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WO2008081631A1 - 重合性化合物及び重合性組成物 - Google Patents

重合性化合物及び重合性組成物 Download PDF

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Publication number
WO2008081631A1
WO2008081631A1 PCT/JP2007/069701 JP2007069701W WO2008081631A1 WO 2008081631 A1 WO2008081631 A1 WO 2008081631A1 JP 2007069701 W JP2007069701 W JP 2007069701W WO 2008081631 A1 WO2008081631 A1 WO 2008081631A1
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Prior art keywords
polymerizable
oco
independently represent
coo
substituent
Prior art date
Application number
PCT/JP2007/069701
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English (en)
French (fr)
Inventor
Rieko Hamada
Masatomi Irisawa
Kiyoshi Murata
Original Assignee
Adeka Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Adeka Corporation filed Critical Adeka Corporation
Priority to CN2007800388231A priority Critical patent/CN101528786B/zh
Priority to EP07829439.4A priority patent/EP2067796B1/en
Priority to KR1020097007300A priority patent/KR101411898B1/ko
Priority to US12/446,299 priority patent/US8197710B2/en
Publication of WO2008081631A1 publication Critical patent/WO2008081631A1/ja

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/32Non-steroidal liquid crystal compounds containing condensed ring systems, i.e. fused, bridged or spiro ring systems
    • C09K19/322Compounds containing a naphthalene ring or a completely or partially hydrogenated naphthalene ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/94Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of polycyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/20Esters of polyhydric alcohols or polyhydric phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F232/08Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/38Polymers
    • C09K19/3833Polymers with mesogenic groups in the side chain
    • C09K19/3842Polyvinyl derivatives
    • C09K19/3852Poly(meth)acrylate derivatives
    • C09K19/3861Poly(meth)acrylate derivatives containing condensed ring systems
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K2019/0444Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
    • C09K2019/0448Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • G02B5/3041Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
    • G02B5/305Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3083Birefringent or phase retarding elements
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F2202/00Materials and properties
    • G02F2202/02Materials and properties organic material
    • G02F2202/022Materials and properties organic material polymeric
    • G02F2202/023Materials and properties organic material polymeric curable

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Nonlinear Science (AREA)
  • Mathematical Physics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polarising Elements (AREA)

Abstract

 下記一般式(1)で表される重合性化合物。 (式(1)中、Z1及びZ2は(メタ)アクリロイルオキシ基を表し、X1及びX2は、相互に独立して、単結合、炭素原子数1~8の分岐を有してもよいアルキレン基、エーテル結合、-COO-、-OCO-、-OCOO-、置換基を有してもよい6員環、又はこれらの組み合わせを表し、R1は、-R’、-OR’、-CO-R’又は-OCO-R’を表し、R’は、ハロゲン原子、炭素原子数1~8の分岐を有してもよいアルキル基又は置換基を有してもよい6員環を表し、L1及びL2は、相互に独立して、単結合、-CH2CH2-、-CH=CH-、-C≡C-、-CH2O-、-OCH2-、-COO-又は-OCO-の何れか一種を表し、mは1~4の整数を表し、複数あるR1は各々異なるものであってもよい。)
PCT/JP2007/069701 2006-12-29 2007-10-09 重合性化合物及び重合性組成物 WO2008081631A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2007800388231A CN101528786B (zh) 2006-12-29 2007-10-09 聚合性化合物和聚合性组合物
EP07829439.4A EP2067796B1 (en) 2006-12-29 2007-10-09 Polymerizable compound and polymerizable composition
KR1020097007300A KR101411898B1 (ko) 2006-12-29 2007-10-09 중합성 화합물 및 중합성 조성물
US12/446,299 US8197710B2 (en) 2006-12-29 2007-10-09 Polymerizable compound and polymerizable composition

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2006-356840 2006-12-29
JP2006356840 2006-12-29
JP2007001727A JP5408841B2 (ja) 2006-12-29 2007-01-09 重合性化合物及び重合性組成物
JP2007-001727 2007-01-09

Publications (1)

Publication Number Publication Date
WO2008081631A1 true WO2008081631A1 (ja) 2008-07-10

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PCT/JP2007/069701 WO2008081631A1 (ja) 2006-12-29 2007-10-09 重合性化合物及び重合性組成物

Country Status (7)

Country Link
US (1) US8197710B2 (ja)
EP (1) EP2067796B1 (ja)
JP (1) JP5408841B2 (ja)
KR (1) KR101411898B1 (ja)
CN (1) CN101528786B (ja)
TW (1) TWI419872B (ja)
WO (1) WO2008081631A1 (ja)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009104468A1 (ja) * 2008-02-22 2009-08-27 株式会社Adeka 重合性化合物を含有する液晶組成物及び該液晶組成物を用いた液晶表示素子
JP2010159324A (ja) * 2009-01-06 2010-07-22 Adeka Corp 重合性液晶化合物を含有する重合性液晶組成物及び該重合性液晶組成物の重合物を含有する光学異方性膜
WO2010116565A1 (ja) * 2009-04-08 2010-10-14 シャープ株式会社 液晶表示装置、液晶表示装置の製造方法、光重合体膜形成用組成物、及び、液晶層形成用組成物
JP2015522085A (ja) * 2012-06-28 2015-08-03 エルジー・ケム・リミテッド 重合性液晶化合物、これを含む液晶組成物及び光学異方体
CN114901628A (zh) * 2019-12-26 2022-08-12 大阪燃气化学有限公司 芴衍生物、其制备方法及其应用

