WO2014123025A1

WO2014123025A1 - Method for producing biaxially oriented film, biaxially oriented film, and laminated film

Info

Publication number: WO2014123025A1
Application number: PCT/JP2014/051742
Authority: WO
Inventors: 真男高重
Original assignee: 出光ユニテック株式会社
Priority date: 2013-02-08
Filing date: 2014-01-28
Publication date: 2014-08-14
Also published as: TW201441014A; JP2014151566A

Abstract

In the present invention, 5-40 mass% inclusive of a thermal history article comprising Ny6 and MXD6 having a melting point of 233-238°C inclusive is added for every 100 mass% of a starting material resulting from melting and mixing at a proportioning ratio of 40-85 mass% inclusive of Ny6 and 15-60 mass% inclusive of MXD6, and then the result is subjected to melt extrusion, forming an original film. The original film is biaxially oriented in a manner such that the greatest strain rate in both an MD direction and TD direction is at least 2.5 sec^-1, and then thermosetting is performed, obtaining a biaxially oriented film having an impact strength of at least 50000 J/m and an Elmendorf tear strength of no greater than 65 N/cm.

Description

Biaxially stretched film manufacturing method, biaxially stretched film, and laminate film

The present invention relates to a method for producing a biaxially stretched film, a biaxially stretched film, and a laminate film.

In the fields of food and medicine, industrial fields such as electronic parts, and the like, the required characteristics for technologies that impart easy tearability to packaging materials are increasing. In particular, easy tearability is desired for packaging materials subjected to high heat treatment such as packaging materials for retort foods and packaging materials for liquid foods. As such a wrapping material, a configuration is adopted in which a predetermined amount of a heat history product is added to impart easy tearability and prevent delamination within the film plane (see, for example, Patent Document 1). ).
The easily tearable film described in Patent Document 1 defines the compounding ratio of nylon 6 (hereinafter also referred to as Ny6) which is a raw material and metaxylylene adipamide (hereinafter also referred to as MXD6). By adding a predetermined amount of the heat history product, easy tearability is imparted and in-layer peeling is prevented in the film plane.

JP 2012-81676 A

However, in recent years, a contradictory function of maintaining high impact strength and being easily tearable has been required for packaging materials subjected to high heat treatment, such as retort food packaging materials and liquid food packaging materials. Therefore, further improvement is desired.

The object of the present invention is to provide a method for producing a biaxially stretched film, a biaxially stretched film, and a laminate film that are excellent in impact strength and tearability.

The method for producing a biaxially stretched film of the present invention is a method for producing a biaxially stretched film obtained by biaxially stretching nylon 6 (hereinafter also referred to as Ny6) and metaxylylene adipamide (hereinafter also referred to as MXD6). The Ny6 and the melting point are 233 ° C. or higher and 238 ° C. with respect to 100% by mass of the raw material melt-kneaded at a mixing ratio of 40% by mass to 85% by mass and MXD6 of 15% by mass to 60% by mass. After adding a heat history product consisting of the following MXD6 at 5% by mass or more and 40% by mass or less, an original film production process for forming an original film by melt extrusion, and the original film in MD and TD directions And a biaxial stretching step in which biaxial stretching is performed at a maximum strain rate of 2.5 sec ⁻¹ or more.

And in this invention, it is preferable to set it as the structure which implements the heat setting process of heat-setting at 160 degreeC or more and 215 degrees C or less after the said biaxial stretching process.
In the present invention, the biaxial stretching step is preferably biaxially stretched by a tubular simultaneous biaxial stretching method.

The biaxially stretched film of the present invention is produced by the method for producing a biaxially stretched film of the present invention.
And in this invention, it is preferable that impact strength is 50000 J / m or more.
In the present invention, the Elmendorf tear strength is preferably 65 N / cm or less.

The laminate film of the present invention is characterized by having a laminated structure having a layer of the biaxially stretched film of the present invention.

According to the present invention, a resin composition having a predetermined composition comprising Ny6 and MXD6 is biaxially stretched under a condition of a predetermined maximum strain rate, so that it has excellent tearability and high strength, and a predetermined heat history product is added. Therefore, it is possible to provide an excellent biaxially stretched film that does not cause an intralayer peeling phenomenon.

