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WO2013104226A1 - Thin film transistor, manufacturing method therefor, array substrate and display device - Google Patents

Thin film transistor, manufacturing method therefor, array substrate and display device Download PDF

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Publication number
WO2013104226A1
WO2013104226A1 PCT/CN2012/086217 CN2012086217W WO2013104226A1 WO 2013104226 A1 WO2013104226 A1 WO 2013104226A1 CN 2012086217 W CN2012086217 W CN 2012086217W WO 2013104226 A1 WO2013104226 A1 WO 2013104226A1
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Prior art keywords
layer
semiconductor
thin film
film transistor
active layer
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PCT/CN2012/086217
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French (fr)
Chinese (zh)
Inventor
袁广才
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京东方科技集团股份有限公司
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Publication of WO2013104226A1 publication Critical patent/WO2013104226A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78606Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device
    • H01L29/78618Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device characterised by the drain or the source properties, e.g. the doping structure, the composition, the sectional shape or the contact structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66969Multistep manufacturing processes of devices having semiconductor bodies not comprising group 14 or group 13/15 materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/7869Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising an oxide semiconductor material, e.g. zinc oxide, copper aluminium oxide, cadmium stannate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78696Thin film transistors, i.e. transistors with a channel being at least partly a thin film characterised by the structure of the channel, e.g. multichannel, transverse or longitudinal shape, length or width, doping structure, or the overlap or alignment between the channel and the gate, the source or the drain, or the contacting structure of the channel

Definitions

  • Embodiments of the present invention relate to a thin film transistor and a method of fabricating the same, an array substrate, and a display device. Background technique
  • OTFT Oxide Thin Film Transistor
  • FIG. 1 is a schematic structural view of a thin film transistor in the prior art.
  • the gate electrode 11, the gate insulating layer 12, the semiconductor active layer 13, the etch stop layer 14, the source electrode 15a, the drain electrode 15b, and the blunt are sequentially formed on the glass substrate 10 by a 6-time exposure mask (Mask) process.
  • the layer 16 and the pixel electrode 18, and the drain electrode 15b are connected to the pixel electrode 18 through the via hole 17.
  • the semiconductor active layer 13 is made of a metal oxide such as indium gallium oxide IGZO.
  • the performance of the active layer determines the characteristics of the thin film transistor, and the conventional oxide thin film transistor shown in FIG. 1 cannot achieve a high off-state current ion while having a low off-state current Ioff, thereby failing to secure an oxide.
  • the performance of thin film transistors ultimately affects the performance of the product. Summary of the invention
  • Embodiments of the present invention provide a thin film transistor, a method of fabricating the same, an array substrate, and a display device, which realize a high on-state current Ion and a low off-state current Ioff to improve characteristics of the thin film transistor.
  • a thin film transistor comprising: a gate, a gate insulating layer, a semiconductor active layer, a source electrode and a drain electrode, wherein the semiconductor active layer is a multilayer structure including at least a semiconductor layer having high conductivity and a low conductivity a semiconductor layer having a high conductivity; the semiconductor layer having a high conductivity is adjacent to the gate, and a semiconductor layer having a low conductivity is adjacent to the source electrode and the drain electrode.
  • a method of manufacturing a thin film transistor comprising: a process of forming a gate electrode, a gate insulating layer, a semiconductor active layer, a source electrode, and a drain electrode on a substrate; wherein, the process of forming the semiconductor active layer
  • the method includes: forming a semiconductor layer having a high conductivity near the gate side; and forming a semiconductor layer having a low conductivity near the source electrode and the drain electrode side.
  • An array substrate comprising the above thin film transistor.
  • a display device comprising the above array substrate.
  • the thin film transistor and the manufacturing method thereof, the array substrate and the display device provided by the embodiments of the present invention layer-by-layer preparation of a high-conductivity semiconductor layer and a low-conductivity semiconductor layer; further, the formed semiconductor active layer includes two layers And a structure of two or more layers, and the semiconductor active layer close to the gate is formed of a semiconductor layer having high conductivity, achieving a high on-state current Ion, and a top layer of the semiconductor active layer close to the source and drain electrodes is turned on The ability to form a semiconductor layer achieves a low off-state current Ioff. The high on-state current Ion improves the characteristics of the oxide thin film transistor and ultimately ensures the performance of the product.
  • FIG. 1 is a schematic structural view of a thin film transistor in the prior art
  • FIG. 2 is a schematic structural diagram of a thin film transistor according to an embodiment of the present invention.
  • FIG. 3A is a first schematic view showing a manufacturing process of an array substrate according to an embodiment of the present invention
  • FIG. 3B is a second schematic diagram of manufacturing an array substrate according to an embodiment of the present invention
  • 3C is a third schematic diagram of manufacturing an array substrate according to an embodiment of the present invention.
  • 3D is a fourth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention.
  • 3E is a fifth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention.
  • 3F is a sixth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention.
  • 3G is a seventh schematic diagram of manufacturing an array substrate according to an embodiment of the present invention.
  • 3H is an eighth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention.
  • FIG. 31 is a ninth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention.
  • FIG. 3 is a fourth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention.
  • FIG. 3K is an eleventh schematic diagram of manufacturing an array substrate according to an embodiment of the present invention.
  • FIG. 3L is a twelfth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention
  • FIG. 3 is a thirteenth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention
  • FIG. 3L is a twelfth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention
  • FIG. 3 is a thirteenth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention
  • FIG. 4 is a schematic structural diagram of a thin film transistor according to another embodiment of the present invention.
  • FIG. 5A is a first schematic diagram of manufacturing an array substrate according to another embodiment of the present invention.
  • FIG. 5B is a second schematic diagram of manufacturing an array substrate according to another embodiment of the present invention.
  • FIG. 5C is a third schematic diagram of manufacturing an array substrate according to another embodiment of the present invention.
  • FIG. 5D is a fourth schematic diagram of manufacturing an array substrate according to another embodiment of the present invention.
  • FIG. 5E is a fifth schematic diagram of manufacturing an array substrate according to another embodiment of the present invention. detailed description
  • An embodiment of the present invention provides a thin film transistor including: a gate, a gate insulating layer, a semiconductor active layer, a source electrode, and a drain electrode;
  • the semiconductor active layer is a multilayer structure including at least a high-conductivity semiconductor layer and a low-conductivity semiconductor layer; wherein the high-conductivity semiconductor layer is close to the gate, and low-conducting capability
  • the semiconductor layer is adjacent to the source and drain electrodes.
  • the thin film transistor When the thin film transistor is a bottom gate structure, the thin film transistor includes a gate, a gate insulating layer, a semiconductor active layer, an etch barrier layer, and source and drain electrodes, wherein the gate is under the semiconductor active layer, the source electrode and the drain electrode The electrode is located above the semiconductor active layer; the semiconductor active layer is a multilayer structure including an etch barrier layer between the semiconductor active layer and the source and drain electrodes.
  • the thin film transistor When the thin film transistor is a top gate structure, the thin film transistor includes a gate, a gate insulating layer, a semiconductor active layer, and a source/drain barrier layer, wherein the gate is above the semiconductor active layer, and the source and drain electrodes are located at the semiconductor active layer Below.
  • a thin film transistor includes: a gate 202 sequentially formed on a substrate 201, a gate insulating layer 203, a semiconductor layer 204 having high conductivity, and low conduction. Capacitive semiconductor layer 205, etch stop layer 206, metallization semiconductor layer, and data line metal layer.
  • the high-conductivity semiconductor layer 204 and the low-conductivity semiconductor layer 205 constitute a semiconductor active layer, the semiconductor active layer is made of a metal oxide material; the etch stop layer 206 is over the oxide semiconductor active layer, Metalized semiconductor layers 207a and 207b on both sides of the etch barrier layer 206 are further formed over the oxide semiconductor active layer, and the data line metal layer includes a data line, a source electrode 208a and a drain electrode 208b of the thin film transistor. .
  • the oxide semiconductor active layer is formed by two or more layers using a layered optimization scheme. As shown in FIG. 2, the underlayer of the oxide semiconductor active layer of the bottom gate structure is a high conductivity semiconductor layer 204 having a high conductivity, and the top layer of the oxide semiconductor active layer is a semiconductor layer 205 having a low conductivity. Formed, but the oxide semiconductor active layer is formed by using a low-oxygen, high-conductivity semiconductor to improve the device's conduction capability, ie, to increase the on-state current (Ion) of the device; An oxide semiconductor with high oxygen content and low conductivity is used to control the leakage current of the device, that is, to reduce the off current (Ioff) of the device, thereby improving device performance.
  • a low-oxygen, high-conductivity semiconductor to improve the device's conduction capability, ie, to increase the on-state current (Ion) of the device.
  • An oxide semiconductor with high oxygen content and low conductivity is used to control the leakage current of the device, that is, to
  • the top layer of the semiconductor active layer is a semiconductor layer with high conductivity
  • the bottom layer of the active layer of the oxide semiconductor is formed of a semiconductor layer with low conductivity, an oxide semiconductor.
  • the purpose of the active layer formation is to use a low-oxygen, high-conductivity semiconductor on the top layer to improve the device's conduction capability, ie, to increase the on-state current (Ion) of the device; the underlying semiconductor uses high oxygen content, A low-conductivity oxide semiconductor that controls the device's leakage current, which reduces the off-state current (Ioff) of the device, thereby improving device performance.
  • Those skilled in the art can select the bottom gate or top gate structure according to the actual situation of the product.
  • an etch stop layer is formed thereon as shown at 206 in FIG.
  • a plasma (plasma) treatment of a gas such as hydrogen, N 2 0, CF 4 or Ar is performed on the oxide semiconductor active layer exposed on both sides of the etch barrier layer, in the oxide semiconductor
  • a metallized semiconductor layer is formed on the surface of the active layer, as shown in Fig. 2, 207a and 207b.
  • the metallization of the semiconductor layer reduces the contact resistance of the active layer of the oxide semiconductor with the source and drain electrodes, thereby improving the ohmic contact characteristics of the device.
  • the combination of the oxide semiconductor active layer, the metallized semiconductor layer, and the source and drain electrodes can achieve better output of device performance.
  • another thin film transistor includes: a gate electrode 602 sequentially formed on a substrate (for example, a transparent glass substrate) 601, a gate insulating layer 603, and a semiconductor layer having high conductivity.
  • a patterned low-oxygen, high-conductivity semiconductor transition layer 607a and 607b is formed over the patterned etch stop layer 606;
  • a source electrode 608a and a drain electrode 608b are formed over the semiconductor transition layers 607a and 607b.
  • the semiconductor transition layers 607a and 607b have a thickness of 5 to 50 nm, and the semiconductor transition layer is made of the same material as the high conductivity semiconductor layer.
  • the semiconductor transition layer having high conductivity can reduce the contact resistance between the active layer of the oxide semiconductor and the source and drain electrodes, thereby improving the ohmic contact characteristics of the device.
  • the oxide semiconductor active layer and the semiconductor transition layer are combined with the source electrode and the drain electrode to form a sandwich TFT device, which can simultaneously have a high on-state current Ion and a low off-state current loff, and can solve the source electrode.
  • the ohmic contact problem with the drain electrode thereby maximally improving the performance of the TFT device.
  • One of the features of the embodiments of the present invention is that in the process of fabricating an oxide TFT, the layered optimization scheme of the above sandwich structure is used to improve the performance of the device.
  • the thin film transistor provided by the invention can improve the on-state current (Ion) of the TFT device due to the layer-optimized oxide semiconductor active layer, and can control the off-state current of the device and reduce the leakage current (loff) of the device. Maximize the characteristics of the TFT.
