WO2015028421A1

WO2015028421A1 - Emulsifier-free, skin conditioning, cosmetic or dermatological preparation which contains repellents

Info

Publication number: WO2015028421A1
Application number: PCT/EP2014/067988
Authority: WO
Inventors: Christian Dingler
Original assignee: Beiersdorf Ag
Priority date: 2013-08-29
Filing date: 2014-08-25
Publication date: 2015-03-05
Also published as: DE102013217239A1

Abstract

The invention relates to an emulsifier-free, skin conditioning cosmetic or dermatological preparation which contains repellents.

Description

Emulsifier-free, skin-conditioning cosmetic or dermatological preparation with repellents

The invention comprises an emulsifier-free, skin-conditioning cosmetic or dermatological preparation with repellents. The preparation is suitable for the

Application on wet skin without being completely rinsed off, thus enabling the creaming and the application of insect repellent during showering.

Applying under moist conditions, skincare under the shower, will

in summary understood as skin conditioning. This means, inter alia .:

1 . Use of a standard shower product to cleanse the skin, rinse off

2. Application / distribution of the preparation according to the invention on wet skin

3. Reapply with warm or cold water

4. Drying of the skin

WO 2013064391 A2 describes cosmetic or dermatological preparations which make it possible to apply cream under the shower.

Due to lack of time, many people want the most efficient

Skin care and simultaneous skin protection, for example against insect bites.

Insect repellents (insect repellents, insect repellents, repellents, repellents) are preparations that are used externally to repel and / or expel insects, as well as ticks and mites, and to prevent them from becoming active on the skin. Insect repellents are intended to protect the skin from nuisance by blood sucking or biting insects and other parasites and / or pests by repelling them before settling on the skin. The funds work

Accordingly, not as contact poisons, but only as a repellent, since they do not kill the animals, but only distribute.

Examples of repellent agents are 1-piperidinecarboxylic acid 2- (2-hydroxyethyl) -1-methylpropyl ester (INN: icaridin, CAS number: 1 19515-38-7, Elincs number: 423-210-8), 3 - (Nn-butyl-N-acetyl-amino) propionate (also as

Ethylbutylacetylaminopropionate or Repellent 3535), N, N-diethyl-3-methylbenzamide (trade name: meta-delphphene, DEET) and DEPA, nootkatone, MKG Repellent 1 1 or KBR 3023.

The following overview shows the structures of the known repellents.

MKG Repellent 11 KBR 3023 I 3535

In WO 2006096876 and WO 2005034626 dihydronepetalactones are disclosed as insect repellents. Catnip or Nepeta is known as a mosquito repellent and should have about ten times stronger defense against mosquitoes than conventional repellents.

Furthermore, DE 102005033845 mentions inter alia certain perfume ingredients for repelling mosquitoes, sandflies, lice, brakes, wasps, bees, flies and ticks.

Mosquitoes, ticks and other insects within the meaning of the present disclosure are primarily characterized by a complex fragrance mixture of lactic acid, fatty acids and

Attracted amino acids, which are exuded by the human skin and the

Surrounding people like a fragrance bell. It is now a drawback to prior art insect repellents that such preparations are the natural, human

Do not mask the fragrance composition directly, but rather add an additional, insect repellent fragrance (the repellent). In order to shift the attractive and repulsive irritation potential to the insects over a longer period in favor of the repulsive irritant effect, it is necessary in the prior art to use relatively large amounts of repellent agents.

The word repellent is derived from the Latin repellere (repel, repel) and is used for substances that are primarily due to their olfactory effect deterrent to sensitive individuals, without killing them. It is desirable to provide a preparation that acts on the one hand insect repellent and on the other hand is made skin-friendly and can be used to save time under shower or on wet skin.

The invention is an emulsifier-free cosmetic or dermatological preparation comprising one or more polyacrylic acid polymers, one or more C14-22 fatty alcohols and one or more waxes and / or a hydrocarbon mixture and one or more repellents.

The preparation preferably comprises waxes, in particular Cera Microcristallina, in the range of more than 0.5% by weight, in particular more than 13% by weight, based on the total mass of the preparation.