Hereinafter, the best mode for carrying out the present invention will be described in detail.
[Configuration of biaxially stretched film]
The biaxially stretched film according to this embodiment is obtained by biaxially stretching a polyamide resin composition composed of Ny6 and MXD6. Here, for the biaxial stretching, a simultaneous biaxial stretching method or a sequential biaxial stretching method can be used, but in order to keep the maximum strain rate during stretching within the range of the present invention, a tubular simultaneous biaxial stretching is used. It is particularly preferred to use the method.

The polyamide resin composition has a melting point of MXD6 of 100% by mass of virgin raw material melt-kneaded in a ratio of Ny6 and MXD6 of 40% by mass to 85% by mass: 15% by mass to 60% by mass. It is obtained by adding a heat history product of 233 ° C. or more and 238 ° C. or less at 5% by mass or more and 40% by mass or less.
Here, the chemical formula of Ny6 is shown in the following chemical formula 1, and the chemical formula of MXD6 is shown in the chemical formula 2 below.

The above-mentioned virgin raw material usually means a raw material that is not a mixed raw material having a history in which Ny6 and MXD6 are mixed and melt-kneaded. For example, even if Ny6 and MXD6 have a history of being melt-kneaded independently (for example, recycled products), they are virgin raw materials when they are not mixed and melt-kneaded.
The mixing ratio of Ny6 and MXD6 in the virgin raw material is that Ny6 is 40% by mass to 85% by mass and MXD6 is 15% by mass to 60% by mass from the viewpoint of impact strength and easy tearability of the biaxially stretched film. Is preferred. In addition, when MXD6 in a virgin raw material is less than 15 mass%, there exists a possibility that the effect of easy tearing may not fully be acquired. On the other hand, when MXD6 is more than 40% by mass, the impact strength is greatly lowered and the practicality becomes poor.

The heat history product is a blended product of Ny6 and MXD6, which has passed through the extruder once. For the present invention, the melting point of MXD6 is 233 ° C. or more and 238 ° C. or less, preferably by a differential scanning calorimeter (DSC), preferably What was hold | maintained in the range of 235 degreeC or more and 237 degrees C or less is used. The heat history product may be a product obtained by recycling the polyamide layer obtained by the present embodiment. Since such a heat history product functions as a compatibilizing agent having affinity for both Ny6 and MXD6, the occurrence of in-layer peeling can be prevented by adding such a heat history product to the polyamide resin mixture.
Here, in-layer peeling refers to a phenomenon in which peeling occurs in a polyamide layer when a biaxially stretched film is laminated with an appropriate sealant film and then the seal portion is opened. The mechanism of this delamination is not necessarily clear, but it is considered that Ny6 and MXD6 are oriented in layers in the polyamide layer, and delamination occurs at the interface.
In addition, the melting point of MXD6 in the heat history product composed of Ny6 and MXD6 refers to the melting point measured in the state before melt-kneading with the virgin raw material. When the melting point of MXD6 in the heat history product is less than 233 ° C., the impact strength of the polyamide layer decreases. In addition, when the melting point of MXD6 in the heat history product is 238 ° C. or higher, the effect of preventing in-layer peeling is reduced.

The content of the heat history product is 5% by mass or more and 40% by mass or less based on 100% by mass of the total amount of the virgin raw material. When the heat history product is less than 5% by mass, when it is used under severe conditions such as cold forming after being formed into a laminate film, it is easy to cause in-layer peeling in the polyamide layer. On the other hand, if the heat history product exceeds 40% by mass, the impact strength of the polyamide layer decreases.
The blending ratio of Ny6 and MXD6 in the thermal history product may be Ny6: MXD6 = 60% by mass or more and 85% by mass or less: 15% by mass or more and 40% by mass or less from the viewpoint of impact strength and anti-layer peeling effect. preferable. In addition, when the blending ratio of MXD6 in the heat history product is less than 15% by mass (the blending ratio of Ny6 is more than 85% by mass), the effect of preventing in-layer peeling of the polyamide layer tends to be low. When the mixing ratio of MXD6 in the heat history product exceeds 40% by mass (the mixing ratio of Ny6 is less than 60% by mass), the impact strength of the polyamide layer tends to decrease.

It should be noted that necessary additives can be appropriately added to the polyamide layer. Examples of such additives include anti-blocking agents (such as inorganic fillers), water repellents (such as ethylene bis stearates), and lubricants (such as calcium stearate).

The biaxially stretched film of the present invention can be applied to various uses by laminating other laminate base materials. Examples of the laminate substrate include an aluminum layer, a film including the aluminum layer, and a sealant layer.
In the laminate packaging material of this embodiment, the total thickness of the biaxially stretched film layer and the other laminate base material is preferably 200 μm or less. When the total thickness exceeds 200 μm, it is difficult to obtain excellent tearability.

