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WO2011014022A3 - Metallocene compound, catalyst composition comprising the same, and olefinic polymers produced using the same - Google Patents

Metallocene compound, catalyst composition comprising the same, and olefinic polymers produced using the same Download PDF

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Publication number
WO2011014022A3
WO2011014022A3 PCT/KR2010/004991 KR2010004991W WO2011014022A3 WO 2011014022 A3 WO2011014022 A3 WO 2011014022A3 KR 2010004991 W KR2010004991 W KR 2010004991W WO 2011014022 A3 WO2011014022 A3 WO 2011014022A3
Authority
WO
WIPO (PCT)
Prior art keywords
same
metallocene compound
olefinic polymers
catalyst composition
produced
Prior art date
Application number
PCT/KR2010/004991
Other languages
French (fr)
Korean (ko)
Other versions
WO2011014022A2 (en
Inventor
이용호
전만성
이기수
권헌용
조민석
박종상
조준희
김현국
송은경
김선경
홍대식
Original Assignee
주식회사 엘지화학
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to EP10804735.8A priority Critical patent/EP2460809B1/en
Priority to SG2012005880A priority patent/SG178126A1/en
Priority to CN201080043648.7A priority patent/CN102574885B/en
Priority to JP2012522765A priority patent/JP5712213B2/en
Priority to US13/386,620 priority patent/US8692009B2/en
Publication of WO2011014022A2 publication Critical patent/WO2011014022A2/en
Publication of WO2011014022A3 publication Critical patent/WO2011014022A3/en
Priority to US14/077,896 priority patent/US9221922B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)

Abstract

The present invention relates to a novel metallocene compound, a catalyst composition comprising the same, and to olefinic polymers produced using the same. The metallocene compound according to the present invention and the catalyst composition comprising the same can be used when producing olefinic polymers, have outstanding copolymerisation properties, and can produce olefinic polymers of high molecular weight. In particular, when the metallocene compound according to the present invention is employed, highly heat resistant block copolymers can be produced, and olefinic polymers can be produced which have a high melting point (Tm) even if the comonomer content is increased when producing the olefinic polymer.
PCT/KR2010/004991 2009-07-31 2010-07-29 Metallocene compound, catalyst composition comprising the same, and olefinic polymers produced using the same WO2011014022A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP10804735.8A EP2460809B1 (en) 2009-07-31 2010-07-29 Metallocene compound, catalyst composition comprising the same, and olefinic polymers produced using the same
SG2012005880A SG178126A1 (en) 2009-07-31 2010-07-29 Metallocene compound, catalyst composition comprising the same, and olefinic polymers produced using the same
CN201080043648.7A CN102574885B (en) 2009-07-31 2010-07-29 Metallocene compound, catalyst composition comprising the same, and olefinic polymers produced using the same
JP2012522765A JP5712213B2 (en) 2009-07-31 2010-07-29 Metallocene compound, catalyst composition containing the same, and olefin polymer produced using the same
US13/386,620 US8692009B2 (en) 2009-07-31 2010-07-29 Metallocene compound, catalyst composition comprising the same, and an olefinic polymer produced using the same
US14/077,896 US9221922B2 (en) 2009-07-31 2013-11-12 Metallocene compound, catalyst composition comprising the same, and an olefinic polymer produced using the same

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20090070574 2009-07-31
KR10-2009-0070574 2009-07-31
KR1020100072934A KR101154507B1 (en) 2009-07-31 2010-07-28 Metallocene compounds, catalyst composition comprising the same, and method for preparation of olefin-based polymer using the same
KR10-2010-0072934 2010-07-28

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US13/386,620 A-371-Of-International US8692009B2 (en) 2009-07-31 2010-07-29 Metallocene compound, catalyst composition comprising the same, and an olefinic polymer produced using the same
US14/077,896 Continuation US9221922B2 (en) 2009-07-31 2013-11-12 Metallocene compound, catalyst composition comprising the same, and an olefinic polymer produced using the same

Publications (2)

Publication Number Publication Date
WO2011014022A2 WO2011014022A2 (en) 2011-02-03
WO2011014022A3 true WO2011014022A3 (en) 2011-06-16

Family

ID=43772998

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/004991 WO2011014022A2 (en) 2009-07-31 2010-07-29 Metallocene compound, catalyst composition comprising the same, and olefinic polymers produced using the same

Country Status (7)

Country Link
US (2) US8692009B2 (en)
EP (1) EP2460809B1 (en)
JP (1) JP5712213B2 (en)
KR (1) KR101154507B1 (en)
CN (1) CN102574885B (en)
SG (1) SG178126A1 (en)
WO (1) WO2011014022A2 (en)