The preferred level refers to both individual waxes and preferably the total amount of multiple waxes.

As repellents are preferably one or more substances from the group N, N-diethyl-m-toluamide (DEET), NN-diethylphenylacetamide (DEPA), Ethylbutylacteylaminopropionat (IR 3535®, Merck) and / or p-menthane-3,8- diol, picaridine (KBR 3023).

According to the invention, it is advantageous to choose the choice of repellents from the group of lipophilic compounds.

Since the basic preparation according to the invention is composed of predominantly lipophilic substances, it is thus possible to achieve a longer retention on the skin.

Preferred repellents are Citronella oil, Lemon oil, Eucalyptus oil and / or neem oil.

The proportion of one or more insect repellents is advantageously up to 5% by weight, in particular in the range of 0.001 to 1% by weight, based on the total mass of the preparation.

It has been found that the simple incorporation of repellents in prior art formulations used under shower does not lead to the desired results.

Rinsing under the shower and drying will usually leave no film on the skin, which ensures a basic insect protection.

Surprisingly, the retention of repellents and thus one succeeds

Insect repellent after rinsing and drying on the skin by the

inventive preparation. The application of the combination of special

Fatty alcohols, waxes and advantageously one or more film formers leads to a protective effect that begins even in the shower.

The preparations according to the invention advantageously comprise one or more film formers. These film formers are advantageously selected from the group hexadecene copolymer, trimethylsiloxysilicate, polypropylsilsesquioxane, polysilicone-25, acrylate copolymer,

Polyurethane, Methacrylate, Polyglyceryl Stearate, Dilinoleate Crosspolymer, Acyl Acrylate / Methacrylic Acid Crosspolymer, IPDI Copolymer, Especially VP / Hexadecenes Copolymer, Octyldodecyl Citrate Crosspolymer, Trimethylsiloxysilicate /

Polypropylsilsesquioxane, Ammonium Acrylate Copolymer, Polyurethane-2 and

Polymethyl methacrylate, polyglyceryl stearate / isostearate dilinoleate - Crosspolymer,

Octadecene / MA copolymer (and) methyl acetylricinoleate (and) diisooctyl adipate,

Trimethylsiloxysilicate, Polyurethane-34, C8-22 Alkyl Acrylates / Methacrylic Acid Crosspolymer and / or Castor Oil / IPDI Copolymer.

The proportion of film formers is advantageously selected in the range from 0.1% by weight, in particular from 0.5% by weight to 10% by weight, based on the total mass of the preparation.

In a comparison, the protective film that forms on the skin is examined, once after the application of a rinse off product with integrated skin care aspects (Nivea cream soft shower gel) alone and once after application of the same product (Nivea cream soft shower gel) and subsequent application of the inventive preparation. After both applications, the skin is rinsed with water.

The skin refatting measurements were made by IR imaging. The measurement technique is called IR-ATR (InfraRed-Attenuated Total Reflectance).

It was found that only after application of the preparation according to the invention does a protective film visible by means of the measurement technique mentioned remain on the skin and can be detected. Detection is via the intensity of the hydrocarbon IR bands (CH-IR bands).

The protective film of the invention comprises a skin-forming film comprising one or more repellents. Advantageous and therefore longer in the film and thus remaining on the skin are lipophilic repellents to choose.

The skin conditioning according to the invention comprises moisturizing

Conditions, in particular the skin care in the shower, whereby a protective film remains even after rinsing on the skin. The protective film can be detected by means of IR-ATR measurement technology and ideally has a thickness of at least 1 μm to 10 μm.

In particular, the skin conditioning according to the invention is characterized in that the protective film on the skin comprises one or more repellents, one or more lipids and one or more skin moisturizers and no skin barrier damaging substances, in particular no emulsifiers and / or surfactants, are included. Only this remaining on the skin film allows the application and also the whereabouts of repellents on the skin.

