe. Configured to grow,
The raw water flow path spacer according to claim 1.
The first mesh structure is configured by alternately arranging a first mesh and an intermediate mesh that is finer than the first mesh,
The second mesh structure is configured by alternately arranging the intermediate mesh and the second mesh having finer mesh than the intermediate mesh.
The raw water flow path spacer according to claim 1 or 2.
A water collecting pipe through which permeate flows,
A sheet-like permeate spacer,
Three sides are sealed in a state of being overlapped on both surfaces of the permeate spacer, and the other side is formed into a bag shape having an open end, and the open end is connected to the water collection pipe and wound around the water collection pipe. A rotated first separation membrane and second separation membrane;
Raw water channel spacer according to any one of claims 1 to 3,
Spiral type membrane element.