  • the semiconductor transition layer can solve the ohmic contact problem between the source electrode and the drain electrode and the active layer, improve the output capability of the device, thereby maximally improving the device performance, improving the yield of the entire substrate, and reducing the production cost.
  • the embodiment of the present invention provides an example of a method of manufacturing two thin film transistors.
  • the fabrication of the thin film transistor is an important part in the fabrication process of the array substrate; in the present embodiment, the fabrication process of the thin film transistor provided in the above embodiment will be described in conjunction with a method of fabricating an array substrate.
  • the manufacturing process of the thin film transistor shown in Fig. 2 will be described by the first method. Specifically, the manufacturing process of the thin film transistor can be described with reference to the manufacturing process of the array substrate shown in FIG. 3A to FIG. 3M, and the specific steps include:
  • a gate metal layer 502 is formed on a substrate (for example, a glass substrate) 501.
  • the gate metal layer is prepared by magnetron sputtering, and the gate material can be selected according to different device structures and process requirements. Commonly used gate metal layers are Mo, Mo-Al-Mo alloy, Mo/Al-Nd/Mo laminated metal layer, Cu and titanium metal and Its alloys, etc., and keep its sheet resistance at a relatively low level.
  • the gate metal layer 502 is typically patterned by a patterning process, such as by wet etching, to form a gate 502a and a gate line 502b as shown in FIG. 3B.
  • a pre-film cleaning (Pre-clean) process is performed.
  • a gate insulating layer 503 is formed on a substrate on which a gate electrode and a gate line are formed by a plasma enhanced chemical vapor deposition (PECVD) method.
  • the material of the gate insulating layer may be, for example, a silicon dioxide (SiO 2 ) film, a silicon nitride film (SiNx ), a silicon oxynitride film (SiOxNy), an aluminum oxide (A1 2 0 3 ) film, a TiOx film, and the like.
  • Layer composite film may be, for example, a silicon dioxide (SiO 2 ) film, a silicon nitride film (SiNx ), a silicon oxynitride film (SiOxNy), an aluminum oxide (A1 2 0 3 ) film, a TiOx film, and the like.
  • the surface of the gate insulating layer is treated by a plasma process to reduce the roughness of the surface of the film, and the metastable substance of the interface is removed to form a more stable interface. In this way, the field effect mobility can be improved and the stability of the TFT can be improved.
  • a semiconductor layer 504 of high conductivity is formed.
  • the most critical aspect of oxide TFT fabrication is the fabrication of semiconductor active layers.
  • the formation of a high-conductivity semiconductor layer is very important.
  • the high-conductivity semiconductor layer formed under a low-oxygen atmosphere forms a state of rich metal ions inside the film, and at the same time forms oxygen vacancies, thereby increasing current carrying capacity. Child's ability to conduct. Therefore, the semiconductor layer has a low oxygen content and a high conduction capability for increasing the on-state current Ion of the TFT device.
  • Oxide semiconductors that are widely used today include indium gallium oxide (IGZO), indium tin oxide (ITZO), or indium oxide (IZO), and the like, and complex ratios thereof.
  • the main production methods are magnetron sputtering deposition and solution method.
  • the material used to fabricate the low-conductivity semiconductor layer is itself indistinguishable from the high-conductivity semiconductor layer.
  • the semiconductor layer with low conductivity and the high-conductivity semiconductor layer are very different in the fabrication details. .
  • the conductive layer of the low-conductivity semiconductor layer is weaker than the low-conductivity semiconductor layer, and a low-conductivity semiconductor layer is formed under a high oxygen atmosphere, and oxygen enrichment is formed inside the semiconductor layer.
  • the state of the ion which limits the conduction of the carrier, can control the leakage current of the device; that is, the semiconductor layer with low conductivity can be low-conducting with high oxygen content.
  • the passivation oxide semiconductor is shown as 505 in Figure 4E. It is used to control the leakage current of the device and reduce the off current (Ioff) of the device to maximize the performance of the device.
  • the high-conductivity semiconductor layer 504 and the low-conductivity semiconductor layer 505 as shown in FIG. 3E constitute an oxide semiconductor active layer, and the oxide semiconductor active layer is patterned by a patterning process, which is generally used. There are two etching methods, one is wet etching and the other is dry etching. Wet etching is now widely used, which can control the etching precision very well.
  • the oxide semiconductor active layer is patterned by etching to form a high-conductivity semiconductor layer 504 and a low-conductivity semiconductor layer 505 as shown in Fig. 3F.
  • an Etch Stop Layer (ESL) 506 is directly formed on the patterned oxide semiconductor active layer, and the material thereof is different according to different process requirements of different manufacturers, usually Inorganic insulating materials such as SiOx, SiNx, SiOxNy, A1 2 0 3 , TiOx, Y 2 0 3 are required, and the purpose thereof is to reduce damage to the oxide semiconductor film during patterning of the data lines, and at the same time be effective.
  • the stability of the TFT device is improved to avoid the influence of the external environment on the TFT device.
  • the etch stop layer is patterned by dry etching as shown at 506a in Figure 3H.
  • the key point in the fabrication of this step is to prevent over-etching of the gate insulating layer during how to control the etching of the etch barrier. If the control is not good, the short circuit or breakdown phenomenon between the gate metal line and the source and drain electrodes may occur during the process of fabricating the panel, thereby causing the panel to fail. If the materials with larger etching selectivity are selected separately for material selection, the above problems will be well avoided. At the same time, the combination of dry and wet etching can also avoid the above problems.
  • the first solution is to deposit an etch barrier layer after depositing the active layer of the oxide semiconductor, and exposing the source electrode and the drain electrode by a patterning process.
  • the contact via of the semiconductor, the peripheral edge pattern of the etch barrier layer is consistent with the pattern of the oxide semiconductor layer, and the ohmic contact region of the active layer of the oxide semiconductor can be directly defined by etching the via of the barrier layer;
  • patterning is performed, and then deposition of an etch barrier layer is performed.
  • the etch barrier layer covers the entire substrate after forming the active layer of the oxide semiconductor, and then the etch barrier layer is performed.
  • the etch stop of the other regions remains on the substrate.
  • the etch stop layer 506a may also cover only a portion of the oxide semiconductor active layer.
  • a source electrode and a drain electrode are formed.
  • Such a fabrication scheme can be combined with an active layer of an oxide semiconductor to achieve a better output of device performance.
  • the surface of the oxide semiconductor can be treated with a plasma of a gas such as hydrogen, N 2 O, CF 4 or Ar, thereby improving the ohmic contact characteristics of the device, as shown in FIG. 3 . Shown in .
  • metallized semiconductor layers 507a and 507b may be formed on the surface of the oxide semiconductor not covered by the etch barrier layer 506a.
  • a data line metal layer is formed.
  • a metal layer is deposited, and a data line and a source electrode 508a and a drain electrode 508b are formed by a patterning process.
  • the metal layer is prepared by magnetron sputtering.
  • the electrode materials can be selected according to different device structures and process requirements. Commonly used electrode metals are Mo, Mo-Al-Mo alloy, Mo/Al-Nd/Mo laminated structure electrode, Cu and titanium metal and its alloy, ITO electrode, Ti/Al/Ti, Mo/ITO, etc. , keeping its sheet resistance at a relatively low level.
  • the metal electrode layer is formed, it is patterned. It is patterned by wet etching, as shown by source 508a and drain 508b in Figure 4J.
  • the fabrication of the thin film transistor has been completed; however, the fabrication of the array substrate further includes: formation of a passivation layer and formation of a pixel electrode, and a detailed description of the formation process of the passivation layer and the pixel electrode will be described below.
  • a passivation layer is formed on the entire substrate, usually using inorganic substances such as SiOx, SiNx, SiOxNy, A1 2 0 3 , TiOx, Y 2 0 3 , etc. Insulating materials; At the same time, in the field of AMOLED (Active Matrix Organic Light Emitting Diode Panel), organic insulating layers such as resin materials and acrylic materials can also be used for the subsequent preparation conditions.
  • a via etching is performed by a patterning process to effect connection of the drain electrode and the pixel electrode, as shown by the via hole 509a and the via hole 509b in FIG. 3K.
  • the TFT device has a high on-state current Ion and a low off-state current Ioff by the structural design of the layer-optimized semiconductor active layer without increasing the number of steps, thereby improving the performance of the TFT device. Further, after the etch barrier layer is patterned, the semiconductor active layer is subjected to plasma treatment to solve the ohmic contact problem between the source electrode and the drain electrode and the oxide semiconductor active layer, thereby improving the TFT characteristics and ensuring product performance.
  • the fabrication process of the thin film transistor according to the embodiment of the present invention will be described below by the description of the second method. Specifically, the fabrication process of the thin film transistor can be described with reference to the method of manufacturing the array substrate shown in Figs. 5A to 5E.
  • steps S710-S711 in addition to the formation of the oxide semiconductor transition layer and the patterning of the data line metal layer and the oxide semiconductor transition layer (here, steps S710-S711) and the process sequence of the implementation of the first method (ie, step S410- S411)
  • steps S710-S711 in addition to the formation of the oxide semiconductor transition layer and the patterning of the data line metal layer and the oxide semiconductor transition layer (here, steps S710-S711) and the process sequence of the implementation of the first method (ie, step S410- S411)
  • the steps may be referred to the above embodiments for the remaining steps.
  • forming a semiconductor layer having low conductivity, a semiconductor layer having high conductivity and a semiconductor layer having low conductivity constitute an oxide semiconductor active layer.
  • the present invention describes the steps S710 to S711 in the second method.
  • the substrate 801 is A gate electrode 802a and a gate line 802b, a gate insulating layer 803, a high-conductivity semiconductor layer 804, a low-conductivity semiconductor layer 805, and an etch barrier layer 806 are formed. Thereafter, a layer of low oxygen, high conductivity oxide semiconductor, ie, a semiconductor transition layer, is formed over the patterned etch stop layer prior to formation of the data line metal layer.
  • the oxide semiconductor transition layer has a thickness of 5 to 50 nm as shown by 807 in Fig. 5B.
  • the oxide semiconductor active layer, the semiconductor transition layer, and the combination of the source and drain electrodes form a sandwich structure device that maximizes device performance.
  • the layered optimization scheme of the above sandwich structure can improve the performance of the device.
  • the material of the semiconductor transition layer and the semiconductor active layer can be made of homogenous or homogenous high-conductivity materials.
  • oxide semiconductor active layer materials are indium gallium oxide (IGZO), indium tin oxide (ITZO), indium oxide (IZO), etc., and complexes of different ratios associated therewith.
  • IGZO indium gallium oxide
  • ITZO indium tin oxide
  • IZO indium oxide
  • the main production methods are magnetron sputtering deposition and solution method. Different etching methods can be selected due to different process requirements.
  • a data line metal layer 808 is formed over the semiconductor transition layer.
  • the metal electrode is prepared by magnetron sputtering, and the electrode material can be selected according to different device structures and process requirements. Commonly used electrode metals are ⁇ , ⁇ - ⁇ 1- ⁇ alloy, Mo/Al-Nd/Mo laminated structure electrode, Cu and titanium metal and its alloy, ITO electrode, Ti/Al/Ti, Mo/ITO Etc., keep its sheet resistance at a relatively low level.
  • the data line metal layer is formed, it is patterned. The pattern was patterned by wet etching to obtain the source electrode 808a and the drain electrode 808b shown in Fig. 7D. At this step, it must be noted that the simultaneous etching of the source and drain electrodes and the oxide semiconductor transition layer is achieved, which not only improves the performance of the device but also increases the overall process, and does not increase production. the cost of.