In the preparation according to the invention are one or more fatty alcohols and at least one additional wax and / or mixture of liquid and solid

Hydrocarbons, having a melting range of 5 ° C to 75 ° C, preferably up to 55 ° C (according to DSC), given together, in particular melted.

That Advantageously, at least one wax is present in addition to at least one fatty alcohol or, in addition to fatty alcohol, at least one mixture of liquid and solid is present

Contain hydrocarbons. Ideally, it contains fatty alcohol, wax and a mixture of hydrocarbons.

Preferred as fatty alcohols are myristyl, cetearyl and / or stearyl alcohols, as waxes Cera Microcristallina, Coco-Glyceride, C18-36 Acid Triglyceride, Synthetic Wax, Cera Alba, Paraffin, Copernicia Cerifera Cera, C18-38 Alkyl Hydroxystearoyl Stearate,

Butyrospermum Parkii Butter, Olus oil, C20-40 alcohol and / or beeswax and as a hydrocarbon mixture to choose Paraffinum Liquidum.

Preference is given to Cera Microcristallina.

The fatty alcohols, waxes and hydrocarbon mixtures advantageously all have a melting range of 5 ° C. to 75 ° C., preferably up to 55 ° C. (according to DSC).

DSC (Differential Scanning Calorimetry) is a thermal method for measuring emitted / absorbed heat quantity of a sample during isothermal operation, heating or cooling (see DIN 53765, DIN 51007, ASTM E 474, ASTM D 3418). DSC is a comparative measurement method that enables the determination of heat quantities of physical and chemical processes. If a material is his

physical state changes, such as melting or transformation of one crystal form into another, or if it reacts chemically, heat is absorbed or released. These amounts of heat can be measured quantitatively with the help of DSC. The method runs cyclically, so that after the first heating curve, a defined cooling takes place and then the sample is heated again in the specified temperature range. This gives two different kinds of information: In the first heating curve, all thermal effects, including the prehistory, are discernible. In the second heating curve, the history has been eliminated and the pure thermal behavior of the sample under defined cooling conditions can be evaluated. The melting range of fatty alcohols, waxes or hydrocarbons between 4.5 ° C and 75 ° C according to DSC is the range determined in the first heating curve. Fats and fat-like substances with a waxy consistency can also be used according to the invention as waxes. These include, inter alia, fats (triglycerides), mono and diglycerides, natural and synthetic waxes, fatty and wax alcohols, esters of fatty alcohols and fatty acids and fatty acid amides or any mixtures of this substance.

Particularly preferred are the waxes from the group of fats, in particular from the group of natural waxes: Shorea Stenoptera Seed Butter, Hydrogenated Vegetable Oil, Hydrogenated Coco-Glycerides, Butyrospermum Parkii Butter, Theobroma Cocoa (Cocoa) Seed Butter, Mango Butter, Hydrogenated Palm Kernel Glycerides, Hydrogenated Palm Glycerides, Sunflower Seed Wax, Soybean Glycerides, Butyrospermum Parkii

Unsaponifiables,, Wool Wax, Cera Alba, Beeswax, Sugar Cane Wax, Cera Carnauba, Candelilla Wax, Japan Wax, Hydrogenated Rapeseed Oil, Shellac Wax, Hydrogenated Lecithin, Hydrogenated Soybean Oil,

from the group of synthetic waxes, in particular:

Cera Microcristallina, Synthetic Beeswax, Synthetic Wax, Polyethylene, Paraffin Wax, Ceresin, Ozokerite

from the group of fatty acids, in particular:

Palmitic Acid, Stearic Acid,

from the group of esters of fatty acids, in particular from

Cetearyl Nonanoates, Methyl Palmitates, Glyceryl Tribehenates, Glyceryl Laurates, Glyceryl Stearates, Cetyl Palmitates; Shea Butter Oleyl Esters, PEG-8 Beeswax

selected.