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US9000115B2 (en) 2011-01-27 2015-04-07 Lg Chem, Ltd. Olefin block copolymers and production methods thereof
WO2012102572A2 (en) * 2011-01-27 2012-08-02 주식회사 엘지화학 Olefin block copolymer
US9056939B2 (en) * 2011-01-27 2015-06-16 Lg Chem, Ltd. Olefin block copolymer
KR101503002B1 (en) * 2011-01-28 2015-04-01 주식회사 엘지화학 Metallocene compounds and olefin based polymer prepared by using the same
EP2760895A4 (en) * 2011-09-30 2015-07-22 Exxonmobil Chem Patents Inc Dynamic modulation of metallocene catalysts
KR101549206B1 (en) 2012-05-08 2015-09-02 주식회사 엘지화학 Ansa-metallocene catalyst and preparation method of supported catalyst by using the same
KR20140075589A (en) 2012-12-11 2014-06-19 주식회사 엘지화학 Novel ligand compound, method for preparing the same, transition metal compound and method for preparing the same
KR101623485B1 (en) * 2013-08-01 2016-05-23 주식회사 엘지화학 Metallocene compound, catalyst composition comprising the same, and method for preparation of olefin-based polymer using the same
KR101650092B1 (en) 2013-08-01 2016-08-22 주식회사 엘지화학 Metallocene compound, catalyst composition comprising the same, and method for preparation of olefin-based polymer using the same
KR101631700B1 (en) 2013-10-18 2016-06-17 주식회사 엘지화학 Method for preparing of supported hybrid metallocene catalyst
KR101644113B1 (en) 2013-10-18 2016-07-29 주식회사 엘지화학 Supported hybrid metallocene catalyst
KR101549209B1 (en) 2013-11-18 2015-09-02 주식회사 엘지화학 Olefin based polymer having excellent processibility
KR101705340B1 (en) * 2014-06-03 2017-02-09 주식회사 엘지화학 Method for preparing polyolefin and polyolefin prepared therefrom
KR101666170B1 (en) * 2014-06-18 2016-10-13 주식회사 엘지화학 Transition metal compounds, catalyst composition comprising the same, and preparation method of poly-olefin
JP6420911B2 (en) * 2014-09-05 2018-11-07 エルジー・ケム・リミテッド Hybrid supported catalyst and method for producing olefin polymer using the same
KR101617870B1 (en) * 2014-09-05 2016-05-03 주식회사 엘지화학 Olefin based polymer having excellent processibility
KR101761394B1 (en) * 2014-09-30 2017-07-25 주식회사 엘지화학 Prepararion method of polyolefin polymer for preparing fiber
KR101726820B1 (en) * 2014-10-13 2017-04-13 주식회사 엘지화학 Ethylene/1-hexene or ethylene/1-butene copolymer having excellent processibility and environmental stress crack resistance
WO2016060445A1 (en) * 2014-10-13 2016-04-21 주식회사 엘지화학 Ethylene/1-hexene or ethylene/1-butene copolymer having outstanding working properties and environmental stress cracking resistance
KR101747396B1 (en) * 2014-12-15 2017-06-14 주식회사 엘지화학 Olefin based polymer having excellent processibility
CN106536534B (en) 2015-01-28 2021-03-12 Lg化学株式会社 Metallocene compound, catalyst composition comprising the same, and method for preparing polyolefin using the same
WO2016122017A1 (en) * 2015-01-28 2016-08-04 주식회사 엘지화학 Metallocene compound, catalyst composition comprising same, and method for preparing olefin-based polymer using same
KR101891638B1 (en) 2015-04-15 2018-08-24 주식회사 엘지화학 Ethylene/alpha-olefin copolymer having excellent processibility
KR20160134464A (en) 2015-05-15 2016-11-23 주식회사 엘지화학 Supported hybrid catalyst system and method for olefin polymerization using the same
US10513474B2 (en) 2015-05-15 2019-12-24 Lg Chem, Ltd. Catalyst composition and method of preparing polyolefin using the same
KR101768194B1 (en) 2015-05-15 2017-08-16 주식회사 엘지화학 Catalyst composition and method for preparing polyolefin using the same
KR101790672B1 (en) 2015-08-24 2017-10-26 주식회사 엘지화학 Transition metal compound, catalyst composition comprising the same, and method for preparing olefin polymer using the same
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US20230025875A1 (en) * 2019-12-04 2023-01-26 Borealis Ag Light weight melt blown webs with improved barrier properties

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Also Published As

Publication number Publication date
KR101154507B1 (en) 2012-06-13
EP2460809B1 (en) 2015-06-17
US20140066288A1 (en) 2014-03-06
WO2011014022A2 (en) 2011-02-03
JP2013500331A (en) 2013-01-07
KR20110013286A (en) 2011-02-09
US20120123078A1 (en) 2012-05-17
CN102574885B (en) 2014-12-31
EP2460809A2 (en) 2012-06-06
EP2460809A4 (en) 2014-09-03
US8692009B2 (en) 2014-04-08
SG178126A1 (en) 2012-03-29
CN102574885A (en) 2012-07-11
JP5712213B2 (en) 2015-05-07
US9221922B2 (en) 2015-12-29

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