  • an oxide thin film transistor and an array substrate as shown in Fig. 5E are formed. As shown in FIG. 5E, 809 is a passivation layer, and 810 is a pixel electrode layer. Thus, the oxide thin film transistor array substrate is completed.
  • the device scheme of the sandwich structure optimized by layering can improve the performance of the device without increasing the process, not only has a high on-state current Ion and a low off-state current Ioff, but also due to the semiconductor transition layer.
  • the existence of the ohmic contact between the source and drain electrodes and the active layer is solved, thereby ensuring device characteristics and product performance.
  • the embodiment of the present invention can improve the performance of the TFT device, thereby playing a very important role in improving the overall substrate yield and reducing the cost.
  • the structure and preparation method of the oxide thin film transistor are described by way of example of the bottom gate structure.
  • embodiments in accordance with the present invention are not limited to the above described bottom gate structure, and may be top gate structures or other various oxide thin film transistor structures.
  • a high-conductivity oxide semiconductor layer is used near the gate side, thereby enabling high on-state current
  • the low-on-state oxide semiconductor layer is close to the source/drain electrode side, so that a low off-state current Ioff can be realized. Therefore, if the oxide semiconductor thin film transistor is a top gate structure, a highly conductive semiconductor layer needs to be disposed on the top layer, and a low conduction semiconductor layer needs to be disposed on the bottom layer. That is, the oxide semiconductor layer is disposed between the source/drain electrode and the gate electrode, and the low-conductivity semiconductor layer in the oxide semiconductor layer is disposed on the source/drain electrode side, and the high-conductivity semiconductor layer is disposed. On the side of the gate.
  • the "high conduction capability” and “low conduction capability” in the semiconductor layer having high on capability and the semiconductor layer having low on capability according to the embodiment of the present invention are two relative concepts, and are set such that both are opened.
  • the purpose of the current and the off current are two relative concepts, and are set such that both are opened.
  • the specific conductivity of the semiconductor layer having high on capability and low on capability is not particularly limited and may be arbitrarily selected depending on the actual situation.
  • the semiconductor active layer has been described by taking a metal oxide semiconductor material as an example, but the semiconductor material according to an embodiment of the present invention is not limited thereto.
  • the semiconductor layer having high conductivity can be used with a metal oxide having a low oxygen content, and the semiconductor layer having a low conductivity can be used with a higher oxygen content.
  • High metal oxides Under the structure of the multilayered semiconductor active layer, the specific oxygen content can be set to an appropriate value according to actual needs.
  • the high conduction capability and the low conduction performance in the embodiment of the present invention are The semiconductor material of the force is not limited to the above-mentioned metal oxide having a low oxygen content and a high oxygen content.
  • the fabrication order of the gate electrode, the gate insulating layer, the semiconductor active layer, the source electrode and the drain electrode is different from that of the bottom gate structure.
  • the source and drain electrodes, the semiconductor active layer, the gate insulating layer, and the gate electrode may be sequentially formed.
  • the present invention also provides an array substrate comprising the thin film transistor described in any of the above embodiments, and the structure shown in Figs. 2 and 4 can be specifically referred to.
  • the present invention provides a display device, which may specifically be a liquid crystal display, an organic light emitting diode (OLED) display, an active electronic paper display, and other display devices driven using the above thin film transistor and array substrate.
  • a display device which may specifically be a liquid crystal display, an organic light emitting diode (OLED) display, an active electronic paper display, and other display devices driven using the above thin film transistor and array substrate.
  • OLED organic light emitting diode

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Abstract

Provided are a thin film transistor, a manufacturing method therefor, an array substrate and a display device. The thin film transistor comprises a gate electrode, a gate insulating layer, a semiconductor active layer, a source electrode and a drain electrode, wherein the semiconductor active layer is in a multilayer structure, and at least comprises a semiconductor layer with a high conducting capability and a semiconductor layer with a low conducting capability; and the semiconductor layer with a high conducting capability is close to the gate electrode, and the semiconductor layer with a low conducting capability is close to the source electrode and the drain electrode.

Description

薄膜晶体管及其制造方法、 阵列基板和显示器件 技术领域  Thin film transistor and manufacturing method thereof, array substrate and display device
本发明的实施例涉及薄膜晶体管及其制造方法、 阵列基板和显示器件。 背景技术  Embodiments of the present invention relate to a thin film transistor and a method of fabricating the same, an array substrate, and a display device. Background technique
OTFT ( Oxide Thin Film Transistor, 氧化物薄膜晶体管)技术最初的研 究目的之一是降低有源显示器件的能耗, 令显示器件更薄更轻, 响应速度更 快。 大约在二十一世纪初开始走向试用阶段。  One of the first research goals of OTFT (Oxide Thin Film Transistor) technology is to reduce the energy consumption of active display devices, making display devices thinner and lighter, and faster. Beginning at the beginning of the 21st century, the trial phase began.
图 1为现有技术中薄膜晶体管的结构示意图。 现有技术通过 6次曝光掩 模(Mask )工艺在玻璃基板 10上依次形成栅极 11、 栅绝缘层 12、 半导体有 源层 13、 刻蚀阻挡层 14、 源电极 15a、 漏电极 15b、 钝化层 16及像素电极 18,漏电极 15b通过过孔 17与像素电极 18连接。半导体有源层 13的制作材 料选用金属氧化物, 比如铟镓辞氧化物 IGZO等材料。  FIG. 1 is a schematic structural view of a thin film transistor in the prior art. In the prior art, the gate electrode 11, the gate insulating layer 12, the semiconductor active layer 13, the etch stop layer 14, the source electrode 15a, the drain electrode 15b, and the blunt are sequentially formed on the glass substrate 10 by a 6-time exposure mask (Mask) process. The layer 16 and the pixel electrode 18, and the drain electrode 15b are connected to the pixel electrode 18 through the via hole 17. The semiconductor active layer 13 is made of a metal oxide such as indium gallium oxide IGZO.
有源层的性能决定了薄膜晶体管的特性, 而基于图 1所示的现有的氧化 物薄膜晶体管无法在实现高的开态电流 ion的同时具备低的关态电流 Ioff, 进而无法确保氧化物薄膜晶体管的性能, 最终影响产品的性能。 发明内容  The performance of the active layer determines the characteristics of the thin film transistor, and the conventional oxide thin film transistor shown in FIG. 1 cannot achieve a high off-state current ion while having a low off-state current Ioff, thereby failing to secure an oxide. The performance of thin film transistors ultimately affects the performance of the product. Summary of the invention
本发明的实施例提供一种薄膜晶体管及其制造方法、 阵列基板和显示器 件, 实现高的开态电流 Ion的同时具备低的关态电流 Ioff, 提高薄膜晶体管 的特性。  Embodiments of the present invention provide a thin film transistor, a method of fabricating the same, an array substrate, and a display device, which realize a high on-state current Ion and a low off-state current Ioff to improve characteristics of the thin film transistor.
为达到上述目的, 本发明的实施例釆用如下技术方案:  In order to achieve the above object, embodiments of the present invention use the following technical solutions:
一种薄膜晶体管, 包括: 栅极、 栅绝缘层、 半导体有源层、 源电极和漏 电极, 其中, 所述半导体有源层为多层结构, 至少包括高导通能力的半导体 层和低导通能力的半导体层; 所述高导通能力的半导体层靠近所述栅极, 且 低导通能力的半导体层靠近所述源电极和所述漏电极。  A thin film transistor comprising: a gate, a gate insulating layer, a semiconductor active layer, a source electrode and a drain electrode, wherein the semiconductor active layer is a multilayer structure including at least a semiconductor layer having high conductivity and a low conductivity a semiconductor layer having a high conductivity; the semiconductor layer having a high conductivity is adjacent to the gate, and a semiconductor layer having a low conductivity is adjacent to the source electrode and the drain electrode.
一种薄膜晶体管的制造方法, 包括: 在基板上形成栅极、 栅绝缘层、 半 导体有源层、 源电极和漏电极的过程; 其中, 形成所述半导体有源层的过程 包括: 在靠近所述栅极侧形成高导通能力的半导体层; 在靠近所述源电极和 漏电极侧形成低导通能力的半导体层。 A method of manufacturing a thin film transistor, comprising: a process of forming a gate electrode, a gate insulating layer, a semiconductor active layer, a source electrode, and a drain electrode on a substrate; wherein, the process of forming the semiconductor active layer The method includes: forming a semiconductor layer having a high conductivity near the gate side; and forming a semiconductor layer having a low conductivity near the source electrode and the drain electrode side.
一种阵列基板, 包括上述薄膜晶体管。  An array substrate comprising the above thin film transistor.
一种显示装置, 包括上述阵列基板。  A display device comprising the above array substrate.
本发明实施例提供的薄膜晶体管及其制造方法、 阵列基板和显示器件, 分层制备高导通能力的半导体层和低导通能力的半导体层; 进一步的, 形成 的半导体有源层包括两层及两层以上结构, 且靠近栅极的半导体有源层由高 导通能力的半导体层形成, 实现高的开态电流 Ion, 靠近源电极和漏电极的 半导体有源层的顶层由低导通能力的半导体层形成, 实现低的关态电流 Ioff。 高的开态电流 Ion, 以提高氧化物薄膜晶体管的特性, 最终确保产品的性能。 附图说明  The thin film transistor and the manufacturing method thereof, the array substrate and the display device provided by the embodiments of the present invention layer-by-layer preparation of a high-conductivity semiconductor layer and a low-conductivity semiconductor layer; further, the formed semiconductor active layer includes two layers And a structure of two or more layers, and the semiconductor active layer close to the gate is formed of a semiconductor layer having high conductivity, achieving a high on-state current Ion, and a top layer of the semiconductor active layer close to the source and drain electrodes is turned on The ability to form a semiconductor layer achieves a low off-state current Ioff. The high on-state current Ion improves the characteristics of the oxide thin film transistor and ultimately ensures the performance of the product. DRAWINGS
为了更清楚地说明本发明实施例的技术方案, 下面将对实施例的附图作 简单地介绍,显而易见地,下面描述中的附图仅仅涉及本发明的一些实施例, 而非对本发明的限制。  In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings of the embodiments will be briefly described below. It is obvious that the drawings in the following description relate only to some embodiments of the present invention, and are not intended to limit the present invention. .
图 1为现有技术中薄膜晶体管的结构示意图;  1 is a schematic structural view of a thin film transistor in the prior art;
图 2为本发明实施例提供的薄膜晶体管的结构示意图;  2 is a schematic structural diagram of a thin film transistor according to an embodiment of the present invention;
图 3A为本发明实施例提供的阵列基板制造过程的第一示意图; 图 3B为本发明实施例提供的制造阵列基板的第二示意图;  3A is a first schematic view showing a manufacturing process of an array substrate according to an embodiment of the present invention; FIG. 3B is a second schematic diagram of manufacturing an array substrate according to an embodiment of the present invention;
图 3C为本发明实施例提供的制造阵列基板的第三示意图;  3C is a third schematic diagram of manufacturing an array substrate according to an embodiment of the present invention;
图 3D为本发明实施例提供的制造阵列基板的第四示意图;  3D is a fourth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention;
图 3E为本发明实施例提供的制造阵列基板的第五示意图;  3E is a fifth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention;
图 3F为本发明实施例提供的制造阵列基板的第六示意图;  3F is a sixth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention;
图 3G为本发明实施例提供的制造阵列基板的第七示意图;  3G is a seventh schematic diagram of manufacturing an array substrate according to an embodiment of the present invention;
图 3H为本发明实施例提供的制造阵列基板的第八示意图;  3H is an eighth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention;
图 31为本发明实施例提供的制造阵列基板的第九示意图;  FIG. 31 is a ninth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention;
图 3J为本发明实施例提供的制造阵列基板的第十示意图;  FIG. 3 is a fourth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention; FIG.