As fatty alcohols C14 to C22 fatty alcohols are used. The fatty alcohols are preferably selected from the group consisting of linear fatty alcohols, especially myristyl (C14H ₃₀ O), cetyl alcohol (or palmityl) (C ₆ H ₃₄ 0), stearyl alcohol (or

Octadecyl) (C ₈ H ₃₈ 0) and cetyl stearyl alcohol (cetearyl alcohol), behenyl alcohol, lanolin alcohol, (a mixture of the alcohols cetyl alcohol hexadecanol) and stearyl alcohol (octadecanol).

The proportion of total C14-22 fatty alcohols is advantageously 0.5 to 10 wt.%, In particular 0.5-5% based on the total mass of the preparation.

Hydrocarbon gels or mixtures of liquid and solid paraffin hydrocarbons are preferably used as hydrocarbon mixtures. The content of solid hydrocarbons in the hydrocarbon mixture is preferably between 1 and 50%, more preferably between 10 and 30%. The use of hydrocarbon mixtures which form fringe micelles or paracrystalline structures is advantageous.

The proportion of the total hydrocarbon mixture is advantageously 1 to 50 wt.%, In particular 20 to 30 wt.%, Based on the total mass of the preparation.

Fatty alcohol, in particular two or three fatty alcohols, according to the invention are necessarily included in the preparation. In addition, one or more waxes are added to the preparation. Preferably, instead of the wax, a hydrocarbon mixture of liquid and solid hydrocarbons which are liquid at room temperature may also be added.

Ideally, the preparation comprises all three building blocks, fatty alcohols, waxes and

Hydrocarbon mixture.

The preparation and preparation according to the invention may then be admixed with cosmetic or dermatological substances known to the person skilled in the art, the addition of which does not confer the skin-conditioning properties and insect protection of the available

May affect the preparation.

Ideally, the forming film and thus the inventive

Preparations of further skin moisturizer

Advantageously, thickeners, fillers and neutralizing agents are added to the preparations.

Thickeners are advantageously suitable for stabilizing the system and enhance the skin-conditioning properties and the special skin feel of the preparations according to the invention.

As a filler, aluminum Starch Octenylsuccinat is preferably added, which also leads to an optimization of the skin feel by the skin protection film acts a little more velvety.

Sodium hydroxide solution is advantageously added as a neutralizing agent so that the thickeners can form their gel network and a stable system is formed.

The preparation according to the invention is emulsifier-free. That the optionally acting as emulsifying polyacrylic acid polymers are not understood according to the invention as emulsifiers.

In other words, in addition to the polyacrylic acid polymers, no further emulsifiers are added to the formulation.

Emulgatorfrei also includes a minimum content of additional emulsifiers of less than 1 wt.%, Based on the total mass of the preparation, for example, by

Contaminants or entrainments may be included. The influence on the

Product performance may be irrelevant in these tonnage ranges. However, preference is given to a content of emulsifiers of 0% by weight.

Polyacrylic acid polymers are understood as meaning the polymers of acrylic and / or methacrylic acid known in cosmetics and acrylate crosspolymers.

Preferably, these are high molecular weight polymers (macromolecules) (> 1 Mg / mole) composed of a backbone of polyacrylic acid and small amounts

Polyalkenylether cross-links exist. They are also referred to as carbomers. These water-soluble or dispersible polymers can cause a significant increase in viscosity in the liquid in which they are dissolved or dispersed. This is caused by the formation of carbomer microgels in the water.

Particularly preferred polyacrylic acid polymers are, in addition to the carbomers, those acrylate crosspolymers which exert a polymeric emulsifier action.

Polymer emulsifiers are mainly high polyacrylic acid polymers

Molecular weight. These emulsifying polyacrylic acid polymers have a small lipophilic portion in addition to the hydrophilic body. For the purposes of the present invention, very particular preference is given to acrylate crosspolymers which have the INCI name

"Acrylates / C 10-30 Alkyl Acrylate Crosspolymer" have and among the

Trade names PemulenTR-1 and Pemulen TR-2 and Carbopol 1342, Carbopol 1382 and Carbopol ETD 2020 are available from NOVEON.

The polyacrylic acid polymers are particularly preferably selected from the group of acrylates / C 10-30 alkyl acrylate crosspolymers and / or carbomers. Especially preferred are acrylates / C 10-30 alkyl acrylate crosspolymer Pemulen® TR-1, e.g. from Lubrizol and Carbopol® 3128 from Lubrizol.

