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WO2008123164A1 - 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、及びゴム組成物 - Google Patents

変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、及びゴム組成物 Download PDF

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Publication number
WO2008123164A1
WO2008123164A1 PCT/JP2008/055340 JP2008055340W WO2008123164A1 WO 2008123164 A1 WO2008123164 A1 WO 2008123164A1 JP 2008055340 W JP2008055340 W JP 2008055340W WO 2008123164 A1 WO2008123164 A1 WO 2008123164A1
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WO
WIPO (PCT)
Prior art keywords
conjugated diene
diene polymer
modified conjugated
rubber composition
producing
Prior art date
Application number
PCT/JP2008/055340
Other languages
English (en)
French (fr)
Inventor
Masahiro Shibata
Takaomi Matsumoto
Tamotsu Nagaoka
Takuo Sone
Toshihiro Tadaki
Original Assignee
Jsr Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jsr Corporation filed Critical Jsr Corporation
Priority to CN2008800133487A priority Critical patent/CN101668780B/zh
Priority to JP2009509086A priority patent/JP5728807B2/ja
Priority to US12/532,764 priority patent/US8178626B2/en
Priority to BRPI0809111-0A priority patent/BRPI0809111B1/pt
Priority to EP08738733.8A priority patent/EP2130842B1/en
Publication of WO2008123164A1 publication Critical patent/WO2008123164A1/ja
Priority to US13/347,115 priority patent/US9206264B2/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/42Introducing metal atoms or metal-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/12Incorporating halogen atoms into the molecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/30Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/30Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00Compositions of rubber derivatives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013Fillers, pigments or reinforcing additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/548Silicon-containing compounds containing sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

 本発明の変性共役ジエン系重合体の製造方法は、少なくとも共役ジエン単位を含む重合体に、アルコキシシリル基と保護されていてもよい第1級アミノ基が結合された、重量平均分子量が15万~200万の共役ジエン系重合体に、金属ハロゲン化合物を反応させることにより、変性共役ジエン系重合体を得る工程、を備え、ムーニー粘度が高く、形状安定性に優れ、加工性が良好な共役ジエン系重合体を良好に得ることができる。
PCT/JP2008/055340 2007-03-23 2008-03-21 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、及びゴム組成物 WO2008123164A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN2008800133487A CN101668780B (zh) 2007-03-23 2008-03-21 改性共轭二烯系聚合物的制造方法、改性共轭二烯系聚合物及橡胶组合物
JP2009509086A JP5728807B2 (ja) 2007-03-23 2008-03-21 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、及びゴム組成物
US12/532,764 US8178626B2 (en) 2007-03-23 2008-03-21 Method for producing modified conjugated diene based (co)polymer, modified conjugated diene based (co)polymer, and rubber composition
BRPI0809111-0A BRPI0809111B1 (pt) 2007-03-23 2008-03-21 Método para a produção de um (co)polímero à base de dieno conjugado modificado, (co)polímero à base de dieno conjugado modificado e composição de borracha
EP08738733.8A EP2130842B1 (en) 2007-03-23 2008-03-21 Method for producing modified conjugated diene polymer, modified conjugated diene polymer, and rubber composition
US13/347,115 US9206264B2 (en) 2007-03-23 2012-01-10 Method for producing modified conjugated diene based (co)polymer, modified conjugated diene based (co)polymer, and rubber composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007077963 2007-03-23
JP2007-077963 2007-03-23

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/532,764 A-371-Of-International US8178626B2 (en) 2007-03-23 2008-03-21 Method for producing modified conjugated diene based (co)polymer, modified conjugated diene based (co)polymer, and rubber composition
US13/347,115 Continuation US9206264B2 (en) 2007-03-23 2012-01-10 Method for producing modified conjugated diene based (co)polymer, modified conjugated diene based (co)polymer, and rubber composition

Publications (1)

Publication Number Publication Date
WO2008123164A1 true WO2008123164A1 (ja) 2008-10-16

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PCT/JP2008/055340 WO2008123164A1 (ja) 2007-03-23 2008-03-21 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、及びゴム組成物

Country Status (7)

Country Link
US (2) US8178626B2 (ja)
EP (1) EP2130842B1 (ja)
JP (1) JP5728807B2 (ja)
KR (1) KR101475966B1 (ja)
CN (1) CN101668780B (ja)
BR (1) BRPI0809111B1 (ja)
WO (1) WO2008123164A1 (ja)