As the aluminum layer used in the laminate packaging material of this embodiment, an aluminum foil made of a soft material of pure aluminum or an aluminum-iron alloy can be used. In this case, from the viewpoint of improving the laminating performance, the aluminum foil is subjected to a pretreatment such as an undercoat treatment or a corona discharge treatment with a silane coupling agent or a titanium coupling agent, and then laminated on the ONy film. Is preferred.
The thickness of such an aluminum layer is preferably 5 μm or more and 50 μm or less. Thereby, oxygen, moisture, etc. can be prevented from permeating through the laminate packaging material.
In addition, when the thickness of the aluminum layer is less than 5 μm, there is a possibility that oxygen, moisture, etc. may permeate through the laminate packaging material. On the other hand, when the thickness of the aluminum layer exceeds 50 μm, it may be difficult to obtain easy tearability.

Furthermore, in addition to the laminate base material and the sealant layer, various functional layers such as an antistatic layer, a printed layer, a barrier layer, and a strength reinforcing layer may be laminated.

[Method for producing biaxially stretched film]
The biaxially stretched film as described above can be suitably produced by a simultaneous biaxial stretching method using a tubular method. Specifically, it can be produced as follows.
First, in the raw film manufacturing process, Ny6 is 40% by mass to 85% by mass, MXD6 is melt-kneaded at a blending ratio of 15% by mass to 60% by mass, and Ny6 is 40% by mass to 85% by mass. Hereinafter, MXD6 is blended in an amount of 15% by mass to 60% by mass and a heat history product having a melting point of MXD6 of 233 ° C. or more and 238 ° C. or less is 5% by mass to 40% by mass with respect to 100% by mass of the virgin raw material. % Or less and melt-kneaded to prepare a melt of this polyamide resin composition.
Next, after melt-extruding a polyamide melt as a cylindrical film from an annular die, it is then rapidly cooled to produce a raw fabric film (raw fabric bubble).

After this, in the biaxial stretching process, the raw fabric bubble is inserted between a pair of nip rolls, and then heated by a heater from the outside through a stretching furnace while gas is being injected into the air bubble. Air is blown from the outside to expand the raw fabric bubble, and taken up by a pair of downstream nip rolls, thereby performing simultaneous biaxial stretching in the MD direction and TD direction by the tubular method to form a stretched bubble. At this time, the maximum strain rate is 2.5 sec ⁻¹ or more in both the MD direction and the TD direction. The maximum strain rate is preferably 3sec ^-1 or 15 sec ^-1 or less.
Here, the maximum strain rate is calculated by calculating the rate of change in the MD direction and the TD direction at each position from the start of stretching to the end of stretching of the original fabric bubble, and indicates the maximum value. The maximum strain rate can be controlled, for example, by adjusting the discharge amount when the melt is melt-extruded from the annular die, and the size (diameter and length) of the annular die and the drawing furnace.

Such a maximum strain rate can be specifically obtained by the following method.
First, a film sample in the middle of stretching is collected. Then, a change in the folding diameter (width) of the sample with respect to the moving distance in the moving direction of the sample is measured, and a curve indicating the relationship between the moving distance and the folding diameter (width) of the sample is created. Here, the time from the start of stretching can be calculated from the moving distance. Moreover, the relationship between the folding diameter of the sample, the folding diameter (width) of the raw film (unstretched film), and the stretching ratio in the TD direction is expressed by the following formula:
(Folded diameter of sample (width)) / (Folded diameter of raw film (width)) = (Stretch ratio in TD direction)
Therefore, by dividing the folding diameter (width) of the sample by the folding diameter (width) of the original film, the stretching ratio in the TD direction can be calculated. Therefore, a curve indicating the relationship between the time from the start of stretching and the stretching ratio in the TD direction can be created from a curve indicating the relationship between the moving distance and the folding diameter of the sample.