In this case, according to the invention, a specific combination of polyacrylic acid polymers having an emulsifying action, such as the Pemulen TR-1 with other polyacrylic acid polymers, such as Carbopol 3128, which improve the sensory properties and ensure the stability of the preparation, especially at higher temperatures, and a connection with free water.

Particularly preferred herein is a combination of three polyacrylic acid polymers wherein a polyacrylic acid polymer has an emulsifying effect, e.g. the pemulen TR-1 or pemulen TR-2, with other polyacrylic acid containing the sensory

Improve properties and stability of the preparation, especially at higher temperatures (eg Carbopol 3128) and a polyacrylic acid polymer, which improve the sensory properties of free water intake (eg Carbopol The preparation according to the invention therefore advantageously comprises at least three polyacrylic acid polymers, in particular three polyacrylic acid polymers, which differ in their properties.

The proportion of total polyacrylic acid polymers is preferably 0.05 to 2 wt.%, In particular 0.2 to 1 wt.%, Based on the total mass of the preparation.

The combination of at least two polyacrylic acid polymers with at least two C 14-22 fatty alcohols for improved stabilization of the preparation and, above all, the skin feel when used on wet / moist skin has not proven to be advantageous

uncomfortable, not waxy, dull or squeaky.

According to the invention, two polyacrylic acid polymers or three polyacrylic acid polymers are understood to mean that one polyacrylic acid polymer differs from the other in at least one property. The substance group acrylates / C 10-30 alkyl acrylate crosspolymers comprises, for example, the commercial products pemulen TR-1 or TR-2.

Carbomers are differentiated, for example, into types A, B and C. Differences here are, for example, their gels with different viscosities (United States Pharmacopoeia, USP).

Also essential to the invention is a proportion of waxes or preferably a mixture of liquid and solid hydrocarbons having a melting range of 4.5 to 75 ° C, in particular up to 55 ° C according to DSC.

As oils may optionally be advantageous nonpolar to medium polar lipids in the

Preparations according to the invention may be added. Otherwise, the stability is more difficult to adjust due to the absence of emulsifiers.

In the context of the present disclosure, the term "lipids" is used as a generic term for fats, oils, waxes and the like, as is well known to the person skilled in the art. Also, the terms "oil phase ,, and" lipid phase ,, are used interchangeably.

Among other things, oils and fats differ in their polarity. It is proposed to assume the interfacial tension against water as a measure of the polarity index of an oil or an oil phase. In this case, the lower the interfacial tension between this oil phase and water, the greater the polarity of the relevant oil phase. According to the invention, the interfacial tension is considered as a possible measure of the polarity of a given oil component.

The interfacial tension is the force acting on an imaginary line of one meter length located in the interface between two phases. The physical unit for this interfacial tension is calculated classically by the force / length relationship and is usually expressed in mN / m (millinewtons divided by meters). It has a positive connotation if it tries to reduce the interface. In the opposite case, it has a negative sign.

The preparation according to the invention makes it possible for the first time to apply the care under the shower as well as the application of light filters already during the showering process.

The preparations according to the invention are advantageously formulated only with preservatives which have a water solubility of more than 0.75% at 20 ° C.

Due to the lack of emulsifiers, destabilization and crystallization can otherwise occur.

The preparations according to the invention are furthermore preferably also free of surfactants.

Surfactants are substances that are the surface tension of a liquid or the

Reduce interfacial tension between two phases and the formation of

Enable or support dispersions. Surfactants cause two actually immiscible liquids, such as oil and water, can be dispersed.

Furthermore, surfactants are described as amphiphilic substances that can dissolve organic, nonpolar substances in water. Due to their specific molecular structure, they provide at least one hydrophilic and one hydrophobic one

Part of the molecule, for a reduction of the surface tension of the water, the

Moisturizing the skin, facilitating the removal of dirt and solution, a

easy rinsing and - as desired - for foam control.