图 3K为本发明实施例提供的制造阵列基板的第十一示意图;  FIG. 3K is an eleventh schematic diagram of manufacturing an array substrate according to an embodiment of the present invention; FIG.
图 3L为本发明实施例提供的制造阵列基板的第十二示意图; 图 3M为本发明实施例提供的制造阵列基板的第十三示意图; FIG. 3L is a twelfth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention; FIG. FIG. 3 is a thirteenth schematic diagram of manufacturing an array substrate according to an embodiment of the present invention; FIG.
图 4为本发明另一实施例提供的薄膜晶体管的结构示意图;  4 is a schematic structural diagram of a thin film transistor according to another embodiment of the present invention;
图 5A为本发明另一实施例提供的制造阵列基板的第一示意图;  FIG. 5A is a first schematic diagram of manufacturing an array substrate according to another embodiment of the present invention; FIG.
图 5B为本发明另一实施例提供的制造阵列基板的第二示意图;  FIG. 5B is a second schematic diagram of manufacturing an array substrate according to another embodiment of the present invention; FIG.
图 5C为本发明另一实施例提供的制造阵列基板的第三示意图;  FIG. 5C is a third schematic diagram of manufacturing an array substrate according to another embodiment of the present invention; FIG.
图 5D为本发明另一实施例提供的制造阵列基板的第四示意图;  FIG. 5D is a fourth schematic diagram of manufacturing an array substrate according to another embodiment of the present invention; FIG.
图 5E为本发明另一实施例提供的制造阵列基板的第五示意图。 具体实施方式  FIG. 5E is a fifth schematic diagram of manufacturing an array substrate according to another embodiment of the present invention. detailed description
为使本发明实施例的目的、 技术方案和优点更加清楚, 下面将结合本发 明实施例的附图,对本发明实施例的技术方案进行清楚、 完整地描述。显然, 所描述的实施例是本发明的一部分实施例, 而不是全部的实施例。 基于所描 述的本发明的实施例, 本领域普通技术人员在无需创造性劳动的前提下所获 得的所有其他实施例, 都属于本发明保护的范围。  The technical solutions of the embodiments of the present invention are clearly and completely described in the following with reference to the accompanying drawings of the embodiments of the present invention. It is apparent that the described embodiments are part of the embodiments of the invention, rather than all of the embodiments. All other embodiments obtained by a person of ordinary skill in the art based on the described embodiments of the present invention without departing from the scope of the invention are within the scope of the invention.
本发明实施例提供一种薄膜晶体管, 该薄膜晶体管包括: 栅极、 栅绝缘 层、 半导体有源层、 源电极和漏电极; 其中,  An embodiment of the present invention provides a thin film transistor including: a gate, a gate insulating layer, a semiconductor active layer, a source electrode, and a drain electrode;
所述半导体有源层为多层结构, 至少包括高导通能力的半导体层和低导 通能力的半导体层; 其中, 所述高导通能力的半导体层靠近栅极, 且低导通 能力的半导体层靠近源电极和漏电极。  The semiconductor active layer is a multilayer structure including at least a high-conductivity semiconductor layer and a low-conductivity semiconductor layer; wherein the high-conductivity semiconductor layer is close to the gate, and low-conducting capability The semiconductor layer is adjacent to the source and drain electrodes.
薄膜晶体管为底栅结构时, 薄膜晶体管包括栅极、 栅绝缘层、 半导体有 源层、 刻蚀阻挡层和源漏电极, 其中, 栅极在半导体有源层的下方, 所述源 电极和漏电极位于所述半导体有源层的上方; 半导体有源层为多层结构, 包 括半导体有源层与源电极和漏电极之间还设置有刻蚀阻挡层。  When the thin film transistor is a bottom gate structure, the thin film transistor includes a gate, a gate insulating layer, a semiconductor active layer, an etch barrier layer, and source and drain electrodes, wherein the gate is under the semiconductor active layer, the source electrode and the drain electrode The electrode is located above the semiconductor active layer; the semiconductor active layer is a multilayer structure including an etch barrier layer between the semiconductor active layer and the source and drain electrodes.
薄膜晶体管为顶栅结构时, 薄膜晶体管包括栅极、栅绝缘层、半导体有 源层和源漏阻挡层, 其中, 栅极在半导体有源层的上方, 源电极和漏电极位 于半导体有源层的下方。  When the thin film transistor is a top gate structure, the thin film transistor includes a gate, a gate insulating layer, a semiconductor active layer, and a source/drain barrier layer, wherein the gate is above the semiconductor active layer, and the source and drain electrodes are located at the semiconductor active layer Below.
下面将结合图 2和图 4来介绍本发明实施例提供的薄膜晶体管的两种改 进结构的实现方式, 但并不局限于此。  The implementation of the two modified structures of the thin film transistor provided by the embodiment of the present invention will be described below with reference to FIG. 2 and FIG. 4, but is not limited thereto.
如图 2所示, 本发明实施例提供的一种薄膜晶体管, 包括: 依次形成在 基板 201上的栅极 202、 栅绝缘层 203、 高导通能力的半导体层 204、 低导通 能力的半导体层 205、 刻蚀阻挡层 206、 金属化半导体层、 和数据线金属层。 高导通能力的半导体层 204和低导通能力的半导体层 205构成半导体有源层, 该半导体有源层釆用金属氧化物材料; 刻蚀阻挡层 206在氧化物半导体有源 层之上, 在氧化物半导体有源层的上方还形成有位于刻蚀阻挡层 206两侧的 金属化半导体层 207a和 207b, 以及所述数据线金属层包括数据线、 薄膜晶 体管的源电极 208a和漏电极 208b。 As shown in FIG. 2, a thin film transistor according to an embodiment of the present invention includes: a gate 202 sequentially formed on a substrate 201, a gate insulating layer 203, a semiconductor layer 204 having high conductivity, and low conduction. Capacitive semiconductor layer 205, etch stop layer 206, metallization semiconductor layer, and data line metal layer. The high-conductivity semiconductor layer 204 and the low-conductivity semiconductor layer 205 constitute a semiconductor active layer, the semiconductor active layer is made of a metal oxide material; the etch stop layer 206 is over the oxide semiconductor active layer, Metalized semiconductor layers 207a and 207b on both sides of the etch barrier layer 206 are further formed over the oxide semiconductor active layer, and the data line metal layer includes a data line, a source electrode 208a and a drain electrode 208b of the thin film transistor. .
氧化物半导体有源层釆用分层优化的方案, 由两层或多层形成。 如图 2 所示, 底栅结构的氧化物半导体有源层的底层为高导通能力的高导通能力的 半导体层 204, 氧化物半导体有源层的顶层为低导通能力的半导体层 205形 成, 但氧化物半导体有源层形成的宗旨在于底层釆用低氧含量、 高导通能力 的半导体, 用以提高器件的导通能力, 即提高器件的开态电流 (Ion); 顶层的 半导体釆用高氧含量、低导通能力的氧化物半导体,用以控制器件的漏电流, 即降低器件的关态电流(Ioff ) , 从而提高器件性能。 可以理解的是, 当薄膜 晶体管为顶栅结构时, 半导体有源层的顶层为高导通能力的半导体层, 氧化 物半导体有源层的底层为低导通能力的半导体层形成, 氧化物半导体有源层 形成的宗旨在于顶层釆用低氧含量、 高导通能力的半导体, 用以提高器件的 导通能力, 即提高器件的开态电流 (Ion); 底层的半导体釆用高氧含量、 低导 通能力的氧化物半导体, 用以控制器件的漏电流, 即降低器件的关态电流 ( Ioff ) , 从而提高器件性能。 本领域技术人员可根据产品的实际情况, 自行 选择底栅或者顶栅结构。  The oxide semiconductor active layer is formed by two or more layers using a layered optimization scheme. As shown in FIG. 2, the underlayer of the oxide semiconductor active layer of the bottom gate structure is a high conductivity semiconductor layer 204 having a high conductivity, and the top layer of the oxide semiconductor active layer is a semiconductor layer 205 having a low conductivity. Formed, but the oxide semiconductor active layer is formed by using a low-oxygen, high-conductivity semiconductor to improve the device's conduction capability, ie, to increase the on-state current (Ion) of the device; An oxide semiconductor with high oxygen content and low conductivity is used to control the leakage current of the device, that is, to reduce the off current (Ioff) of the device, thereby improving device performance. It can be understood that when the thin film transistor is a top gate structure, the top layer of the semiconductor active layer is a semiconductor layer with high conductivity, and the bottom layer of the active layer of the oxide semiconductor is formed of a semiconductor layer with low conductivity, an oxide semiconductor. The purpose of the active layer formation is to use a low-oxygen, high-conductivity semiconductor on the top layer to improve the device's conduction capability, ie, to increase the on-state current (Ion) of the device; the underlying semiconductor uses high oxygen content, A low-conductivity oxide semiconductor that controls the device's leakage current, which reduces the off-state current (Ioff) of the device, thereby improving device performance. Those skilled in the art can select the bottom gate or top gate structure according to the actual situation of the product.
在制作完上述的有源层氧化物半导体后, 在其上形成刻蚀阻挡层, 如图 2中的 206所示。 在刻蚀阻挡层 206形成后, 对暴露在刻蚀阻挡层两侧的氧 化物半导体有源层进行氢气、 N20、 CF4或者 Ar等气体的 Plasma (等离子体) 处理, 在氧化物半导体有源层表面形成金属化半导体层, 如图 2所示的 207a 和 207b。金属化半导体层可降低氧化物半导体有源层与源电极和漏电极的接 触电阻, 进而改善器件的欧姆接触特性。 氧化物半导体有源层、 金属化半导 体层和源电极和漏电极相结合可以实现较好的器件性能的输出。 After the active layer oxide semiconductor described above is formed, an etch stop layer is formed thereon as shown at 206 in FIG. After the etch barrier layer 206 is formed, a plasma (plasma) treatment of a gas such as hydrogen, N 2 0, CF 4 or Ar is performed on the oxide semiconductor active layer exposed on both sides of the etch barrier layer, in the oxide semiconductor A metallized semiconductor layer is formed on the surface of the active layer, as shown in Fig. 2, 207a and 207b. The metallization of the semiconductor layer reduces the contact resistance of the active layer of the oxide semiconductor with the source and drain electrodes, thereby improving the ohmic contact characteristics of the device. The combination of the oxide semiconductor active layer, the metallized semiconductor layer, and the source and drain electrodes can achieve better output of device performance.
如图 4所示, 本发明实施例提供的另一种薄膜晶体管, 包括: 依次形成 在基板(例如为透明玻璃基板) 601上的栅极 602、 栅绝缘层 603、 高导通能 力的半导体层 604、 低导通能力的半导体层 605、 刻蚀阻挡层 606; 其中, 在 已图形化的刻蚀阻挡层 606之上形成有一层低氧含量、 高导的半导体过渡层 607a和 607b; 在半导体过渡层 607a和 607b的上方形成有源电极 608a和漏 电极 608b。 半导体过渡层 607a和 607b的厚度在 5-50nm, 半导体过渡层与 高导通能力的半导体层选用的材料相同。 As shown in FIG. 4, another thin film transistor according to an embodiment of the present invention includes: a gate electrode 602 sequentially formed on a substrate (for example, a transparent glass substrate) 601, a gate insulating layer 603, and a semiconductor layer having high conductivity. 604, a low-conductivity semiconductor layer 605, an etch stop layer 606; A patterned low-oxygen, high-conductivity semiconductor transition layer 607a and 607b is formed over the patterned etch stop layer 606; a source electrode 608a and a drain electrode 608b are formed over the semiconductor transition layers 607a and 607b. The semiconductor transition layers 607a and 607b have a thickness of 5 to 50 nm, and the semiconductor transition layer is made of the same material as the high conductivity semiconductor layer.