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US8557142B2 (en) 2009-09-25 2013-10-15 Merck Patent Gmbh Compounds for a liquid crystal medium and high-frequency components containing said liquid crystal medium
JP5623547B2 (ja) * 2009-12-17 2014-11-12 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 液晶混合物
JP5708972B2 (ja) * 2010-03-31 2015-04-30 Dic株式会社 重合性液晶組成物、及び、それを用いたコレステリック反射フィルム、反射型偏光板
WO2011132137A1 (en) * 2010-04-20 2011-10-27 Basf Se Polymerized films with line texture or fingerprint texture
US9222024B2 (en) 2010-04-20 2015-12-29 Basf Se Polymerized films with line texture or fingerprint texture
DE102011015546A1 (de) * 2010-04-26 2012-01-26 Merck Patent Gmbh Polymerisierbare Verbindungen und ihre Verwendung in Flüssigkristallmedien und Flüssigkristallanzeigen
TWI622598B (zh) * 2011-03-29 2018-05-01 Dainippon Ink & Chemicals 聚合性化合物、聚合性組成物及光學各向異性體
JP6206413B2 (ja) * 2012-10-19 2017-10-04 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
KR102114521B1 (ko) * 2013-03-12 2020-05-22 닛산 가가쿠 가부시키가이샤 광 반응성기를 갖는 가교성 화합물을 함유하는 액정 배향제
CN103242863B (zh) * 2013-04-19 2015-07-29 北京京东方光电科技有限公司 液晶复合材料、显示面板、显示装置及显示面板制造方法
WO2014189040A1 (ja) * 2013-05-21 2014-11-27 富士フイルム株式会社 偏光板およびその製造方法ならびに転写材料
CN105527758B (zh) * 2016-02-22 2018-06-15 京东方科技集团股份有限公司 一种配向组合物、配向膜及其配向方法、显示面板
KR102285438B1 (ko) * 2018-11-27 2021-08-02 주식회사 엘지화학 아크릴산 에스테르 화합물 제조 방법
CN113620805B (zh) * 2021-07-23 2024-05-24 江苏创拓新材料有限公司 可聚合化合物、组合物及光学各向异性体

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Title
See also references of EP2067796A4 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009104468A1 (ja) * 2008-02-22 2009-08-27 株式会社Adeka 重合性化合物を含有する液晶組成物及び該液晶組成物を用いた液晶表示素子
US8283000B2 (en) 2008-02-22 2012-10-09 Adeka Corporation Liquid crystal composition containing polymerizable compound and liquid crystal display using the liquid crystal composition
JP2010159324A (ja) * 2009-01-06 2010-07-22 Adeka Corp 重合性液晶化合物を含有する重合性液晶組成物及び該重合性液晶組成物の重合物を含有する光学異方性膜
WO2010116565A1 (ja) * 2009-04-08 2010-10-14 シャープ株式会社 液晶表示装置、液晶表示装置の製造方法、光重合体膜形成用組成物、及び、液晶層形成用組成物
CN102378937A (zh) * 2009-04-08 2012-03-14 夏普株式会社 液晶显示装置、液晶显示装置的制造方法、光聚合物膜形成用组合物和液晶层形成用组合物
JPWO2010116565A1 (ja) * 2009-04-08 2012-10-18 シャープ株式会社 液晶表示装置、液晶表示装置の製造方法、光重合体膜形成用組成物、及び、液晶層形成用組成物
CN102378937B (zh) * 2009-04-08 2014-08-20 夏普株式会社 液晶显示装置、液晶显示装置的制造方法、光聚合物膜形成用组合物和液晶层形成用组合物
US8860913B2 (en) 2009-04-08 2014-10-14 Sharp Kabushiki Kaisha Liquid crystal display device, method for manufacturing liquid crystal display device, composition for forming photopolymer film, and composition for forming liquid crystal layer
JP2015522085A (ja) * 2012-06-28 2015-08-03 エルジー・ケム・リミテッド 重合性液晶化合物、これを含む液晶組成物及び光学異方体
CN114901628A (zh) * 2019-12-26 2022-08-12 大阪燃气化学有限公司 芴衍生物、其制备方法及其应用

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TWI419872B (zh) 2013-12-21
KR101411898B1 (ko) 2014-06-26
TW200831459A (en) 2008-08-01
CN101528786B (zh) 2011-08-17
EP2067796A1 (en) 2009-06-10
EP2067796B1 (en) 2013-05-29
JP2008179654A (ja) 2008-08-07
EP2067796A4 (en) 2010-04-14
KR20090100333A (ko) 2009-09-23
CN101528786A (zh) 2009-09-09
JP5408841B2 (ja) 2014-02-05
US8197710B2 (en) 2012-06-12

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