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JP2009263511A (ja) * 2008-04-25 2009-11-12 Bridgestone Corp 空気入りタイヤ
JP2010215716A (ja) * 2009-03-13 2010-09-30 Bridgestone Corp 変性共役ジエン重合体又は共重合体の製造方法、その方法により得られた変性共役ジエン重合体又は共重合体、ゴム組成物及びタイヤ
WO2012073880A1 (ja) * 2010-12-01 2012-06-07 Jsr株式会社 変性共役ジエン系ゴムの製造方法、変性共役ジエン系ゴム、及びゴム組成物
US20130023624A1 (en) * 2010-04-16 2013-01-24 Asahi Kasei Chemicals Corporation Method for Producing Modified Conjugated Diene-Based Polymer, Modified Conjugated Diene-Based Polymer, and Modified Conjugated Diene-Based Polymer Composition
EP2425990A4 (en) * 2009-04-30 2013-06-12 Bridgestone Corp TIRE
JP2014501327A (ja) * 2010-12-31 2014-01-20 株式会社ブリヂストン 加水分解性官能基を含むポリマーの安定化
US20140371383A1 (en) * 2011-08-26 2014-12-18 Asahi Kasei Chemicals Corporation Method for Producing Modified Conjugated Diene Polymer, Modified Conjugated Diene Polymer, Modified Conjugated Diene Polymer Composition, Rubber Composition and Tire
WO2017061831A1 (ko) * 2015-10-08 2017-04-13 주식회사 엘지화학 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물
WO2018025998A1 (ja) * 2016-08-05 2018-02-08 住友化学株式会社 変性共役ジエン系重合体の製造方法及び重合体組成物の製造方法
JP2018513907A (ja) * 2015-04-10 2018-05-31 シントス エス.アー.Synthos S.A. [ビス(トリヒドロカルビルシリル)アミノシリル]官能化スチレンおよびその調製方法
KR20180087380A (ko) 2016-06-24 2018-08-01 제이에스알 가부시끼가이샤 변성 공액 디엔계 중합체의 제조 방법, 변성 공액 디엔계 중합체, 중합체 조성물, 가교체, 타이어 및 화합물
WO2018181176A1 (ja) * 2017-03-31 2018-10-04 住友化学株式会社 共役ジエン系重合体及び共役ジエン系重合体の製造方法
WO2020179705A1 (ja) 2019-03-07 2020-09-10 Jsr株式会社 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、重合体組成物、架橋体及びタイヤ
WO2020196899A1 (ja) 2019-03-27 2020-10-01 Jsr株式会社 水添共役ジエン系重合体、重合体組成物、架橋体及びタイヤ
JP2022516666A (ja) * 2019-09-11 2022-03-01 エルジー・ケム・リミテッド 変性共役ジエン系重合体、およびそれを含むゴム組成物
WO2022196643A1 (ja) 2021-03-15 2022-09-22 株式会社Eneosマテリアル 共役ジエン系重合体及びその製造方法、重合体組成物、架橋体並びにタイヤ
WO2023074773A1 (ja) 2021-10-29 2023-05-04 株式会社Eneosマテリアル 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、重合体組成物、架橋体、タイヤ及び化合物
WO2023085309A1 (ja) 2021-11-10 2023-05-19 株式会社Eneosマテリアル 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、重合体組成物、架橋体及びタイヤ
US12110353B2 (en) 2019-09-11 2024-10-08 Lg Chem, Ltd. Modified conjugated diene-based polymer, method for preparing the same and rubber composition including the same

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BR112012006333B1 (pt) 2009-10-02 2019-09-17 Asahi Kasei Chemicals Corporation Método para produzir um polímero à base de dieno conjugado modificado
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BR112012024516B8 (pt) 2010-03-31 2023-04-18 Jsr Corp Método para produzir borracha de dieno conjugado modificado, borracha de dieno conjugado modificado, composição de borracha, e, pneus
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CN104136238B (zh) 2012-02-29 2017-07-04 盛禧奥欧洲有限责任公司 产生二烯聚合物的方法
US9718931B2 (en) 2012-06-06 2017-08-01 Firestone Polymers, Llc Method of making base stabilized polymers, polymer compositions and articles containing such polymers
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KR101249352B1 (ko) 2012-09-24 2013-04-02 금호석유화학 주식회사 에테르 그룹과 디알킬아미노 그룹이 동시에 포함된 알킬알콕시실란 화합물과 이의 제조방법
KR101365902B1 (ko) * 2013-01-14 2014-03-12 금호석유화학 주식회사 공역 디엔계 고분자의 말단 변성제
KR101310868B1 (ko) 2013-02-26 2013-10-14 금호석유화학 주식회사 알콕시실란 유도체에 의해 말단 변성된 공역 디엔계 고분자
KR101508519B1 (ko) 2013-08-27 2015-04-07 금호석유화학 주식회사 알콕시실란 단위가 포함된 공역 디엔계 랜덤 공중합체
KR101704862B1 (ko) * 2013-09-30 2017-02-08 주식회사 엘지화학 개질 공액 디엔계 중합체, 그 제조방법 및 고무 조성물
ES2716377T3 (es) 2014-06-27 2019-06-12 Kuraray Co Método para la producción de un polímero hidrogenado
KR101700954B1 (ko) 2014-11-05 2017-01-31 금호석유화학 주식회사 말단 변성 공액 디엔계 중합체 및 그 제조방법
KR102435190B1 (ko) * 2015-02-26 2022-08-22 니폰 제온 가부시키가이샤 변성 공액 디엔계 고무의 제조 방법
EP3309180B1 (en) * 2015-06-12 2019-08-07 Asahi Kasei Kabushiki Kaisha Modified conjugated diene-based polymer and production method
JP6686308B2 (ja) * 2015-07-13 2020-04-22 横浜ゴム株式会社 難燃ホース用ゴム組成物及び難燃ホース
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CN109642055B (zh) * 2016-09-02 2021-07-02 株式会社可乐丽 橡胶组合物
KR101926619B1 (ko) 2018-03-29 2018-12-11 금호석유화학 주식회사 기능성 단량체를 포함하는 공중합체 및 그 제조방법
TW202124465A (zh) * 2019-10-31 2021-07-01 日商Jsr股份有限公司 改質共軛二烯系聚合物的製造方法、聚合物組成物、交聯體及輪胎

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Cited By (44)

* Cited by examiner, † Cited by third party
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