Next, for the sample described above, a change in the thickness of the sample with respect to the moving distance in the moving direction of the sample is measured, and a curve indicating the relationship between the moving distance and the thickness of the sample is created. Here, the time from the start of stretching can be calculated from the moving distance. Moreover, the relationship between the thickness of the sample, the thickness of the raw film, and the overall draw ratio of MD × TD is expressed by the following formula:
(Thickness of original film) / (Thickness of sample) = (Total draw ratio of MD × TD)
Therefore, the total draw ratio of MD × TD can be calculated by dividing the thickness of the sample from the thickness of the raw film. Moreover, the relationship between the MD × TD total draw ratio, the TD direction draw ratio, and the MD direction draw ratio is given by the following formula:
(MD × TD total draw ratio) / (TD direction draw ratio) = (MD direction draw ratio)
Therefore, by dividing the calculated stretching ratio in the TD direction from the total stretching ratio of MD × TD, the stretching ratio in the MD direction can be calculated. Therefore, a curve indicating the relationship between the time from the start of stretching and the stretching ratio in the MD direction can be created from the curve indicating the relationship between the moving distance and the thickness of the sample.
With the two curves that can be created as described above, the change state of the draw ratio in the MD direction and the TD direction with respect to the time from the start of drawing can be quantified. In these curves, the maximum strain rate in the MD direction and the TD direction can be obtained by obtaining the slope of the portion where the slope of the curve is maximum.
It should be noted that when either the MD direction or the TD direction becomes slower than 2.5 sec ⁻¹ , the maximum strain rate decreases the impact strength (for example, decreases to less than 50000 J / m), and easily tears and linearly cuts. This causes the disadvantage of lowering.

And after the above-mentioned biaxial stretching process, the stretched film is put in a tenter type heat treatment furnace, and the biaxially stretched film of this embodiment is obtained by carrying out a heat setting process of heat setting at 160 to 215 ° C. Obtainable.
The obtained biaxially stretched film has an impact strength of 50,000 J / m or more, particularly 53000 J / m or more, and an Elmendorf tear strength of 65 N / cm or less, particularly 63 N / cm or less.

As described above, in the above embodiment, the melt of the polyamide resin composition having a predetermined composition composed of Ny6 and MXD6 is biaxially stretched under the condition of a predetermined maximum strain rate, so that it is excellent in easy tearing and impact strength. In addition, since a predetermined heat history product is added, an excellent biaxially stretched film that does not cause an in-layer peeling phenomenon can be provided.

Although the best configuration for carrying out the present invention has been disclosed in the above description, the present invention is not limited to this. That is, the present invention has been described primarily with reference to specific embodiments, but with respect to the above-described embodiments without departing from the scope of the technical idea and object of the present invention, the material, quantity, and other details. In this configuration, those skilled in the art can make various modifications.
Accordingly, the description of the materials, layer structures, and the like disclosed above is exemplary for easy understanding of the present invention, and does not limit the present invention. Descriptions with names excluding some or all of the limitations are included in the present invention.
For example, in this embodiment, the tubular method is adopted as the simultaneous biaxial stretching method, but a tenter method may be used.
Moreover, not only simultaneous biaxial stretching but it is good also as sequential biaxial stretching.

Next, the present invention will be described in more detail with reference to examples and comparative examples. However, the present invention is not limited to these examples.

[Example 1]
To 100% by mass of virgin raw material with 70% by mass of Ny6 and 30% by mass of MXD6, 25% by mass of a heat history product having a melting point of MXD6 of 236 ° C was added, and after melt extrusion at 270 ° C, The raw film was prepared by cooling.
Ny6: nylon 6 manufactured by Ube Industries, Ltd. (UBE nylon 1022FD (trade name), relative viscosity ηr = 3.5)
MXD6; MXD6 manufactured by Mitsubishi Gas Chemical Co., Ltd. (MAX nylon 6007 (trade name))

The original tubular biaxial stretch the fabric film, stretching ratio MD / TD = 3.5 / 3.2, the maximum strain rate MD5.0Sec ^-1, after simultaneous biaxial stretching under the condition of TD3.5Sec ^-1, tenter The film was heat-set at 210 ° C. with a heat treatment apparatus to produce a biaxially stretched film having a thickness of 15 μm. The obtained biaxially stretched film had good stretch moldability and good thickness accuracy.
And the polypropylene-type sealant film was laminated | stacked on the obtained biaxially stretched film, and the laminate film was produced. The following evaluation was performed on this laminate film. The results are shown in Table 1 below.