具有高导通能力的半导体过渡层可降低氧化物半导体有源层与源电极和 漏电极之间的接触电阻, 进而改善器件的欧姆接触特性。 氧化物半导体有源 层、 半导体过渡层与源电极和漏电极相结合, 形成一个三明治结构的 TFT器 件, 不仅可以同时具有高的开态电流 Ion和低的关态电流 loff, 而且可以解 决源电极和漏电极的欧姆接触问题, 从而最大程度地改善 TFT器件的性能。 本发明实施例的特点之一在于在制作氧化物 TFT的过程中,釆用上述三明治 结构的分层优化方案, 来提高器件的性能。  The semiconductor transition layer having high conductivity can reduce the contact resistance between the active layer of the oxide semiconductor and the source and drain electrodes, thereby improving the ohmic contact characteristics of the device. The oxide semiconductor active layer and the semiconductor transition layer are combined with the source electrode and the drain electrode to form a sandwich TFT device, which can simultaneously have a high on-state current Ion and a low off-state current loff, and can solve the source electrode. The ohmic contact problem with the drain electrode, thereby maximally improving the performance of the TFT device. One of the features of the embodiments of the present invention is that in the process of fabricating an oxide TFT, the layered optimization scheme of the above sandwich structure is used to improve the performance of the device.
本发明提供的薄膜晶体管, 由于分层优化的氧化物半导体有源层既可以 提高 TFT器件的开态电流(Ion ) , 同时可以控制器件的关态电流, 降低器 件的漏电流(loff) , 可最大限度的改善 TFT的特性。 半导体过渡层可以解 决源电极和漏电极与有源层的欧姆接触问题, 提高器件的输出能力, 从而最 大限度的改善器件性能, 提高了整个基板的良品率, 降低了生产成本。  The thin film transistor provided by the invention can improve the on-state current (Ion) of the TFT device due to the layer-optimized oxide semiconductor active layer, and can control the off-state current of the device and reduce the leakage current (loff) of the device. Maximize the characteristics of the TFT. The semiconductor transition layer can solve the ohmic contact problem between the source electrode and the drain electrode and the active layer, improve the output capability of the device, thereby maximally improving the device performance, improving the yield of the entire substrate, and reducing the production cost.
针对以上薄膜晶体管在形成分层优化的氧化物半导体有源层和金属化半 导体层 /氧化物半导体过渡层的工艺顺序的不同,本发明实施例提供两种薄膜 晶体管的制造方法示例。  In view of the difference in the process sequence of forming the layer-optimized oxide semiconductor active layer and the metallized semiconductor layer/oxide semiconductor transition layer of the above thin film transistor, the embodiment of the present invention provides an example of a method of manufacturing two thin film transistors.
薄膜晶体管的制作是阵列基板制作过程中的一个重要部分; 在本实施例 中将结合一种阵列基板的制作方法来介绍上述实施例中提供的薄膜晶体管的 制作过程。  The fabrication of the thin film transistor is an important part in the fabrication process of the array substrate; in the present embodiment, the fabrication process of the thin film transistor provided in the above embodiment will be described in conjunction with a method of fabricating an array substrate.
下面将通过方法一来介绍图 2所示的薄膜晶体管的制造过程。 具体地, 薄膜晶体管的制作过程可参照图 3A〜图 3M所示的阵列基板的制造过程进行 说明, 其具体步骤包括:  Next, the manufacturing process of the thin film transistor shown in Fig. 2 will be described by the first method. Specifically, the manufacturing process of the thin film transistor can be described with reference to the manufacturing process of the array substrate shown in FIG. 3A to FIG. 3M, and the specific steps include:
S401、 在基板上形成栅极金属层;  S401, forming a gate metal layer on the substrate;
如图 3A所示, 在基板(例如为玻璃基板) 501上形成栅极金属层 502。 在 TFT的制作过程中, 栅极金属层多釆用磁控溅射的方法来制备, 栅极材料 根据不同的器件结构和工艺要求可以进行选择。 通常被釆用的栅极金属层有 Mo, Mo-Al-Mo合金, Mo/Al-Nd/Mo叠成结构的金属层、 Cu以及金属钛及 其合金等, 且令其方块电阻保持在一个相对比较低的水平。 As shown in FIG. 3A, a gate metal layer 502 is formed on a substrate (for example, a glass substrate) 501. In the fabrication process of the TFT, the gate metal layer is prepared by magnetron sputtering, and the gate material can be selected according to different device structures and process requirements. Commonly used gate metal layers are Mo, Mo-Al-Mo alloy, Mo/Al-Nd/Mo laminated metal layer, Cu and titanium metal and Its alloys, etc., and keep its sheet resistance at a relatively low level.
S402、 对栅极金属层进行图形化;  S402. Graphically pattern a gate metal layer.
如图 3B所示, 一般利用构图工艺, 例如通过湿法刻蚀的方法, 对栅极 金属层 502进行图形化, 形成如图 3B中的栅极 502a和栅线 502b。  As shown in FIG. 3B, the gate metal layer 502 is typically patterned by a patterning process, such as by wet etching, to form a gate 502a and a gate line 502b as shown in FIG. 3B.
S403、 在栅极上形成栅绝缘层;  S403, forming a gate insulating layer on the gate;
如图 3C所示, 在栅极图形化之后, 进行成膜前清洗(Pre-clean )工艺。 通过等离子体增强化学汽相淀积(PECVD )法, 在形成有栅极和栅线的基板 上制备栅绝缘层 503。 栅绝缘层的材料例如可以为二氧化硅(Si02 )薄膜、 氮化硅薄膜(SiNx ) 、 氮氧化硅薄膜(SiOxNy ) 、 氧化铝 ( A1203 )薄膜、 TiOx薄膜以及上述薄膜的多层复合薄膜。 As shown in FIG. 3C, after the gate patterning, a pre-film cleaning (Pre-clean) process is performed. A gate insulating layer 503 is formed on a substrate on which a gate electrode and a gate line are formed by a plasma enhanced chemical vapor deposition (PECVD) method. The material of the gate insulating layer may be, for example, a silicon dioxide (SiO 2 ) film, a silicon nitride film (SiNx ), a silicon oxynitride film (SiOxNy), an aluminum oxide (A1 2 0 3 ) film, a TiOx film, and the like. Layer composite film.
S404、 对栅绝缘层进行表面处理;  S404, performing surface treatment on the gate insulating layer;
利用等离子体工艺对栅绝缘层表面进行处理 ,使薄膜表面的粗糙度下降, 界面亚稳态物质被去除, 以形成更稳定的界面。 这样, 可提高场效迁移率, TFT的稳定性得以改善。  The surface of the gate insulating layer is treated by a plasma process to reduce the roughness of the surface of the film, and the metastable substance of the interface is removed to form a more stable interface. In this way, the field effect mobility can be improved and the stability of the TFT can be improved.
S405、 形成高导通能力的半导体层;  S405, forming a semiconductor layer with high conductivity;
如图 3D所示, 形成高导通能力的半导体层 504。 氧化物 TFT制作最为 关键的环节就是半导体有源层的制作。 高导通能力的半导体层的形成是非常 重要的, 在低氧气氛下形成的高导通能力的半导体层, 在薄膜内部形成了一 个富金属离子的状态, 同时形成氧空位, 进而提高载流子的导通能力。 因此, 该半导体层具备低氧含量、 高导通能力, 用以提高 TFT器件的开态电流 Ion。 现在广为使用的氧化物半导体有铟镓辞氧化物 (IGZO ) 、 铟锡辞氧化物 ( ITZO )或铟辞氧化物( IZO )等以及与其相关的不同比例的配合物。 主要 的制作方法有磁控溅射沉积以及溶液法等。  As shown in Fig. 3D, a semiconductor layer 504 of high conductivity is formed. The most critical aspect of oxide TFT fabrication is the fabrication of semiconductor active layers. The formation of a high-conductivity semiconductor layer is very important. The high-conductivity semiconductor layer formed under a low-oxygen atmosphere forms a state of rich metal ions inside the film, and at the same time forms oxygen vacancies, thereby increasing current carrying capacity. Child's ability to conduct. Therefore, the semiconductor layer has a low oxygen content and a high conduction capability for increasing the on-state current Ion of the TFT device. Oxide semiconductors that are widely used today include indium gallium oxide (IGZO), indium tin oxide (ITZO), or indium oxide (IZO), and the like, and complex ratios thereof. The main production methods are magnetron sputtering deposition and solution method.
S406、 形成低导通能力的半导体层;  S406, forming a semiconductor layer with low conductivity;
制作低导通能力的半导体层所选用的材料本身是与高导通能力的半导体 层没有区别, 在制作细节上低导通能力的半导体层和高导通能力的半导体层 是有很大区别的。 首先, 为了防止漏电流, 低导通能力的半导体层的导电能 力要弱于低导通能力的半导体层,在高氧气氛下形成低导通能力的半导体层, 在该半导体层内部形成富氧离子的状态, 对载流子的导通起到了限制作用, 进而可以控制器件的漏电流; 即低导通能力的半导体层釆用高氧含量的低导 通能力氧化物半导体, 如图 4E中的 505所示。 用以控制器件的漏电流, 降 低器件的关态电流(Ioff) , 最大限度的改善器件性能。 The material used to fabricate the low-conductivity semiconductor layer is itself indistinguishable from the high-conductivity semiconductor layer. The semiconductor layer with low conductivity and the high-conductivity semiconductor layer are very different in the fabrication details. . First, in order to prevent leakage current, the conductive layer of the low-conductivity semiconductor layer is weaker than the low-conductivity semiconductor layer, and a low-conductivity semiconductor layer is formed under a high oxygen atmosphere, and oxygen enrichment is formed inside the semiconductor layer. The state of the ion, which limits the conduction of the carrier, can control the leakage current of the device; that is, the semiconductor layer with low conductivity can be low-conducting with high oxygen content. The passivation oxide semiconductor is shown as 505 in Figure 4E. It is used to control the leakage current of the device and reduce the off current (Ioff) of the device to maximize the performance of the device.
S407、 对氧化物半导体有源层进行图形化;  S407, patterning an active layer of the oxide semiconductor;
如图 3E中所示的高导通能力的半导体层 504和低导通能力的半导体层 505 构成氧化物半导体有源层, 利用构图工艺对氧化物半导体有源层进行图 形化, 通常釆用的刻蚀方法有两种, 一种为湿法刻蚀, 另一种为干法刻蚀。 现在广泛使用的是湿法刻蚀, 其可以很好的控制刻蚀精度。 通过刻蚀的方法 对氧化物半导体有源层图形化后形成如图 3F 中所示的高导通能力的半导体 层 504和低导通能力的半导体层层 505。  The high-conductivity semiconductor layer 504 and the low-conductivity semiconductor layer 505 as shown in FIG. 3E constitute an oxide semiconductor active layer, and the oxide semiconductor active layer is patterned by a patterning process, which is generally used. There are two etching methods, one is wet etching and the other is dry etching. Wet etching is now widely used, which can control the etching precision very well. The oxide semiconductor active layer is patterned by etching to form a high-conductivity semiconductor layer 504 and a low-conductivity semiconductor layer 505 as shown in Fig. 3F.