The hydrophilic fractions of a surfactant molecule are usually polar functional groups, for example -COO ^" , -OSO ₃ ^2" , -SO ₃ ^" , while the hydrophobic moieties generally represent nonpolar hydrocarbon radicals

Generally classified by type and charge of the hydrophilic part of the molecule. Here four groups can be distinguished:

Anionic surfactants,

Cationic surfactants,

• amphoteric surfactants and

• nonionic surfactants.

Anionic surfactants generally have carboxylate, sulfate or sulfonate groups as functional groups. In aqueous solution they form negatively charged organic ions in an acidic or neutral medium. Cationic surfactants are almost exclusively characterized by the presence of a quaternary ammonium group. In aqueous solution they form positively charged organic ions in an acidic or neutral environment. Amphoteric surfactants contain both anionic and cationic groups and behave accordingly in aqueous solution depending on the pH as anionic or cationic surfactants. They have a positive charge in a strongly acidic environment and a negative charge in an alkaline environment.

Furthermore, washing-active substances, such as, for example, cationic surfactants, in particular quaternary ammonium compounds, are known. A detergent substance is used in detergents, dishwashing detergents, shampoos, shower gels and denotes the proportion of the formulation which influences the washing or cleaning performance. Detergent Active

Substances increase the "solubility" of fat and dirt particles in water that adhere to the laundry or body, they can be of natural or synthetic origin and are classified according to the nature of their charge in anionic, cationic, ampholytic or nonionic.

Emulsifiers cause two immiscible liquids (for example, oil in water) to mix together to form an emulsion. Due to the amphiphilic character, they penetrate into the oil with their fat-soluble part. As a result of the hydrophilic part, the oil droplets that are now formed by stirring can be dispersed in the aqueous environment. "Primarily, emulsifiers have no detergent surfactants

Character.

Emulsifiers and surfactants can damage the skin's barrier layer. The

Preparations are therefore neither emulsifiers nor surfactants added, so advantageous no washing-active substances.

Advantageously, the preparations skin moisturizer, moisturizer added.

The preparations are used on wet skin and especially for shaving.

The preparation according to the invention can be used for skin conditioning.

It allows the production of a skin protection film after application of the preparation on the skin and subsequent rinsing with water.

The protective film that forms is ideally at least 1 μm thick (measured according to IR-ATR measurement technology) and / or does not comprise substances which damage the skin barrier, in particular no emulsifiers, surfactants, PEG ^'s and / or organohalogen compounds.

In the case of restrictions on preferred substances, whether lipids, waxes, repellents or film formers or further preferred components, their preferred ranges of proportions then also relate to the individual constituents then selected. The others, which are excluded from the restriction, will no longer be included in the listed proportions. The following examples illustrate the preparation according to the invention to obtain preparations according to the invention.

The numerical values are parts by weight, based on the total mass of the preparation.

6 7 8 9 Myristyl Alcohol 1.00 1.00 1.00

Cetearyl Alcohol 1.00 1.00 1.00 1.00

Stearyl Alcohol 2.00 2.00 2.00

Hydrogenated Coco-Glycerides 3.00 3.00 3.00

Cera Microcristallina 7.24 5.00

Paraffin Liquidum 2.04

Paraffin 7.24 5.00

Aluminum Starch Octenylsuccinate + Aqua 1.00 1.00 1.00 1.00

Perfume 1.00 1.00 1.00 1.00

Glycerine + Aqua 0,90 0,90 0,90 0,90

Aqua + Sodium Hydroxide 0.16 0.16 0.16 0.16

Phenoxyethanol 0.80 0.80 0.80 0.80

Ethylparaben 0.10 0.10

Methylparaben 0.30 0.30

Acrylates / C 10-30 Alkyl Acrylate Crosspolymer 0.10 0.10 0.10 0.10

Carbomer 0.02 0.02 0.02 0.02

Acrylates / C 10-30 Alkyl Acrylate Crosspolymer 0.10 0.10 0.10 0.10

Trisodium EDTA 0.10 0.10 0.10 0.10

Hexadecene copolymer 0.5 0.35

Citronella Oil 0.01 0.03

Lemon oil 0.30 0.10

Eucalyptus oil 0.10 0.025 0.01

Neem oil 0.50 1.00 0.001

Ethyl butyl lactylaminopropionate 0.20 0.001

Aqua ad100 ad100 ad100 ad 100

Claims

claims

1 . An emulsifier-free cosmetic or dermatological preparation comprising one or more polyacrylic acid polymers, one or more C 14-22 fatty alcohols, one or more waxes and / or a hydrocarbon mixture, characterized in that one or more repellents are present.