(In-layer peeling)
A strip-shaped test piece having a width of 15 mm was cut out from the laminate film, and the end thereof was subjected to interfacial peeling by several cm by hand to separate it into a biaxially stretched film and a sealant film. Thereafter, each film piece was set in a tensile tester (Instron universal tester 1123 type), and a peel test of the laminate portion was performed at a speed of 300 mm / min (90 ° peel). In addition, since peeling strength will sharply reduce if the peeling in the layer occurs in the biaxially stretched film during the peeling test, it can be determined whether or not the peeling in the layer has occurred depending on whether or not such a behavior has occurred. For example, at the start of the peel test, if the peel strength is about 7 N / 15 mm width, but suddenly decreases to about 1 to 2 N / 15 mm width in the middle of the peel test, it can be judged that peeling within the layer has occurred. .
And the thing which did not show the behavior of peeling in a layer inside a biaxially stretched film was determined as "A", and the thing which showed the behavior of peeling in a layer was determined as "B".

(Easily tearable: straight cut)
The tear strength was measured with a biaxially stretched film not laminated with a polypropylene sealant film. Based on the Elmendorf tear strength test (JISK 7128), the tear strength in the MD direction and the TD direction of the biaxially stretched film was measured.
The tear strength of 70 N / cm or less was evaluated as “A”, and 71 N / cm or more was evaluated as “B”.

(Impact strength)
The impact strength (J / m) of the biaxially stretched film was measured using a film impact tester (manufactured by Toyo Seiki, 30 Kg-cm 1/2 inch hemispherical head). The measurement results were evaluated according to the following criteria.
A: 50000 J / m or more B: Less than 50000 J / m

(Comprehensive evaluation)
When there was no “B” in each evaluation item, the overall evaluation was “A”, and when there was at least one “B”, the overall evaluation was “B”.

[Example 2]
Example 1 except that the heat history product of Example 1, the thickness of the biaxially stretched film, the conditions of the tubular biaxial stretching, and the temperature of heat setting in the tenter thermal test apparatus were changed as shown in Table 1 and below. In the same manner as in Example 1, a biaxially stretched film was obtained. And it evaluated similarly to Example 1. FIG.
・ History product: 15% by mass of heat history product with MXD6 melting point of 237 ° C. added to 100% by mass of virgin raw material ・ Thickness dimension: 25 μm
-Stretch ratio MD / TD = 3.5 / 3.5
Maximum strain rate: MD direction 3.5 sec ⁻¹ , TD direction 3.1 sec ⁻¹
・ Heat setting temperature: 213 ℃

[Example 3]
Except for changing the blending ratio of the virgin raw material and the heat history product of Example 1, the conditions of tubular biaxial stretching, and the temperature of heat setting in the tenter thermal test apparatus as shown in Table 1 and below, the same as Example 1 Thus, a biaxially stretched film was obtained. And it evaluated similarly to Example 1. FIG.
・ Virgin raw materials: Ny6 75% by mass, MXD6 25% by mass
・ History product: 15% by mass of heat history product with MXD6 melting point of 237 ° C. added to 100% by mass of virgin raw material ・ Stretch ratio MD / TD = 3.3 / 3.3
Maximum strain rate: MD direction 7.5 sec ⁻¹ , TD direction 6.7 sec ⁻¹
・ Heat setting temperature: 213 ℃

[Example 4]
Except for changing the blending ratio of the virgin raw material and the heat history product of Example 1, the conditions of tubular biaxial stretching, and the temperature of heat setting in the tenter thermal test apparatus as shown in Table 1 and below, the same as Example 1 Thus, a biaxially stretched film was obtained. And it evaluated similarly to Example 1. FIG.
・ History product: 15% by mass of heat history product with MXD6 melting point of 237 ° C. added to 100% by mass of virgin raw material ・ Stretch ratio MD / TD = 3.5 / 3.5
• The maximum strain rate: MD direction ^9.0sec -1, TD direction 8.2sec ^-1
・ Heat setting temperature: 213 ℃

[Example 5]
A biaxially stretched film was obtained in the same manner as in Example 1 except that the blending ratio of the virgin raw material and the heat history product of Example 1 and the conditions of tubular biaxial stretching were changed as shown in Table 1 and below. It was. And it evaluated similarly to Example 1. FIG.
・ Virgin raw materials: Ny6 72% by mass, MXD6 28% by mass
Thermal history products: For virgin material 100 wt%, the thermal history article 20 mass% additives, maximum strain rate: MD direction ^{2.8 sec} -1, TD direction 2.5sec ^-1

[Comparative Example 1]
A biaxially stretched film was obtained in the same manner as in Example 1 except that the conditions of the tubular biaxial stretching of Example 1 were changed as shown in Table 1 and the following. And it evaluated similarly to Example 1. FIG.
Maximum strain rate: MD direction 2.3 sec ⁻¹ , TD direction 0.6 sec ⁻¹