S408、 形成刻蚀阻挡层;  S408, forming an etch barrier layer;
如图 3G所示, 在已经图形化的氧化物半导体有源层上直接形成刻蚀阻 挡层( Etch Stop Layer, ESL ) 506, 其材料因不同的厂家针对各自的工艺要求 的不同而不同, 通常需用如 SiOx、 SiNx, SiOxNy、 A1203、 TiOx、 Y203等无 机绝缘材料, 其目的就是为了减少在数据线图形化的过程中, 对氧化物半导 体薄膜造成伤害, 同时可以有效地改善 TFT器件的稳定性, 避免外界环境对 TFT器件的影响。 As shown in FIG. 3G, an Etch Stop Layer (ESL) 506 is directly formed on the patterned oxide semiconductor active layer, and the material thereof is different according to different process requirements of different manufacturers, usually Inorganic insulating materials such as SiOx, SiNx, SiOxNy, A1 2 0 3 , TiOx, Y 2 0 3 are required, and the purpose thereof is to reduce damage to the oxide semiconductor film during patterning of the data lines, and at the same time be effective The stability of the TFT device is improved to avoid the influence of the external environment on the TFT device.
S409、 对刻蚀阻挡层进行图形化;  S409, patterning the etch barrier layer;
通过干法刻蚀的方法对刻蚀阻挡层进行图形化,如图 3H中的 506a所示。 本步工艺的制作关键点是在如何控制刻蚀阻挡层刻蚀过程中防止对栅绝缘层 的过刻。 如果控制不好在制作面板的过程中会造成栅极金属线和源漏电极中 间的短路或者击穿现象, 从而导致面板失效。 如果在材料选择上分别选用具 有较大刻蚀选择比的材料, 将会很好的避免上述问题。 同时可釆用干法和湿 法刻蚀相结合的方式也可以很好的避免上述问题。  The etch stop layer is patterned by dry etching as shown at 506a in Figure 3H. The key point in the fabrication of this step is to prevent over-etching of the gate insulating layer during how to control the etching of the etch barrier. If the control is not good, the short circuit or breakdown phenomenon between the gate metal line and the source and drain electrodes may occur during the process of fabricating the panel, thereby causing the panel to fail. If the materials with larger etching selectivity are selected separately for material selection, the above problems will be well avoided. At the same time, the combination of dry and wet etching can also avoid the above problems.
进一步的, 刻蚀阻挡层的形成有两种方案, 第一种方案是沉积完氧化物 半导体有源层后, 继续沉积刻蚀阻挡层, 通过构图工艺, 刻蚀暴露出源电极 和漏电极与半导体的接触过孔, 刻蚀阻挡层的外围边缘图案和氧化物半导体 层的图案一致, 通过刻蚀阻挡层的过孔可直接定义出氧化物半导体有源层的 欧姆接触区域; 第二种方案是沉积完氧化物半导体有源层后,先进行图形化, 然后再进行刻蚀阻挡层的沉积, 刻蚀阻挡层覆盖形成氧化物半导体有源层后 的整个基板, 然后对刻蚀阻挡层进行图形化, 只需暴露出源电极和漏电极与 有源层接触的部位, 其他区域的刻蚀阻挡层依然保留在基板上。 然而, 根据 本发明实施例并不限定于上述方法或结构, 如图 3H所示, 刻蚀阻挡层 506a 也可以仅覆盖部分的氧化物半导体有源层。 Further, there are two solutions for forming the etch barrier layer. The first solution is to deposit an etch barrier layer after depositing the active layer of the oxide semiconductor, and exposing the source electrode and the drain electrode by a patterning process. The contact via of the semiconductor, the peripheral edge pattern of the etch barrier layer is consistent with the pattern of the oxide semiconductor layer, and the ohmic contact region of the active layer of the oxide semiconductor can be directly defined by etching the via of the barrier layer; After depositing the active layer of the oxide semiconductor, patterning is performed, and then deposition of an etch barrier layer is performed. The etch barrier layer covers the entire substrate after forming the active layer of the oxide semiconductor, and then the etch barrier layer is performed. Graphical, just expose the source and drain electrodes and Where the active layer contacts, the etch stop of the other regions remains on the substrate. However, embodiments in accordance with the present invention are not limited to the above method or structure. As shown in FIG. 3H, the etch stop layer 506a may also cover only a portion of the oxide semiconductor active layer.
5410、 进行金属化的等离子体处理;  5410, performing metallization plasma treatment;
在制备完刻蚀阻挡层之后, 形成源电极和漏电极。 这样的制作方案与氧 化物半导体有源层相配合可以实现一个比较好的器件性能的输出。 优选的, 在形成源电极和漏电极之前, 可以先利用氢气、 N20、 CF4或者 Ar等气体的 等离子体对氧化物半导体的表面进行处理, 进而改善器件欧姆接触特性, 如 图 3 I中所示。 经过步骤 410, 可以在氧化物半导体的未被刻蚀阻挡层 506a 覆盖的表面上形成金属化半导体层 507a和 507b。 After the etch stop layer is prepared, a source electrode and a drain electrode are formed. Such a fabrication scheme can be combined with an active layer of an oxide semiconductor to achieve a better output of device performance. Preferably, before the source electrode and the drain electrode are formed, the surface of the oxide semiconductor can be treated with a plasma of a gas such as hydrogen, N 2 O, CF 4 or Ar, thereby improving the ohmic contact characteristics of the device, as shown in FIG. 3 . Shown in . Through step 410, metallized semiconductor layers 507a and 507b may be formed on the surface of the oxide semiconductor not covered by the etch barrier layer 506a.
5411、 形成数据线金属层, 并图形化形成源电极和漏电极;  5411, forming a data line metal layer, and patterning the source electrode and the drain electrode;
如图 3J所示,在 S409和 S410工艺过程之后,形成数据线金属层。首先, 沉积一层金属层, 利用构图工艺, 形成数据线及源电极 508a和漏电极 508b。 金属层多釆用磁控溅射的方法来制备。 电极材料根据不同的器件结构和工艺 要求可以进行选择。 通常釆用的电极金属有 Mo、 Mo-Al-Mo 合金、 Mo/Al-Nd/Mo叠层结构的电极、 Cu以及金属钛及其合金、 ITO电极、 Ti/Al/Ti、 Mo/ITO 等, 令其方块电阻保持在一个相对比较低的水平。 在金属电极层形 成后, 对其进行图形化工艺。 通过釆用湿法刻蚀的方法对其进行图形化, 如 图 4J中的源极 508a和漏极 508b所示。  As shown in FIG. 3J, after the S409 and S410 processes, a data line metal layer is formed. First, a metal layer is deposited, and a data line and a source electrode 508a and a drain electrode 508b are formed by a patterning process. The metal layer is prepared by magnetron sputtering. The electrode materials can be selected according to different device structures and process requirements. Commonly used electrode metals are Mo, Mo-Al-Mo alloy, Mo/Al-Nd/Mo laminated structure electrode, Cu and titanium metal and its alloy, ITO electrode, Ti/Al/Ti, Mo/ITO, etc. , keeping its sheet resistance at a relatively low level. After the metal electrode layer is formed, it is patterned. It is patterned by wet etching, as shown by source 508a and drain 508b in Figure 4J.
至此, 薄膜晶体管的制作已经完成; 不过, 阵列基板的制作还包括: 钝 化层的形成和像素电极的形成, 下面针对钝化层及像素电极的形成过程进行 详细描述。  So far, the fabrication of the thin film transistor has been completed; however, the fabrication of the array substrate further includes: formation of a passivation layer and formation of a pixel electrode, and a detailed description of the formation process of the passivation layer and the pixel electrode will be described below.
5412、 钝化层的形成和过孔刻蚀;  5412, formation of a passivation layer and via etching;
如图 3K所示, 在源电极和漏电极图形化之后, 在整个基板上形成一层 钝化层, 通常需用如 SiOx、 SiNx, SiOxNy、 A1203、 TiOx、 Y203等无机绝缘 材料; 同时在 AMOLED (有源矩阵有机发光二极体面板)领域应用时, 为了后 续的制备条件更加优异, 也可以釆用有机绝缘层, 如树脂材料和亚克力系材 料等。 在钝化层形成之后利用构图工艺, 进行过孔的刻蚀, 用以实现漏电极 与像素电极的连接, 如图 3K中的过孔 509a和过孔 509b所示。 As shown in FIG. 3K, after the source electrode and the drain electrode are patterned, a passivation layer is formed on the entire substrate, usually using inorganic substances such as SiOx, SiNx, SiOxNy, A1 2 0 3 , TiOx, Y 2 0 3 , etc. Insulating materials; At the same time, in the field of AMOLED (Active Matrix Organic Light Emitting Diode Panel), organic insulating layers such as resin materials and acrylic materials can also be used for the subsequent preparation conditions. After the passivation layer is formed, a via etching is performed by a patterning process to effect connection of the drain electrode and the pixel electrode, as shown by the via hole 509a and the via hole 509b in FIG. 3K.
S413、 像素电极的形成及图形化; 如图 3L所示, 在过孔形成之后, 形成像素电极层 510, 并通过湿法刻蚀 的方法进行构图工艺, 像素电极现在广为釆用的是铟锡氧化物, 最终形成如 图 3M所示的氧化物薄膜晶体管及阵列基板。 S413, forming and patterning a pixel electrode; As shown in FIG. 3L, after the via is formed, the pixel electrode layer 510 is formed, and the patterning process is performed by a wet etching method. The pixel electrode is now widely used as indium tin oxide, and finally formed as shown in FIG. 3M. The oxide thin film transistor and the array substrate are shown.
这样, 在不增加工序的情况下, 通过分层优化的半导体有源层的结构设 计,使 TFT器件具有高的开态电流 Ion和低的关态电流 Ioff,进而改善了 TFT 器件的性能。 进一步的, 在刻蚀阻挡层图形化后, 对半导体有源层进行等离 子体处理, 解决源电极和漏电极与氧化物半导体有源层的欧姆接触问题, 进 而提高了 TFT特性, 确保产品性能。  Thus, the TFT device has a high on-state current Ion and a low off-state current Ioff by the structural design of the layer-optimized semiconductor active layer without increasing the number of steps, thereby improving the performance of the TFT device. Further, after the etch barrier layer is patterned, the semiconductor active layer is subjected to plasma treatment to solve the ohmic contact problem between the source electrode and the drain electrode and the oxide semiconductor active layer, thereby improving the TFT characteristics and ensuring product performance.
下面将通过方法二的描述来介绍根据本发明实施例的薄膜晶体管的制作 过程。 具体地, 薄膜晶体管的制作过程可参照图 5A〜图 5E所示的阵列基板 的制造方法进行说明。  The fabrication process of the thin film transistor according to the embodiment of the present invention will be described below by the description of the second method. Specifically, the fabrication process of the thin film transistor can be described with reference to the method of manufacturing the array substrate shown in Figs. 5A to 5E.
本发明实施例除了氧化物半导体过渡层的形成及数据线金属层和氧化物 半导体过渡层的图形化(此处为步骤 S710— S711 )与上述方法一的实施的工 艺制作顺序 (即步骤 S410— S411 ) 不同外, 其余步骤均可参考上述实施例。  In the embodiment of the present invention, in addition to the formation of the oxide semiconductor transition layer and the patterning of the data line metal layer and the oxide semiconductor transition layer (here, steps S710-S711) and the process sequence of the implementation of the first method (ie, step S410- S411) The steps may be referred to the above embodiments for the remaining steps.
根据该实施例的制造方法的步骤包括:  The steps of the manufacturing method according to this embodiment include:
5701、 在基板上形成栅极金属层。  5701. Form a gate metal layer on the substrate.
5702、 对栅极金属层进行图形化。  5702. Graphically pattern the gate metal layer.
5703、 在栅极上形成栅绝缘层。  5703. Form a gate insulating layer on the gate.
5704、 对栅绝缘层表面进行处理。  5704. Process the surface of the gate insulating layer.