2. Preparation according to claim 1, characterized in that the wax or waxes to a proportion of more than 0.5 wt.%, In particular more than 13 wt.%, Based on the total mass of the preparation selected.

3. Preparation according to one of the preceding claims, characterized in that the polyacrylic acid polymers are selected from the group of acrylates / Cl 0-30 alkyl acrylate cross-polymers and / or carbomers.

4. Preparation according to one of the preceding claims, characterized in that the proportion of polyacrylic acid polymers in total from 0.05 to 2 wt.%, In particular 0.2 to 1 wt.%, Based on the total mass of the preparation is.

5. Preparation according to one of the preceding claims, characterized in that are selected as fatty alcohols myristyl, cetearyl and / or stearyl alcohols.

6. Preparation according to one of the preceding claims, characterized in that as wax Cera Microcristallina, Coco glyceride, C18-36 acid triglyceride, synthetic wax, Cera Alba, paraffin, Copernicia cerifera Cera, C18-38 alkyl hydroxystearoyl stearate, Butyrospermum Parkii butter, Olus oil, C20-40 alcohol and / or beeswax.

7. Preparation according to one of the preceding claims, characterized in that one or more film formers are included.

8. Preparation according to claim 7, characterized in that as a film former

Hexadecene copolymer, trimethylsiloxysilicate, polypropylsilsesquioxane, polysilicone-25, acrylate copolymer, polyurethane, methacrylate, polyglyceryl stearate, dilinoleate crosspolymer, alkyl acrylate / methacrylic acid crosspolymer, IPDI copolymer, especially VP / hexadecene copolymer, octyldodecyl citrate crosspolymer, trimethylsiloxysilicate / polypropylsilsesquioxane, ammonium acrylate copolymer , Acrylate Copolymer, Polyurethane-2 and Polymethylmethacrylate, Polyglyceryl Stearate / Isostearate Dilinoleate Crosspolymer, Octadecene / MA Copolymer (and)

Methyl acetylricinoleate (and) diisooctyl adipate, trimethylsiloxysilicate, polyurethane-34, C8-22 alkyl acrylate / methacrylic acid crosspolymer and / or castor oil / IPDI copolymer.

9. Preparation according to claim 7 or 8, characterized in that are selected as film former Castor Oil / IPDI copolymer, trimethylsiloxysilicate / Polypropylsilsesquioxan and / or acrylate copolymer.

10. Preparation according to claim 7, 8 or 9, characterized in that the film former or the film formers to a proportion of 0.1 to 10 wt.%, Based on the total mass of the preparation are selected.

1 1. A preparation according to one of the claim 1 or 2, characterized in that as

Repellents one or more substances from the group N, N-diethyl-m-toluamide (DEET), N, N-diethylphenylacetamide (DEPA), Ethylbutylacteylaminopropionat (IR 3535®, Merck), p-menthane-3,8-diol, picaridine (KBR 3023), citronella oil, lemon oil, eucalyptus oil and / or neem oil.

12. Preparation according to one of the preceding claims, characterized in that the repellents are lipophilic.

13. Preparation according to one of the preceding claims, characterized in that the proportion of repellents in the range 0.001 to 1 wt.%, Based on the

Total mass of the preparation is selected.

14. Preparation according to one of the preceding claims, characterized in that one or more skin moisturizing agents are included.

15. Preparation according to one of the preceding claims, characterized in that the preparation is free of surfactants.

16. Use of the preparation according to one of the above on wet skin.