[Comparative Example 2]
Instead of the tubular biaxial stretching of Example 1, the film was stretched simultaneously in the longitudinal and lateral directions under the following conditions by the simultaneous biaxial stretching tenter method, and then heat-set in the same manner as in Example 1 to obtain a stretched film. It was. And it evaluated similarly to Example 1. FIG.
-Tenter method simultaneous biaxial stretching method-Maximum strain rate: MD direction 0.5 sec ^-1 TD direction 0.5 sec ^-1

[Comparative Example 3]
Instead of the tubular biaxial stretching of Example 1, after sequentially stretching in the longitudinal and lateral directions under the following conditions by a sequential biaxial stretching tenter method, the film was heat-fixed in the same manner as in Example 1 to determine the thickness dimension. A stretched film of 25 μm was obtained. And it evaluated similarly to Example 1. FIG.
・ Thickness dimension: 25μm
· Tenter successive biaxial stretching method, maximum strain rate: MD direction ^{0.3 sec} -1, TD direction 0.3 sec ^-1

[Comparative Example 4]
Instead of the tubular biaxial stretching of Example 1, the film was sequentially stretched in the longitudinal and lateral directions under the following conditions by a sequential biaxial stretching tenter method, and then thermally fixed in the same manner as in Example 1 to have a thickness of 15 μm. A stretched film was obtained. And it evaluated similarly to Example 1. FIG.
・ Thickness dimension: 15μm
・ Tenter method sequential biaxial stretching method ・ Maximum strain rate: MD direction 0.4 sec ⁻¹ , TD direction 0.3 sec ⁻¹

[result]
As shown in Table 1, in Comparative Example 2, it is biaxially stretched by the tenter type simultaneous biaxial stretching method, and in Comparative Examples 3 and 4, since it is biaxially stretched by the tenter type sequential stretching method, The maximum strain rate within the range of the present invention in which biaxial stretching is performed by the tubular simultaneous biaxial stretching method is not obtained. Therefore, in these Comparative Examples 2 to 4, the impact strength was weak and the tearability was not sufficient. In Comparative Example 1, biaxial stretching is performed by the tubular simultaneous biaxial stretching method, but the impact strength is inferior because the maximum strain rate is outside the scope of the present invention.
On the other hand, in Examples 1 to 5, biaxial stretching was performed at the maximum strain rate within the range of the present invention by the tubular simultaneous biaxial stretching method, so that easy tearability and film impact strength were good.

The present invention can be used as a method for producing a biaxially stretched film having excellent impact strength and easy tearability, a biaxially stretched film, and a laminate film in food and pharmaceutical fields, industrial fields, and the like.

Claims

A method for producing a biaxially stretched film obtained by biaxially stretching nylon 6 (hereinafter also referred to as Ny6) and metaxylylene adipamide (hereinafter also referred to as MXD6),
The Ny6 and the melting point are 233 ° C. or more and 238 ° C. or less with respect to 100% by mass of the raw material melt-kneaded with a mixing ratio of 40% by mass to 85% by mass and MXD6 of 15% by mass to 60% by mass. After adding the heat history goods which consist of MXD6 in 5 mass% or more and 40 mass% or less, the original film production process which shape | molds an original film by melt-extrusion,
A biaxial stretching step in which the original film is biaxially stretched at a maximum strain rate of 2.5 sec −1 or more in both the MD and TD directions. .
A method for producing a biaxially stretched film according to claim 1,
After the said biaxial stretching process, the heat setting process of heat-setting at 160 degreeC or more and 215 degrees C or less is implemented. The manufacturing method of the biaxial stretching film characterized by the above-mentioned.
A method for producing a biaxially stretched film according to claim 1 or 2,
The method for producing a biaxially stretched film, wherein the biaxial stretching step is biaxially stretched by a tubular simultaneous biaxial stretching method.
It manufactured with the manufacturing method of the biaxially stretched film as described in any one of Claim 1- Claim 3. The biaxially stretched film characterized by the above-mentioned.
The biaxially stretched film according to claim 4,
The biaxially stretched film characterized by having an impact strength of 50000 J / m or more.
The biaxially stretched film according to claim 4 or 5, wherein
The biaxially stretched film characterized by having an Elmendorf tear strength of 65 N / cm or less.
It is a laminated structure which has the layer of the biaxially stretched film as described in any one of Claim 4 to 6. The laminated film characterized by the above-mentioned.