S705、 形成高导通能力的半导体层。  S705, forming a semiconductor layer with high conductivity.
5706、 形成低导通能力的半导体层, 高导通能力的半导体层和低导通能 力的半导体层组成氧化物半导体有源层。  5706, forming a semiconductor layer having low conductivity, a semiconductor layer having high conductivity and a semiconductor layer having low conductivity constitute an oxide semiconductor active layer.
5707、 对氧化物半导体有源层进行图形化。  5707. Patterning an active layer of an oxide semiconductor.
5708、 形成刻蚀阻挡层。  5708. Form an etch barrier layer.
S709、 对刻蚀阻挡层进行图形化;  S709, patterning the etch barrier layer;
在步骤 S709之前与方法一是一致的, 只是与步骤 S410 S411等工艺过 程有所不同, 在步骤 S412之后所进行的工艺步骤亦相同, 所以本发明针对 方法二中的步骤 S710~S711进行描述。  It is the same as the first method before the step S709, except that the process is different from the process of the step S410 S411, and the process steps are the same after the step S412. Therefore, the present invention describes the steps S710 to S711 in the second method.
S710、 形成半导体过渡层;  S710, forming a semiconductor transition layer;
如图 5A所示, 为步骤 S701 709工艺完成后的示意图, 在基板 801上依 次形成栅极 802a和栅线 802b、 栅绝缘层 803、 高导通能力的半导体层 804、 低导通能力的半导体层 805及刻蚀阻挡层 806。 之后, 在数据线金属层形成 之前,在已图形化的刻蚀阻挡层之上形成一层低氧、高导的氧化物半导体层, 即半导体过渡层。 该氧化物半导体过渡层的厚度在 5-50nm, 如图 5B中 807 所示。 在数据线金属层与氧化物半导体有源层之间形成一个过渡层, 实现源 电极和漏电极与氧化物半导体有源层之间的欧姆接触, 最大程度的降低器件 的接触电阻, 进而提高器件的性能。 氧化物半导体有源层、 半导体过渡层及 源电极和漏电极相结合, 形成一个三明治结构的器件的方案, 其可以最大程 度的改善器件的性能。 As shown in FIG. 5A, after the process of step S701 709 is completed, the substrate 801 is A gate electrode 802a and a gate line 802b, a gate insulating layer 803, a high-conductivity semiconductor layer 804, a low-conductivity semiconductor layer 805, and an etch barrier layer 806 are formed. Thereafter, a layer of low oxygen, high conductivity oxide semiconductor, ie, a semiconductor transition layer, is formed over the patterned etch stop layer prior to formation of the data line metal layer. The oxide semiconductor transition layer has a thickness of 5 to 50 nm as shown by 807 in Fig. 5B. Forming a transition layer between the data line metal layer and the oxide semiconductor active layer, achieving ohmic contact between the source electrode and the drain electrode and the oxide semiconductor active layer, thereby minimizing the contact resistance of the device, thereby improving the device Performance. The oxide semiconductor active layer, the semiconductor transition layer, and the combination of the source and drain electrodes form a sandwich structure device that maximizes device performance.
根据本发明的实施例, 在制作薄膜晶体管的过程中, 釆用上述三明治结 构的分层优化方案, 可以提高器件的性能。 半导体过渡层的材料与半导体有 源层可以釆用同质或者同系的高导的材料, 现在广为使用的氧化物半导体有 源层材料有铟镓辞氧化物 (IGZO ) 、 铟锡辞氧化物 (ITZO ) 、 铟辞氧化物 ( IZO )等以及与其相关的不同比例的配合物。 只要控制好其工艺过程, 实 现其高导通的性能, 同时要降低源电极和漏电极和氧化物半导体有源层之间 的欧姆接触。 主要的制作方法有磁控溅射沉积以及溶液法等。 因工艺要求不 同可以选择不同的刻蚀方法。  According to an embodiment of the present invention, in the process of fabricating a thin film transistor, the layered optimization scheme of the above sandwich structure can improve the performance of the device. The material of the semiconductor transition layer and the semiconductor active layer can be made of homogenous or homogenous high-conductivity materials. Currently widely used oxide semiconductor active layer materials are indium gallium oxide (IGZO), indium tin oxide (ITZO), indium oxide (IZO), etc., and complexes of different ratios associated therewith. As long as the process is controlled, its high-conductivity performance is achieved, and the ohmic contact between the source and drain electrodes and the active layer of the oxide semiconductor is reduced. The main production methods are magnetron sputtering deposition and solution method. Different etching methods can be selected due to different process requirements.
S711、 形成数据线金属层, 并对数据线金属层和半导体过渡层进行图形 化;  S711, forming a data line metal layer, and patterning the data line metal layer and the semiconductor transition layer;
如图 5C所示, 在完成 S710工艺之后, 在半导体过渡层之上形成数据线 金属层 808。 金属电极多釆用磁控溅射的方法来制备, 电极材料根据不同的 器件结构和工艺要求可以进行选择。通常被釆用的电极金属有 Μο、Μο-Α1-Μο 合金、 Mo/Al-Nd/Mo叠层结构的电极、 Cu以及金属钛及其合金、 ITO电极、 Ti/Al/Ti、 Mo/ITO等, 令其方块电阻保持在一个相对比较低的水平。 在数据 线金属层形成后, 对其进行图形化工艺。 通过釆用湿法刻蚀的方法对其进行 图形化, 得到图 7D 中所示的源电极 808a和漏电极 808b。 在此步刻蚀工艺 过程中一定要注意的是, 实现源电极和漏电极和氧化物半导体过渡层的同步 刻蚀, 这样既改善了器件的性能又不增加整体的工艺过程, 不会增加生产的 成本。  As shown in FIG. 5C, after the S710 process is completed, a data line metal layer 808 is formed over the semiconductor transition layer. The metal electrode is prepared by magnetron sputtering, and the electrode material can be selected according to different device structures and process requirements. Commonly used electrode metals are Μο, Μο-Α1-Μο alloy, Mo/Al-Nd/Mo laminated structure electrode, Cu and titanium metal and its alloy, ITO electrode, Ti/Al/Ti, Mo/ITO Etc., keep its sheet resistance at a relatively low level. After the data line metal layer is formed, it is patterned. The pattern was patterned by wet etching to obtain the source electrode 808a and the drain electrode 808b shown in Fig. 7D. At this step, it must be noted that the simultaneous etching of the source and drain electrodes and the oxide semiconductor transition layer is achieved, which not only improves the performance of the device but also increases the overall process, and does not increase production. the cost of.
S712、 钝化层的形成和过孔刻蚀。 S713、 像素电极层的形成及构图; S712, formation of a passivation layer, and via etching. S713, formation and patterning of the pixel electrode layer;
最终形成如图 5E所示的氧化物薄膜晶体管及阵列基板。如图 5E所示 809 为钝化层, 810为像素电极层, 至此, 氧化物薄膜晶体管阵列基板制作完毕。  Finally, an oxide thin film transistor and an array substrate as shown in Fig. 5E are formed. As shown in FIG. 5E, 809 is a passivation layer, and 810 is a pixel electrode layer. Thus, the oxide thin film transistor array substrate is completed.
这样, 在不增加工序的情况下, 通过分层优化的三明治结构的器件方案 可以很好的提高器件的性能, 不仅具有高的开态电流 Ion和低的关态电流 Ioff, 而且由于半导体过渡层的存在,解决了源电极和漏电极与有源层之间的 欧姆接触问题, 进而确保器件特性和产品的性能。 根据本发明的实施例可改 善 TFT器件的性能, 从而对整个基板良率的提升, 降低成本起到非常关键的 作用。  In this way, the device scheme of the sandwich structure optimized by layering can improve the performance of the device without increasing the process, not only has a high on-state current Ion and a low off-state current Ioff, but also due to the semiconductor transition layer. The existence of the ohmic contact between the source and drain electrodes and the active layer is solved, thereby ensuring device characteristics and product performance. The embodiment of the present invention can improve the performance of the TFT device, thereby playing a very important role in improving the overall substrate yield and reducing the cost.
可以理解的是, 上述通过底栅结构为例描述了氧化物薄膜晶体管的结构 和制备方法。 然而, 根据本发明的实施例并不限制于上述底栅极结构, 也可 以为顶栅极结构或者其他各种氧化物薄膜晶体管结构。 根据本发明实施例利 用高导通能力的氧化物半导体层靠近栅极一侧, 从而能够实现高的开态电流 It can be understood that the structure and preparation method of the oxide thin film transistor are described by way of example of the bottom gate structure. However, embodiments in accordance with the present invention are not limited to the above described bottom gate structure, and may be top gate structures or other various oxide thin film transistor structures. According to an embodiment of the present invention, a high-conductivity oxide semiconductor layer is used near the gate side, thereby enabling high on-state current
Ion; 另外, 利用低导通能力的氧化物半导体层靠近源漏电极一侧, 从而能够 实现低的关态电流 Ioff。 因此, 如果氧化物半导体薄膜晶体管为顶栅极结构, 则高导通能力的半导体层需要设置在顶层, 而低导通能力的半导体层需要设 置在底层。 也就是说, 氧化物半导体层设在源漏电极和栅极之间, 且氧化物 半导体层中的低导通能力的半导体层设置在源漏电极一侧, 而高导通能力的 半导体层设置在栅极一侧。 Ion; In addition, the low-on-state oxide semiconductor layer is close to the source/drain electrode side, so that a low off-state current Ioff can be realized. Therefore, if the oxide semiconductor thin film transistor is a top gate structure, a highly conductive semiconductor layer needs to be disposed on the top layer, and a low conduction semiconductor layer needs to be disposed on the bottom layer. That is, the oxide semiconductor layer is disposed between the source/drain electrode and the gate electrode, and the low-conductivity semiconductor layer in the oxide semiconductor layer is disposed on the source/drain electrode side, and the high-conductivity semiconductor layer is disposed. On the side of the gate.
另外, 根据本发明实施例中高导通能力的半导体层和低导通能力的半导 体层中的 "高导通能力" 和 "低导通能力" 为两个相对的概念, 如此设置以 使得兼顾开态电流和关态电流的目的。 另外, 在根据本发明的实施例中, 高 导通能力和低导通能力的半导体层的具体电导率没有特别限制, 可以根据实 际情况而任意选择。  In addition, the "high conduction capability" and "low conduction capability" in the semiconductor layer having high on capability and the semiconductor layer having low on capability according to the embodiment of the present invention are two relative concepts, and are set such that both are opened. The purpose of the current and the off current. Further, in the embodiment according to the present invention, the specific conductivity of the semiconductor layer having high on capability and low on capability is not particularly limited and may be arbitrarily selected depending on the actual situation.
在上述各实施例中, 半导体有源层以金属氧化物半导体材料为例进行了 描述, 但根据本发明实施例的半导体材料不限于此。 在半导体有源层釆用金 属氧化物半导体材料的情况下, 高导通能力的半导体层可以釆用氧含量较低 的金属氧化物, 而低导通能力的半导体层则可以釆用氧含量较高的金属氧化 物。 多层半导体有源层的结构下, 具体的氧含量可以根据实际需要而设置为 合适的值。 另外需要说明的是, 对于本发明实施例中高导通能力和低导通能 力的半导体材料不限于上述低氧含量和高氧含量的金属氧化物。 In each of the above embodiments, the semiconductor active layer has been described by taking a metal oxide semiconductor material as an example, but the semiconductor material according to an embodiment of the present invention is not limited thereto. In the case where the semiconductor active layer is made of a metal oxide semiconductor material, the semiconductor layer having high conductivity can be used with a metal oxide having a low oxygen content, and the semiconductor layer having a low conductivity can be used with a higher oxygen content. High metal oxides. Under the structure of the multilayered semiconductor active layer, the specific oxygen content can be set to an appropriate value according to actual needs. In addition, it should be noted that the high conduction capability and the low conduction performance in the embodiment of the present invention are The semiconductor material of the force is not limited to the above-mentioned metal oxide having a low oxygen content and a high oxygen content.
另外, 在上述制造方法的实施例中, 仅仅给出了底栅极结构薄膜晶体管 的制造方法示例。 对于顶栅极结构薄膜晶体管的制造方法, 在栅极、 栅极绝 缘层、半导体有源层、 源电极和漏电极的制作顺序与底栅极结构不同。例如, 可以依次形成源电极和漏电极、 半导体有源层、 栅极绝缘层和栅极。 对于其 他结构或更详细步骤, 可以参照对底栅极结构制造方法的示例, 这里不再赘 述。  Further, in the embodiment of the above manufacturing method, only an example of the manufacturing method of the bottom gate structure thin film transistor is given. For the fabrication method of the top gate structure thin film transistor, the fabrication order of the gate electrode, the gate insulating layer, the semiconductor active layer, the source electrode and the drain electrode is different from that of the bottom gate structure. For example, the source and drain electrodes, the semiconductor active layer, the gate insulating layer, and the gate electrode may be sequentially formed. For other structures or more detailed steps, reference may be made to an example of a method of fabricating a bottom gate structure, which will not be described herein.
本发明还提供一种阵列基板, 其包括上述任一实施例中所描述的薄膜晶 体管, 具体的可以参照图 2和图 4所示的结构。  The present invention also provides an array substrate comprising the thin film transistor described in any of the above embodiments, and the structure shown in Figs. 2 and 4 can be specifically referred to.
同时本发明提供一种显示器件,所述显示器件,具体可以是液晶显示器、 有机发光二极管 (OLED )显示器、 有源电子纸显示器及其它使用上述薄膜 晶体管、 阵列基板驱动的显示装置。  In the meantime, the present invention provides a display device, which may specifically be a liquid crystal display, an organic light emitting diode (OLED) display, an active electronic paper display, and other display devices driven using the above thin film transistor and array substrate.
以上所述仅是本发明的示范性实施方式, 而非用于限制本发明的保护范 围, 本发明的保护范围由所附的权利要求确定。  The above is only an exemplary embodiment of the present invention, and is not intended to limit the scope of the present invention. The scope of the present invention is defined by the appended claims.

Claims

权利要求书 Claim
1、 一种薄膜晶体管, 包括: 栅极、 栅绝缘层、 半导体有源层、 源电极和 漏电极, 其中, A thin film transistor comprising: a gate, a gate insulating layer, a semiconductor active layer, a source electrode, and a drain electrode, wherein
所述半导体有源层为多层结构, 至少包括高导通能力的半导体层和低导 通能力的半导体层;  The semiconductor active layer is a multilayer structure including at least a semiconductor layer having high conductivity and a semiconductor layer having low conductivity;
所述高导通能力的半导体层靠近所述栅极, 且低导通能力的半导体层靠 近所述源电极和所述漏电极。  The high-conductivity semiconductor layer is adjacent to the gate, and the low-conductivity semiconductor layer is adjacent to the source electrode and the drain electrode.
2、 根据权利要求 1所述的薄膜晶体管, 其中,  2. The thin film transistor according to claim 1, wherein
所述低导通能力的半导体层与所述源电极和漏电极之间还设有高导通能 力的半导体过渡层。  The low-conductivity semiconductor layer and the source and drain electrodes are further provided with a high-conductivity semiconductor transition layer.
3、 根据权利要求 2所述的薄膜晶体管, 其中,  3. The thin film transistor according to claim 2, wherein
所述高导通能力的半导体过渡层与所述高导通能力的半导体层选用的材 料相同。  The high conductivity semiconductor transition layer is the same material as the high conductivity semiconductor layer.
4、 根据权利要求 2或 3所述的薄膜晶体管, 其中,  4. The thin film transistor according to claim 2 or 3, wherein
所述半导体过渡层的厚度为 5~50nm。  The semiconductor transition layer has a thickness of 5 to 50 nm.
5、 根据权利要求 1 ~ 4中任一项所述的薄膜晶体管, 其中,  The thin film transistor according to any one of claims 1 to 4, wherein
所述低导通能力的半导体层与所述源电极和漏电极之间还设有金属化半 导体层。  A metallization semiconductor layer is further disposed between the low-conductivity semiconductor layer and the source and drain electrodes.
6、 根据权利要求 1 ~ 5中任一项所述的薄膜晶体管, 其中,  The thin film transistor according to any one of claims 1 to 5, wherein
所述高导通能力的半导体层与所述源电极和漏电极之间还设有刻蚀阻挡 层。  An etch barrier layer is further disposed between the high conductivity semiconductor layer and the source and drain electrodes.
7、 根据权利要求 1 ~ 6中任一项所述的薄膜晶体管, 其中, 所述半导体 有源层的材料为金属氧化物材料。  The thin film transistor according to any one of claims 1 to 6, wherein a material of the semiconductor active layer is a metal oxide material.
8、 根据权利要求 1 ~ 5中任一项所述的薄膜晶体管, 其中,  The thin film transistor according to any one of claims 1 to 5, wherein
所述栅极在所述半导体有源层的下方, 所述源电极和漏电极位于所述半 导体有源层的上方;  The gate is below the semiconductor active layer, and the source and drain electrodes are located above the active layer of the semiconductor;
所述半导体有源层与所述源电极和漏电极之间还设置有刻蚀阻挡层。  An etch stop layer is further disposed between the semiconductor active layer and the source and drain electrodes.
9、 根据权利要求 1 ~ 5中任一项所述的薄膜晶体管, 其中, The thin film transistor according to any one of claims 1 to 5, wherein
所述栅极在所述半导体有源层的上方, 所述源电极和漏电极位于所述半 导体有源层的下方。 The gate is above the semiconductor active layer, and the source and drain electrodes are located in the half Below the active layer of the conductor.
10、 一种薄膜晶体管的制造方法, 包括: 在基板上形成栅极、栅绝缘层、 半导体有源层、 源电极和漏电极的过程; 其中,  10. A method of fabricating a thin film transistor, comprising: a process of forming a gate electrode, a gate insulating layer, a semiconductor active layer, a source electrode, and a drain electrode on a substrate;
形成所述半导体有源层的过程包括:  The process of forming the semiconductor active layer includes:
在靠近所述栅极侧形成高导通能力的半导体层;  Forming a semiconductor layer with high conductivity near the gate side;
在靠近所述源电极和漏电极侧形成低导通能力的半导体层。  A semiconductor layer having a low conductivity is formed on the side close to the source electrode and the drain electrode.
11、 根据权利要求 10中所述的薄膜晶体管的制造方法, 其中, 所述半导体有源层在所述栅极和所述栅极绝缘层之后且在所述源电极和 漏电极之前形成, 且 法还包括形成刻蚀阻挡层的图形。  The method of manufacturing a thin film transistor according to claim 10, wherein the semiconductor active layer is formed after the gate electrode and the gate insulating layer and before the source electrode and the drain electrode, and The method also includes forming a pattern of the etch stop layer.
12、 根据权利要求 10中所述的薄膜晶体管的制造方法, 其中, 所述半导体有源层在所述源电极和漏电极之后且在所述栅极和所述栅极 绝缘层之前形成。  The method of manufacturing a thin film transistor according to claim 10, wherein the semiconductor active layer is formed after the source and drain electrodes and before the gate electrode and the gate insulating layer.
13、根据权利要求 11所述的薄膜晶体管的制造方法, 其中,在所述半导 体有源层和所述源电极和漏电极之间形成所述刻蚀阻挡层之后且在形成所述 源电极和漏电极之前, 还包括:  The method of manufacturing a thin film transistor according to claim 11, wherein after forming the etch stop layer between the semiconductor active layer and the source electrode and the drain electrode, and forming the source electrode and Before draining the electrode, it also includes:
利用等离子体处理工艺对所述半导体有源层上未覆盖刻蚀阻挡层的表面 进行金属化处理, 在半导体有源层表面形成金属化半导体层。  The surface of the semiconductor active layer not covered with the etch barrier layer is metallized by a plasma treatment process to form a metallized semiconductor layer on the surface of the semiconductor active layer.
14、 根据权利要求 11或 13所述的薄膜晶体管的制造方法, 其中, 在所 述半导体有源层和所述源电极和漏电极层之间, 还包括:  The method of manufacturing a thin film transistor according to claim 11 or 13, wherein, between the semiconductor active layer and the source and drain electrode layers, further comprising:
在形成所述刻蚀阻挡层之后且在形成所述源电极和漏电极之前 ,还包括: 在形成有所述刻蚀阻挡层图案的基板上形成高导通能力的半导体过渡层。  After forming the etch stop layer and before forming the source and drain electrodes, the method further includes: forming a high conductivity semiconductor transition layer on the substrate on which the etch barrier layer pattern is formed.
15、根据权利要求 12所述的薄膜晶体管的制造方法, 其特征在于, 在所 述半导体有源层和所述源电极和漏电极之间, 还包括:  The method of manufacturing a thin film transistor according to claim 12, further comprising: between the semiconductor active layer and the source and drain electrodes, further comprising:
在形成所述源电极和漏电极之后且在形成所述半导体有源层之前, 还包 括: 在成有所述源电极和漏电极的基板上形成高导通能力的半导体过渡层。  After forming the source and drain electrodes and before forming the semiconductor active layer, the method further includes: forming a semiconductor layer having high conductivity on the substrate on which the source and drain electrodes are formed.
16、根据权利要求 10~15中任一项所述的薄膜晶体管的制造方法,其中, 所述半导体过渡层与所述高导通能力的半导体层选用的材料相同。  The method of manufacturing a thin film transistor according to any one of claims 10 to 15, wherein the semiconductor transition layer is the same material as that of the high conductivity semiconductor layer.
17、根据权利要求 10~15中任一项所述的薄膜晶体管的制造方法, 其特 征在于, 所述半导体过渡层的厚度为 5~50nm。 The method of manufacturing a thin film transistor according to any one of claims 10 to 15, wherein The semiconductor transition layer has a thickness of 5 to 50 nm.
18、据权利要求 11中所述的薄膜晶体管的制造方法, 其中, 所述形成半 导体有源层和刻蚀阻挡层的过程包括:  The method of manufacturing a thin film transistor according to claim 11, wherein the process of forming the semiconductor active layer and the etch stop layer comprises:
在形成有栅绝缘层的基板上, 依次形成半导体有源层薄膜和刻蚀阻挡层 薄膜;  Forming a semiconductor active layer film and an etch barrier film on the substrate on which the gate insulating layer is formed;
通过一次构图工艺形成所述半导体有源层和刻蚀阻挡层。  The semiconductor active layer and the etch stop layer are formed by one patterning process.
19、根据权利要求 10~12中任一项所述的薄膜晶体管的制造方法,其中, 所述半导体有源层材料为金属氧化物材料。  The method of manufacturing a thin film transistor according to any one of claims 10 to 12, wherein the semiconductor active layer material is a metal oxide material.
20、 一种阵列基板, 包括权利要求 1 ~ 9中任一项所述的薄膜晶体管。 An array substrate comprising the thin film transistor according to any one of claims 1 to 9.
21、 一种显示装置, 包括权利要求 20所述的阵列基板。 A display device comprising the array substrate of claim 20.
PCT/CN2012/086217 2012-01-13 2012-12-07 Thin film transistor, manufacturing method therefor, array substrate and display device WO2013104226A1 (en)

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